This document provides guidelines for establishing UNESCO Green Academies across Africa and globally. It begins with background on population growth, natural resource and waste management issues in Africa. It then discusses the history and rationale behind UNESCO Green Academies. The functioning of Biosphere Reserves is also explained. The core of the guidelines focus on the five pillars of UNESCO Green Academies: rainwater utilization, wastewater recycling, production of clean energy, production of biomass, and establishing youth clubs. Case studies of existing green schools and academies are also presented. The document concludes with recommendations for recognizing UNESCO Green Academies.