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POLARIZATION OF LIGHT
by Dr. Vishal Jain
Geetanjali Institute of Technical Studies, Udaipur
Polarization of Light:- The phenomena is which vibration of electric
field vector of light are confined is a definite direction by any mean is known as
polarization of light and this type of light is called polarized light
Or
“The process of transfer unpolarized light into polarized light is called
polarization”
Light is a transverse wave,
an electromagnetic wave
Demonstration of polarized light
Elliptical polarization means the electric field vector is
rotating in a plane perpendicular to the direction of
propagation as it travels. Also the magnitude of the electric
field vector changes as it rotates
Circular polarization means the electric field vector
rotates as it travels but the magnitude of electric field
vector remains constant.
Plane of polarization/Plane of vibration
Malus’s Law
Double refraction, also called birefringence, an optical property in
which a single ray of unpolarized light entering an anisotropic medium
is split into two rays, each traveling in a different direction. One ray
(called the extraordinary ray) is bent, or refracted, at an angle as it
travels through the medium; the other ray (called the ordinary ray)
passes through the medium unchanged
Calcite crystal also known as Iceland
spar, chemically known as Calcium
Carbonate CaCo3 that have
rhombohedra structure
The calcite crystal and quartz crystal has an
important characteristic i.e. there is only one
direction through the calcite crystal along which
no double refraction take place. This particular
axis is called optic axis. ADGF
A doubly refracting uniaxial crystal plate of uniform thickness having
refracting surface parallel to direction of optic axis and capable of producing
a definite phase difference between the ordinary and the extraordinary ray,is
called phase retardation plate.
Incident ray
Emergent
Light
Phase
Retardation
Plate
Direction of
Optic axis
In calcite crystal the velocity of E-
ray VE is greater than that of O-ray
VO so that the difference in time
taken by these waves to cross the
plate of thickness d can be given
as
eo ttt  --------------eq 1
Here tO and tE ate the time taken by O-ray and E-ray
E
e
O
o
V
d
t
V
d
t  , --------------eq 2
Putting the values in equation 1
EO V
d
V
d
t  --------------eq 3
So that the path difference occurs between E-ray and O-ray on passing the
plate thickness d can be given as













EOEO V
c
V
c
d
V
d
V
d
ctc --------------eq 4
Since
E
E
O
O
V
c
V
c
  , --------------eq 5
)( EOd   --------------eq 6
Here µ and μ are the refractive indices of calcite crystal plate for O-ray and E-
ray respectively and Δ is the path difference Hence the phase difference
between O-Ray and E-ray is given by
dEO )(
2
)(
2





  --------------eq 7
For quartz crystal (positive crystal E-ray velocity is higher then O-ray so the
path difference and phase difference given by
)( OEd  
dOE )(
2
)(
2





 
QUARTER WAVE PLATE
A doubly refracting uniaxial
crystal plate having refracting
faces parallel to the direction of
the optic axis, having a
thickness such as to create a path
difference of λ /4 or a phase
difference of π/2 between the O-
ray and the E-ray , is called
Quarter wave plate. For quarter
wave plate :
where λ is the wavelength of the
incident light.
4
)(

  OEd
)(4 OE
d




Q.W.P E.P.L
P.P.L
P.P.L
NOT
45°
45°
C.P.L
HAlF WAVE PLATE
A doubly refracting uniaxial
crystal plate having refracting
faces parallel to the direction of
the optic axis, having a
thickness such as to create a path
difference of λ /2 or a phase
difference of π between the O-
ray and the E-ray , is called half
wave plate. For quarter wave
plate :
where λ is the wavelength of the
incident light.
2
)(

  OEd
)(2 OE
d




Anti-clockwise clockwise
(c.p.l) H.W.P (c.p.l)
If a plane polarized light having an amplitude of Eo is incident on the
face of calcite plate making an angle θ with its optic axis
θ θ
Incident ray
Emergent Light
EPL, CPL and PPL
Depend on angle
and phase difference
Due to the double
refraction its amplitude
divided into two
components Eocosθ and
Eosinθ
Eo cosθ foe E-ray
Eo sinθ for O-ray
Let us assume Eocosθ is amplitude of
E-ray and Eosinθ amplitude of O-ray
Now let us assume incident ray is
represented by
wtEE
wtEE
wtEE
Oy
Ox
O
sinsin
)sin(cos
sin




 --------------eq 1
--------------eq 2
--------------eq 3
Here we put
bEyE
aExE
Oy
Ox




sin,
cos,
So eq 2 and 3 rewritten as
wtby
wtax
sin
)sin(

  --------------eq 4
--------------eq 5
2
2
2
1sin1cos
,sin
sincoscossin
b
y
wtwt
wt
b
y
wtwt
a
x


 
--------------eq 6
--------------eq 7






2
2
2
2
2
222
2
2
2
2
2
2
2
2
2
2
2
2
2
2
22
2
2
2
2
sincos
2
sincos
2
)sin(cos
sin1cos
2
cos
sin1cos
,
sin1cos
sin1cos




















ab
xy
b
y
a
x
ab
xy
b
y
a
x
b
y
ab
xy
b
y
a
x
b
y
b
y
a
x
sqauringby
b
y
b
y
a
x
b
y
b
y
a
x
--------------eq 8
--------------eq 9
--------------eq 10
Equation 10 represent an ellipse so the light
emerge from calcite crystal is generally elliptical
under certain condition it shows PPL, CPL
Special Cases
Case 1 :- PPL if the thickness of the wave plate is such that
)(,
0,0
0
2
2
2
2
2
2
x
a
b
y
b
y
a
x
b
y
a
x
b
y
a
x
ab
xy
b
y
a
x









(a) From δ= 0, 2π, 4π, 6π……..2nπ
eq 10 sinδ =0 and cosδ=1 So
(b) From δ= π, 3π, 5π……..(2n+1)π
eq 10 sinδ =0 and cosδ= -1 So
)(,
0,0
0
2
2
2
2
2
2
x
a
b
y
b
y
a
x
b
y
a
x
b
y
a
x
ab
xy
b
y
a
x









This represent a pair of straight line passing
through the origin and having positive slope
This represent a pair of straight line passing
through the origin and having negative slope
Case 2 :- EPL/CPL if the thickness of the wave plate is such that
(a) From δ= π/2, 3π/2, 5π/2……..(2n+1)π/2
eq 10 sinδ =1 and cosδ=0 So
This represent an ellipse so the emergent light
is elliptical
12
2
2
2

b
y
a
x
(b) If a=b it means
o
O
O
means
E
E
45
2/1sin
,2/1cos






This represent an
circle so the
emergent light
is circular
122
 yx
Optical Activity
When a plane polarized light is allowed to pas through certain substances, it is
found that the plane of polarization of the emergent light is not the same as that of
the incident light and it is rotated through a certain angle.
This property of rotating the plane of
polarization of the emergent light is
called optical activity or rotatory
polarization, substances showing such
property are known as optically active
substances.
Biot’s Law of Optical Rotation
l
C
2
/1  
Specific Rotation
Specific rotation ([S]) is a property of a compound. It is defined as the change in orientation of
plane polarized light per unit distance–concentration product, as the light passes through a
sample of a compound in solution.
For Solid:- At a constant temperature for PPL of definite wavelength the angle of rotation θ of
the plane of polarization is directly proportional to the length traversed by polarized light is the
solid.
For Liquid :- At a constant temperature for PPL of definite wavelength the angle of rotation θ
of the plane of polarization is directly proportional to the length traversed by polarized light is
the liquid of density d.
For Solution:- At a constant temperature for PPL of definite wavelength the angle of rotation θ
of the plane of polarization is directly proportional to the length traversed by polarized light is
the solutionof concentration c.
l
S
Sll



 ,
ld
S
Sldld



 ,
lc
S
Slclc



 ,
Lorentz Half Shade Polarimeter
It is used for the measurement of the angle of rotation of optically active substance in solution.
That is, angle through which the plane of the polarized light is rotated on passing through a
specific length of solution of known concentration.
Polarisation of light by Dr. Vishal Jain

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Polarisation of light by Dr. Vishal Jain

  • 1. POLARIZATION OF LIGHT by Dr. Vishal Jain Geetanjali Institute of Technical Studies, Udaipur
  • 2. Polarization of Light:- The phenomena is which vibration of electric field vector of light are confined is a definite direction by any mean is known as polarization of light and this type of light is called polarized light Or “The process of transfer unpolarized light into polarized light is called polarization” Light is a transverse wave, an electromagnetic wave
  • 4. Elliptical polarization means the electric field vector is rotating in a plane perpendicular to the direction of propagation as it travels. Also the magnitude of the electric field vector changes as it rotates
  • 5. Circular polarization means the electric field vector rotates as it travels but the magnitude of electric field vector remains constant.
  • 6.
  • 9. Double refraction, also called birefringence, an optical property in which a single ray of unpolarized light entering an anisotropic medium is split into two rays, each traveling in a different direction. One ray (called the extraordinary ray) is bent, or refracted, at an angle as it travels through the medium; the other ray (called the ordinary ray) passes through the medium unchanged
  • 10. Calcite crystal also known as Iceland spar, chemically known as Calcium Carbonate CaCo3 that have rhombohedra structure The calcite crystal and quartz crystal has an important characteristic i.e. there is only one direction through the calcite crystal along which no double refraction take place. This particular axis is called optic axis. ADGF
  • 11. A doubly refracting uniaxial crystal plate of uniform thickness having refracting surface parallel to direction of optic axis and capable of producing a definite phase difference between the ordinary and the extraordinary ray,is called phase retardation plate. Incident ray Emergent Light Phase Retardation Plate Direction of Optic axis In calcite crystal the velocity of E- ray VE is greater than that of O-ray VO so that the difference in time taken by these waves to cross the plate of thickness d can be given as eo ttt  --------------eq 1 Here tO and tE ate the time taken by O-ray and E-ray E e O o V d t V d t  , --------------eq 2
  • 12. Putting the values in equation 1 EO V d V d t  --------------eq 3 So that the path difference occurs between E-ray and O-ray on passing the plate thickness d can be given as              EOEO V c V c d V d V d ctc --------------eq 4 Since E E O O V c V c   , --------------eq 5 )( EOd   --------------eq 6 Here µ and μ are the refractive indices of calcite crystal plate for O-ray and E- ray respectively and Δ is the path difference Hence the phase difference between O-Ray and E-ray is given by dEO )( 2 )( 2        --------------eq 7 For quartz crystal (positive crystal E-ray velocity is higher then O-ray so the path difference and phase difference given by )( OEd   dOE )( 2 )( 2       
  • 13. QUARTER WAVE PLATE A doubly refracting uniaxial crystal plate having refracting faces parallel to the direction of the optic axis, having a thickness such as to create a path difference of λ /4 or a phase difference of π/2 between the O- ray and the E-ray , is called Quarter wave plate. For quarter wave plate : where λ is the wavelength of the incident light. 4 )(    OEd )(4 OE d     Q.W.P E.P.L P.P.L P.P.L NOT 45° 45° C.P.L
  • 14. HAlF WAVE PLATE A doubly refracting uniaxial crystal plate having refracting faces parallel to the direction of the optic axis, having a thickness such as to create a path difference of λ /2 or a phase difference of π between the O- ray and the E-ray , is called half wave plate. For quarter wave plate : where λ is the wavelength of the incident light. 2 )(    OEd )(2 OE d     Anti-clockwise clockwise (c.p.l) H.W.P (c.p.l)
  • 15. If a plane polarized light having an amplitude of Eo is incident on the face of calcite plate making an angle θ with its optic axis θ θ Incident ray Emergent Light EPL, CPL and PPL Depend on angle and phase difference Due to the double refraction its amplitude divided into two components Eocosθ and Eosinθ Eo cosθ foe E-ray Eo sinθ for O-ray Let us assume Eocosθ is amplitude of E-ray and Eosinθ amplitude of O-ray Now let us assume incident ray is represented by wtEE wtEE wtEE Oy Ox O sinsin )sin(cos sin      --------------eq 1 --------------eq 2 --------------eq 3
  • 16. Here we put bEyE aExE Oy Ox     sin, cos, So eq 2 and 3 rewritten as wtby wtax sin )sin(    --------------eq 4 --------------eq 5 2 2 2 1sin1cos ,sin sincoscossin b y wtwt wt b y wtwt a x     --------------eq 6 --------------eq 7       2 2 2 2 2 222 2 2 2 2 2 2 2 2 2 2 2 2 2 2 22 2 2 2 2 sincos 2 sincos 2 )sin(cos sin1cos 2 cos sin1cos , sin1cos sin1cos                     ab xy b y a x ab xy b y a x b y ab xy b y a x b y b y a x sqauringby b y b y a x b y b y a x --------------eq 8 --------------eq 9 --------------eq 10 Equation 10 represent an ellipse so the light emerge from calcite crystal is generally elliptical under certain condition it shows PPL, CPL
  • 17. Special Cases Case 1 :- PPL if the thickness of the wave plate is such that )(, 0,0 0 2 2 2 2 2 2 x a b y b y a x b y a x b y a x ab xy b y a x          (a) From δ= 0, 2π, 4π, 6π……..2nπ eq 10 sinδ =0 and cosδ=1 So (b) From δ= π, 3π, 5π……..(2n+1)π eq 10 sinδ =0 and cosδ= -1 So )(, 0,0 0 2 2 2 2 2 2 x a b y b y a x b y a x b y a x ab xy b y a x          This represent a pair of straight line passing through the origin and having positive slope This represent a pair of straight line passing through the origin and having negative slope Case 2 :- EPL/CPL if the thickness of the wave plate is such that (a) From δ= π/2, 3π/2, 5π/2……..(2n+1)π/2 eq 10 sinδ =1 and cosδ=0 So This represent an ellipse so the emergent light is elliptical 12 2 2 2  b y a x (b) If a=b it means o O O means E E 45 2/1sin ,2/1cos       This represent an circle so the emergent light is circular 122  yx
  • 18.
  • 19. Optical Activity When a plane polarized light is allowed to pas through certain substances, it is found that the plane of polarization of the emergent light is not the same as that of the incident light and it is rotated through a certain angle. This property of rotating the plane of polarization of the emergent light is called optical activity or rotatory polarization, substances showing such property are known as optically active substances.
  • 20.
  • 21. Biot’s Law of Optical Rotation l C 2 /1  
  • 22. Specific Rotation Specific rotation ([S]) is a property of a compound. It is defined as the change in orientation of plane polarized light per unit distance–concentration product, as the light passes through a sample of a compound in solution. For Solid:- At a constant temperature for PPL of definite wavelength the angle of rotation θ of the plane of polarization is directly proportional to the length traversed by polarized light is the solid. For Liquid :- At a constant temperature for PPL of definite wavelength the angle of rotation θ of the plane of polarization is directly proportional to the length traversed by polarized light is the liquid of density d. For Solution:- At a constant temperature for PPL of definite wavelength the angle of rotation θ of the plane of polarization is directly proportional to the length traversed by polarized light is the solutionof concentration c. l S Sll     , ld S Sldld     , lc S Slclc     ,
  • 23. Lorentz Half Shade Polarimeter It is used for the measurement of the angle of rotation of optically active substance in solution. That is, angle through which the plane of the polarized light is rotated on passing through a specific length of solution of known concentration.