This document provides a safety data sheet for Pigment Green 50, an inorganic pigment. It identifies hazards such as skin sensitization, carcinogenicity, and specific target organ toxicity from repeated inhalation exposure. It provides details on product identification, composition, first aid measures, firefighting measures, accidental release measures, handling and storage, exposure controls and personal protection, physical and chemical properties, stability and reactivity, toxicological information, ecological information, and disposal considerations.

1. Material Safety Data Sheet
Pigment Green 50
1. Identification
Product identifier used on the label
Pigment Green 50
Recommended use of the chemical and restriction on use
Recommended use*: colourant(s)
Suitable for use in industrial sector: plastics processing industry
* The “Recommended use” identified for this product is provided solely to comply with a Federal
requirement and is not part of the seller's published specification. The terms of this Safety Data Sheet
(SDS) do not create or infer any warranty, express or implied, including by incorporation into or reference
in the seller's sales agreement.Details of the supplier of the safety data sheet
Company
Dongguan Baoxu Chemical Technology.,ltd.
Caijin Business Bldg DongGuan CN 523071
+86 0769 22821082 Fax 86 0769 22821083
www.additivesforpolymer.com
info@additivesforpolymer.com
Emergency telephone number
Other means of identification
Molecular formula: Co2TiO4 with modifiers NiO, ZnO Chemical
family: inorganic pigments
Synonyms: C.I. Pigment Green 50, C.I. 77377
2. Hazards Identification
According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part
1910.1200 Classification of the product
Skin Sens. 1 Skin sensitization
Carc. 1 Carcinogenicity
STOT RE 1 (by inhalation) Specific target organ toxicity — repeated
exposure
Label elements

2. Pictogram:
Signal Word:
Danger
Hazard Statement:
H317 May cause an allergic skin reaction.
H350 May cause cancer.
H372 Causes damage to organs (Lung) through prolonged or repeated
exposure (inhalation).
Precautionary Statements (Prevention):
P280 Wear protective gloves/protective clothing/eye protection/face
protection.
P201 Obtain special instructions before use.
P260 Do not breathe dust/gas/mist/vapours.
P202 Do not handle until all safety precautions have been read and
understood.
P270 Do not eat, drink or smoke when using this product.
P264 Wash with plenty of water and soap thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
Precautionary Statements (Response):
P308 + P311 IF exposed or concerned: Call a POISON CENTER or doctor/physician.
P303 + P352 IF ON SKIN (or hair): Wash with plenty of soap and water.
P333 + P311 If skin irritation or rash occurs: Call a POISON CENTER or
doctor/physician.
P362 + P364 Take off contaminated clothing and wash before reuse.
Precautionary Statements (Storage):
P405 Store locked up.
Precautionary Statements (Disposal):
P501 Dispose of contents/container to hazardous or special waste collection
point.
Hazards not otherwise classified
No specific dangers known, if the regulations/notes for storage and handling are considered.
3. Composition / Information on Ingredients
According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part
1910.1200
CAS Number Weight % Chemical name
68186-85-6 80.0 - 100.0% C.I. Pigment Green 50
1345-16-0 7.0 - 15.0% C.I. Pigment Blue 28
12035-39-1 2.0 - 7.0% Nickel titanium oxide (NiTiO3)

3. 4. First-Aid Measures Description of first aid measures General advice:
Immediately remove contaminated clothing. If the patient is likely to become unconscious,
place and transport in stable sideways position (recovery position). First aid personnel should
pay attention to their own safety.
If inhaled:
If difficulties occur after dust has been inhaled, remove to fresh air and seek medical attention.
If on skin:
Wash affected areas with water while removing contaminated clothing. Seek medical attention.
If in eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open. If
irritation develops, seek medical attention.
If swallowed:
Immediately rinse mouth and then drink plenty of water, do not induce vomiting, seek
medical attention.
Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the
labelling (see section 2) and/or in section 11., Further important symptoms and effects
are so far not known.
Indication of any immediate medical attention and special treatment needed
Note to physician
Treatment: Treat according to symptoms (decontamination, vital functions), no
known specific antidote.
5. Fire-Fighting Measures Extinguishing media
Suitable extinguishing
media: dry powder, foam
Unsuitable extinguishing media for safety
reasons: carbon dioxide
Special hazards arising from the substance or mixture
Hazards during fire-
fighting: harmful vapours
Evolution of fumes/fog. The substances/groups of substances mentioned can be released in
case of fire.
Advice for fire-fighters
Protective equipment for fire-fighting:
Wear a self-contained breathing apparatus.

4. Further information:
The degree of risk is governed by the burning substance and the fire conditions.
Contaminated extinguishing water must be disposed of in accordance with official
regulations.
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Avoid dust formation. Use personal protective clothing.
Environmental precautions
Contain contaminated water/firefighting water. Do not discharge into drains/surface
wate rs / ground water.
Methods and material for containment and cleaning up
For small amounts: Pick up with suitable appliance and dispose of. For large amounts:
Contain with dust binding material and dispose of. Avoid raising dust.
7. Handling and Storage
Precautions for safe handling
Breathing must be protected when large quantities are decanted without local exhaust
ventilation. Protection against fire and explosion:
Avoid dust formation. Take precautionary measures against static discharges.
Conditions for safe storage, including any incompatibilities
Further information on storage conditions: Keep container tightly closed and dry; store
in a cool place.
8. Exposure Controls/Personal Protection
Components with occupational exposure limits
C.I. Pigment Green 50
ACGIH TLV TWA value 0.02 mg/m3 (cobalt (Co));
Nickel titanium oxide OSHA PEL PEL 1 mg/m3 (Nickel (Ni)); TWA value 1
(NiTiO3) mg/m3 (Nickel (Ni));
ACGIH TLV TWA value 0.2 mg/m3 Inhalable fraction (Nickel
(Ni));
Advice on system design:
Provide local exhaust ventilation to control dust.
Personal protective equipment
Respiratory protection:
Wear a NIOSH-certified (or equivalent) organic vapour/particulate respirator.

5. Hand protection:
Chemical resistant protective gloves
Eye protection:
Safety glasses with side-shields. Wear face shield if splashing hazard exists.
Body protection:
Body protection must be chosen based on level of activity and exposure.
General safety and hygiene measures:
Handle in accordance with good industrial hygiene and safety practice. Wash soiled clothing
immediately. Hands and/or face should be washed before breaks and at the end of the shift.
Noeating, drinking, smoking or tobacco use at the place of work.
9. Physical and Chemical Properties
Form: powder
Odour: odourless
Odour threshold: Not determined due to potential health hazard by inhalation.
Colour: green
pH value: approx. 8 (DIN EN ISO 787-9)
(50 g/l, 20 °C)
Melting point: > 1,000 °C
(1,013 hPa)
Boiling point: not applicable
Flash point: not applicable
Flammability: not flammable
Lower explosion limit: For solids not relevant for
classification and labelling.
Upper explosion limit: For solids not relevant for
classification and labelling.
Autoignition: not determined
Vapour pressure: not applicable, solid with a melting
temperature over 300 °C
Density: 4.9 g/cm3 (DIN EN ISO 787-
(20 °C) 10)
Relative density: 4.9
(20 °C)
Bulk density: approx. 900 kg/m3
Vapour density: The product is a non-volatile solid.
Partitioning coefficient
n-
Study scientifically not justified.
octanol/water (log
Pow):Self-ignition not self-igniting
temperature:
Thermal
decomposition:
No decomposition if correctly stored and handled.
Viscosity, kinematic: not applicable
Particle size: No data available.
Solubility in water: insoluble
Evaporation rate: The product is a non-volatile solid.
10. Stability and Reactivity
Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Oxidizing properties:

6. not fire-propagating
Chemical stability
The product is stable if stored and handled as prescribed/indicated.
Possibility of hazardous reactions
No hazardous reactions when stored and handled according to instructions.
The product is chemically stable.
Conditions to avoid
Avoid dust formation. Avoid deposition of dust.
Incompatible materials
No substances known that should be avoided.
Hazardous decomposition products
Decomposition products:
Hazardous decomposition products: No hazardous decomposition products if stored and
handled as
prescribed/indicated.
Thermal decomposition:
No decomposition if correctly stored and handled.
11. Toxicological information
Primary routes of exposure
Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or
skin contact. Routes of entry for gases include inhalation and eye contact. Skin contact may
be a route of entry for liquefied gases.
Acute Toxicity/Effects
Acute toxicity
Assessment of acute toxicity: Virtually nontoxic after a single ingestion. The product has
not been tested. The statement has been derived from the properties of the individual
components.
Oral
Type of value: LD50 Species: rat
Value: > 5,000 mg/kg (OECD Guideline 401)
The product has not been tested. The statement has been derived from the properties of
the individual components.
Inhalation
Type of value: LC50 No data available.
Dermal
Type of value: LD50 No data available.
Assessment other acute effects Assessment of STOT single:
Based on the available information there is no specific target organ toxicity to be expected
after a single exposure.

7. Irritation / corrosion
Assessment of irritating effects: Not irritating to the skin. Not irritating to the eyes. The
product has not been tested. The statement has been derived from the properties of the
individual components.
Skin
Species: rabbit
Result: non-irritant
Method: OECD Guideline 404
The product has not been tested. The statement has been derived from the properties of
the individual components.
Eye
Species: rabbit
Result: non-irritant
Method: OECD Guideline 405
The product has not been tested. The statement has been derived from the properties of
the individual components.
Sensitization
Assessment of sensitization: Sensitization after skin contact possible. The product has not
been tested. The statement has been derived from the properties of the individual
components.
No data available.
Aspiration Hazard No aspiration hazard expected.
Chronic Toxicity/Effects
Repeated dose toxicity
Assessment of repeated dose toxicity: Repeated inhalation exposure may affect certain
organs. Genetic toxicity
Assessment of mutagenicity: Based on the ingredients, there is no suspicion of a
mutagenic effect. The product has not been tested. The statement has been derived from
the properties of the individual components.
Carcinogenicity
Assessment of carcinogenicity: May cause cancer by inhalation. The product has not been
tested. The statement has been derived from the properties of the individual components.
Reproductive toxicity
Assessment of reproduction toxicity: Based on the ingredients, there is no suspicion of a
toxic effect on reproduction. The product has not been tested. The statement has been
derived from the properties of the individual components.
Teratogenicity
Assessment of teratogenicity: Based on the ingredients, there is no suspicion of a teratogenic
effect. The product has not been tested. The statement has been derived from the properties
of the individual components.
Other Information
The product contains heavy metals.
Symptoms of Exposure

8. The most important known symptoms and effects are described in the labelling (see
section 2) and/or in section 11., Further important symptoms and effects are so far not
known.
12. Ecological Information
Toxicity
Aquatic toxicity
Assessment of aquatic toxicity:
There is a high probability that the product is not acutely harmful to aquatic organisms.
Toxicity to fish
LC50 (96 h) > 100 mg/l, Leuciscus idus (DIN 38412 Part 15, static)
The product has not been tested. The statement has been derived from the properties
of the individual components.
Aquatic invertebrates
EC50 (48 h) > 100 mg/l, Daphnia magna (Directive 92/69/EEC, C.2, static)
The product has not been tested. The statement has been derived from the properties
of the individual components.
Aquatic plants
EC50 (72 h) > 100 mg/l (growth rate), Desmodesmus subspicatus (OECD Guideline 201,
static) The product has not been tested. The statement has been derived from the
properties of the individual components.
Chronic toxicity to fish No data available.
Chronic toxicity to aquatic invertebrates No data available.
Assessment of terrestrial toxicity
No data available concerning terrestrial toxicity.
Microorganisms/Effect on activated sludge
Toxicity to microorganisms bacteria/EC50 (0.5 h): not determined
Persistence and degradability
Assessment biodegradation and elimination (H2O)
The product is virtually insoluble in water and can thus be separated from water
mechanically in suitable effluent treatment plants.
Bioaccumulative potential
Bioaccumulation potential
Because of the product's consistency and low water solubility, bioavailability is
improbable. The product contains heavy metal(s). Prevent release into the environment.
Special pretreatment required. The product has not been tested. The statement has
been derived from substances/products of a similar structure or composition.
Mobility in soil

9. Assessment transport between environmental
compartments not determined
Additional information
Adsorbable organically-bound halogen (AOX):
This product contains no organically-bound halogen.
The product contains: cobalt, Nickel, zinc
The local waste-water limit values are to be considered for the mentioned heavy
metals. Other ecotoxicological advice:
Do not discharge product into the environment without control.
13. Disposal considerations
Waste disposal of
substance:
Dispose of in a licensed facility. Do not discharge into drains/surface
waters/groundwater. It is the waste generator's responsibility to determine if a particular
waste is hazardous under RCRA.
Container disposal:
Dispose of in a licensed facility. Recommend crushing, puncturing or other means to
prevent unauthorized use of used containers. WARNING: Empty containers may still
contain hazardous residue.
RCRA: None
14. Transport Information
Land transport
USDOT
Not classified as a dangerous good under transport regulations
Sea transport
IMDG
Not classified as a dangerous good under transport regulations
Air transport
IATA/ICAO
Not classified as a dangerous good under transport regulations
15. Regulatory Information
Federal Regulations Registration status:
Chemical TSCA, US released / listed
EPCRA 311/312 (Hazard categories): Acute; Chronic

10. EPCRA 313: CAS
Number
1345-16-0~
68186-85-6
12035-39-1
Chemical name
C.I. Pigment Blue 28 C.I.
Pigment Green 50 Nickel
titanium oxide (NiTiO3)
State regulations State
RTK
NJ
CAS Number Chemical name
1345-16-0~ C.I. Pigment Blue 28
68186-85-6 C.I. Pigment Green 50
12035-39-1 Nickel titanium oxide (NiTiO3)
CA Prop. 65:
WARNING: THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER.
NFPA Hazard codes:
Health : 2 Fire: 0 Reactivity: 0 Special: HMIS III rating
Health: 2^ Flammability: 0 Physical hazard:0
16. Other Information
SDS Prepared by: