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Ivey-sol® Surfactant Enhanced Oil Recovery
                                   SEORTM Technology

OVERVIEW:
Enhanced Oil Recovery (EOR) is the process of obtaining stranded oil not recovered from oil
reservoirs through certain extraction processes. EOR uses methods including thermal recovery, gas
injection, chemical injection and low-salinity water flooding. Although these methods have shown
promise, SEOR (Surfactant Enhanced Oil Recovery) utilizes a modified formulation of the
internationally known Ivey-sol® non-ionic surfactant, non-toxic product, that has a proven capacity to
expedite oil mass recovery not being realized by conventional EOR methodologies.

Ivey-sol® Surfactant Enhanced Oil Recovery (SEORTM) Technology was developed by George A. Ivey,
of Ivey International Incorporated (IVEY) in the mid to late 1990’s. The technology first surfaced when
IVEY started sub-surface (in-situ) Ivey-sol® injection treatments at down-stream oil contaminated sites
to enhance oil (i.e., petroleum hydrocarbon) mass removal from subsurface soil and saturated
groundwater regimes, in a non-destructive method. Applied case studies, and peer reviewed journal
publications and international conference presentations have verified the EOR capacity of Ivey-sol®.

The SEOR approach significantly improved oil mass recovery by 400% to 1200% compared to
conventional pumping extraction methods alone. The oil impacts to the subsurface soils and
groundwater were the result of uncontrolled spills from downstream underground storage tanks (UST)
at fuel stations, above ground storage tanks (AST) at refineries, and along pipe lines.




Ivey-sol® was injected into the subsurface well sites and began desorbing hydrocarbon contaminants
from the soil base and moving them to the oil extraction wells for rapid recovery. It was these early
successes that lead IVEY to focus their energy on Upstream Oil & Gas SEOR applications for
improving oil mass recovery during secondary and tertiary oil recovery programs to maximize the
value of the subject reserves.
Ivey-sol® TECHNOLOGY:
Ivey-sol® is a non-ionic, biodegradable, non-toxic surfactant formulation that utilizes water as its base
with specially designed surfactant molecules that can ‘selectively’ desorb sorbed oils from soils into the
aqueous phase for enhanced oil recovery. Ivey-sol® is unique in its able to desorb unavailable oil and
make them more “Physically Available” for expedited subsurface recovery. The Ivey-sol® products are
uniquely effective well below the CMC (Critical Micelle Concentration); hence they will not form
emulsions, making oil recovery possible. It can also reduce the surface tension of saline formation
water tension from >73 dyne to <30 dyne allowing for improved fluid flow (K) rates within oil laden
saline formations to the nearby oil extraction wells within a given oil production field. This approach is
primarily targeted at SEOR™ during the secondary and/or tertiary oil recovery phases. The following
image illustrates how Ivey-sol® SEOR™ process can be incorporated into existing oil field to aid EOR
during secondary and tertiary oil recovery programs.




MECHANISM:
For years, many scientists have been trying to achieve controlled desorption of stationary sorbed oils
within an oil fields, which has been a significant limiting factor for oil field operations and financial
viability. The mechanism of how the Ivey-sol® product works is illustrated below. The Ivey-sol® is
shown desorbing the oils off a soil grain within an oil field. Once liberated, the desorbed oil has
increased ‘Physical Availability’ for improving the associated in-situ mass recovery at nearby oil
extraction wells.
FIELD TRIALS:
Application of the Ivey-sol® surfactant technology to enhance in-situ oil mass recovery in sands, silts,
clays and fractured bedrock was first successfully applied in the early 1990’s. Since that time the
technology has been applied at hundreds of sites globally. The ability of the Ivey-sol® products to
desorb the oil below the CMC, and not form emulsions, was the primary key to expediting the rate of
oil recovery. For the downstream site applications, this meant going from multi-year remediation
treatment plans (i.e., oil recovery) timeframes to the order of weeks and months.

                                                            As shown in the figure to the left, the
                                                            heavy-oil from a pipeline spill site was
                                                            made miscible for enhanced oil recovery
                                                            in the aquious phase. This benchscale
                                                            application was the basis for a successful
                                                            field trial at a pipeline spill site.

                                                            The Ivey-sol® took the free phase oils into
                                                            solution for the C10-19 by >2,621%, and the
                                                            C19-32 by greater than 1,761%. Although
                                                            C32-50 was not reported in this test, the
                                                            effects are obvious.


Regarding SEOR™ within oil fields, Ivey-sol® is capable of desorbing the sorbed oil from organics,
fine sands, silts, clays and fractured bedrock. Desorption of the sorbed oil is central to the effective
recovery of trapped oils for Enhanced Oil Recovery within upstream oil recovery programs. The Ivey-
sol® SEOR™ products will not negatively affect the quality of the recovered oil during upstream
refinement, storage and downstream distribution as this is a “NON-CHEMICAL” application.

The following images illustrate the pre to post Ivey-sol® SEOR™ soil washing application of Frac-sand
(>10%), Refinery Soils (>50,000 ppm) and sands and gravel originating from am Manufactured Gas
Plant (MGP) site. The results are generally immediate and significant with the option for oil recovery.




Proposal: Ivey-sol® SEOR™ Technology is now available in the Middle East using Bahrain as our
business hub. If SEOR™ Technology is of interest to your petroleum company, we would like to
establish a pilot project on an existing marginal production well to demonstrate the efficiency of this
technology to increase well capability and production in a non-hazardous sustainable way.

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Ivey Sol Seor Document

  • 1. Ivey-sol® Surfactant Enhanced Oil Recovery SEORTM Technology OVERVIEW: Enhanced Oil Recovery (EOR) is the process of obtaining stranded oil not recovered from oil reservoirs through certain extraction processes. EOR uses methods including thermal recovery, gas injection, chemical injection and low-salinity water flooding. Although these methods have shown promise, SEOR (Surfactant Enhanced Oil Recovery) utilizes a modified formulation of the internationally known Ivey-sol® non-ionic surfactant, non-toxic product, that has a proven capacity to expedite oil mass recovery not being realized by conventional EOR methodologies. Ivey-sol® Surfactant Enhanced Oil Recovery (SEORTM) Technology was developed by George A. Ivey, of Ivey International Incorporated (IVEY) in the mid to late 1990’s. The technology first surfaced when IVEY started sub-surface (in-situ) Ivey-sol® injection treatments at down-stream oil contaminated sites to enhance oil (i.e., petroleum hydrocarbon) mass removal from subsurface soil and saturated groundwater regimes, in a non-destructive method. Applied case studies, and peer reviewed journal publications and international conference presentations have verified the EOR capacity of Ivey-sol®. The SEOR approach significantly improved oil mass recovery by 400% to 1200% compared to conventional pumping extraction methods alone. The oil impacts to the subsurface soils and groundwater were the result of uncontrolled spills from downstream underground storage tanks (UST) at fuel stations, above ground storage tanks (AST) at refineries, and along pipe lines. Ivey-sol® was injected into the subsurface well sites and began desorbing hydrocarbon contaminants from the soil base and moving them to the oil extraction wells for rapid recovery. It was these early successes that lead IVEY to focus their energy on Upstream Oil & Gas SEOR applications for improving oil mass recovery during secondary and tertiary oil recovery programs to maximize the value of the subject reserves.
  • 2. Ivey-sol® TECHNOLOGY: Ivey-sol® is a non-ionic, biodegradable, non-toxic surfactant formulation that utilizes water as its base with specially designed surfactant molecules that can ‘selectively’ desorb sorbed oils from soils into the aqueous phase for enhanced oil recovery. Ivey-sol® is unique in its able to desorb unavailable oil and make them more “Physically Available” for expedited subsurface recovery. The Ivey-sol® products are uniquely effective well below the CMC (Critical Micelle Concentration); hence they will not form emulsions, making oil recovery possible. It can also reduce the surface tension of saline formation water tension from >73 dyne to <30 dyne allowing for improved fluid flow (K) rates within oil laden saline formations to the nearby oil extraction wells within a given oil production field. This approach is primarily targeted at SEOR™ during the secondary and/or tertiary oil recovery phases. The following image illustrates how Ivey-sol® SEOR™ process can be incorporated into existing oil field to aid EOR during secondary and tertiary oil recovery programs. MECHANISM: For years, many scientists have been trying to achieve controlled desorption of stationary sorbed oils within an oil fields, which has been a significant limiting factor for oil field operations and financial viability. The mechanism of how the Ivey-sol® product works is illustrated below. The Ivey-sol® is shown desorbing the oils off a soil grain within an oil field. Once liberated, the desorbed oil has increased ‘Physical Availability’ for improving the associated in-situ mass recovery at nearby oil extraction wells.
  • 3. FIELD TRIALS: Application of the Ivey-sol® surfactant technology to enhance in-situ oil mass recovery in sands, silts, clays and fractured bedrock was first successfully applied in the early 1990’s. Since that time the technology has been applied at hundreds of sites globally. The ability of the Ivey-sol® products to desorb the oil below the CMC, and not form emulsions, was the primary key to expediting the rate of oil recovery. For the downstream site applications, this meant going from multi-year remediation treatment plans (i.e., oil recovery) timeframes to the order of weeks and months. As shown in the figure to the left, the heavy-oil from a pipeline spill site was made miscible for enhanced oil recovery in the aquious phase. This benchscale application was the basis for a successful field trial at a pipeline spill site. The Ivey-sol® took the free phase oils into solution for the C10-19 by >2,621%, and the C19-32 by greater than 1,761%. Although C32-50 was not reported in this test, the effects are obvious. Regarding SEOR™ within oil fields, Ivey-sol® is capable of desorbing the sorbed oil from organics, fine sands, silts, clays and fractured bedrock. Desorption of the sorbed oil is central to the effective recovery of trapped oils for Enhanced Oil Recovery within upstream oil recovery programs. The Ivey- sol® SEOR™ products will not negatively affect the quality of the recovered oil during upstream refinement, storage and downstream distribution as this is a “NON-CHEMICAL” application. The following images illustrate the pre to post Ivey-sol® SEOR™ soil washing application of Frac-sand (>10%), Refinery Soils (>50,000 ppm) and sands and gravel originating from am Manufactured Gas Plant (MGP) site. The results are generally immediate and significant with the option for oil recovery. Proposal: Ivey-sol® SEOR™ Technology is now available in the Middle East using Bahrain as our business hub. If SEOR™ Technology is of interest to your petroleum company, we would like to establish a pilot project on an existing marginal production well to demonstrate the efficiency of this technology to increase well capability and production in a non-hazardous sustainable way.