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Adv chem chapt 6

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Thermochemistry Advanced Chemistry Chapter 6
Thermodynamics ,[object Object]
Energy ,[object Object],[object Object],[object Object]
Fossil Fuels ,[object Object],[object Object],[object Object]
Chemical Energy ,[object Object],[object Object],[object Object]
The Nature of Energy 6.1
Energy ,[object Object],[object Object],[object Object]
Potential Energy ,[object Object],[object Object],[object Object]
Kinetic Energy ,[object Object],[object Object]
Conservation of Energy ,[object Object],[object Object],[object Object]
Conversion of Energy ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Conversion of Energy ,[object Object],[object Object]
Heat vs. Temperature ,[object Object],[object Object],[object Object],[object Object]
Pathway ,[object Object],[object Object]
State Function ,[object Object],[object Object],[object Object],[object Object]
State Function Example ,[object Object],[object Object]
Chemical Energy ,[object Object],[object Object],[object Object],[object Object],[object Object]
Exothermic ,[object Object],[object Object]
Endothermic ,[object Object],[object Object]
Chemical Energy ,[object Object],[object Object],[object Object]
Chemical Energy ,[object Object],[object Object]
Chemical Energy ,[object Object]
Chemical Energy ,[object Object],[object Object],[object Object]
Chemical Energy ,[object Object],[object Object]
Internal energy ,[object Object],[object Object],[object Object],[object Object],[object Object]
Thermodynamics ,[object Object],[object Object],[object Object],[object Object]
Endothermic ,[object Object],[object Object],[object Object],[object Object]
Endothermic Example
Exothermic ,[object Object],[object Object],[object Object],[object Object]
Exothermic Example
Thermodynamic Quantities
Internal Energy Example ,[object Object],[object Object],[object Object],[object Object]
Chemical Work Processes ,[object Object],[object Object]
Pressure vs. Work ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Work ,[object Object],[object Object],[object Object],[object Object],[object Object]
Work ,[object Object],[object Object],[object Object],[object Object],[object Object]
Work Example ,[object Object],[object Object],[object Object],[object Object]
Energy, Heat and Work Example ,[object Object]
Energy, Heat and Work Example ,[object Object],[object Object],[object Object],[object Object],[object Object],ΔE = q + w w = −PΔV ΔE = 8 x 10 7 J
Enthalpy and Calorimetry 6.2
Enthalpy ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Enthalpy ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Enthalpy Change ,[object Object],[object Object],[object Object],[object Object],[object Object]
Enthalpy Example ,[object Object],[object Object],[object Object],[object Object]
Calorimetry ,[object Object],[object Object],[object Object],[object Object]
Coffee Cup Calorimeter ,[object Object],[object Object]
Heat Capacity ,[object Object],[object Object],[object Object],[object Object]
Specific Heat ,[object Object],[object Object],[object Object],[object Object],[object Object]
Specific Heat
Calorimetry Example ,[object Object]
Calorimetry Example ,[object Object],[object Object],[object Object],[object Object],[object Object],H + + OH −  H 2 O  Change in heat = s  mass  ΔT 2.9 x 10 3 J
Extensive vs. Intensive ,[object Object],[object Object],[object Object],[object Object]
Calorimetry Example ,[object Object]
Calorimetry Example ,[object Object],[object Object],[object Object],[object Object],[object Object],Ba 2+ (aq) + SO 4 2 (aq) -  BaSO 4(s) q p = −26 kJ ΔH = −26 kJ/mol
Constant Volume Calorimetry ,[object Object],[object Object],[object Object],[object Object]
Bomb Calorimeter
Bomb Calorimeter
Constant Volume Calorimetry Example ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Constant Volume Example ,[object Object]
Constant Volume Example ,[object Object],[object Object],[object Object],[object Object],Energy of 1.5g CH 4 = 11.3kJ/°C x 7.3°C = 83 kJ Energy of 1.0 g CH 4 = 55 kJ/g Energy of 1.15g H 2 = 11.3 kJ/°C x 14.3°C = 162 kJ Energy of 1.0 g H 2 = 141 kJ/g
Hess’s Law 6.3
Hess’s Law ,[object Object]
Hess’s Example ,[object Object],[object Object],[object Object],[object Object],[object Object]
Rules for Hess’s Law Calculations ,[object Object],[object Object],[object Object],[object Object],[object Object]
Hess’s Law Example ,[object Object],[object Object]
Hess’s Law Example ,[object Object],[object Object],[object Object],ΔH = 2 kJ
Hess’s Law Example ,[object Object],[object Object],[object Object],[object Object]
Hess’s Law Example ,[object Object],[object Object],[object Object],[object Object],[object Object],ΔH = 36 kJ/mol
Standard Enthalpies of Formation 6.4
Standard Enthalpies of Formation ,[object Object],[object Object]
Standard Enthalpies of Formation ,[object Object]
Standard State Definitions ,[object Object],[object Object],[object Object],[object Object]
Enthalpy of Formation ,[object Object],[object Object],[object Object],[object Object]
Enthalpies of Formation
Example of Enthalpy Calculations ,[object Object],[object Object],− 891 kJ
Enthalpy Formation ,[object Object],[object Object],[object Object]
Enthalpy Problem 1 ,[object Object],[object Object]
Enthalpy Problem 1 ,[object Object],− 1396 kJ
Enthalpy Problem 2 ,[object Object],[object Object],[object Object]
Enthalpy Problem 2 ,[object Object],− 850. kJ
Enthalpy Problem 3 ,[object Object]
Enthalpy Problem 3 ,[object Object],− 22.6 kJ/g
Enthalpy Problem 3 ,[object Object],− 47.7 kJ/g
Enthalpy Problem 3 ,[object Object]
Present Sources of Energy 6.5
Present Energy Sources ,[object Object]
Energy Sources used in US
Petroleum and Natural Gas ,[object Object]
Common Hydrocarbons
Largest Oil Rig in the World
Petroleum and Natural Gas ,[object Object],[object Object]
Petroleum and Natural Gas ,[object Object]
Petroleum and Natural Gas ,[object Object],[object Object]
Petroleum and Natural Gas
Petroleum and Natural Gas ,[object Object]
Petroleum and Natural Gas ,[object Object]
Coal ,[object Object]
Coal ,[object Object]
Coal
Coal ,[object Object]
Coal Mining
Coal Mining
Early Strip Mining
Strip Mining Coal
Coal Plant
Coal Acid Mine Drainage (AMD)
Coal Slurry
CO 2 and Climate ,[object Object]
CO 2 and Climate ,[object Object]
CO 2 and Climate
CO 2 and Climate ,[object Object]
CO 2 and Climate ,[object Object]
CO 2 and Climate ,[object Object]
CO 2 and Climate ,[object Object]
New Energy Sources 6.6
New Energy Sources ,[object Object]
Coal Conversion ,[object Object]
Coal Conversion ,[object Object]
Coal Conversion
Coal Conversion ,[object Object]
Coal Conversion ,[object Object]
Coal Conversion ,[object Object]
Hydrogen as a Fuel ,[object Object]
Hydrogen as a Fuel ,[object Object]
Hydrogen as a Fuel ,[object Object]
Hydrogen as a Fuel ,[object Object]
Hydrogen as a Fuel ,[object Object]
Hydrogen as a Fuel ,[object Object]
Hydrogen as a Fuel ,[object Object]
Hydrogen as a Fuel ,[object Object]
Hydrogen as a Fuel ,[object Object]
Hydrogen as a Fuel ,[object Object]
Hydrogen as a Fuel ,[object Object]
Hydrogen as a Fuel ,[object Object]
Hydrogen as a Fuel ,[object Object]
Hydrogen as a Fuel ,[object Object]
Hydrogen as a Fuel ,[object Object],[object Object]
Other Energy Alternatives ,[object Object]
Other Energy Alternatives ,[object Object]
Other Energy Alternatives ,[object Object]
This Promotion Bus Both Advertises Biodiesel and Demonstrates its Usefulness
Other Energy Alternatives ,[object Object]
THE END

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