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BIODIESEL &
Presented by Olivia Wilson
• Biomass consists of all forms of animal and plant organic matters:
wood/dead plants, animal remains, leaves, living plants, vegetable oils,
wastes from agricultural, residential and industrial sources and so on
and can be used as a renewable and sustainable source of energy.
• Biomass’s chemical composition includes gases like hydrogen, carbon,
nitrogen, oxygen, certain alkali atoms, alkaline earth metals and heavy
metals.
• Biomass is different from fossil fuels, though both are formed from
the same organic matter i.e. plant and animal remains. Scientists
believe that fossil fuels come from matter that has undergone
numerous changes over several millions of years , whereas biomass
originates from recently dead or living plant and animals called biomass
feedstocks.
• Biomass can be converted into different forms of energy like solid
biomass , biogas, biofuels, bio charcoal ,synthetic fuels, bio oils and
many other forms through various processes, such as burning,
fermentation, and anaerobic digestion. This can be used for heating,
electricity generation, or as a fuel for vehicles.
WHAT IS BIOMASS?
There can be various aspects to understand, how conversion of biomass to
biofuels like biodiesel, ethanol can be beneficial over the conversion of biomass
to other sources of energy and use of fossil fuels.
1.Renewable Energy: Biofuels are considered renewable energy sources because
they are derived from organic materials that can be replenished over time,
unlike fossil fuels, which also are a large source of air pollution. This makes them
a more sustainable option for meeting energy needs.
2.Reduced Greenhouse Gas Emissions: Biofuels emit fewer greenhouse gases
(GHGs) compared to fossil fuels when burned for energy. This is because the
carbon in biofuels is derived from recently living plants, which absorbed carbon
dioxide (CO2) from the atmosphere during their growth. In contrast, fossil fuels
release carbon that has been sequestered underground for millions of years,
adding to the net amount of CO2 in the atmosphere.
3.Energy Density: Biofuels generally have higher energy density than biogas,
which means they contain more energy per unit of volume or weight. This can
make biofuels more suitable for applications that require higher energy content,
such as transportation fuels.
Why do we convert Biomass to Biofuels ? (I)
4.Flexibility: Biofuels can be used in a wide range of applications, including
transportation, heating, and electricity generation. This flexibility allows them
to replace fossil fuels in various sectors, reducing greenhouse gas emissions
and dependence on imported oil.
5.Infrastructure: In some cases, biofuels can be used in existing infrastructure
with minimal modifications. For example, ethanol can be blended with
gasoline and used in conventional gasoline engines, and biodiesel can be used
in existing diesel engines.
6)Energy Security: Biofuels can be produced domestically, reducing
dependence on imported fossil fuels and enhancing energy security.
7)Economic Benefits: Biofuel production can create jobs and stimulate
economic growth in rural areas where biomass feedstocks are abundant.
Why do we convert Biomass to Biofuels ? (II)
However, it's important to note that biofuels also have their limitations and challenges. For example, the production of
biofuels can compete with food production, leading to potential conflicts over land use. Additionally, some biofuel production
methods may have negative environmental impacts, such as increased water use or habitat destruction.
Ultimately, the choice between converting biomass to biofuels or other forms of energy depends on factors such as the type
of biomass available, the desired end use, and the environmental and economic considerations of each option.
HOW IS BIOMASS CONVERTED INTO BIOFUELS
Biomass is the only renewable energy source that can be converted into liquid biofuels such
as ethanol and biodiesel. Biofuel is used to power vehicles, and is being produced by gasification in
countries such as Sweden, Austria, and the United States.
Ethanol is made by fermenting biomass that is high in carbohydrates, such as sugarcane, wheat, or
corn. Biodiesel is made from combining ethanol with animal fat, recycled cooking fat, or vegetable oil.
Biofuels do not operate as efficiently as gasoline. However, they can be blended with gasoline to
efficiently power vehicles and machinery, and do not release the emissions associated with fossil
fuels.
For biodiesel production, the most common method is transesterification, which involves reacting
vegetable oils or animal fats with an alcohol, such as methanol or ethanol, in the presence of a
catalyst, typically sodium or potassium hydroxide. Ethanol, on the other hand, is primarily produced
through fermentation of sugars in biomass feedstocks, such as sugarcane, corn, or cellulosic
materials.
Advantages of Biofuels
1.Energy Storage: Biofuels can be stored relatively easily and used when needed, unlike solar and wind
energy, which are intermittent and depend on weather conditions. This makes biofuels a more reliable
option for meeting energy demands.
2.Flexibility: Biofuels can be used in existing infrastructure with minimal modifications. For example, ethanol
can be blended with gasoline and used in conventional gasoline engines, and biodiesel can be used in existing
diesel engines. This makes biofuels a more flexible option for reducing greenhouse gas emissions from
transportation.
3.Potential for Advanced Biofuels: Research is ongoing to develop advanced biofuels that can be produced
from non-food biomass sources, such as agricultural residues, algae, and dedicated energy crops. These
advanced biofuels have the potential to offer even greater environmental and economic benefits than
traditional biofuels.
4.Reduced Greenhouse Gas Emissions: Biofuels emit fewer greenhouse gases (GHGs) compared to fossil fuels
when burned for energy. This is because the carbon in biofuels is derived from recently living plants, which
absorbed carbon dioxide (CO2) from the atmosphere during their growth. In contrast, fossil fuels release
carbon that has been sequestered underground for millions of years, adding to the net amount of CO2 in the
atmosphere.
Various Generations of Biofuels
•First Generation Biofuels:
• These are made from food sources such as sugar, starch, vegetable oil, or animal fats using
conventional technology.
• Common first-generation biofuels include Bio alcohols, Biodiesel, Vegetable oil, Bio ethers,
Biogas.
• Though the process of conversion is easy but use of food sources in the production of biofuels
creates an imbalance in the food economy, leading to increased food prices and hunger.
•Second Generation Biofuels:
• These are produced from non-food crops or portions of food crops that are not edible and
considered as wastes, e.g., stems, husks, wood chips, and fruit skins and peeling.
• Examples include cellulose ethanol, biodiesel.
• Thermochemical reactions or biochemical conversion processes are used for producing such
fuels.
• Though these fuels do not affect food economy, their production is quite complicated.
• Also, it is reported that these biofuels emit less greenhouse gases when compared to first
generation biofuels.
Various Generations of Biofuels
•Third Generation Biofuels:
• These are produced from micro-organisms like algae.
• Example- Butanol
• Micro-organisms like algae can be grown using land and water unsuitable for food production,
therefore reducing the strain on already depleted water sources.
• One disadvantage is that fertilizers used in the production of such crops lead to environmental
pollution.
•Fourth Generation Biofuels:
• In the production of these fuels, crops that are genetically engineered to take in high amounts of
carbon are grown and harvested as biomass.
• The crops are then converted into fuel using second generation techniques.
• The fuel is pre-combusted, and the carbon is captured. Then the carbon is geo-sequestered,
meaning that the carbon is stored in depleted oil or gas fields or in unmineable coal seams.
• Some of these fuels are considered carbon negative as their production pulls out carbon from
the environment.
Types of Biofuels
•Any hydrocarbon fuel that is produced from an organic matter (living or once living material) in a short
period of time (days, weeks, or even months) is considered a biofuel.
•Biofuels may be solid, liquid or gaseous in nature.
• Solid: Wood, dried plant material, and manure
• Liquid: Bioethanol and Biodiesel
• Gaseous: Biogas
Biodiesel as a Biofuel
Biodiesel is a renewable, biodegradable fuel manufactured domestically from vegetable oils, animal fats, or recycled restaurant grease.
Biodiesel is a liquid fuel often referred to as B100, pure, or neat biodiesel in its unblended form. Like petroleum diesel, biodiesel is used
to fuel compression-ignition engines.
It is typically made through a process called transesterification, where the oil or fat is combined with an alcohol (usually methanol or
ethanol) and a catalyst (like sodium hydroxide) to create biodiesel and glycerin as a byproduct. Biodiesel can be used in conventional
diesel engines without any modifications, which makes it a convenient substitute for petroleum diesel. Moreover, it produces fewer
greenhouse gas emissions compared to fossil fuels, contributing to a cleaner environment. Additionally, biodiesel can be produced from
a variety of feedstocks, including soybeans, canola, palm oil, and even recycled cooking oil, allowing for versatility and a reduced
dependence on specific crops. As a renewable energy source, biodiesel plays a crucial role in reducing our carbon footprint and
mitigating climate change.
Early Beginnings
Biofuels have a long history, with early uses including ethanol for cars in the early 20thcentury, vegetable
oils and animal fats for lighting and heating, and biogas from organic materials for cooking. These biofuels
were integral to energy needs before widespread fossil fuel us.
Ancient civilizations relied on biomass, like wood, animal dung, and agricultural residues, for heating and
cooking.
• Biogas, a mixture of methane and other gases, has been used for heating and cooking in some societies
for centuries.
• Before the widespread use of petroleum-based fuels, vegetable oils were commonly used for lighting
and heating.
• Rendered animal fats were also used historically as a fuel source, particularly for lighting lamps
Industrial Revolution
During the Industrial Revolution, the demand for energy
skyrocketed due to advancements in manufacturing,
transportation etc.
• Traditional biomass fuels like wood and animal power
proved inadequate to meet the escalating energy
demands. Consequently, there was a significant shift
towards biofuels such as coal, which became
indispensable for powering steam engines and industrial
processes.
• The quest for more efficient energy sources during the
Industrial Revolution fueled technological advancements
in biofuel production and utilization. Innovations in
machinery, processing methods, and transportation
systems played a pivotal role in enhancing the efficiency
and accessibility of biofuels to meet the growing energy
demands of industrialized societies.
Rise in Biofuels
The rise in biofuels emerged in response to growing environmental concerns and the need for enhanced
energy security.
• With increasing awareness of climate change and pollution from fossil fuels, biofuels gained attention
as a renewable alternative.
• Additionally, reliance on imported oil prompted governments to seek domestic biofuel production,
reducing dependency on foreign energy sources and enhancing national security.
History of Biodiesel
• Developed in the 1890s by inventor Rudolph Diesel, the diesel engine has become the engine of choice
for power, reliability, and high fuel economy, worldwide.
• Early experimenters on vegetable oil fuels included the French government and Dr. Diesel himself, who
envisioned that pure vegetable oils could power early diesel engines for agriculture in remote areas of
the world, where petroleum was not available at the time.
History of Biodiesel
• Modern biodiesel fuel, which is made by converting vegetable oils into
compounds called fatty acid methyl esters, has its roots in research
conducted in the 1930s in Belgium
• The diesel engine was developed out of a desire to improve upon
inefficient, cumbersome and sometimes dangerous steam engines of
the late 1800s.
• The diesel engine works on the principal of compression ignition, in
which fuel is injected into the engine’s cylinder after air has been
compressed to a high pressure and temperature.
• As the fuel enters the cylinder it self-ignites and burns rapidly,
forcing the piston back down and converting the chemical energy in
the fuel into mechanical energy.
• Dr. Rudolph Diesel, for which the engine is named, holds the first
patent for the compression ignition engine, issued in 1893. Diesel
became known worldwide for his innovative engine which could use a
variety of fuels.
Development and Evolution
• Biodiesel evolved from early experiments with vegetable oils to a globally recognized renewable fuel.
• Key milestones include its use in diesel engines by Rudolf Diesel, the surge in interest during the 1970s oil
crisis, and the refinement of production processes in the 1990s.
• Today, biodiesel faces challenges such as feedstock availability and sustainability concerns, but ongoing
research and policy support aim to secure its place as a cleaner alternative to traditional diesel fuel.
• Engine modifications and blending techniques improved performance and compatibility with existing
infrastructure.
• Government mandates and incentives further spurred its adoption, fostering a growing market.
India’s National Policy on Biofuels
The National Policy on Biofuels was created by the
Ministry of New and Renewable Energy in 2009. This
was because India’s domestic energy needs largely
depended on imported crude oil. In 2018, the policy
was revised by the Ministry of Petroleum and Natural
Gas and was published as National Policy on Biofuels.
The policy aims to reduce petroleum imports by
promoting domestic fuel production. In June 2022,
the Central Government revised its target of 20%
ethanol blending in petrol by the year 2030 to the year
2025.
Main Objective of National Policy on Biofuels
Objectives of National Policy on Biofuels 2018
The National Policy on Biofuels 2018 aimed to achieve
a 20% blending of biofuels with fossil fuels by 2030.
This target was revised, and it will be completed by
2025.
The policy’s primary objective is to guarantee a
consistent and sufficient supply of domestic feedstock
for producing biofuels.
This would boost farmers’ income, reduce imports,
generate employment, and create opportunities for
waste-to-wealth initiatives.
The National Policy of Biofuels embodies the
government’s efforts to enhance the country’s energy
infrastructure.
Additionally, it helps to meet sustainable development
goals.
Pradhan Mantri Ji-Van Yojna
• The main aims of this scheme to provide financial support to Integrated Bioethanol Projects using
lignocellulosic biomass and other renewable feedstock or 2nd generation integrated bioethanol
projects.
• The current scheme envisages setting up of 12 Commercial scale Second Generation (2G) Bioethanol
projects and 10 demonstration scale 2G Bioethanol projects based on non-food biomass feedstocks
and other renewable feedstocks.
• To contribute to Swacch Bharat Mission by supporting the aggregation of non-food biofuel
feedstocks such as waste biomass and urban waste.
• Indigenisation of second generation biomass to ethanol technologies.
(GOBARdhan)
The Galvanizing Organic Bio-Agro Resources Dhan
(GOBARdhan) scheme is a government initiative that
aims to convert organic waste into valuable
resources. The scheme was launched in April 2018 by
the Department of Drinking Water and Sanitation as
part of the Swachh Bharat Mission.
The objective of the scheme is to support villages to
safely manage their cattle waste, agricultural waste
and eventually all organic waste. The scheme
promotes rural entrepreneurship, employment and
income-generation opportunities.
A total of 589 Biogas/CBG (Compressed Biogas) plants
are functional under the GOBAR-Dhan scheme.
Additionally, 251 are under construction. So far, 168
districts have been covered under the scheme.
RUCO (Repurposed Used Cooking Oil
• RUCO stands for Repurpose Used
Cooking Oil, an initiative by the Food
Safety and Standards Authority of
India (FSSAI). The initiative's goal is to
collect and convert used cooking oil
into bio-diesel.
• Under this initiative, 64 companies at
101 locations have been identified to
enable collection of used cooking oil.
For instance: McDonald’s has already
started converting used cooking oil to
biodiesel from 100 outlets in Mumbai
and Pune.
Environmentalists concerns over biofuels Product
• Following are some concerns regarding biofuels production.
• Deforestation -: Biofuels are often derived from crops like corn, sugarcane, or soybeans, which
require a lot of land for cultivation.
• Biodiversity loss -: Biofuel production can lead to deforestation and biodiversity loss due to
expansion of cropland.
• Water pollution ÷ Production of biofuel feed stocks, especially food crops like corn and soy, can
increase water pollution from nutrients, pesticides, and sediment.
• To prevent these we must need to increase our production of biofuels from waste that
generated by us only. Examples á production of biogas from cow dungs.
Global Actions on Biofuels Management
• The Global Biofuel Alliance launched at the
G20 Summit in India in September. It brings
together 19 countries and 12 international
organizations – including the World
Economic Forum, the World Bank and the
Asian Development Bank – to try to expand
the use of sustainable biofuels.
• World Biofuel Day is observed every year on
10th August to create awareness about the
importance of non-fossil fuels as an
alternative to conventional fossil fuels.
Introduction to Biodiesel Production
The awareness of energy issues and environmental problems associated with burning fossil fuels
has globally encouraged many researchers to investigate the possibility of using alternative
sources of energy instead of oil and its derivatives. Among them, biodiesel seems very
interesting for several reasons. Biodiesel is defined as mono-alkyl esters of long chain fatty acids
derived from vegetable oils or animal fats and alcohol with or without a catalyst resting for
several reasons.
Raw Materials for Production
The oils most used for worldwide biodiesel production are rapeseed (mainly in
the European Union countries), soybean (Argentina and the United States of
America), palm (Asian and Central American countries) and sunflower,
although other oils are also used, including peanut, linseed, safflower, used
vegetable oils, and also animal fats. Methanol is the most frequently used
alcohol although ethanol can also be used. Since cost is the main concern in
biodiesel production and trading (mainly due to oil prices), the use of non-
edible vegetable oils has been studied for several years with good results.
The raw materials for
biodiesel production are
• Vegetable oils
• animal fats and short
chain alcohols.
Characteristics of Oils & Fats used
• The US Department of Energy indicates that a perfect biodiesel should only
comprise mono-unsaturated fatty acids.
• Vegetable oils may also contain small percentages of monoglycerides and
diglycerides.
• In addition, there will also be small amounts of free fatty acids (in most
vegetable oils, less than 1%, except for palm oil, where they can reach up to
15%).
• The composition of vegetable oils influences their properties . For instance,
the pour point and cloud point temperatures, cetane number and the iodine
index depend on the number of unsaturation's and the length of the fatty
acid chains. A higher content of double covalent bonds gives a lower
solidification point and a higher iodine index.
Characteristics of Alcohols used
• Alcohols that can be used in biodiesel production are those with short chains,
including methanol, ethanol, butanol, and amylic alcohol. The most widely used
alcohols are methanol (CH3OH) and ethanol (C2H5OH) because of their low cost
and properties. Methanol is often preferred to ethanol in spite of its high toxicity
because its use in biodiesel production requires simpler technology; excess
alcohol may be recovered at a low cost and higher reaction speeds are reached.
• It must be remembered that in order for biodiesel to be a fully renewable fuel, it
should be obtained from vegetable oils and animal fats, together with an alcohol
that is produced from biomass such as bioethanol, instead of being a
petrochemical product. Several countries are carrying out research towards this
objective, such as Spain and Brazil.
• Most important alcohols are Methanol and Ethanol.
• Methanol- Most widely used, in spite of its toxicity. It is a substance of
petrochemical origin.
• Ethanol - Less used, requires more complex production technology and the
reaction speeds are lower. It can be produced from biomass.
Biodiesel Production Process
• Biodiesel is produced from vegetable oils or animal fats and an alcohol, through a transesterification
reaction .
• This chemical reaction converts an ester (vegetable oil or animal fat) into a mixture of esters of the fatty
acids that makes up the oil (or fat).
• Biodiesel is obtained from the purification of the mixture of fatty acid methyl esters (FAME).
• A catalyst is used to accelerate the reaction .
• According to the catalyst used, transesterification can be basic, acidic or enzymatic, the former being
the most frequently used.
Transesterification Reactions for Biodiesel Production
Basic. Most frequently used at all production scales.
Acid. Less frequent in industrial production, sometimes used a first stage with highly acidic raw materials.
Enzymatic. Less used; the enzymes are usually lipases.
Stages of Biodiesel Production
1. Treatment Of Raw Materials
The content of free fatty acids, water and non - saponificable substances are key
parameters to achieve high conversion efficient
The use of basic catalysts in triglycerides with high content of free fatty acids is not advisable , since part
of the latter reacts with the catalyst to form soaps. In consequence, part of the catalyst is spent, and it is no
longer available for transesterification. In summary the efficiency of the reaction diminishes with the
increase of the acidity of the oil; basic transesterification is viable if the content of free fatty acids (FFAs) is
less than 2%.
In the case of highly acidic raw materials (animal fats from cattle, poultry, pork; vegetable oils from cotton,
coconut, most used oils, etc.) an acid transesterification is necessary as a preliminary stage, to reduce the
level of FFAs to the above-mentioned value.
Besides having low humidity and acid content, it is important that the oil presents a low level of non-
saponificable substances. If the latter were to be present in significant amounts and soluble in biodiesel, it
would reduce the level of esters in the product, making it difficult to comply with the minimum ester
content required by the standards.
Stages of Biodiesel Production
2. Alcohol Catalyst Mixing
• The alcohol used for biodiesel production must be mixed with the catalyst before adding the oil. The
mixture is stirred until the catalyst is completely dissolved in the alcohol. It must be noted that the
alcohol must be water-free (anhydrous) for the reasons explained in the previous paragraph.
• Sodium and potassium hydroxides are among the most widely used basic catalysts. For production on
an industrial scale, sodium or potassium methoxides or methylate's are commercially available.
• Of course, due caution must be exercised, and all applicable safety regulations must be followed, when
working with methanol, hydroxides and methoxides, independently of the production scale.
3. Chemical Reaction
The chemical reaction takes place when the oil is mixed with the alkoxide (alcohol–catalyst mix)
This requires certain conditions of time, temperature and stirring. Since alcohols and oils do not mix at
room temperature, the chemical reaction is usually carried out at a higher temperature and under
continuous stirring, to increase the mass transfer between the phases.
Stages of Biodiesel Production
4. Separation of the reaction products
• The separation of reaction products takes place by decantation: the mixture of fatty acids methyl esters
(FAME) separates from glycerin forming two phases, since they have different densities; the two phases
begin to form immediately after the stirring of the mixture is stopped. Due to their different chemical
affinities, most of the catalyst and excess alcohol will concentrate in the lower phase (glycerin), while
most of the mono-, di-, and triglycerides will concentrate in the upper phase (FAME). Once the
interphase is clearly and completely defined, the two phases may be physically separated. It must be
noted that if decantation takes place due to the action of gravity alone, it will take several hours to
complete. This constitutes a ‘‘bottleneck’’ in the production process, and in consequence the exit stream
from the transesterification reactor is split into several containers. Centrifugation is a faster, albeit more
expensive alternative.
• After the separation of glycerin, the FAME mixture contains impurities such as remnants of alcohol,
catalyst and mono-, di-, and triglycerides. These impurities confer undesirable characteristics to FAME,
for instance, increased cloud point and pour point, lower flash point, etc. In consequence a purification
process is necessary for the final product to comply with standards. This will be discussed in the next
section.
Stages of Biodiesel Production
5. Purification of the Reaction Products
• The mixture of fatty acids methyl esters (FAME) obtained from the transesterification reaction must be
purified in order to comply with established quality standards for biodiesel. Therefore, FAME must be
washed, neutralized and dried.
• Successive washing steps with water remove the remains of methanol, catalyst and glycerin, since these
contaminants are water-soluble. Care must be taken to avoid the formation of emulsions during the
washing steps, since they would reduce the efficiency of the process. The first washing step is carried
out with acidified water, to neutralize the mixture of esters. Then, two additional washing steps are
made with water only. Finally the traces of water must be eliminated by a drying step. After drying, the
purified product is ready for characterization as biodiesel according to international standards.
• An alternative to the purification process described above is the use of ion exchange resins or silicates.
Glycerin as obtained from the chemical reaction is not of high quality and has no commercial value.
Therefore, it must be purified after the phase separation
Introduction
In this part , we will explore the pros and cons of biodiesel as a sustainable biofuel. We will uncover its
environmental impact, economic feasibility, and potential for reducing greenhouse gas emissions.
“Biofuel is an inexhaustible, biodegradable fuel manufactured from Biomass.
Environmental Benefits
Its use can contribute to cleaner air and a healthier
environment for future generations. Fossil fuels,
when burnt, release greenhouse gases like carbon
dioxide into the atmosphere. This raises the
temperature and causes global warming. To
protect the environment from further heating up,
many people have adopted the use of biofuels.
Experts believe using biodiesel instead of
petroleum diesel can reduce greenhouse gases by
up to 78.45%.
Lower sulfur content—less toxic—reduced
particulate matter
Economic Viability
One of the primary benefits of using biodiesel is energy efficiency. While petroleum diesel is currently
more efficient for use in a car or truck, biodiesel production is more energy efficient. According to
researchers at the University of Idaho and the, for every fossil fuel energy unit needed to grow and
refine soybeans for biodiesel, four and a half units of energy are generated. With petroleum diesel, less
than one unit of energy is generated in return. Energy Security: Diversification of fuel sources reduces
dependence on imported fossil fuels, enhancing national energy security. Job Creation: Biodiesel
production generates employment opportunities across the supply chain, fostering economic growth.
Cost-Competitive in the Long Run: As technology advances and economies of scale come into play,
biodiesel production costs may become more competitive with traditional diesel, further enhancing
its economic viability.
Impacts on Air Quality
Using biodiesel reduces life cycle emissions because carbon dioxide released from biodiesel combustion is
offset by the carbon dioxide absorbed from growing soybeans or other feedstock's used to produce the fuel.
Life cycle analysis completed by Argonne National Laboratory found that B100 use reduces carbon dioxide
emissions by 74% compared with petroleum diesel. The California Air Resources Board (CARB) from various
sources for its life cycle analysis of biodiesel. Air quality benefits of biodiesel are roughly commensurate with
the amount of biodiesel in the blend.
Technological Advancements
Ongoing research and development in biodiesel technology aim to improve efficiency, reduce production
costs, and expand the range of feedstock's.
Waste Utilization: Innovative technologies facilitate the use of waste materials and by-products, improving
the overall sustainability of biodiesel production while reducing environmental impact.
Biotechnology Applications: Biotechnological approaches, such as genetic modification of feedstock crops or
enzyme-assisted processes, can enhance efficiency and potentially lead to the development of superior
biodiesel feedstock's.
Bio refineries----Nano catalysis----Microbial biodiesel production
Reduced Foreign Oil Dependence
Opting for renewable energy like biofuel will help reduce America’s dependence on foreign oil in
combination with other sustainable measures. For example, experts say that using biogas, enacting tax
incentives for hybrids and fuel-cell vehicles, and raising fuel economy standards for motor vehicles will help
wean the United States off the need for foreign oil.
"Biodiesel is a biofuel produced straight from animal oil/fat, vegetable oil, waste cooking oil,
agriculture waste, fat, and waste cooking oil. This combustible fuel is made by alcohol (methanol) with
vegetable oil or oil seeds.“
To fulfill the petroleum consumption in the country, India must import it from countries like Iraq, Iran, and
others. Still, biodiesel can be extracted from home-based products within a country. It instantly can't fulfill
all the requirements but can reduce the fuel extinction issue to a great extent. A country doesn't need to
depend on foreign countries for fuel if it starts producing biodiesel indigenously. This solution can also
balance the country's economy and reduce geopolitical tensions.
Challenges of Biodiesel Production
Feedstock variability. The quality and availability of feedstock's, such as vegetable oils or animal fats, can
fluctuate, impacting the efficiency and consistency of biodiesel production processes. This variability poses a
challenge in maintaining a reliable and cost-effective supply chain for biodiesel production.. Another
challenge in biodiesel production is competition for feedstock's with food and other industrial applications.
As demand for biofuels grows, there's a potential conflict between using agricultural resources for fuel
production and addressing global food needs. Balancing these competing demands requires sustainable
practices and the development of advanced feedstock options to mitigate potential negative impacts on
food security and prices.
Challenges & Disadvantages
1. Land Use Impact: The cultivation of crops for biodiesel production can contribute to
deforestation and habitat destruction, affecting biodiversity.
2. Water Usage: Biodiesel production often requires significant amounts of water, potentially
leading to water scarcity issues in regions with limited water resources.
3. Energy Intensive Production: The process of converting raw materials into biodiesel can be
energy intensive, partially offsetting the environmental benefits of the fuel.
4. Cold Weather Performance: Biodiesel has a higher cloud point and can gel at lower temperatures
compared to traditional diesel, potentially causing engine performance issues in cold climates.
5. Cost Competitiveness: Biodiesel production costs can be higher than conventional diesel,
impacting its competitiveness in the market, especially when oil prices are low.
6. Eutrophication Risk: The runoff of nutrients from biodiesel crop cultivation can contribute to
water pollution, potentially causing eutrophication in water bodies.
Future Outlook
The future of biodiesel hinges on advancements in technology, sustainable feedstock sourcing, and
supportive. Collaboration among stakeholders is vital to ensure that biodiesel continues to evolve as
a viable and environmentally friendly fuel option
1. Technological Advancements
2. Sustainability Practices
3. Policy Support
4. Emerging Technologies
5. Global Demand and Market
6. Dynamics
DID YOU KNOW?
Smell the Fries: If your car ever smells like
French fries, it might be running on
biodiesel. Biodiesel made from recycled
cooking oil can carry a faint scent of
whatever was cooked in that oil before.
Petrol's Jealous Rival: Biodiesel is so eco-
friendly that gasoline
sometimes gives it jealous glares at the fuel
station, wondering why
it's not as green and clean.
Coffee grounds, animal dung, agricultural
wastes, food wastes, biodegradable wastes
and other municipal wastes can be used as a
source for producing biofuel
Conclusion
THANK YOU

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Okay okayokayokayokayokayokayokayoka.pptx

  • 1. BIODIESEL & Presented by Olivia Wilson
  • 2.
  • 3.
  • 4. • Biomass consists of all forms of animal and plant organic matters: wood/dead plants, animal remains, leaves, living plants, vegetable oils, wastes from agricultural, residential and industrial sources and so on and can be used as a renewable and sustainable source of energy. • Biomass’s chemical composition includes gases like hydrogen, carbon, nitrogen, oxygen, certain alkali atoms, alkaline earth metals and heavy metals. • Biomass is different from fossil fuels, though both are formed from the same organic matter i.e. plant and animal remains. Scientists believe that fossil fuels come from matter that has undergone numerous changes over several millions of years , whereas biomass originates from recently dead or living plant and animals called biomass feedstocks. • Biomass can be converted into different forms of energy like solid biomass , biogas, biofuels, bio charcoal ,synthetic fuels, bio oils and many other forms through various processes, such as burning, fermentation, and anaerobic digestion. This can be used for heating, electricity generation, or as a fuel for vehicles. WHAT IS BIOMASS?
  • 5. There can be various aspects to understand, how conversion of biomass to biofuels like biodiesel, ethanol can be beneficial over the conversion of biomass to other sources of energy and use of fossil fuels. 1.Renewable Energy: Biofuels are considered renewable energy sources because they are derived from organic materials that can be replenished over time, unlike fossil fuels, which also are a large source of air pollution. This makes them a more sustainable option for meeting energy needs. 2.Reduced Greenhouse Gas Emissions: Biofuels emit fewer greenhouse gases (GHGs) compared to fossil fuels when burned for energy. This is because the carbon in biofuels is derived from recently living plants, which absorbed carbon dioxide (CO2) from the atmosphere during their growth. In contrast, fossil fuels release carbon that has been sequestered underground for millions of years, adding to the net amount of CO2 in the atmosphere. 3.Energy Density: Biofuels generally have higher energy density than biogas, which means they contain more energy per unit of volume or weight. This can make biofuels more suitable for applications that require higher energy content, such as transportation fuels. Why do we convert Biomass to Biofuels ? (I)
  • 6. 4.Flexibility: Biofuels can be used in a wide range of applications, including transportation, heating, and electricity generation. This flexibility allows them to replace fossil fuels in various sectors, reducing greenhouse gas emissions and dependence on imported oil. 5.Infrastructure: In some cases, biofuels can be used in existing infrastructure with minimal modifications. For example, ethanol can be blended with gasoline and used in conventional gasoline engines, and biodiesel can be used in existing diesel engines. 6)Energy Security: Biofuels can be produced domestically, reducing dependence on imported fossil fuels and enhancing energy security. 7)Economic Benefits: Biofuel production can create jobs and stimulate economic growth in rural areas where biomass feedstocks are abundant. Why do we convert Biomass to Biofuels ? (II) However, it's important to note that biofuels also have their limitations and challenges. For example, the production of biofuels can compete with food production, leading to potential conflicts over land use. Additionally, some biofuel production methods may have negative environmental impacts, such as increased water use or habitat destruction. Ultimately, the choice between converting biomass to biofuels or other forms of energy depends on factors such as the type of biomass available, the desired end use, and the environmental and economic considerations of each option.
  • 7. HOW IS BIOMASS CONVERTED INTO BIOFUELS Biomass is the only renewable energy source that can be converted into liquid biofuels such as ethanol and biodiesel. Biofuel is used to power vehicles, and is being produced by gasification in countries such as Sweden, Austria, and the United States. Ethanol is made by fermenting biomass that is high in carbohydrates, such as sugarcane, wheat, or corn. Biodiesel is made from combining ethanol with animal fat, recycled cooking fat, or vegetable oil. Biofuels do not operate as efficiently as gasoline. However, they can be blended with gasoline to efficiently power vehicles and machinery, and do not release the emissions associated with fossil fuels. For biodiesel production, the most common method is transesterification, which involves reacting vegetable oils or animal fats with an alcohol, such as methanol or ethanol, in the presence of a catalyst, typically sodium or potassium hydroxide. Ethanol, on the other hand, is primarily produced through fermentation of sugars in biomass feedstocks, such as sugarcane, corn, or cellulosic materials.
  • 8. Advantages of Biofuels 1.Energy Storage: Biofuels can be stored relatively easily and used when needed, unlike solar and wind energy, which are intermittent and depend on weather conditions. This makes biofuels a more reliable option for meeting energy demands. 2.Flexibility: Biofuels can be used in existing infrastructure with minimal modifications. For example, ethanol can be blended with gasoline and used in conventional gasoline engines, and biodiesel can be used in existing diesel engines. This makes biofuels a more flexible option for reducing greenhouse gas emissions from transportation. 3.Potential for Advanced Biofuels: Research is ongoing to develop advanced biofuels that can be produced from non-food biomass sources, such as agricultural residues, algae, and dedicated energy crops. These advanced biofuels have the potential to offer even greater environmental and economic benefits than traditional biofuels. 4.Reduced Greenhouse Gas Emissions: Biofuels emit fewer greenhouse gases (GHGs) compared to fossil fuels when burned for energy. This is because the carbon in biofuels is derived from recently living plants, which absorbed carbon dioxide (CO2) from the atmosphere during their growth. In contrast, fossil fuels release carbon that has been sequestered underground for millions of years, adding to the net amount of CO2 in the atmosphere.
  • 9. Various Generations of Biofuels •First Generation Biofuels: • These are made from food sources such as sugar, starch, vegetable oil, or animal fats using conventional technology. • Common first-generation biofuels include Bio alcohols, Biodiesel, Vegetable oil, Bio ethers, Biogas. • Though the process of conversion is easy but use of food sources in the production of biofuels creates an imbalance in the food economy, leading to increased food prices and hunger. •Second Generation Biofuels: • These are produced from non-food crops or portions of food crops that are not edible and considered as wastes, e.g., stems, husks, wood chips, and fruit skins and peeling. • Examples include cellulose ethanol, biodiesel. • Thermochemical reactions or biochemical conversion processes are used for producing such fuels. • Though these fuels do not affect food economy, their production is quite complicated. • Also, it is reported that these biofuels emit less greenhouse gases when compared to first generation biofuels.
  • 10. Various Generations of Biofuels •Third Generation Biofuels: • These are produced from micro-organisms like algae. • Example- Butanol • Micro-organisms like algae can be grown using land and water unsuitable for food production, therefore reducing the strain on already depleted water sources. • One disadvantage is that fertilizers used in the production of such crops lead to environmental pollution. •Fourth Generation Biofuels: • In the production of these fuels, crops that are genetically engineered to take in high amounts of carbon are grown and harvested as biomass. • The crops are then converted into fuel using second generation techniques. • The fuel is pre-combusted, and the carbon is captured. Then the carbon is geo-sequestered, meaning that the carbon is stored in depleted oil or gas fields or in unmineable coal seams. • Some of these fuels are considered carbon negative as their production pulls out carbon from the environment.
  • 11. Types of Biofuels •Any hydrocarbon fuel that is produced from an organic matter (living or once living material) in a short period of time (days, weeks, or even months) is considered a biofuel. •Biofuels may be solid, liquid or gaseous in nature. • Solid: Wood, dried plant material, and manure • Liquid: Bioethanol and Biodiesel • Gaseous: Biogas Biodiesel as a Biofuel Biodiesel is a renewable, biodegradable fuel manufactured domestically from vegetable oils, animal fats, or recycled restaurant grease. Biodiesel is a liquid fuel often referred to as B100, pure, or neat biodiesel in its unblended form. Like petroleum diesel, biodiesel is used to fuel compression-ignition engines. It is typically made through a process called transesterification, where the oil or fat is combined with an alcohol (usually methanol or ethanol) and a catalyst (like sodium hydroxide) to create biodiesel and glycerin as a byproduct. Biodiesel can be used in conventional diesel engines without any modifications, which makes it a convenient substitute for petroleum diesel. Moreover, it produces fewer greenhouse gas emissions compared to fossil fuels, contributing to a cleaner environment. Additionally, biodiesel can be produced from a variety of feedstocks, including soybeans, canola, palm oil, and even recycled cooking oil, allowing for versatility and a reduced dependence on specific crops. As a renewable energy source, biodiesel plays a crucial role in reducing our carbon footprint and mitigating climate change.
  • 12.
  • 13. Early Beginnings Biofuels have a long history, with early uses including ethanol for cars in the early 20thcentury, vegetable oils and animal fats for lighting and heating, and biogas from organic materials for cooking. These biofuels were integral to energy needs before widespread fossil fuel us. Ancient civilizations relied on biomass, like wood, animal dung, and agricultural residues, for heating and cooking. • Biogas, a mixture of methane and other gases, has been used for heating and cooking in some societies for centuries. • Before the widespread use of petroleum-based fuels, vegetable oils were commonly used for lighting and heating. • Rendered animal fats were also used historically as a fuel source, particularly for lighting lamps
  • 14. Industrial Revolution During the Industrial Revolution, the demand for energy skyrocketed due to advancements in manufacturing, transportation etc. • Traditional biomass fuels like wood and animal power proved inadequate to meet the escalating energy demands. Consequently, there was a significant shift towards biofuels such as coal, which became indispensable for powering steam engines and industrial processes. • The quest for more efficient energy sources during the Industrial Revolution fueled technological advancements in biofuel production and utilization. Innovations in machinery, processing methods, and transportation systems played a pivotal role in enhancing the efficiency and accessibility of biofuels to meet the growing energy demands of industrialized societies.
  • 15. Rise in Biofuels The rise in biofuels emerged in response to growing environmental concerns and the need for enhanced energy security. • With increasing awareness of climate change and pollution from fossil fuels, biofuels gained attention as a renewable alternative. • Additionally, reliance on imported oil prompted governments to seek domestic biofuel production, reducing dependency on foreign energy sources and enhancing national security. History of Biodiesel • Developed in the 1890s by inventor Rudolph Diesel, the diesel engine has become the engine of choice for power, reliability, and high fuel economy, worldwide. • Early experimenters on vegetable oil fuels included the French government and Dr. Diesel himself, who envisioned that pure vegetable oils could power early diesel engines for agriculture in remote areas of the world, where petroleum was not available at the time.
  • 16. History of Biodiesel • Modern biodiesel fuel, which is made by converting vegetable oils into compounds called fatty acid methyl esters, has its roots in research conducted in the 1930s in Belgium • The diesel engine was developed out of a desire to improve upon inefficient, cumbersome and sometimes dangerous steam engines of the late 1800s. • The diesel engine works on the principal of compression ignition, in which fuel is injected into the engine’s cylinder after air has been compressed to a high pressure and temperature. • As the fuel enters the cylinder it self-ignites and burns rapidly, forcing the piston back down and converting the chemical energy in the fuel into mechanical energy. • Dr. Rudolph Diesel, for which the engine is named, holds the first patent for the compression ignition engine, issued in 1893. Diesel became known worldwide for his innovative engine which could use a variety of fuels.
  • 17. Development and Evolution • Biodiesel evolved from early experiments with vegetable oils to a globally recognized renewable fuel. • Key milestones include its use in diesel engines by Rudolf Diesel, the surge in interest during the 1970s oil crisis, and the refinement of production processes in the 1990s. • Today, biodiesel faces challenges such as feedstock availability and sustainability concerns, but ongoing research and policy support aim to secure its place as a cleaner alternative to traditional diesel fuel. • Engine modifications and blending techniques improved performance and compatibility with existing infrastructure. • Government mandates and incentives further spurred its adoption, fostering a growing market.
  • 18.
  • 19. India’s National Policy on Biofuels The National Policy on Biofuels was created by the Ministry of New and Renewable Energy in 2009. This was because India’s domestic energy needs largely depended on imported crude oil. In 2018, the policy was revised by the Ministry of Petroleum and Natural Gas and was published as National Policy on Biofuels. The policy aims to reduce petroleum imports by promoting domestic fuel production. In June 2022, the Central Government revised its target of 20% ethanol blending in petrol by the year 2030 to the year 2025.
  • 20. Main Objective of National Policy on Biofuels Objectives of National Policy on Biofuels 2018 The National Policy on Biofuels 2018 aimed to achieve a 20% blending of biofuels with fossil fuels by 2030. This target was revised, and it will be completed by 2025. The policy’s primary objective is to guarantee a consistent and sufficient supply of domestic feedstock for producing biofuels. This would boost farmers’ income, reduce imports, generate employment, and create opportunities for waste-to-wealth initiatives. The National Policy of Biofuels embodies the government’s efforts to enhance the country’s energy infrastructure. Additionally, it helps to meet sustainable development goals.
  • 21. Pradhan Mantri Ji-Van Yojna • The main aims of this scheme to provide financial support to Integrated Bioethanol Projects using lignocellulosic biomass and other renewable feedstock or 2nd generation integrated bioethanol projects. • The current scheme envisages setting up of 12 Commercial scale Second Generation (2G) Bioethanol projects and 10 demonstration scale 2G Bioethanol projects based on non-food biomass feedstocks and other renewable feedstocks. • To contribute to Swacch Bharat Mission by supporting the aggregation of non-food biofuel feedstocks such as waste biomass and urban waste. • Indigenisation of second generation biomass to ethanol technologies.
  • 22. (GOBARdhan) The Galvanizing Organic Bio-Agro Resources Dhan (GOBARdhan) scheme is a government initiative that aims to convert organic waste into valuable resources. The scheme was launched in April 2018 by the Department of Drinking Water and Sanitation as part of the Swachh Bharat Mission. The objective of the scheme is to support villages to safely manage their cattle waste, agricultural waste and eventually all organic waste. The scheme promotes rural entrepreneurship, employment and income-generation opportunities. A total of 589 Biogas/CBG (Compressed Biogas) plants are functional under the GOBAR-Dhan scheme. Additionally, 251 are under construction. So far, 168 districts have been covered under the scheme.
  • 23. RUCO (Repurposed Used Cooking Oil • RUCO stands for Repurpose Used Cooking Oil, an initiative by the Food Safety and Standards Authority of India (FSSAI). The initiative's goal is to collect and convert used cooking oil into bio-diesel. • Under this initiative, 64 companies at 101 locations have been identified to enable collection of used cooking oil. For instance: McDonald’s has already started converting used cooking oil to biodiesel from 100 outlets in Mumbai and Pune.
  • 24. Environmentalists concerns over biofuels Product • Following are some concerns regarding biofuels production. • Deforestation -: Biofuels are often derived from crops like corn, sugarcane, or soybeans, which require a lot of land for cultivation. • Biodiversity loss -: Biofuel production can lead to deforestation and biodiversity loss due to expansion of cropland. • Water pollution á Production of biofuel feed stocks, especially food crops like corn and soy, can increase water pollution from nutrients, pesticides, and sediment. • To prevent these we must need to increase our production of biofuels from waste that generated by us only. Examples á production of biogas from cow dungs.
  • 25. Global Actions on Biofuels Management • The Global Biofuel Alliance launched at the G20 Summit in India in September. It brings together 19 countries and 12 international organizations – including the World Economic Forum, the World Bank and the Asian Development Bank – to try to expand the use of sustainable biofuels. • World Biofuel Day is observed every year on 10th August to create awareness about the importance of non-fossil fuels as an alternative to conventional fossil fuels.
  • 26.
  • 27. Introduction to Biodiesel Production The awareness of energy issues and environmental problems associated with burning fossil fuels has globally encouraged many researchers to investigate the possibility of using alternative sources of energy instead of oil and its derivatives. Among them, biodiesel seems very interesting for several reasons. Biodiesel is defined as mono-alkyl esters of long chain fatty acids derived from vegetable oils or animal fats and alcohol with or without a catalyst resting for several reasons. Raw Materials for Production The oils most used for worldwide biodiesel production are rapeseed (mainly in the European Union countries), soybean (Argentina and the United States of America), palm (Asian and Central American countries) and sunflower, although other oils are also used, including peanut, linseed, safflower, used vegetable oils, and also animal fats. Methanol is the most frequently used alcohol although ethanol can also be used. Since cost is the main concern in biodiesel production and trading (mainly due to oil prices), the use of non- edible vegetable oils has been studied for several years with good results. The raw materials for biodiesel production are • Vegetable oils • animal fats and short chain alcohols.
  • 28. Characteristics of Oils & Fats used • The US Department of Energy indicates that a perfect biodiesel should only comprise mono-unsaturated fatty acids. • Vegetable oils may also contain small percentages of monoglycerides and diglycerides. • In addition, there will also be small amounts of free fatty acids (in most vegetable oils, less than 1%, except for palm oil, where they can reach up to 15%). • The composition of vegetable oils influences their properties . For instance, the pour point and cloud point temperatures, cetane number and the iodine index depend on the number of unsaturation's and the length of the fatty acid chains. A higher content of double covalent bonds gives a lower solidification point and a higher iodine index.
  • 29. Characteristics of Alcohols used • Alcohols that can be used in biodiesel production are those with short chains, including methanol, ethanol, butanol, and amylic alcohol. The most widely used alcohols are methanol (CH3OH) and ethanol (C2H5OH) because of their low cost and properties. Methanol is often preferred to ethanol in spite of its high toxicity because its use in biodiesel production requires simpler technology; excess alcohol may be recovered at a low cost and higher reaction speeds are reached. • It must be remembered that in order for biodiesel to be a fully renewable fuel, it should be obtained from vegetable oils and animal fats, together with an alcohol that is produced from biomass such as bioethanol, instead of being a petrochemical product. Several countries are carrying out research towards this objective, such as Spain and Brazil. • Most important alcohols are Methanol and Ethanol. • Methanol- Most widely used, in spite of its toxicity. It is a substance of petrochemical origin. • Ethanol - Less used, requires more complex production technology and the reaction speeds are lower. It can be produced from biomass.
  • 30. Biodiesel Production Process • Biodiesel is produced from vegetable oils or animal fats and an alcohol, through a transesterification reaction . • This chemical reaction converts an ester (vegetable oil or animal fat) into a mixture of esters of the fatty acids that makes up the oil (or fat). • Biodiesel is obtained from the purification of the mixture of fatty acid methyl esters (FAME). • A catalyst is used to accelerate the reaction . • According to the catalyst used, transesterification can be basic, acidic or enzymatic, the former being the most frequently used. Transesterification Reactions for Biodiesel Production Basic. Most frequently used at all production scales. Acid. Less frequent in industrial production, sometimes used a first stage with highly acidic raw materials. Enzymatic. Less used; the enzymes are usually lipases.
  • 31. Stages of Biodiesel Production 1. Treatment Of Raw Materials The content of free fatty acids, water and non - saponificable substances are key parameters to achieve high conversion efficient The use of basic catalysts in triglycerides with high content of free fatty acids is not advisable , since part of the latter reacts with the catalyst to form soaps. In consequence, part of the catalyst is spent, and it is no longer available for transesterification. In summary the efficiency of the reaction diminishes with the increase of the acidity of the oil; basic transesterification is viable if the content of free fatty acids (FFAs) is less than 2%. In the case of highly acidic raw materials (animal fats from cattle, poultry, pork; vegetable oils from cotton, coconut, most used oils, etc.) an acid transesterification is necessary as a preliminary stage, to reduce the level of FFAs to the above-mentioned value. Besides having low humidity and acid content, it is important that the oil presents a low level of non- saponificable substances. If the latter were to be present in significant amounts and soluble in biodiesel, it would reduce the level of esters in the product, making it difficult to comply with the minimum ester content required by the standards.
  • 32. Stages of Biodiesel Production 2. Alcohol Catalyst Mixing • The alcohol used for biodiesel production must be mixed with the catalyst before adding the oil. The mixture is stirred until the catalyst is completely dissolved in the alcohol. It must be noted that the alcohol must be water-free (anhydrous) for the reasons explained in the previous paragraph. • Sodium and potassium hydroxides are among the most widely used basic catalysts. For production on an industrial scale, sodium or potassium methoxides or methylate's are commercially available. • Of course, due caution must be exercised, and all applicable safety regulations must be followed, when working with methanol, hydroxides and methoxides, independently of the production scale. 3. Chemical Reaction The chemical reaction takes place when the oil is mixed with the alkoxide (alcohol–catalyst mix) This requires certain conditions of time, temperature and stirring. Since alcohols and oils do not mix at room temperature, the chemical reaction is usually carried out at a higher temperature and under continuous stirring, to increase the mass transfer between the phases.
  • 33. Stages of Biodiesel Production 4. Separation of the reaction products • The separation of reaction products takes place by decantation: the mixture of fatty acids methyl esters (FAME) separates from glycerin forming two phases, since they have different densities; the two phases begin to form immediately after the stirring of the mixture is stopped. Due to their different chemical affinities, most of the catalyst and excess alcohol will concentrate in the lower phase (glycerin), while most of the mono-, di-, and triglycerides will concentrate in the upper phase (FAME). Once the interphase is clearly and completely defined, the two phases may be physically separated. It must be noted that if decantation takes place due to the action of gravity alone, it will take several hours to complete. This constitutes a ‘‘bottleneck’’ in the production process, and in consequence the exit stream from the transesterification reactor is split into several containers. Centrifugation is a faster, albeit more expensive alternative. • After the separation of glycerin, the FAME mixture contains impurities such as remnants of alcohol, catalyst and mono-, di-, and triglycerides. These impurities confer undesirable characteristics to FAME, for instance, increased cloud point and pour point, lower flash point, etc. In consequence a purification process is necessary for the final product to comply with standards. This will be discussed in the next section.
  • 34. Stages of Biodiesel Production 5. Purification of the Reaction Products • The mixture of fatty acids methyl esters (FAME) obtained from the transesterification reaction must be purified in order to comply with established quality standards for biodiesel. Therefore, FAME must be washed, neutralized and dried. • Successive washing steps with water remove the remains of methanol, catalyst and glycerin, since these contaminants are water-soluble. Care must be taken to avoid the formation of emulsions during the washing steps, since they would reduce the efficiency of the process. The first washing step is carried out with acidified water, to neutralize the mixture of esters. Then, two additional washing steps are made with water only. Finally the traces of water must be eliminated by a drying step. After drying, the purified product is ready for characterization as biodiesel according to international standards. • An alternative to the purification process described above is the use of ion exchange resins or silicates. Glycerin as obtained from the chemical reaction is not of high quality and has no commercial value. Therefore, it must be purified after the phase separation
  • 35.
  • 36. Introduction In this part , we will explore the pros and cons of biodiesel as a sustainable biofuel. We will uncover its environmental impact, economic feasibility, and potential for reducing greenhouse gas emissions. “Biofuel is an inexhaustible, biodegradable fuel manufactured from Biomass.
  • 37. Environmental Benefits Its use can contribute to cleaner air and a healthier environment for future generations. Fossil fuels, when burnt, release greenhouse gases like carbon dioxide into the atmosphere. This raises the temperature and causes global warming. To protect the environment from further heating up, many people have adopted the use of biofuels. Experts believe using biodiesel instead of petroleum diesel can reduce greenhouse gases by up to 78.45%. Lower sulfur content—less toxic—reduced particulate matter
  • 38. Economic Viability One of the primary benefits of using biodiesel is energy efficiency. While petroleum diesel is currently more efficient for use in a car or truck, biodiesel production is more energy efficient. According to researchers at the University of Idaho and the, for every fossil fuel energy unit needed to grow and refine soybeans for biodiesel, four and a half units of energy are generated. With petroleum diesel, less than one unit of energy is generated in return. Energy Security: Diversification of fuel sources reduces dependence on imported fossil fuels, enhancing national energy security. Job Creation: Biodiesel production generates employment opportunities across the supply chain, fostering economic growth. Cost-Competitive in the Long Run: As technology advances and economies of scale come into play, biodiesel production costs may become more competitive with traditional diesel, further enhancing its economic viability.
  • 39. Impacts on Air Quality Using biodiesel reduces life cycle emissions because carbon dioxide released from biodiesel combustion is offset by the carbon dioxide absorbed from growing soybeans or other feedstock's used to produce the fuel. Life cycle analysis completed by Argonne National Laboratory found that B100 use reduces carbon dioxide emissions by 74% compared with petroleum diesel. The California Air Resources Board (CARB) from various sources for its life cycle analysis of biodiesel. Air quality benefits of biodiesel are roughly commensurate with the amount of biodiesel in the blend. Technological Advancements Ongoing research and development in biodiesel technology aim to improve efficiency, reduce production costs, and expand the range of feedstock's. Waste Utilization: Innovative technologies facilitate the use of waste materials and by-products, improving the overall sustainability of biodiesel production while reducing environmental impact. Biotechnology Applications: Biotechnological approaches, such as genetic modification of feedstock crops or enzyme-assisted processes, can enhance efficiency and potentially lead to the development of superior biodiesel feedstock's. Bio refineries----Nano catalysis----Microbial biodiesel production
  • 40. Reduced Foreign Oil Dependence Opting for renewable energy like biofuel will help reduce America’s dependence on foreign oil in combination with other sustainable measures. For example, experts say that using biogas, enacting tax incentives for hybrids and fuel-cell vehicles, and raising fuel economy standards for motor vehicles will help wean the United States off the need for foreign oil. "Biodiesel is a biofuel produced straight from animal oil/fat, vegetable oil, waste cooking oil, agriculture waste, fat, and waste cooking oil. This combustible fuel is made by alcohol (methanol) with vegetable oil or oil seeds.“ To fulfill the petroleum consumption in the country, India must import it from countries like Iraq, Iran, and others. Still, biodiesel can be extracted from home-based products within a country. It instantly can't fulfill all the requirements but can reduce the fuel extinction issue to a great extent. A country doesn't need to depend on foreign countries for fuel if it starts producing biodiesel indigenously. This solution can also balance the country's economy and reduce geopolitical tensions.
  • 41. Challenges of Biodiesel Production Feedstock variability. The quality and availability of feedstock's, such as vegetable oils or animal fats, can fluctuate, impacting the efficiency and consistency of biodiesel production processes. This variability poses a challenge in maintaining a reliable and cost-effective supply chain for biodiesel production.. Another challenge in biodiesel production is competition for feedstock's with food and other industrial applications. As demand for biofuels grows, there's a potential conflict between using agricultural resources for fuel production and addressing global food needs. Balancing these competing demands requires sustainable practices and the development of advanced feedstock options to mitigate potential negative impacts on food security and prices.
  • 42. Challenges & Disadvantages 1. Land Use Impact: The cultivation of crops for biodiesel production can contribute to deforestation and habitat destruction, affecting biodiversity. 2. Water Usage: Biodiesel production often requires significant amounts of water, potentially leading to water scarcity issues in regions with limited water resources. 3. Energy Intensive Production: The process of converting raw materials into biodiesel can be energy intensive, partially offsetting the environmental benefits of the fuel. 4. Cold Weather Performance: Biodiesel has a higher cloud point and can gel at lower temperatures compared to traditional diesel, potentially causing engine performance issues in cold climates. 5. Cost Competitiveness: Biodiesel production costs can be higher than conventional diesel, impacting its competitiveness in the market, especially when oil prices are low. 6. Eutrophication Risk: The runoff of nutrients from biodiesel crop cultivation can contribute to water pollution, potentially causing eutrophication in water bodies.
  • 43. Future Outlook The future of biodiesel hinges on advancements in technology, sustainable feedstock sourcing, and supportive. Collaboration among stakeholders is vital to ensure that biodiesel continues to evolve as a viable and environmentally friendly fuel option 1. Technological Advancements 2. Sustainability Practices 3. Policy Support 4. Emerging Technologies 5. Global Demand and Market 6. Dynamics DID YOU KNOW? Smell the Fries: If your car ever smells like French fries, it might be running on biodiesel. Biodiesel made from recycled cooking oil can carry a faint scent of whatever was cooked in that oil before. Petrol's Jealous Rival: Biodiesel is so eco- friendly that gasoline sometimes gives it jealous glares at the fuel station, wondering why it's not as green and clean. Coffee grounds, animal dung, agricultural wastes, food wastes, biodegradable wastes and other municipal wastes can be used as a source for producing biofuel