Sun Power help against the world climate change

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Alumni Meeting "Landscapes under the influence of growing climate variability – risks, vulnerability and resilience" organized by ITT in Viña del Mar 2008, Chile

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Sun Power help against the world climate change

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Automatizacion de un proceso de Reciclaje, mediante Robot KUKA y elementos FESTO

Elías Urrejola

In the photovoltaic industry both the reduction of the silicon material thickness and the increase of the solar cells efficiency are critical topics for optimizing cost reduction. This work presents an innovative and industrially applicable Si-based passivation layer deposited by PECVD, with high passivation quality for the un-doped p-type rear surface of PERC solar cells. Avoiding an extra thermal oxidation step, the PERC process as presented as follows, might be completely feasible for industrial applications. We achieved efficiencies of 19% on monocrystalline p-type Cz-Si and above 17.2% on multicrystalline p-type wafers. The processing of the wafers is developed at a standard industrial level, and no special equipment or processing was required for achieving this efficiencies.

HIGH EFFICIENCY INDUSTRIAL PERC SOLAR CELLS WITH ALL PECVD-BASED REAR SURFACE...

Elías Urrejola

in order to further improve the efficiency of multicrystalline solar cells, both a dielectric passivation and local contact formation at the rear are important design contributions. The dielectric passivation presents many advantages compared to the standard fully covered Al back contact. Our work is centred in the analysis of the contact formation between Al and Si for the passivated emitter and rear cell device structure, PERC. We give an experimental explanation for the observed dependence of the contact resistivity of Al fingers on the Si-contact area. Our observation is based on the analysis of the geometry of the Al-Si alloy formation below the contacts, giving important conclusions for PERC solar cells. Scanning electron microscopy (SEM) and energy dispersive X-ray spectrometry (EDS/EDX) supports the analysis of the Al-Si alloy geometry, giving an understanding of its formation, and effect on the contact resistivity.

INFLUENCE OF THE AL-SI ALLOY FORMATION IN NARROW DIELECTRIC BARRIER OPE...

Elías Urrejola

We present a study on the formation of voids normally originated instead of an Al-Si eutectic alloy on rear passivated solar cells with local rear contacts, using standard screen-printed aluminum pastes. In previous works, we explain the formation of these voids due to the difference between the diffusivity of aluminum and silicon1, showing that the geometry of the rear pattern (contact spacing and contact size) strongly influences their formation2. In the present work, we found that the gravity field orientation can strongly vary the microstructure of Al-Si forming alloy. We show that the voids may partially be avoided by sintering the samples with the solid/liquid (S/L) interface, n, oriented opposite to the direction of the gravity field, g. A deeper p+-doped silicon region (known as local BSF) has been found underneath the voids using this approach. This phenomenon strongly applies to rear passivated solar cells, which have exhibited strong FF losses.

Understanding and avoiding the formation of voids for rear passivated silicon...

Elías Urrejola

Solar cell concepts with passivated, locally contacted rear side have gained much interest over the last years due to the development of advanced passivation techniques. However, there are still open questions regarding the understanding of the local Al-Si contact formation and its influence on the local back-surface-field formation for industrial screen-printed aluminum pastes. In this work we show that the geometry of the rear pattern (contact size and contact spacing) strongly influences the Al-Si interaction in the local contact openings: Si diffuses in Al through narrow dielectric barrier openings and spreads laterally to a determined limit determined by the firing temperature. We found that the contact spacing can affect the tendency for formation of Kirkendall voids below the Al-Si contacts instead of an eutectic layer. When decreasing the contact spacing and therefore the overlap of Al on each side of the local opening, the melt saturates faster and the formation of a high-quality local back-surface-field is increased, minimizing the presence of voids. This physical observation can enhance the design of the rear pattern for rear passivated solar cells and gives further understanding of the Al-Si interaction during the firing process.

Distribution of Silicon iin the Allumiinum Matriix for Rear Passiivated Solla...

Elías Urrejola

Solar cells with dielectrically passivated rear side and screen printed local rear contacts combine the high performance potential of the PERC (passivated emitter and rear) concept with the well-established metallization method of nowaday’s industrial solar cells. This article presents a specific analysis of the formation of such localized screen printed Al-Si contacts. We observe that the contact resistivity depends on the width of the contact openings, and decreases when reducing the contact area. The optimal contact formation is observed for lateral contact widths smaller than 50–80 μm. Analysis of the Al-Si alloy formation by scanning electron microscopy (SEM) and energy dispersive X-ray spectrometry (EDS/EDX) analysis shows that the alloy formation below the contacts is more homogeneous in such small openings than in larger ones.

Al-Si alloy formation in narrow p-Si contact areas

Elías Urrejola

We present an innovative process for the formation of a selective emitter by using an advanced phosphorous glass as a barrier layer against subsequent diffusion. The advanced barrier glass was achieved by the formation of a standard phosphorous glass treated with additional thermal oxidation immediately after deposition in the same process tube. The resistant layer is used as a barrier for the second diffusion after selective opening of the finger contact areas by screen printing of a SiO2 etching paste. The process was applied for multicrystalline Elkem Solar SoG-Si wafers as well as for references from standard EG-Si. The achieved cell parameters were compared with cell results from a homogenous emitter process. While the efficiency was not enhanced so far due to the relatively high shadow loss of the selective emitter solar cells, the open collector voltage could be increased by up to 9 mV and the short wavelength spectral response increased slightly with this selective emitter. The aim of this work was to combine the SiO2 barrier with the shallow POCl3 diffusion in one process step and the optimization of the screen printing process for selective emitter solar cells.

Poster presentation at 24th EUPVSEC, HAMBURG (2009)

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