Chapter 2 of 'C++ Programming with Design Patterns Revealed' by Tomasz Müldner introduces fundamental C++ concepts, contrasting them with Java, including data types, control structures, dynamic memory management, and I/O operations. It discusses critical aspects such as functions, type conversions, parameters, and pointers, emphasizing the differences in memory management and function handling between C++ and Java. Additionally, it covers best practices for variable declarations, comments, and the use of references and arrays in C++.