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Technical Data Sheet
SPUR+* 1015LM
SPUR+* 1015LM
Description
SPUR + 1015LM prepolymer is a silylated polyurethane resin for manufacturing one-part , moisture-curing
sealants and adhesives. Plasticizer-free and of relatively low viscosity, it is an excellent base resin for low
modulus sealants in building and construction applications where good elastic recovery is required.
Key Features and Benefits
Broad formulation latitude
Easy application characteristics
Excellent adhesion to many surfaces without primer
High durability indoors and outdoors
Good water and chemical resistance
High elastic recovery
Long shelf life
Silane-terminated polyurethanes have become increasingly attractive to manufacturers of adhesives,
sealants and coatings. This high-performance hybrid technology is a result of the synergy between the
silane-curing mechanism and polyurethane backboneproperties.
Formulations based on SPUR+ prepolymers offer fast roomtemperature cure and good durability: the
sealants or adhesives are free of unreacted isocyanate, making for products that are less harmful to the
environment. Benefits also include freedom from bubbling during cure and a broadening of the formulation
latitude compared to conventional polyurethane technologies. SPUR+ prepolymers allow the formulator the
use of a wide variety of additives and adhesion promoters to meet performance needs, including:
Good elasticity and durability1.
Primerless adhesion to both organic and inorganic, porous and non-porous substrates2.
Superior chemical resistance, such as to automotive fluids (e.g. glycols, motor and transmission
fluids)
3.
Minimal shrinkage4.
Excellent weatherability5.
Immediate paintability6.
Non-staining of porous substrates7.
Candidate for clear adhesives8.
Lower VOC formulated products9.
Page 1 of 5
*SPUR+ is a trademark of Momentive Performance Materials Inc.
Typical Physical Properties
Appearance: Clear, viscous liquid
Viscosity cP @ 25°C ~ 50,000
Shelf Life >-12 months
Tensile Strength (N/mm2
) ~0.55
Elongation (%) ~320
100% Modulus (N/mm2
) ~0.24
Shore A Hardness ~17
(These figures are intended as guideline, not specifications)
Figure 1: Viscosity vs. Temperature
Patent Status
This technology is covered by, at the very least, Johnston US5990257A and EP0931800B1.
Nothing contained herein shall be construed to imply the nonexistence of any relevant patents or to
constitute a permission, inducement or recommendation to practice any invention covered by any patent,
without authority from the owner of the patent.
Product Safety, Handling and Storage
[1] Huang, M.W., Lacroix, C. and Waldman, B.A.; “A New Low Viscosity, Plasticizer Free SPUR+ Prepolymer”,
PU TECH 2005, New Delhi India; presented at A&SC fall convention 2005.
[2) Huang, M.W. and Handel, R.; “New Developments in Silylated Polyurethane Technology”; Adhesives, Age,
April 1999.
[3] Johnston, R.R. and Lehmann, P.; US 5,990,257.
[4] Landon, S.J., Dawkins, M.B., Waldman, B.A. and Johnston R.R.; “The Adhesion of Hydbrid Resins to
Plastic Substrates”; Adhesives Age, April 1997.
[5] Feng. T.M. and Waldman, B.A.; “Silylated Urethane Polymers Enhance Properties of Construction
Sealants”: Adhesives Age, April 1995.
SPUR+* 1015LM
Page 2 of 5
*SPUR+ is a trademark of Momentive Performance Materials Inc.
[6] Landon, S.J., Guillet, A. and Johnston, R.R.; “Silylated Urethane Polymers for Sealants”; European
Adhesives and Sealants; Dec. 1995.
Customers should review the latest Safety Data Sheet (SDS) and label for product safety information, safe
handling instructions, personal protective equipment if necessary, emergency service contact information,
and any special storage conditions required for safety. Momentive Performance Materials (MPM) maintains
an around-the-clock emergency service for its products. SDS are available at www.momentive.com or, upon
request, from any MPM representative. For product storage and handling procedures to maintain the product
quality within our stated specifications, please review Certificates of Analysis, which are available in the
Order Center. Use of other materials in conjunction with MPM products (for example, primers) may require
additional precautions. Please review and follow the safety information provided by the manufacturer of such
other materials.
Processing Recommendations
The following two generic sealant formulations with different silane adhesion promoters may be used to
demonstrate the properties and adhesion of the SPUR+ prepolymer:
Ingredients (wt%) Sealant A Sealant B
SPUR+ 1015LM prepolymer 23.1 22.9
Plasticizer (DIDP) 18.5 18.4
Moisture Scavenger (Silquest A-171* silane) 0.4 0.3
Calcium Carbonate 55.5 55.1
UV Stabilizers 0.5 0.5
Thixotropic Agent (SiO2) 0.2 1.1
Colorant (such as TiO2) 1.2 1.2
Adhesion Promoter (Silquest* A-1110 silane) 0.58 –
Adhesion Promoter (Silquest A-1120 silane) – 0.57
Catalyst (dibutylyin dilaurate) 0.05 0.03
The mechanical properties are measured after curing the sealant for 2 weeks at 23°C/50% relative humidity
and then tested according to ISO 37 or ASTM D 412 respectively for tensile strength and elongation, and ISO
868 or ASTM C 661 for hardness.
SPUR+ 1015LM Sealant Sealant A Sealant B
Test Methods ISO ASTM
Tensile Strength @ Break (N/mm2
) 2.16 1.48
Modulus @ 100% Extension (N/mm2
) 0.95 0.69
Elongation @ Break (%) 420 430
SPUR+* 1015LM
Page 3 of 5
*SPUR+ is a trademark of Momentive Performance Materials Inc.
Hardness Shore A 37.3 36
Tack Free Time (hr.) 1 3
(These figures are intended as guideline, not specifications)
Adhesion is measured after curing the sample species for 2 weeks at 23°C/50% relative humidity, and
tested according to ISO 8510-2 (dry adhesion) followed by water immersion for four days and one day at
room temperature according to ISO 10591 (wet adhesion). For Sealant B, the peel strength is measured
according to ASTM C 794 test method and tested soon after water immersion for seven days (wet adhesion).
Substrates† Sealant A Sealant B
Dry Adhesion(1)
(N/mm
2
/ %CF)
Wet Adhesion(2)
(N/mm
2
/ %CF)
Wet Adhesion(3)
(N/mm
2
/ %CF)
Aluminium 2.17/100%CF 3.01/100%CF 3.92/100%CF
Anodised Aluminium
(ALMg1) 5005A
2.06/100%CF 2.87/100%CF n.d.
Galvanized Steel
Dx51 D+Z275
2.81/100%CF 3.07/100%CF n.d.
Glass 3.00/100%CF 3.35/100%CF 3.21/100%CF
PVC (standard) 3.58/100%CF 4.16/100%CF 3.22/100%CF
PVC (Komadur ES) 4.70/100%CF n.d. n.d.
Polycarbonate
(Lexan 9030)
2.81/100%CF n.d. n.d.
ABS n.d n.d. 3.45/100%CF
Polystyrene n.d n.d. 3.85/100%CF
Concrete
(method 1 in ISO13640)
2.19/50%CF n.d. n.d.
Concrete
(method 2 in ISO13640)
1.59/30%CF n.d. n.d.
Concrete
(from US markets)
n.d. n.d. 3.9/25%CF (dry)
(These figures are intended as guideline, not specifications)
CF = cohesive failure
† Most of the testing substrates were kindly supplied by Rocholl Gmbh
(1) ISO 8510-2; (2) ISO 10591; (3) ASTM C-794
The results showed the SPUR+ 1015LM sealants provide balanced mechanical properties and excellent
adhesion to a wide range of substrates, both inorganic and organic. In addition to the abovementioned
advantages, this SPUR+ 1015LM prepolymer provides additional features of non-yellowing and improved
tack free and deep section cure performance. These performance advantages provide formulators with more
freedom to optimize their products for market needs.
Limitations
Customers must evaluate Momentive Performance Materials products and make their own determination as
SPUR+* 1015LM
Page 4 of 5
*SPUR+ is a trademark of Momentive Performance Materials Inc.
to fitness of use in their particular applications.
Contact Information
For product prices, availability, or order placement, contact our customer service at Momentive.com/contact
/customer-service
For literature and technical assistance, visit our website at: www.momentive.com
DISCLAIMER:
THE MATERIALS, PRODUCTS AND SERVICES OF MOMENTIVE PERFORMANCE MATERIALS INC. AND ITS
SUBSIDIARIES AND AFFILIATES (COLLECTIVELY “SUPPLIER”), ARE SOLD SUBJECT TO SUPPLIER’S
STANDARD CONDITIONS OF SALE, WHICH ARE INCLUDED IN THE APPLICABLE DISTRIBUTOR OR OTHER
SALES AGREEMENT, PRINTED ON THE BACK OF ORDER ACKNOWLEDGMENTS AND INVOICES, AND
AVAILABLE UPON REQUEST. ALTHOUGH ANY INFORMATION, RECOMMENDATIONS, OR ADVICE CONTAINED
HEREIN IS GIVEN IN GOOD FAITH, SUPPLIER MAKES NO WARRANTY OR GUARANTEE, EXPRESS OR
IMPLIED, (i) THAT THE RESULTS DESCRIBED HEREIN WILL BE OBTAINED UNDER END-USE CONDITIONS, OR
(ii) AS TO THE EFFECTIVENESS OR SAFETY OF ANY DESIGN INCORPORATING ITS PRODUCTS, MATERIALS,
SERVICES, RECOMMENDATIONS OR ADVICE. EXCEPT AS PROVIDED IN SUPPLIER’S STANDARD
CONDITIONS OF SALE, SUPPLIER AND ITS REPRESENTATIVES SHALL IN NO EVENT BE RESPONSIBLE FOR
ANY LOSS RESULTING FROM ANY USE OF ITS MATERIALS, PRODUCTS OR SERVICES DESCRIBED HEREIN.
Each user bears full responsibility for making its own determination as to the suitability of Supplier’s
materials, services, recommendations, or advice for its own particular use. Each user must identify and
perform all tests and analyses necessary to assure that its finished parts incorporating Supplier’s products,
materials, or services will be safe and suitable for use under end-use conditions. Nothing in this or any other
document, nor any oral recommendation or advice, shall be deemed to alter, vary, supersede, or waive any
provision of Supplier’s standard Conditions of Sale or this Disclaimer, unless any such modification is
specifically agreed to in a writing signed by Supplier. No statement contained herein concerning a possible
or suggested use of any material, product, service or design is intended, or should be construed, to grant
any license under any patent or other intellectual property right of Supplier covering such use or design, or as
a recommendation for the use of such material, product, service or design in the infringement of any patent
or other intellectual property right.
*SPUR+ is a trademark of Momentive Performance Materials Inc.
Momentive and the Momentive logo are trademarks of Momentive Performance Materials Inc.
SPUR+* 1015LM
Page 5 of 5HCD-10211 (Rev. 1/23/2016 11:14:44 AM)

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SPUR 1015+ LM.PDF

  • 1. Technical Data Sheet SPUR+* 1015LM SPUR+* 1015LM Description SPUR + 1015LM prepolymer is a silylated polyurethane resin for manufacturing one-part , moisture-curing sealants and adhesives. Plasticizer-free and of relatively low viscosity, it is an excellent base resin for low modulus sealants in building and construction applications where good elastic recovery is required. Key Features and Benefits Broad formulation latitude Easy application characteristics Excellent adhesion to many surfaces without primer High durability indoors and outdoors Good water and chemical resistance High elastic recovery Long shelf life Silane-terminated polyurethanes have become increasingly attractive to manufacturers of adhesives, sealants and coatings. This high-performance hybrid technology is a result of the synergy between the silane-curing mechanism and polyurethane backboneproperties. Formulations based on SPUR+ prepolymers offer fast roomtemperature cure and good durability: the sealants or adhesives are free of unreacted isocyanate, making for products that are less harmful to the environment. Benefits also include freedom from bubbling during cure and a broadening of the formulation latitude compared to conventional polyurethane technologies. SPUR+ prepolymers allow the formulator the use of a wide variety of additives and adhesion promoters to meet performance needs, including: Good elasticity and durability1. Primerless adhesion to both organic and inorganic, porous and non-porous substrates2. Superior chemical resistance, such as to automotive fluids (e.g. glycols, motor and transmission fluids) 3. Minimal shrinkage4. Excellent weatherability5. Immediate paintability6. Non-staining of porous substrates7. Candidate for clear adhesives8. Lower VOC formulated products9. Page 1 of 5 *SPUR+ is a trademark of Momentive Performance Materials Inc.
  • 2. Typical Physical Properties Appearance: Clear, viscous liquid Viscosity cP @ 25°C ~ 50,000 Shelf Life >-12 months Tensile Strength (N/mm2 ) ~0.55 Elongation (%) ~320 100% Modulus (N/mm2 ) ~0.24 Shore A Hardness ~17 (These figures are intended as guideline, not specifications) Figure 1: Viscosity vs. Temperature Patent Status This technology is covered by, at the very least, Johnston US5990257A and EP0931800B1. Nothing contained herein shall be construed to imply the nonexistence of any relevant patents or to constitute a permission, inducement or recommendation to practice any invention covered by any patent, without authority from the owner of the patent. Product Safety, Handling and Storage [1] Huang, M.W., Lacroix, C. and Waldman, B.A.; “A New Low Viscosity, Plasticizer Free SPUR+ Prepolymer”, PU TECH 2005, New Delhi India; presented at A&SC fall convention 2005. [2) Huang, M.W. and Handel, R.; “New Developments in Silylated Polyurethane Technology”; Adhesives, Age, April 1999. [3] Johnston, R.R. and Lehmann, P.; US 5,990,257. [4] Landon, S.J., Dawkins, M.B., Waldman, B.A. and Johnston R.R.; “The Adhesion of Hydbrid Resins to Plastic Substrates”; Adhesives Age, April 1997. [5] Feng. T.M. and Waldman, B.A.; “Silylated Urethane Polymers Enhance Properties of Construction Sealants”: Adhesives Age, April 1995. SPUR+* 1015LM Page 2 of 5 *SPUR+ is a trademark of Momentive Performance Materials Inc.
  • 3. [6] Landon, S.J., Guillet, A. and Johnston, R.R.; “Silylated Urethane Polymers for Sealants”; European Adhesives and Sealants; Dec. 1995. Customers should review the latest Safety Data Sheet (SDS) and label for product safety information, safe handling instructions, personal protective equipment if necessary, emergency service contact information, and any special storage conditions required for safety. Momentive Performance Materials (MPM) maintains an around-the-clock emergency service for its products. SDS are available at www.momentive.com or, upon request, from any MPM representative. For product storage and handling procedures to maintain the product quality within our stated specifications, please review Certificates of Analysis, which are available in the Order Center. Use of other materials in conjunction with MPM products (for example, primers) may require additional precautions. Please review and follow the safety information provided by the manufacturer of such other materials. Processing Recommendations The following two generic sealant formulations with different silane adhesion promoters may be used to demonstrate the properties and adhesion of the SPUR+ prepolymer: Ingredients (wt%) Sealant A Sealant B SPUR+ 1015LM prepolymer 23.1 22.9 Plasticizer (DIDP) 18.5 18.4 Moisture Scavenger (Silquest A-171* silane) 0.4 0.3 Calcium Carbonate 55.5 55.1 UV Stabilizers 0.5 0.5 Thixotropic Agent (SiO2) 0.2 1.1 Colorant (such as TiO2) 1.2 1.2 Adhesion Promoter (Silquest* A-1110 silane) 0.58 – Adhesion Promoter (Silquest A-1120 silane) – 0.57 Catalyst (dibutylyin dilaurate) 0.05 0.03 The mechanical properties are measured after curing the sealant for 2 weeks at 23°C/50% relative humidity and then tested according to ISO 37 or ASTM D 412 respectively for tensile strength and elongation, and ISO 868 or ASTM C 661 for hardness. SPUR+ 1015LM Sealant Sealant A Sealant B Test Methods ISO ASTM Tensile Strength @ Break (N/mm2 ) 2.16 1.48 Modulus @ 100% Extension (N/mm2 ) 0.95 0.69 Elongation @ Break (%) 420 430 SPUR+* 1015LM Page 3 of 5 *SPUR+ is a trademark of Momentive Performance Materials Inc.
  • 4. Hardness Shore A 37.3 36 Tack Free Time (hr.) 1 3 (These figures are intended as guideline, not specifications) Adhesion is measured after curing the sample species for 2 weeks at 23°C/50% relative humidity, and tested according to ISO 8510-2 (dry adhesion) followed by water immersion for four days and one day at room temperature according to ISO 10591 (wet adhesion). For Sealant B, the peel strength is measured according to ASTM C 794 test method and tested soon after water immersion for seven days (wet adhesion). Substrates† Sealant A Sealant B Dry Adhesion(1) (N/mm 2 / %CF) Wet Adhesion(2) (N/mm 2 / %CF) Wet Adhesion(3) (N/mm 2 / %CF) Aluminium 2.17/100%CF 3.01/100%CF 3.92/100%CF Anodised Aluminium (ALMg1) 5005A 2.06/100%CF 2.87/100%CF n.d. Galvanized Steel Dx51 D+Z275 2.81/100%CF 3.07/100%CF n.d. Glass 3.00/100%CF 3.35/100%CF 3.21/100%CF PVC (standard) 3.58/100%CF 4.16/100%CF 3.22/100%CF PVC (Komadur ES) 4.70/100%CF n.d. n.d. Polycarbonate (Lexan 9030) 2.81/100%CF n.d. n.d. ABS n.d n.d. 3.45/100%CF Polystyrene n.d n.d. 3.85/100%CF Concrete (method 1 in ISO13640) 2.19/50%CF n.d. n.d. Concrete (method 2 in ISO13640) 1.59/30%CF n.d. n.d. Concrete (from US markets) n.d. n.d. 3.9/25%CF (dry) (These figures are intended as guideline, not specifications) CF = cohesive failure † Most of the testing substrates were kindly supplied by Rocholl Gmbh (1) ISO 8510-2; (2) ISO 10591; (3) ASTM C-794 The results showed the SPUR+ 1015LM sealants provide balanced mechanical properties and excellent adhesion to a wide range of substrates, both inorganic and organic. In addition to the abovementioned advantages, this SPUR+ 1015LM prepolymer provides additional features of non-yellowing and improved tack free and deep section cure performance. These performance advantages provide formulators with more freedom to optimize their products for market needs. Limitations Customers must evaluate Momentive Performance Materials products and make their own determination as SPUR+* 1015LM Page 4 of 5 *SPUR+ is a trademark of Momentive Performance Materials Inc.
  • 5. to fitness of use in their particular applications. Contact Information For product prices, availability, or order placement, contact our customer service at Momentive.com/contact /customer-service For literature and technical assistance, visit our website at: www.momentive.com DISCLAIMER: THE MATERIALS, PRODUCTS AND SERVICES OF MOMENTIVE PERFORMANCE MATERIALS INC. AND ITS SUBSIDIARIES AND AFFILIATES (COLLECTIVELY “SUPPLIER”), ARE SOLD SUBJECT TO SUPPLIER’S STANDARD CONDITIONS OF SALE, WHICH ARE INCLUDED IN THE APPLICABLE DISTRIBUTOR OR OTHER SALES AGREEMENT, PRINTED ON THE BACK OF ORDER ACKNOWLEDGMENTS AND INVOICES, AND AVAILABLE UPON REQUEST. ALTHOUGH ANY INFORMATION, RECOMMENDATIONS, OR ADVICE CONTAINED HEREIN IS GIVEN IN GOOD FAITH, SUPPLIER MAKES NO WARRANTY OR GUARANTEE, EXPRESS OR IMPLIED, (i) THAT THE RESULTS DESCRIBED HEREIN WILL BE OBTAINED UNDER END-USE CONDITIONS, OR (ii) AS TO THE EFFECTIVENESS OR SAFETY OF ANY DESIGN INCORPORATING ITS PRODUCTS, MATERIALS, SERVICES, RECOMMENDATIONS OR ADVICE. EXCEPT AS PROVIDED IN SUPPLIER’S STANDARD CONDITIONS OF SALE, SUPPLIER AND ITS REPRESENTATIVES SHALL IN NO EVENT BE RESPONSIBLE FOR ANY LOSS RESULTING FROM ANY USE OF ITS MATERIALS, PRODUCTS OR SERVICES DESCRIBED HEREIN. Each user bears full responsibility for making its own determination as to the suitability of Supplier’s materials, services, recommendations, or advice for its own particular use. Each user must identify and perform all tests and analyses necessary to assure that its finished parts incorporating Supplier’s products, materials, or services will be safe and suitable for use under end-use conditions. Nothing in this or any other document, nor any oral recommendation or advice, shall be deemed to alter, vary, supersede, or waive any provision of Supplier’s standard Conditions of Sale or this Disclaimer, unless any such modification is specifically agreed to in a writing signed by Supplier. No statement contained herein concerning a possible or suggested use of any material, product, service or design is intended, or should be construed, to grant any license under any patent or other intellectual property right of Supplier covering such use or design, or as a recommendation for the use of such material, product, service or design in the infringement of any patent or other intellectual property right. *SPUR+ is a trademark of Momentive Performance Materials Inc. Momentive and the Momentive logo are trademarks of Momentive Performance Materials Inc. SPUR+* 1015LM Page 5 of 5HCD-10211 (Rev. 1/23/2016 11:14:44 AM)