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Jordan Valley Innovation Center
524 N. Boonville Ave.
Springfield, MO 65806
High Performance
Supercapacitors Utilizing
Electroactive
and Conductive Polymers
(ICPs)
Self-Detoxifying
System for Toxic
Chemicals and
Bacteria
Crosslink, Inc.
Yevgenia V. Ulyanova
(Electrochemist),
Von Howard M. Ebron
(Chemist),
Siqiang Zhu
(Chemical Engineer),
Olga Shulga
(Bioanalytical Chemist)
Elizabeth Elliott
(Organic Chemist)
Natick, US Army
Julia McAdams
JVIC Collaborators
Center for Biomedical and Life
Sciences (CBLS)
Crosslink, Inc.
Sriram Viswanathan
(Polymer Chemist),
Young-Gi Kim
(Polymer Chemist)
June-Ho Jung
(Organometallic Chemist),
Joseph Mbugua
(Physical Chemist)
ARDEC, US Army
Hai-Long Nguyen
JVIC Collaborators
Brewer Sciences
Research & Development Projects
High Performance Supercapacitors Utilizing Electroactive
and Conductive Polymers (ECPs)
Supercapacitors:
Also known as Electric double-layer capacitors, (EDLCs), or
ultracapacitors, supercapacitors are electrochemical capacitors
that have high energy density in comparison to standard capacitors.
For example, a typical D-cell sized electrolytic capacitor will have a
capacitance in the range millifarads while supercapacitors are in the
farads. Supercapacitors aim to fill the gap between capacitors and
batteries.
Advantages over existing
technology:
• higher energy and power
• long cycle life
• lightweight
• cheaper to manufacture
• safer/easier to dispose Schematic of a supercapacitor
using Crosslinks ECPs
Supercapacitors from Crosslink
contain a ECP film which is,
• Metallically Conductive
(1000 S/cm)
• Solution Processable
• Mechanically and thermally
stable
ECPs
Crosslink
5 seconds
Applications:
• Pulsed power: flash for cameras, cell phones and wireless
transmitters such as radio frequency ID tags)
• Energy Storage Systems: solar panels, wind turbines and
hybrid vehicles
ECP Film
Self-Detoxifying System
for Toxic Chemicals and Bacteria
Scope of Project:
To develop a printed fabric system that slowly releases hydrogen
peroxide (H2O2), a strong oxidant. This system will provide a
continuously regenerated supply of H2O2, in-situ, which can react
with and destroy both toxic chemicals and bacteria.
Catalyst layer
Catalyst Activation
H2O2 + catalyst  H2O2-catalyst*
Destruction/Oxidation
Toxic agent + H2O2-catalyst* 
Safe Oxidation Products + catalyst*
Safe Oxidation/Hydrolysis
Products
Toxic Agent
Flexible or Rigid
Fabric or Substrate
Cathode Electrode
Reaction
O2 + 2H+ + 2e-  H2O2
Polymer gel electrolyte
(PGE)
Anode Electrode
Reaction
2H2O  O2 + 4e- + 4H+
0.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
-2.4 -3 -3.5 -4 -4.5
Applied Potential (V)
[H2O2]nmol/cm2
-2.50
-2.00
-1.50
-1.00
-0.50
0.00
MeasuredI(mA)
[H2O2] nmol/cm2
Measured I (mA)
Detoxification of B. atrophaeus:
Before (A: Control) and after
(B) exposure to fabric
generating hydrogen peroxide.
Applications:
• Military: Protection for soldiers on the battlefield
• Medical: Alternative treatment to chemical sterilization
especially for anti-biotic resistance bacteria

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IDEA Exposition slides

  • 1. Jordan Valley Innovation Center 524 N. Boonville Ave. Springfield, MO 65806 High Performance Supercapacitors Utilizing Electroactive and Conductive Polymers (ICPs) Self-Detoxifying System for Toxic Chemicals and Bacteria Crosslink, Inc. Yevgenia V. Ulyanova (Electrochemist), Von Howard M. Ebron (Chemist), Siqiang Zhu (Chemical Engineer), Olga Shulga (Bioanalytical Chemist) Elizabeth Elliott (Organic Chemist) Natick, US Army Julia McAdams JVIC Collaborators Center for Biomedical and Life Sciences (CBLS) Crosslink, Inc. Sriram Viswanathan (Polymer Chemist), Young-Gi Kim (Polymer Chemist) June-Ho Jung (Organometallic Chemist), Joseph Mbugua (Physical Chemist) ARDEC, US Army Hai-Long Nguyen JVIC Collaborators Brewer Sciences Research & Development Projects
  • 2. High Performance Supercapacitors Utilizing Electroactive and Conductive Polymers (ECPs) Supercapacitors: Also known as Electric double-layer capacitors, (EDLCs), or ultracapacitors, supercapacitors are electrochemical capacitors that have high energy density in comparison to standard capacitors. For example, a typical D-cell sized electrolytic capacitor will have a capacitance in the range millifarads while supercapacitors are in the farads. Supercapacitors aim to fill the gap between capacitors and batteries. Advantages over existing technology: • higher energy and power • long cycle life • lightweight • cheaper to manufacture • safer/easier to dispose Schematic of a supercapacitor using Crosslinks ECPs Supercapacitors from Crosslink contain a ECP film which is, • Metallically Conductive (1000 S/cm) • Solution Processable • Mechanically and thermally stable ECPs Crosslink 5 seconds Applications: • Pulsed power: flash for cameras, cell phones and wireless transmitters such as radio frequency ID tags) • Energy Storage Systems: solar panels, wind turbines and hybrid vehicles ECP Film
  • 3. Self-Detoxifying System for Toxic Chemicals and Bacteria Scope of Project: To develop a printed fabric system that slowly releases hydrogen peroxide (H2O2), a strong oxidant. This system will provide a continuously regenerated supply of H2O2, in-situ, which can react with and destroy both toxic chemicals and bacteria. Catalyst layer Catalyst Activation H2O2 + catalyst  H2O2-catalyst* Destruction/Oxidation Toxic agent + H2O2-catalyst*  Safe Oxidation Products + catalyst* Safe Oxidation/Hydrolysis Products Toxic Agent Flexible or Rigid Fabric or Substrate Cathode Electrode Reaction O2 + 2H+ + 2e-  H2O2 Polymer gel electrolyte (PGE) Anode Electrode Reaction 2H2O  O2 + 4e- + 4H+ 0.00 100.00 200.00 300.00 400.00 500.00 600.00 700.00 800.00 900.00 1000.00 -2.4 -3 -3.5 -4 -4.5 Applied Potential (V) [H2O2]nmol/cm2 -2.50 -2.00 -1.50 -1.00 -0.50 0.00 MeasuredI(mA) [H2O2] nmol/cm2 Measured I (mA) Detoxification of B. atrophaeus: Before (A: Control) and after (B) exposure to fabric generating hydrogen peroxide. Applications: • Military: Protection for soldiers on the battlefield • Medical: Alternative treatment to chemical sterilization especially for anti-biotic resistance bacteria