The Digital Humanities Lab (DHLab) is a research group within the faculty of Humanities of the University of Basel. The group was founded in the 1920 as scientific photography lab. In the project “Digital Materiality”, we applied and enhanced Reflection Transformation Imaging (RTI) enabling this technique to capture artwork that is characterized by surfaces that strongly interact with light. Standard photographic approaches are unable to capture the dynamic component of the light-surface interdependence specific for these kinds of objects. RTI is a promising approach to go beyond the limitations of conventional photography. However, RTI has some drawbacks that are critical in the context of the reproduction of surfaces composed of materials of different kind. Typical RTI images reduce any mixture of materials with an average gloss for the whole surface. Our improvements of the technology take into account more sophisticated but still robust and simple reflection models for the realistic visualization of localized diffuse and specular surfaces within the same digital reproduction. The quality of a RTI rendering can be judged by various parameters. The most important is certainly the photorealism of a specific viewing situation. In photography one of the most important aspects is the visual appearance of color. Proper color transformation and reproduction is in a state-of-the-art digital photography workflow. However, when RTI was first developed color management was not a common process in photography workflows. Therefore, in typical implementations of RTI, color is handled as RGB data without any further explanation about what color primaries are chosen to span a color space. We will show what workflow can be used to optimize color representation in RTIs to enhance photorealism.