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双单体法 合成
两亲性 超支化 聚 ( β- 环糊精 )
          及其性能研究

              般若
              黑
合
                                                                               成
                                                                                   路
反应 1 d
沉降 & 干燥 2d
                                                                                    线

             反应 2h
             沉降 &
             干燥 2d




                          反应 4d+ 透析 & 干燥 1 0d



                                           反应 1 d+
                                           沉降 & 干燥 2d



                                                        反应 2d+ 透析 & 干燥 1 0d


                                                           HB P
                     B x-OT s单体                            PN I PAm-COOH



                         B x-N H2 单体                     接枝核壳 HB P
合
                                                       成
                                                           路
                                                            线

                                   DMAP

                             HCl




                        吡啶




B x-OT s   B x-N H2   HB P                接枝核壳 HB P
S T
LC




           LCST
度
   粒1400

        1200
                                                                HBP
        1000

            800
Diam (nm)




            600

            400

            200
                             LCST=52℃                 接枝核壳 HBP
              0

            -200
                   10   20     30   40     50    60   70   80    90   100
                                         T (℃)
C
    M
C




            CMC
C
        M                     7000
                                           -6
                                                                 335 nm    339 nm
C                                     1×10-6
                                      5×10-5
                                      1×10-5
                              6000    5×10-4
                                      1×10-4
Excitation Intensity (a.u.)



                                      5×10-3
                                      1×10-3
                              5000    5×10 -2
                                      1×10 -2
                                      5×10-1
                              4000    1×10-1
                                      5×10
                                      1
                                      40
                              3000    50
                                      70
                                      100
                              2000

                              1000

                                0

                                     280        300        320            340       360
                                                      Wavelength (nm)
C
        M
    C       1.1              5 mg/ml
                             4 mg/ml
                             3 mg/ml
            1.0
                             2 mg/ml
                             1 mg/ml
I335/I339




            0.9
                             0.5 mg/ml
                             0.4 mg/ml
            0.8              0.3 mg/ml
                             0.2 mg/ml
                             0.1 mg/ml
            0.7                                 CMC =0.71mg/ml


                  -3   -2   -1         0        1      1         1
                                 log C(mg/ml)
光
                             荧
                    -9600
 合                                          -5
                                      LL(X× mol/L)
                                           10
包                                          pH=7.4           0mg/ml
                             9400
 emission intensity (a.u.)




                                                          2 mg/ml
                             9200

                                                           3 mg/ml
                             9000
                                                           4 mg/ml

                             8800
                                                           5 mg/ml

                             8600


                             8400
                                440              450            460      470
                                                       Wavelength (nm)
光
                荧
     -
 合
包                                                                Wavelength=457.8 nm
                                 9400


 结论:
     emission intensity (a.u.)




                                 9200

CM C 点
      以上,
物可对        聚合                    9000


      LL 形成
的包合        稳定                    8800



                                 8600
                                        0.0   0.5    1       2       3      4      5
                                                    Concentration (mg/ml)
总
        GP C
                 D SC           紫




                                                 结
                                外        粒
    核
    磁                                   度
                        T GA


            性
         单体改
                                             D SC
红            法
外        双单体                   测定
                               LCST


                                               紫
                                               外



                                                    荧
                                      客体包载
                                                    光
答辩模板6
答辩模板6

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答辩模板6

  • 1. 双单体法 合成 两亲性 超支化 聚 ( β- 环糊精 ) 及其性能研究 般若 黑
  • 2. 成 路 反应 1 d 沉降 & 干燥 2d 线 反应 2h 沉降 & 干燥 2d 反应 4d+ 透析 & 干燥 1 0d 反应 1 d+ 沉降 & 干燥 2d 反应 2d+ 透析 & 干燥 1 0d HB P B x-OT s单体 PN I PAm-COOH B x-N H2 单体 接枝核壳 HB P
  • 3. 成 路 线 DMAP HCl 吡啶 B x-OT s B x-N H2 HB P 接枝核壳 HB P
  • 4. S T LC LCST
  • 5. 粒1400 1200 HBP 1000 800 Diam (nm) 600 400 200 LCST=52℃ 接枝核壳 HBP 0 -200 10 20 30 40 50 60 70 80 90 100 T (℃)
  • 6. C M C CMC
  • 7. C M 7000 -6 335 nm 339 nm C 1×10-6 5×10-5 1×10-5 6000 5×10-4 1×10-4 Excitation Intensity (a.u.) 5×10-3 1×10-3 5000 5×10 -2 1×10 -2 5×10-1 4000 1×10-1 5×10 1 40 3000 50 70 100 2000 1000 0 280 300 320 340 360 Wavelength (nm)
  • 8. C M C 1.1 5 mg/ml 4 mg/ml 3 mg/ml 1.0 2 mg/ml 1 mg/ml I335/I339 0.9 0.5 mg/ml 0.4 mg/ml 0.8 0.3 mg/ml 0.2 mg/ml 0.1 mg/ml 0.7 CMC =0.71mg/ml -3 -2 -1 0 1 1 1 log C(mg/ml)
  • 9. 荧 -9600 合 -5 LL(X× mol/L) 10 包 pH=7.4 0mg/ml 9400 emission intensity (a.u.) 2 mg/ml 9200 3 mg/ml 9000 4 mg/ml 8800 5 mg/ml 8600 8400 440 450 460 470 Wavelength (nm)
  • 10. 荧 - 合 包 Wavelength=457.8 nm 9400 结论: emission intensity (a.u.) 9200 CM C 点 以上, 物可对 聚合 9000 LL 形成 的包合 稳定 8800 8600 0.0 0.5 1 2 3 4 5 Concentration (mg/ml)
  • 11. GP C D SC 紫 结 外 粒 核 磁 度 T GA 性 单体改 D SC 红 法 外 双单体 测定 LCST 紫 外 荧 客体包载 光

Editor's Notes

  1. 首先配置一系列浓度的聚合物的芘溶液。分别测定芘的激发强度。