The Pick.Click.Give. program, initiated by the Alaska state legislature in 2008, allows residents to donate a portion of their Permanent Fund Dividend (PFD) to various charitable organizations. Participants can contribute during the PFD filing period from January 1 to March 31, with donations being reported and checks sent to organizations by mid-October. The program aims to enhance charitable giving in Alaska, and offers resources for nonprofits to promote their participation.