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Understanding Rapid Dewatering of
Cellulose Fibre Suspensions
Daniel Paterson
MASc. Thesis Defense
Mechanical Engineering
April 18, 2016
Outline
• Introduction to Industrial Problem
• Background: Past Dewatering Modeling Efforts
• Problem: Past Methods
• Project Objectives
• Part I: Extending the Modeling Approach
• Part II/III: Determining Material Parameters
• Part IV: Modeling Dewatering Trends
• Part V: Validating Dewatering Models
• Conclusion
2
Introduction
• Dewatering: Important unit process in industry
• Pulp and paper, ceramics, mining, etc.
• Examples in pulp and paper:
• Paper machine: Forming and pressing sections
• Thickeners, screw presses, wash presses
• Twin roll presses
3
• Understand dewatering in twin press rolls
• Used to optimize design
• Focused on “nip point”
• Modelled as 1D, constant dewatering rate consolidation
4(Hi – Hf) << L
Background
• Geometry
• Permeable piston at 𝑧 = ℎ 𝑡
• Closed base at 𝑧 = 0
• Compressive load: 𝜎 𝑡
• We want to model varying
dewatering rates
• Varying
𝑑ℎ 𝑡
𝑑 𝑡
5
• Modeling Approach
• Follow work of Landman, Buscall, and White [1].
• Assumptions:
• Neglect gravity, inertial, and viscous terms
6
(1)
(2)
(3)
(4)
(5)
Solid
Continuity
Fluid
Continuity
Darcian
Expression
Total Compressive
Stress Conservation
Constitutive
Equation
• Governing Equation (Base Model)
• What is needed?
• Permeability:
• Compressive Yield Stress:
7
`
• Material Parameters
• Compressive Yield Stress : The maximum
network stress (effective solid stress) that can be
withstood without solid network consolidation.
• Increasing function with (solidity)
• Permeability : A measurement of the resistance
fluid flow experiences flowing through a porous media
• Decreasing function with
8
• Model Solutions
9
Slow Compression Fast Compression
Problem: Preliminary Results
• Source?
• Suggested in the literature to be due to cellulose
fibres porous, hollow structure [2]
• Viscous component to compaction due to fluid
escaping fibres
10
Nylon Fibres Cellulose Fibres
• Expand the modeling efforts of Landman, Buscall, and
White
• In conjunction with math postdoc
• Develop equipment and protocol for collecting material
parameters
• Compressive Yield Stress
• Permeability
• Validate base model and test suitability of extended model
for various suspensions of cellulose fibres
11
Project Objectives
• Suggested in the literature the
source of discrepancy comes
from porous cellulose fibres
• Consolidation:
• Dynamic Compressibility:
12
= 0
Base Model
Instantaneous
particle compaction
Base Model
Remove this assumption
Part I: Extending the Modeling Approach
• Functional Form
• Proportional to fibre wall
permeability?
• Proposed Functional Form:
• Crude model of flow out of a porous
fibre to find fibre permeability:
13
L
2r
Suggested Form Only!
• Governing Equation (Extended Model)
• What is needed?
• Permeability:
• Compressive Yield Stress:
• Fitted Parameter: 14
• Compressive Yield Stress: The maximum network
stress (effective solid stress) that can be withstood without
consolidation
• Techniques:
Permeation Trials
• Approximation neglecting
flow induced compaction:
• Control error
Part II: Material Parameter
Slow Speed Compaction
• Simplified continuity:
• Uniform consolidation
15
• Experimental Apparatus
• Movement: 100 mm
• Load: 1.3 MPa
• Rate 0.001 – 10 mm/s
16
• Materials
• Varying species, pulping process, refinement, and
flocculation state
• Ideal fibre suspension for base model validation
17
• Equipment Validation
18
: Softwood chemical pulp [2]
: Softwood chemical pulp [3]
: Coal-mining tailing [4]
: Zirconia suspension [5]
: Water treatment sludge [6]
: Alumina suspension [7]
: Series 1 (NBSK) Slow Speed Technique
: Series 1 (NBSK) Permeation Technique
• Representative Results
19
Account: Fit a Functional Form
• Model equations
• Fit functional form
• Permeability: A measurement of the resistance fluid flow
experiences flowing through a porous media
• Concern: Flow induced compaction
Part III: Material Parameter
Neglect: Manage Error
• Evaluate at
• Control error
20
• Experimental Apparatus
• Movement: 160 mm
• Load: 1.0 MPa
• Pressure: 1.0 MPa
21
• Equipment Validation
22
: Series 1 (NBSK)
: Softwood chemical pulp [8]
: Softwood chemical pulp [9]
: Softwood chemical pulp [10]
: Nylon fibre suspension [11]
: Nylon fibre suspension [11]
: Glass fibre suspension [11]
: Acrylamide polymer gel [11]
: Lattice-Boltzmann simulation [12]
• Representative Results
23
• Experimental dewatering trends collected for varying rates
• 0.001 – 10 mm/s
• Load versus solid volume fraction trends
24
Part IV: Model Dewatering Trends
• Nylon Fibre Experimental Results:
25
• Discussion
• Increased difficulty in dewatering with higher rates
• Initial load growth with high dewatering rates
• Nylon Fibre Model Results:
26
Base Model
Experiment
• Discussion
• Predictive trends (no free parameters)
• Base model works well with “solid” nylon fibres
• Discussion
• Increased difficulty in dewatering with higher rates
• Dewatering curves do not trend back to
• NBSK (Series 1) Experimental Results:
27
• NBSK (Series 1) Model Results:
28
Base Model
Extended Model
Experiment
• Discussion
• Extended model trends fitted
• Improved with extended model
• Investigate models effectiveness in representing solid
phase movement during consolidation
• Nylon Fibres  Base Model
• NBSK (Series 1)  Extended Model
• Film dewatering events to develop velocity profiles
29
Part V: Validating Models
30
Experimental Base Model
3.0 mm/s
0.25 mm/s
• Nylon Fibre Velocity Profiles:
• Discussion
• 0.25 mm/s: Closer to linear, small solidity gradients
• 3.0 mm/s: Nonlinear velocity, large solidity gradients
• Base models provides good representation
• NBSK (Series 1) Velocity Profiles:
• Discussion
• Both velocities quite linear, small solidity gradients
• Base model provides poor representation
• Extended model provides improved representation
31
Experimental Base Model Extended Model
10.0 mm/s
1.5 mm/s
• Equipment and experimental protocol developed for
collecting material parameters and
• Extended model provided improved representation of
cellulose fibre dewatering over the base model
• Acceptable form of
• Base model provided good representation of nylon fibre
suspension
• Constitutive function is well suited to hard particles
• Both models represented their corresponding suspensions
well in capturing the movement of the solid particles
32
Conclusions
33
Thank You,
Questions
Sponsors
34
References
[1]
[2]
[3]
[4]
[5]
[6]
35
[7]
[8]
[9]
[10]
[11]
[12]
• Further cellulose trials
• Assess the continued suitability of dynamic
compressibility function:
• Continue cataloging dewatering behaviours of various
cellulose fibre suspensions
• Investigate a few experimental concerns
• Temperature impact on compressed cellulose fibres
• Retention challenges: TMP
36
Future Work
37
Functional form of Dynamic Compressibility
38

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Understanding Rapid Dewatering of Cellulose Fibre Suspensions

  • 1. Understanding Rapid Dewatering of Cellulose Fibre Suspensions Daniel Paterson MASc. Thesis Defense Mechanical Engineering April 18, 2016
  • 2. Outline • Introduction to Industrial Problem • Background: Past Dewatering Modeling Efforts • Problem: Past Methods • Project Objectives • Part I: Extending the Modeling Approach • Part II/III: Determining Material Parameters • Part IV: Modeling Dewatering Trends • Part V: Validating Dewatering Models • Conclusion 2
  • 3. Introduction • Dewatering: Important unit process in industry • Pulp and paper, ceramics, mining, etc. • Examples in pulp and paper: • Paper machine: Forming and pressing sections • Thickeners, screw presses, wash presses • Twin roll presses 3
  • 4. • Understand dewatering in twin press rolls • Used to optimize design • Focused on “nip point” • Modelled as 1D, constant dewatering rate consolidation 4(Hi – Hf) << L
  • 5. Background • Geometry • Permeable piston at 𝑧 = ℎ 𝑡 • Closed base at 𝑧 = 0 • Compressive load: 𝜎 𝑡 • We want to model varying dewatering rates • Varying 𝑑ℎ 𝑡 𝑑 𝑡 5
  • 6. • Modeling Approach • Follow work of Landman, Buscall, and White [1]. • Assumptions: • Neglect gravity, inertial, and viscous terms 6 (1) (2) (3) (4) (5) Solid Continuity Fluid Continuity Darcian Expression Total Compressive Stress Conservation Constitutive Equation
  • 7. • Governing Equation (Base Model) • What is needed? • Permeability: • Compressive Yield Stress: 7 `
  • 8. • Material Parameters • Compressive Yield Stress : The maximum network stress (effective solid stress) that can be withstood without solid network consolidation. • Increasing function with (solidity) • Permeability : A measurement of the resistance fluid flow experiences flowing through a porous media • Decreasing function with 8
  • 9. • Model Solutions 9 Slow Compression Fast Compression
  • 10. Problem: Preliminary Results • Source? • Suggested in the literature to be due to cellulose fibres porous, hollow structure [2] • Viscous component to compaction due to fluid escaping fibres 10 Nylon Fibres Cellulose Fibres
  • 11. • Expand the modeling efforts of Landman, Buscall, and White • In conjunction with math postdoc • Develop equipment and protocol for collecting material parameters • Compressive Yield Stress • Permeability • Validate base model and test suitability of extended model for various suspensions of cellulose fibres 11 Project Objectives
  • 12. • Suggested in the literature the source of discrepancy comes from porous cellulose fibres • Consolidation: • Dynamic Compressibility: 12 = 0 Base Model Instantaneous particle compaction Base Model Remove this assumption Part I: Extending the Modeling Approach
  • 13. • Functional Form • Proportional to fibre wall permeability? • Proposed Functional Form: • Crude model of flow out of a porous fibre to find fibre permeability: 13 L 2r Suggested Form Only!
  • 14. • Governing Equation (Extended Model) • What is needed? • Permeability: • Compressive Yield Stress: • Fitted Parameter: 14
  • 15. • Compressive Yield Stress: The maximum network stress (effective solid stress) that can be withstood without consolidation • Techniques: Permeation Trials • Approximation neglecting flow induced compaction: • Control error Part II: Material Parameter Slow Speed Compaction • Simplified continuity: • Uniform consolidation 15
  • 16. • Experimental Apparatus • Movement: 100 mm • Load: 1.3 MPa • Rate 0.001 – 10 mm/s 16
  • 17. • Materials • Varying species, pulping process, refinement, and flocculation state • Ideal fibre suspension for base model validation 17
  • 18. • Equipment Validation 18 : Softwood chemical pulp [2] : Softwood chemical pulp [3] : Coal-mining tailing [4] : Zirconia suspension [5] : Water treatment sludge [6] : Alumina suspension [7] : Series 1 (NBSK) Slow Speed Technique : Series 1 (NBSK) Permeation Technique
  • 20. Account: Fit a Functional Form • Model equations • Fit functional form • Permeability: A measurement of the resistance fluid flow experiences flowing through a porous media • Concern: Flow induced compaction Part III: Material Parameter Neglect: Manage Error • Evaluate at • Control error 20
  • 21. • Experimental Apparatus • Movement: 160 mm • Load: 1.0 MPa • Pressure: 1.0 MPa 21
  • 22. • Equipment Validation 22 : Series 1 (NBSK) : Softwood chemical pulp [8] : Softwood chemical pulp [9] : Softwood chemical pulp [10] : Nylon fibre suspension [11] : Nylon fibre suspension [11] : Glass fibre suspension [11] : Acrylamide polymer gel [11] : Lattice-Boltzmann simulation [12]
  • 24. • Experimental dewatering trends collected for varying rates • 0.001 – 10 mm/s • Load versus solid volume fraction trends 24 Part IV: Model Dewatering Trends
  • 25. • Nylon Fibre Experimental Results: 25 • Discussion • Increased difficulty in dewatering with higher rates • Initial load growth with high dewatering rates
  • 26. • Nylon Fibre Model Results: 26 Base Model Experiment • Discussion • Predictive trends (no free parameters) • Base model works well with “solid” nylon fibres
  • 27. • Discussion • Increased difficulty in dewatering with higher rates • Dewatering curves do not trend back to • NBSK (Series 1) Experimental Results: 27
  • 28. • NBSK (Series 1) Model Results: 28 Base Model Extended Model Experiment • Discussion • Extended model trends fitted • Improved with extended model
  • 29. • Investigate models effectiveness in representing solid phase movement during consolidation • Nylon Fibres  Base Model • NBSK (Series 1)  Extended Model • Film dewatering events to develop velocity profiles 29 Part V: Validating Models
  • 30. 30 Experimental Base Model 3.0 mm/s 0.25 mm/s • Nylon Fibre Velocity Profiles: • Discussion • 0.25 mm/s: Closer to linear, small solidity gradients • 3.0 mm/s: Nonlinear velocity, large solidity gradients • Base models provides good representation
  • 31. • NBSK (Series 1) Velocity Profiles: • Discussion • Both velocities quite linear, small solidity gradients • Base model provides poor representation • Extended model provides improved representation 31 Experimental Base Model Extended Model 10.0 mm/s 1.5 mm/s
  • 32. • Equipment and experimental protocol developed for collecting material parameters and • Extended model provided improved representation of cellulose fibre dewatering over the base model • Acceptable form of • Base model provided good representation of nylon fibre suspension • Constitutive function is well suited to hard particles • Both models represented their corresponding suspensions well in capturing the movement of the solid particles 32 Conclusions
  • 36. • Further cellulose trials • Assess the continued suitability of dynamic compressibility function: • Continue cataloging dewatering behaviours of various cellulose fibre suspensions • Investigate a few experimental concerns • Temperature impact on compressed cellulose fibres • Retention challenges: TMP 36 Future Work
  • 37. 37 Functional form of Dynamic Compressibility
  • 38. 38

Editor's Notes

  1. Actually consolidation???