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Liquid-liquid extraction of radioactive europium f.
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RN:38059917
Liquid-liquid extraction of radioactive europium from radioactive samarium with crown ether
by El-Mohty, A.; El-Azony, K.M.; Aydia, M.E. (Radioisotopes and Generators Dept.,
Hot Labs Centre, Atomic Energy Authority, Cairo (Egypt)); El-Didamony, H.
(Faculty of Science, Zagazig University, Zagazig (Egypt))
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[en] The separation of samarium from europium using a solvent extraction method was investigated. Some factors affecting the
separation, such as HCl concentration, dicyclohexyl-18-crown-6 (DCH18C6) concentration. The use of non-polar organic solvents (ethyl
acetate, benzene, carbon tetrachloride, xylene or toluene) and polar organic solvents (chloroform, dinitrobenzene, dichloro-ethane or
dichlorobenzene) were studied. The optimum conditions were deduced in a simple form. The low concentration of DCH18C6 (0.03 M in
chloroform) as extracting agent is sufficient to extract the europium with uptake yield ∼ 99.9 %, whereas samarium remains in the
aqueous phase (8 M HCl), and the time needed was 15 min for the separation process. Europium was re-extracted from the chosen
concentration of DCH18C6 into the aqueous phase by using 1 M HCl
Subject INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY (S37)
Source/Report Isotope and Radiation Research; v. 38(3); ISSN 0021-1907; ; 2007; p. 741-750
Record Type Journal article
Country/Org. Egypt
DEC CHLORINATED ALIPHATIC HYDROCARBONS, CHLORINE COMPOUNDS,
DISPERSIONS, ELEMENTS, ETHERS, EXTRACTION, HALOGEN COMPOUNDS,
HALOGENATED ALIPHATIC HYDROCARBONS, HOMOGENEOUS MIXTURES,
HYDROGEN COMPOUNDS, INORGANIC ACIDS, INORGANIC COMPOUNDS, METALS,
MIXTURES, NONAQUEOUS SOLVENTS, ORGANIC CHLORINE COMPOUNDS, ORGANIC
COMPOUNDS, ORGANIC HALOGEN COMPOUNDS, ORGANIC OXYGEN COMPOUNDS,
RARE EARTHS, SEPARATION PROCESSES, SOLUTIONS, SOLVENTS
DEI AQUEOUS SOLUTIONS, CHLOROFORM, CROWN ETHERS, EUROPIUM,
HYDROCHLORIC ACID, ORGANIC SOLVENTS, RADIOACTIVITY, SAMARIUM,
SEPARATION PROCESSES, SOLVENT EXTRACTION, SPECTROPHOTOMETRY, UPTAKE
Language English
Ref. Number 38059917
Publ. Year 2007
INIS Volume 38
INIS Issue 27
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