1. Jordan Valley Innovation Center
524 N. Boonville Ave.
Springfield, MO 65806
High Performance
Supercapacitors Utilizing
Electroactive
and Conductive Polymers
(ICPs)
Self-Detoxifying
System for Toxic
Chemicals and
Bacteria
Crosslink, Inc.
Yevgenia V. Ulyanova
(Electrochemist),
Von Howard M. Ebron
(Chemist),
Siqiang Zhu
(Chemical Engineer),
Olga Shulga
(Bioanalytical Chemist)
Elizabeth Elliott
(Organic Chemist)
Natick, US Army
Julia McAdams
JVIC Collaborators
Center for Biomedical and Life
Sciences (CBLS)
Crosslink, Inc.
Sriram Viswanathan
(Polymer Chemist),
Young-Gi Kim
(Polymer Chemist)
June-Ho Jung
(Organometallic Chemist),
Joseph Mbugua
(Physical Chemist)
ARDEC, US Army
Hai-Long Nguyen
JVIC Collaborators
Brewer Sciences
Research & Development Projects
2. High Performance Supercapacitors Utilizing Electroactive
and Conductive Polymers (ECPs)
Supercapacitors:
Also known as Electric double-layer capacitors, (EDLCs), or
ultracapacitors, supercapacitors are electrochemical capacitors
that have high energy density in comparison to standard capacitors.
For example, a typical D-cell sized electrolytic capacitor will have a
capacitance in the range millifarads while supercapacitors are in the
farads. Supercapacitors aim to fill the gap between capacitors and
batteries.
Advantages over existing
technology:
• higher energy and power
• long cycle life
• lightweight
• cheaper to manufacture
• safer/easier to dispose Schematic of a supercapacitor
using Crosslinks ECPs
Supercapacitors from Crosslink
contain a ECP film which is,
• Metallically Conductive
(1000 S/cm)
• Solution Processable
• Mechanically and thermally
stable
ECPs
Crosslink
5 seconds
Applications:
• Pulsed power: flash for cameras, cell phones and wireless
transmitters such as radio frequency ID tags)
• Energy Storage Systems: solar panels, wind turbines and
hybrid vehicles
ECP Film
3. Self-Detoxifying System
for Toxic Chemicals and Bacteria
Scope of Project:
To develop a printed fabric system that slowly releases hydrogen
peroxide (H2O2), a strong oxidant. This system will provide a
continuously regenerated supply of H2O2, in-situ, which can react
with and destroy both toxic chemicals and bacteria.
Catalyst layer
Catalyst Activation
H2O2 + catalyst H2O2-catalyst*
Destruction/Oxidation
Toxic agent + H2O2-catalyst*
Safe Oxidation Products + catalyst*
Safe Oxidation/Hydrolysis
Products
Toxic Agent
Flexible or Rigid
Fabric or Substrate
Cathode Electrode
Reaction
O2 + 2H+ + 2e- H2O2
Polymer gel electrolyte
(PGE)
Anode Electrode
Reaction
2H2O O2 + 4e- + 4H+
0.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
-2.4 -3 -3.5 -4 -4.5
Applied Potential (V)
[H2O2]nmol/cm2
-2.50
-2.00
-1.50
-1.00
-0.50
0.00
MeasuredI(mA)
[H2O2] nmol/cm2
Measured I (mA)
Detoxification of B. atrophaeus:
Before (A: Control) and after
(B) exposure to fabric
generating hydrogen peroxide.
Applications:
• Military: Protection for soldiers on the battlefield
• Medical: Alternative treatment to chemical sterilization
especially for anti-biotic resistance bacteria