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Repair of esthetic restorations
10/21/2019
Dr.Sherif sultan,BDS,MSc,PhD,Fixed
prosthodontics
1
Indications
1. When the extent of the fracture
does not recommend the
replacement of the restoration.
2. To conserve tooth structure,
cost and time.
10/21/2019
Dr.Sherif sultan,BDS,MSc,PhD,Fixed
prosthodontics
2
Advantages
• Restores function and esthetic in an easy,
inexpensive and rapid form.
• Removes pain and discomfort associated with
replacement of fractured prosthesis.
10/21/2019
Dr.Sherif sultan,BDS,MSc,PhD,Fixed
prosthodontics
3
Causes of fracture of porcelain
intraorally.
• Contamination and other errors in fabrication(Improper
design, micro defects within the material.);
• Incorrect treatment planning with inappropriate use of the
material, notably in relation to the occlusion, and failure to
create sufficient space for the restoration.
• Incompatible thermal expansion coefficient between the
porcelain and metal substructure.
• Seating force during insertion.
• Trauma.
10/21/2019
Dr.Sherif sultan,BDS,MSc,PhD,Fixed
prosthodontics
4
Techniques for repair
1- The direct technique (intra oral).
• It is done by the use of what is commercially known as porcelain
repair kits (e.g- Ultradent R Porcelain Repair Kit , Ceram-Etch kit and
Co jet porcelain repair kit).
• The porcelain repair kit mainly contains a surface treatment
material , coupling agent ,bonding agent and then composite is
applied directly to the fractured restoration.
• Advantages
• Less chair time, lower cost, and ease of application.
• Disadvantages.
• Low strength, poor wear qualities.
• Poor esthetic appearance due to lack of translucency or shade-
matching to the remaining teeth.
• Long-term success especially in load bearing surfaces is
unpredictable.
10/21/2019
Dr.Sherif sultan,BDS,MSc,PhD,Fixed
prosthodontics
5
2. Indirect technique (extra oral or laboratory).
• Porcelain is applied as a laboratory procedure.
• Advantages.
1.Better esthetics due to match between repair
porcelain and remaining porcelain.
2.High wear resistance.
Disadvantages
cost and time
10/21/2019
Dr.Sherif sultan,BDS,MSc,PhD,Fixed
prosthodontics
6
Repair of PFM restorations
1.Indirect repair.
• 2 techniques:-
• A- PFM overcastting.
• -used to repair fractured pontics.
10/21/2019
Dr.Sherif sultan,BDS,MSc,PhD,Fixed
prosthodontics
7
• Steps:-
• remove porcelain from the pontic using
carbide burs to provide adequate space for
the metal overcastting, opaque material and
porcelain.
• Impression.
• Make overcastting which should be rigid and
thin using non precious alloy.
• Apply porcelain to the over casting, which is
then tried intraorally, stained and glazed.
• Cement the PFM overcastting.
10/21/2019
Dr.Sherif sultan,BDS,MSc,PhD,Fixed
prosthodontics
8
B. PFM pin retained casting.
- Used in case of fractured porcelain facing
(porcelain on labial surface only).
- All porcelain is removed and a feather edge
margin is created along the entire labial surface of
the metal framework.
- Make parallel tapered pinholes using tapered
fissure bur.
- Make rubber base impression.
- Fabricate pin retained PFM restoration.
10/21/2019
Dr.Sherif sultan,BDS,MSc,PhD,Fixed
prosthodontics
9
2- Direct repair.
• Traditionally relied on mechanical
roughening of the fractured surface, followed
by application of a silane coupling agent to
enhance the resin -to-porcelain bond.
• Since direct repair of fractured PFM
restoration is made by resin composite, we
should know the nature of bond between
resins and (metals or ceramics.)
10/21/2019
Dr.Sherif sultan,BDS,MSc,PhD,Fixed
prosthodontics
10
Resin to metal bond
• In order to improve the bond between the metal and the resin a number of
different approaches have been explored.
1- Macro mechanical bonding.
• It depends on macroscopic features in the metal framework to give retention
to the resin (e.g:- roughening with a diamond or making undercuts).
2- Micro mechanical bonding (electrolytic etching of metal with hydrofluoric
acid).
This technique is only applicable to Ni- Cr or Co-Cr alloys, which have a
eutectic(multiphase) microstructure
10/21/2019
Dr.Sherif sultan,BDS,MSc,PhD,Fixed
prosthodontics
11
3- Chemical modification of the alloy surface.
A. Tin plating
10/21/2019
Dr.Sherif sultan,BDS,MSc,PhD,Fixed
prosthodontics
12
Intraoral tin plating. A, Tin-plating system in which direct current is used to
deposit tin from an amide solution (Micro- Tin Materilas). B, The system in
use intraorally. Note the gray color change. The tin is being deposited from
the solution and carried to the metal in the cotton pledget affixed to one
electrode of the plater; the circuit is completed with the alligator clip, which
is in electrical contact with the prosthesis.
10/21/2019
Dr.Sherif sultan,BDS,MSc,PhD,Fixed
prosthodontics
13
B. Tribochemical silicoating(Co jet
system)
10/21/2019
Dr.Sherif sultan,BDS,MSc,PhD,Fixed
prosthodontics
14
C. Metal Primers
• They are usually supplied as single-liquid primers
composed of a polymerisable monomer in a suitable
solvent. (The products are invariably called primers
despite them being in fact coupling agents.)
• The monomer has a bifunctional structure with one
end carrying a methacrylate group for resin bonding
and the other end carrying mercapto or thiol (-SH)
groups for bonding to the precious metal alloy.
10/21/2019
Dr.Sherif sultan,BDS,MSc,PhD,Fixed
prosthodontics
15
4- chemically adhesive resins.
• In order to improve the adhesive bond of
resins to the metal surface, a variety of dual-
cure composite resins have been developed in
which the resin component has been modified
to provide the ability to bond chemically to
suitably prepared metal surfaces. These resins
are generally referred to as chemically
adhesive resins to differentiate them from the
simple Bis-GMA type resins.
10/21/2019
Dr.Sherif sultan,BDS,MSc,PhD,Fixed
prosthodontics
16
• Examples
1. C&B Metabond (Parkell, Farmingdale, NY), in which the active
constituent is the carboxylic monomer 4-META (4-methacryloxy-
ethyl trimellitate anhydride), which has been demonstrated to
adhere to all types of metal alloys as well.
2. Panavia 21 resin cement (Kuraray Co, Osaka, Japan). In which
the active ingredient is a phosphorylated methacrylate monomer
such as MDP (methacryloxyethyl-phenyl phosphate).
Resin bonding is facilitated by the high affinity of
carboxylic acid or phosphoric acid derivative
containing resins for the metal oxide on the base
metal alloy.
10/21/2019
Dr.Sherif sultan,BDS,MSc,PhD,Fixed
prosthodontics
17
Resin-to-ceramic bond
• The resin-to-ceramic bond is based on an acid
etchant creating a micromechanically retentive
surface and a coupling agent providing the
chemical bond to the ceramic.
10/21/2019
Dr.Sherif sultan,BDS,MSc,PhD,Fixed
prosthodontics
18
-Hydrofluoric-Acid Etching.
• -concentrations :- 2.5-10%,liquid or gel form.
• -etching time :- 1-4 minutes.
• -Mechanism of action:- attacks the glass phase of
ceramic leaving a honeycomb – like surface.( This
process is generated by the preferential chemical
reaction between hydrofluoric acid and the silica phase
of feldspathic ceramics forming a salt named
hexafluorosilicate, which is removed by water spray.)
10/21/2019
Dr.Sherif sultan,BDS,MSc,PhD,Fixed
prosthodontics
19
-Silane coupling agents.
• Organo-silanes, generally referred to simply as
“silanes” in dentistry, are compounds that contain
a silicon (Si) atom or atoms, and display dual
reactivity. One end of a silane molecule is
organically functional (e.g.,vinyl–CH CH2,amino–
NH2),and can polymerize with an organic matrix
(e.g.,a methacrylate) in the composite.The other
end is generally comprised of alkoxy groups
(e.g.,methoxy–OCH3,ethoxy OCH2CH3), which
can react with a hydroxylated surface, like
porcelain.
10/21/2019
Dr.Sherif sultan,BDS,MSc,PhD,Fixed
prosthodontics
20
CONCLUSION
• N.B:-In general direct repair of PFM
restorations includes:-
• When metal infrastructure exposed,
sandblasting with alumina or alumina
modified with silicic acid+ silane+ adhesive
resin+ composite.
• When fracture is adhesive in porcelain only,
etching with hydrofluoric acid+ silane+
adhesive resin+ composite.
10/21/2019
Dr.Sherif sultan,BDS,MSc,PhD,Fixed
prosthodontics
21
Direct repair of all ceramic
restorations.
1- Repair of silica based ceramics
• In general it involves:- etching with hydrofluoric acid+
silane+ adhesive resin+ composite.
2- Repair of zirconia ceramics (non silica based ceramics).
• All-ceramic systems, in particular when used for bridges,
have mostly a two-layer structure consisting of a high
strength ceramic substructure core and a weaker
veneering ceramic layer.
• -Core fracture
It is rare because of high strength, if occur replace the
restoration.
10/21/2019
Dr.Sherif sultan,BDS,MSc,PhD,Fixed
prosthodontics
22
-Veneer fracture.
• If the fracture is in the veneer only make etching
then silane then bonding agent then composite.
• If the core is exposed it may be etachable (contains
silica) then make the same steps
• If the core is not etchable as zirconia , it will be a
problem. As most of zirconia is not etchable
10/21/2019
Dr.Sherif sultan,BDS,MSc,PhD,Fixed
prosthodontics
23
-Problems in repair of zirconia.
• 1- Zirconia is not readily etched by HF, and
requires very aggressive mechanical abrasion
methods to increase surface roughness, possibly
creating strength reducing surface flaws,
Therefore, alternate surface treatment methods
are required for zirconia ceramics.
• 2-The lack of silica also removes the chemical
bonding between silica–silane necessary for
silanization. But this problem was solved by
tribochemical silica coating mentioned previously
which can be applied also to zirconia.
10/21/2019
Dr.Sherif sultan,BDS,MSc,PhD,Fixed
prosthodontics
24
Novel surface treatment methods of
zirconia.
1. Glass micro pearls.
2. Selective infiltration etching (SIE).
3. Laser irradiation.
4. Nanostructured alumina coating.
5. Internal coating with porcelain.
6. Pyrosil pen technology (SurA Instruments,Jena,
Germany).e.g:- Silano pen.
10/21/2019
Dr.Sherif sultan,BDS,MSc,PhD,Fixed
prosthodontics
25
The most important thing before doing
repair
• is TO REMOVE THE CAUSE OF
FRACTURE AND TO TELL THE
PATIENT THAT REPLACEMENT
IS BETTER THAN REPAIR.
10/21/2019
Dr.Sherif sultan,BDS,MSc,PhD,Fixed
prosthodontics
26

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Repair of esthetic restorations [autosaved]

  • 1. Repair of esthetic restorations 10/21/2019 Dr.Sherif sultan,BDS,MSc,PhD,Fixed prosthodontics 1
  • 2. Indications 1. When the extent of the fracture does not recommend the replacement of the restoration. 2. To conserve tooth structure, cost and time. 10/21/2019 Dr.Sherif sultan,BDS,MSc,PhD,Fixed prosthodontics 2
  • 3. Advantages • Restores function and esthetic in an easy, inexpensive and rapid form. • Removes pain and discomfort associated with replacement of fractured prosthesis. 10/21/2019 Dr.Sherif sultan,BDS,MSc,PhD,Fixed prosthodontics 3
  • 4. Causes of fracture of porcelain intraorally. • Contamination and other errors in fabrication(Improper design, micro defects within the material.); • Incorrect treatment planning with inappropriate use of the material, notably in relation to the occlusion, and failure to create sufficient space for the restoration. • Incompatible thermal expansion coefficient between the porcelain and metal substructure. • Seating force during insertion. • Trauma. 10/21/2019 Dr.Sherif sultan,BDS,MSc,PhD,Fixed prosthodontics 4
  • 5. Techniques for repair 1- The direct technique (intra oral). • It is done by the use of what is commercially known as porcelain repair kits (e.g- Ultradent R Porcelain Repair Kit , Ceram-Etch kit and Co jet porcelain repair kit). • The porcelain repair kit mainly contains a surface treatment material , coupling agent ,bonding agent and then composite is applied directly to the fractured restoration. • Advantages • Less chair time, lower cost, and ease of application. • Disadvantages. • Low strength, poor wear qualities. • Poor esthetic appearance due to lack of translucency or shade- matching to the remaining teeth. • Long-term success especially in load bearing surfaces is unpredictable. 10/21/2019 Dr.Sherif sultan,BDS,MSc,PhD,Fixed prosthodontics 5
  • 6. 2. Indirect technique (extra oral or laboratory). • Porcelain is applied as a laboratory procedure. • Advantages. 1.Better esthetics due to match between repair porcelain and remaining porcelain. 2.High wear resistance. Disadvantages cost and time 10/21/2019 Dr.Sherif sultan,BDS,MSc,PhD,Fixed prosthodontics 6
  • 7. Repair of PFM restorations 1.Indirect repair. • 2 techniques:- • A- PFM overcastting. • -used to repair fractured pontics. 10/21/2019 Dr.Sherif sultan,BDS,MSc,PhD,Fixed prosthodontics 7
  • 8. • Steps:- • remove porcelain from the pontic using carbide burs to provide adequate space for the metal overcastting, opaque material and porcelain. • Impression. • Make overcastting which should be rigid and thin using non precious alloy. • Apply porcelain to the over casting, which is then tried intraorally, stained and glazed. • Cement the PFM overcastting. 10/21/2019 Dr.Sherif sultan,BDS,MSc,PhD,Fixed prosthodontics 8
  • 9. B. PFM pin retained casting. - Used in case of fractured porcelain facing (porcelain on labial surface only). - All porcelain is removed and a feather edge margin is created along the entire labial surface of the metal framework. - Make parallel tapered pinholes using tapered fissure bur. - Make rubber base impression. - Fabricate pin retained PFM restoration. 10/21/2019 Dr.Sherif sultan,BDS,MSc,PhD,Fixed prosthodontics 9
  • 10. 2- Direct repair. • Traditionally relied on mechanical roughening of the fractured surface, followed by application of a silane coupling agent to enhance the resin -to-porcelain bond. • Since direct repair of fractured PFM restoration is made by resin composite, we should know the nature of bond between resins and (metals or ceramics.) 10/21/2019 Dr.Sherif sultan,BDS,MSc,PhD,Fixed prosthodontics 10
  • 11. Resin to metal bond • In order to improve the bond between the metal and the resin a number of different approaches have been explored. 1- Macro mechanical bonding. • It depends on macroscopic features in the metal framework to give retention to the resin (e.g:- roughening with a diamond or making undercuts). 2- Micro mechanical bonding (electrolytic etching of metal with hydrofluoric acid). This technique is only applicable to Ni- Cr or Co-Cr alloys, which have a eutectic(multiphase) microstructure 10/21/2019 Dr.Sherif sultan,BDS,MSc,PhD,Fixed prosthodontics 11
  • 12. 3- Chemical modification of the alloy surface. A. Tin plating 10/21/2019 Dr.Sherif sultan,BDS,MSc,PhD,Fixed prosthodontics 12
  • 13. Intraoral tin plating. A, Tin-plating system in which direct current is used to deposit tin from an amide solution (Micro- Tin Materilas). B, The system in use intraorally. Note the gray color change. The tin is being deposited from the solution and carried to the metal in the cotton pledget affixed to one electrode of the plater; the circuit is completed with the alligator clip, which is in electrical contact with the prosthesis. 10/21/2019 Dr.Sherif sultan,BDS,MSc,PhD,Fixed prosthodontics 13
  • 14. B. Tribochemical silicoating(Co jet system) 10/21/2019 Dr.Sherif sultan,BDS,MSc,PhD,Fixed prosthodontics 14
  • 15. C. Metal Primers • They are usually supplied as single-liquid primers composed of a polymerisable monomer in a suitable solvent. (The products are invariably called primers despite them being in fact coupling agents.) • The monomer has a bifunctional structure with one end carrying a methacrylate group for resin bonding and the other end carrying mercapto or thiol (-SH) groups for bonding to the precious metal alloy. 10/21/2019 Dr.Sherif sultan,BDS,MSc,PhD,Fixed prosthodontics 15
  • 16. 4- chemically adhesive resins. • In order to improve the adhesive bond of resins to the metal surface, a variety of dual- cure composite resins have been developed in which the resin component has been modified to provide the ability to bond chemically to suitably prepared metal surfaces. These resins are generally referred to as chemically adhesive resins to differentiate them from the simple Bis-GMA type resins. 10/21/2019 Dr.Sherif sultan,BDS,MSc,PhD,Fixed prosthodontics 16
  • 17. • Examples 1. C&B Metabond (Parkell, Farmingdale, NY), in which the active constituent is the carboxylic monomer 4-META (4-methacryloxy- ethyl trimellitate anhydride), which has been demonstrated to adhere to all types of metal alloys as well. 2. Panavia 21 resin cement (Kuraray Co, Osaka, Japan). In which the active ingredient is a phosphorylated methacrylate monomer such as MDP (methacryloxyethyl-phenyl phosphate). Resin bonding is facilitated by the high affinity of carboxylic acid or phosphoric acid derivative containing resins for the metal oxide on the base metal alloy. 10/21/2019 Dr.Sherif sultan,BDS,MSc,PhD,Fixed prosthodontics 17
  • 18. Resin-to-ceramic bond • The resin-to-ceramic bond is based on an acid etchant creating a micromechanically retentive surface and a coupling agent providing the chemical bond to the ceramic. 10/21/2019 Dr.Sherif sultan,BDS,MSc,PhD,Fixed prosthodontics 18
  • 19. -Hydrofluoric-Acid Etching. • -concentrations :- 2.5-10%,liquid or gel form. • -etching time :- 1-4 minutes. • -Mechanism of action:- attacks the glass phase of ceramic leaving a honeycomb – like surface.( This process is generated by the preferential chemical reaction between hydrofluoric acid and the silica phase of feldspathic ceramics forming a salt named hexafluorosilicate, which is removed by water spray.) 10/21/2019 Dr.Sherif sultan,BDS,MSc,PhD,Fixed prosthodontics 19
  • 20. -Silane coupling agents. • Organo-silanes, generally referred to simply as “silanes” in dentistry, are compounds that contain a silicon (Si) atom or atoms, and display dual reactivity. One end of a silane molecule is organically functional (e.g.,vinyl–CH CH2,amino– NH2),and can polymerize with an organic matrix (e.g.,a methacrylate) in the composite.The other end is generally comprised of alkoxy groups (e.g.,methoxy–OCH3,ethoxy OCH2CH3), which can react with a hydroxylated surface, like porcelain. 10/21/2019 Dr.Sherif sultan,BDS,MSc,PhD,Fixed prosthodontics 20
  • 21. CONCLUSION • N.B:-In general direct repair of PFM restorations includes:- • When metal infrastructure exposed, sandblasting with alumina or alumina modified with silicic acid+ silane+ adhesive resin+ composite. • When fracture is adhesive in porcelain only, etching with hydrofluoric acid+ silane+ adhesive resin+ composite. 10/21/2019 Dr.Sherif sultan,BDS,MSc,PhD,Fixed prosthodontics 21
  • 22. Direct repair of all ceramic restorations. 1- Repair of silica based ceramics • In general it involves:- etching with hydrofluoric acid+ silane+ adhesive resin+ composite. 2- Repair of zirconia ceramics (non silica based ceramics). • All-ceramic systems, in particular when used for bridges, have mostly a two-layer structure consisting of a high strength ceramic substructure core and a weaker veneering ceramic layer. • -Core fracture It is rare because of high strength, if occur replace the restoration. 10/21/2019 Dr.Sherif sultan,BDS,MSc,PhD,Fixed prosthodontics 22
  • 23. -Veneer fracture. • If the fracture is in the veneer only make etching then silane then bonding agent then composite. • If the core is exposed it may be etachable (contains silica) then make the same steps • If the core is not etchable as zirconia , it will be a problem. As most of zirconia is not etchable 10/21/2019 Dr.Sherif sultan,BDS,MSc,PhD,Fixed prosthodontics 23
  • 24. -Problems in repair of zirconia. • 1- Zirconia is not readily etched by HF, and requires very aggressive mechanical abrasion methods to increase surface roughness, possibly creating strength reducing surface flaws, Therefore, alternate surface treatment methods are required for zirconia ceramics. • 2-The lack of silica also removes the chemical bonding between silica–silane necessary for silanization. But this problem was solved by tribochemical silica coating mentioned previously which can be applied also to zirconia. 10/21/2019 Dr.Sherif sultan,BDS,MSc,PhD,Fixed prosthodontics 24
  • 25. Novel surface treatment methods of zirconia. 1. Glass micro pearls. 2. Selective infiltration etching (SIE). 3. Laser irradiation. 4. Nanostructured alumina coating. 5. Internal coating with porcelain. 6. Pyrosil pen technology (SurA Instruments,Jena, Germany).e.g:- Silano pen. 10/21/2019 Dr.Sherif sultan,BDS,MSc,PhD,Fixed prosthodontics 25
  • 26. The most important thing before doing repair • is TO REMOVE THE CAUSE OF FRACTURE AND TO TELL THE PATIENT THAT REPLACEMENT IS BETTER THAN REPAIR. 10/21/2019 Dr.Sherif sultan,BDS,MSc,PhD,Fixed prosthodontics 26

Editor's Notes

  1. The etching process preferentially removes one of the phases, which results in a pitted and grooved surface appearance