This document provides safety information for a fertilizer product called Rooter. It contains the following key details: - Rooter is an EC fertilizer solution containing phosphoric acid as the main hazardous component. - It can cause severe skin and eye damage upon contact. Proper protective equipment should be worn when handling. - In the event of accidental skin or eye exposure, immediate first aid measures such as rinsing with water are recommended. - The product should be stored in its original labeled container away from food and animal feed at temperatures above -10°C.

1. Name : Rooter page 1/5
S A F E T Y D A T A S H E E T
Version: 2.0 Date of update: 24/06/15 Supersedes: 1.0
NAME OF THE PRODUCT Rooter
Standard denomination EC FERTILIZER - PK solution
Identified uses Agriculture - Fertilizer, for foliar spraying.
Laboratoires GOËMAR S.A.S
Parc Technopolitain Atalante - CS 41908
35435 SAINT MALO - FRANCE
Phone : +33.(0)2.99.19.19.19
Fax. : +33.(0)1.41.30.99.63
ORFILA France (INRS) ANTI-POISON CENTER (Angers)
+33 (0)1.45.42.59.59 (24H/24, 7j/7) +33 (0)2.41.48.21.21 (24H/24, 7j/7)
SECTION 2 - HAZARDS IDENTIFICATION
Classification according to the Regulation (EC) 1272/2008
Skin corr. 1B H314
Eye dam. 1 H318
Met. Corr. 1 H290
Classification according to Directive 1999/45/EC
Xi R38 R41
Labelling according to Regulation (EC) 1272/2008
Hazards Pictograms
Signal word Danger
Hazard statements H314: Causes severe skin burn and eye damage
H318: Causes seriuos eye damage
H290: May be corrosive to metals
Precautionary statements P264: Wash hand thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353: IF ON SKIN : Remove/Take off immediately all contaminated clothing.
Rinse skin with water/shower
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P234: Keep only in original container.
P406: Store in corrosive resistant/container with a resistant inner liner.
No data/information available
SECTION 3 - COMPOSITION / INFORMATION ON INGREDIENTS
For the full text of Risk phrases R and Hazard Statements H: see SECTION 16
denomination / CAS n° / EC n° %w/w classification
Components involved
in the hazards phosphoric acid >10% Directive n° 1999/45/CE
7664-38-2 / 015-011-00-6 C, R34
Reglement n°1272/2008
Skin corr. 1B H314
Components presenting
a hazard None
Material Safety Data Sheet n°1001/std
2.3 Other hazards
3.2 Mixture
SECTION 1 - IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1 Product identifier
1.2 Relevant identified uses of the substance or mixture and uses advised against
1.3 Details of the supplier of the safety data sheet
fds@goemar.com
www.goemar.com
1.4 Emergency telephone number
2.1 Classification of the substance or mixture
2.2 Label elements

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SECTION 4 - FIRST AID MEASURES
IN CASE OF :
Eye contact Flush immediately with plenty of water for 15 mn.
In case of persistent irritation, ask the advice of an ophthalmologist .
Skin contact Take off dirty clothes.
Rinse immediately and thoroughly with clean water during 15min.
Ingestion Wash out mouth with water.
Depending on the amount ingested seek medical advice, and show this SDS,
or for lack, the label.
Inhalation Not specifically concerned (aqueous liquid).
Remove from the contaminated area and bring to fresh air.
According to the pathway: tingling, redness, irritation, nausea, vomiting, diarrhoea.
No data/information available
SECTION 5 - FIREFIGHTING MEASURES
Suitable extinguishing media All extinguishing agents usable (water, foam, powders, CO2, …)
Unsuitable extinguishing media None
Specific hazards No data/information available
By thermal decomposition, product may emit oxides of...
Do not enter or remain in the danger zone without chemical protection clothing or autonomous
breathing equipment.
Wearing autonomous, insulating breathing equipment is recommended when entering the danger
zone. Avoid pouring fire water down the drains.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Personnel precaution Avoid contact with the skin and eyes.
Individual protection: see SECTION 8
Environmental precautions Limit and impound discharge.
Prevent entry into drains, waters or soil.
Clean up methods Do not water down. Collect with a neutral absorbent material and sweep it .
Do not reintroduce into original container ; treat as a waste.
Refer to sections 8 and 13
SECTION 7 - HANDLING AND STORAGE
HANDLING For personal protective equipments, see section 8 for details.
Avoid accidental dispersion and spatter.
STORAGE
Technical measures Recommended limit height of stacking : 2 pallets
Conditions of storage Store out of frost (-10°C) and if possible in a cool place.
Store away from food, drink and animal feedingstuffs.
Packaging Keep the product into original container labelled and closed.
No date/information available
Material Safety Data Sheet n°1001/std
7.1 Precautions for safe handling
7.2 Condition for safe storage, including any incompatibilities
7.3 Specific end use(s)
6.4 Reference to other sections
4.1 Description of first aid measures
4.2 Most important symptoms and effetcs, both acute and delayed
4.3 Indication of any immediate medical attention and special treatment needed
5.1 Extinguishing media
5.2 Sepcial hazards aristing from the substance or mixture
5.3 Advice for firefighters
6.1 Personal precautions, protective equipment and emergency procedures
6.2 Environmental precautions
6.3 Methods and material for containment and cleaning up

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SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
Technical measures Work in the open air.
Exposure limit values No study has been carried out for the moment on this mixture.
Data substance: phosphoric acid (France) : VLE = 3mg/m 3
; VME = 1mg/m 3
8.2 Exposure controls
Monitoring procedures Medical examination yearly.
PPE : Personal
Protection Equipments Respect general rules for handling of chemical products :
Respiratory protection Mask recommended while spraying the mixture. Anti-aerosol mask with filter type P1
Hand protection Protective gloves, such as latex, PVC, rubber. (according to standard EN 374)
Eye protection Safety goggles (according to standard EN 166)
Skin and body protection Protective clothing, such as overall.
Hygiene measures Wash hands with water after handling the product.
Do not eat or drink during the handling.
Environmental protection Rinse the containers with water and pour rinsing water into spraying tank.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basi physical and chemical properties
Appearance : physical state, colour Liquid, green
Odour Slight odour, not qualified
Odour threshold Not determined
pH 1,60-2,10 (pure product)
Melting point/freezing point Not determined
Initial boiling point and boiling range Not determined
Flash point Not applicable (aqueous solution)
Evaporation rate Not determined
Flammability (solide, gaz) Not applicable (aqueous solution, no flammable component)
Upper/lower flammability or explosive limits Non applicable
Vapour pressure Not determined
Vapour density Not determined
Relative density 1,151-1,166
Solubility(ies) Totally soluble in water in all proportions
Partition coefficient: n-octanol/water Not determined
Auto-ignition temperature Not determined
Decomposition temperature Not determined
Viscosity Not determined
Explosive properties Not applicable (aqueous solution, no explosive component)
Oxidising properties Not applicable (aqueous solution, no oxidizing component)
9.2 Other information
No additional information
SECTION 10 - STABILITY AND REACTIVITY
10.1 Reactivity
No data/information available (no specific risk expected)
10.2 Chemical stability
Stability The product is stable in normal conditions of use.
Product colour changes with time, without effect on its properties.
10.3 Possibility of hazardous reactions
No data/information available (no specific risk expected)
10.4 Conditions to avoid
Store at temperature above 40°C and below -10°C (cf SECTION 7)
10.5 Incompatible materials
Materials to avoid Avoid storage of the product into metallic containers.
10.6 Hazardous decomposition products
In the event of fire: see section 5
Material Safety Data Sheet n°1001/std
8.1 Control parameters

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SECTION 11 - TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
No tests carried out directly on the mixture. The classification was made with the existing data on the substances in this mixture (conventional
method)
Acute toxicity Not classified (conventional method)
Data substance: phosphoric acid: acute oral tox. (rat) LD50 = 3500mg/kg
acute dermal tox. (rat) LD50 = 1260 mg/kg
Irritation
Corrosivity
Sensitisation No information available on this mixture (do not contain substance concerned)
Repeated dose toxicity No information available on this mixture (do not contain substance concerned)
Carcinogenicity No information available on this mixture (do not contain carcinogenic substance)
Mutagenicity No information available on this mixture (do not contain mutagenic substance)
Toxicity for reproduction No information available on this mixture (do not contain substance toxic for reproduction)
SECTION 12 - ECOLOGICAL INFORMATION
12.1 Toxicity
No study has been carried out for the moment on this mixture.
Data substance: phosphoric acid: CL50-96H (Gambusia affinis) = 138 mg/L ;
EC50-48H (Daphnia magna) > 100mg/L
12.2 Persistence and degradability
No adverse effect expected on sewage plant working all components are degradable,
or biodegradable, or assimilable
12.3 Bioaccumulative potential
No data/information available
12.4 Mobility in soil
Mixture components are completely soluble in water
12.5 Results of PBT and vPvB assessment
No study has been carried out for the moment on the mixture.
12.6 Other adverse effects
No data/information available
SECTION 13 - DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods
Residues waste Do not empty into drains.
Destruction / disposal Dispose of in authorised waste collection plant.
Contaminated packaging
Decontamination / cleaning Rinse with water and pour into the spraying tank.
Destruction / disposal Dispose of rinsed plastic packagings and cardboard in an authorised
plant (incineration or recycling).
SECTION 14 - TRANSPORT INFORMATION
In accordance with the requirements ADR/RID/ and ADN (by road), IMDG (by sea), OACI/IATA (by air)
14.1 UN number
UN 1805
14.2 UN proper shipping name
Phosphoric acid solution
14.3 Transport hazard class(es)
Classe 8
14.4 Packing group
III
Others informations: ADR/RID/ADN: Hazard code: 80 ; Transport Code: C1 ; Tunnel Restriction Code: (E) ;
Limited quantity LQ: 5L
IMDG: Savety sheet code: F-A, S-B, Limited quantity LQ: 5L
OACI-IT/IATA DGR: limited quantity: Y841, 1L; passenger aircraft: IE852, 5L;
cargo aircraft: IE856, 60L
14.5 Environmental hazards Not regulated
14.6 Special precautions for user May be corrosive to metals
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not concerned
SECTION 15 - REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.2 Chemical safety assessment
No chemical Safety Assessment has been carried out for the mixture. No exposure scenarios
available on the mixture. No exposure scenarios available for the moment on the substance
(data suppliers)
Material Safety Data Sheet n°1001/std
Mains components of this preparation are repeated in the European EINECS substances inventory
Not classified (conventional method)
Classified corrosif to skin

5. Name : Rooter page 5/5
SECTION 16 - OTHER INFORMATION
The content and format of this safety data sheet is in according with the Regulation EC 1907/2006 and Regulation EC 453/2010
Revision details: Classification CLP
List of Risk phrases R mentioned section 2
R38: Irriting to skin
R41: Risk of serious damage to eyes
S26 : in case of contact with eyes,rinse immediately with plenty of water and seek medical advice
S37 : wear suitable gloves
S39: Wear eye/face protection
List of Risk phrases R and Hazard Statements H mentioned section 3
C: Corrosive
R34 : cause burns
H290: May be corrosive metal
H314: Causes severe skin burns and eye damage
N .B. : The information written here above are based on our relative knowledge of the concerned product,
at the time of writting this safety data sheet. They are honestly written.
A list of the main regulation, legislation and administrative texts can be joined
to this sheet as indication. The use of the product for other purposes than those indicated on the label
Material Safety Data Sheet n°1001/std