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TABLE OF CONTENTS
1 3M ADHESIVE PRODUCTS
2 3M FIRE CAULKING
3 3M HEAVY DUTY 20 SPRAY ADEHSIVE
4 3M SPRAY ADHESIVE 90
5 BLACK CHALK
6 BLUE CHALK
7 CLARKDIETRICH METAL PRODUCTS
8 CLINCH ON CORNER BEAD
9 DAP DYNAGRIP ALL PURPOSE ADHESIVE
10 FRP FAST GRAB
11 HILTI GAS GC41
12 HOMAX WALL TEXTURE
13 IPG MASKING TAPE
14 NATURES SWEEPEING COMPOUND
15 PABCO DRYWALL
16 PLS 180
17 PLS 3
18 PLS 360
19 PYRO-GUARD WOOD PRODUCTS
20 RAMSET BATTERY
21 RAMSET FUEL CELL
22 RAMSET POWDER LOADS
23 RED CHALK
24 RTV SILICONE
25 SEYMOUR CLEAR SPRAY
26 SEYMOUR COLOR SPRAY
27 UGS ACOUSTICAL SEALANT
28 UNITED METALS
29 WD-40
30 WHITE LIGHTNING ACRYLIC LATEX
31 WESTPAC PAPER TAPE
32 WESTPAC POWDERED JOINT COMP.
33 WESTPAC PREP COAT
34 WESTPAC READY-MIX
35 WESTPAC SETTING COMPOUNDS
36
W
ES
T
WESTPAC SMOOTH COAT
3M™ Abrasive Products, 362L, 372L, 382L 08/25/14
Page 1 of 10
SECTION 1: Identification
Safety Data Sheet
Copyright,2014,3MCompany.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group: 23-7173-0 Version Number: 2.12
Issue Date: 08/25/14 Supercedes Date: 03/21/14
1.1. Product identifier
3M™ Abrasive Products, 362L, 372L, 382L
1.2. Recommended use and restrictions on use
Recommended use
Abrasive Product
1.3. Supplier’s details
MANUFACTURER: 3M
DIVISION: Abrasive Systems Division
ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA
Telephone: 1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
2.1. Hazard classification
Not classified as hazardous according to OSHA Hazard Communication Standard, 29 CFR 1910.1200.
2.2. Label elements
Signal word
Not applicable.
Symbols
Not applicable.
Pictograms
Not applicable.
2.3. Hazards not otherwise classified
None.
29% of the mixture consists of ingredients of unknown acute oral toxicity.
SECTION 3: Composition/information on ingredients
SECTION 2: Hazard identification
3M™ Abrasive Products, 362L, 372L, 382L 08/25/14
Page 2 of 10
Ingredient C.A.S. No. % by Wt
Aluminum Oxide Mineral (non-fibrous) 1344-28-1 3 - 35
Filler 1317-65-3 3 - 20
Filler 1332-58-7 0 - 5
Crystalline Free Fumed Silica 112945-52-5 0 - 5
Titanium Dioxide 13463-67-7 0.2 - 2.5
Quartz Silica 14808-60-7 0.001 - 0.4
Cured Resin Mixture 5 - 30
Film Backing Mixture 20 - 75
4.1. Description of first aid measures
Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
Wash with soap and water. If signs/symptoms develop, get medical attention.
Eye Contact:
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.
If Swallowed:
No need for first aid is anticipated.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
Hazardous Decomposition or By-Products
Substance Condition
Aldehydes During Combustion
Carbon monoxide During Combustion
Carbon dioxide During Combustion
5.3. Special protective actions for fire-fighters
No special protective actions for fire-fighters are anticipated.
SECTION 6: Accidental release measures
SECTION 5: Fire-fighting measures
SECTION 4: First aid measures
3M™ Abrasive Products, 362L, 372L, 382L 08/25/14
Page 3 of 10
6.1. Personal precautions, protective equipment and emergency procedures
Observe precautions from other sections.
6.2. Environmentalprecautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Not applicable.
7.1. Precautions for safe handling
For industrial or professional use only. Avoid breathing of dust created by sanding, grinding or machining. Damaged product
can break apart during use and cause serious injury to face or eyes. Check product for damage such as cracks or nicks prior
to use. Replace if damaged. Always wear eye and face protection when working at sanding or grinding operations or when
near such operations. Avoid release to the environment. Combustible dust may form by action of this product on another
material (substrate). Dust generated from the substrate during use of this product may be explosive if in sufficient
concentration with an ignition source. Dust deposits should not be allowed to accumulate on surfaces because of the potential
for secondary explosions.
7.2. Conditions for safe storage including any incompatibilities
No special storage requirements.
8.1. Control parameters
Occupational exposure limits
Ingredient C.A.S. No. Agency Limit type Additional Comments
SILICA, AMORPHOUS 112945-52-
5
OSHA TWA concentration:0.8
mg/m3;TWA:20 millions of
particles/cu. ft.
Filler 1317-65-3 OSHA TWA(as total dust):15
mg/m3;TWA(respirable
fraction):5 mg/m3
KAOLIN, TOTAL DUST 1332-58-7 OSHA TWA(as total dust):15
mg/m3;TWA(respirable
fraction):5 mg/m3
Filler 1332-58-7 ACGIH TWA(respirable fraction):2
mg/m3
A4: Not class. as human
carcin
Aluminum Oxide Mineral (non-
fibrous)
1344-28-1 CMRG TWA:1 fiber/cc
Aluminum, insoluble compounds 1344-28-1 ACGIH TWA(respirable fraction):1
mg/m3
A4: Not class. as human
carcin
Aluminum Oxide Mineral (non-
fibrous)
1344-28-1 OSHA TWA(as total dust):15
mg/m3;TWA(respirable
fraction):5 mg/m3
Titanium Dioxide 13463-67-7 OSHA TWA(as total dust):15 mg/m3
Titanium Dioxide 13463-67-7 ACGIH TWA:10 mg/m3 A4: Not class. as human
carcin
Titanium Dioxide 13463-67-7 CMRG TWA(as respirable dust):5
mg/m3
Quartz Silica 14808-60-7 OSHA TWA concentration(as total
SECTION 8: Exposure controls/personal protection
SECTION 7: Handling and storage
3M™ Abrasive Products, 362L, 372L, 382L 08/25/14
Page 4 of 10
dust):0.3 mg/m3;TWA
concentration(respirable):0.1
mg/m3(2.4 millions of
particles/cu. ft.)
Quartz Silica 14808-60-7 ACGIH TWA(respirable
fraction):0.025 mg/m3
A2: Suspected human
carcin.
Film Backing Mixture CMRG TWA(as respirable dust):5
mg/m3;TWA(as total dust):10
mg/m3
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Provide appropriate local exhaust ventilation for sanding, grinding or machining. Use general dilution ventilation and/or local
exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control
dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Provide local exhaust at
process emission sources to control exposure near the source and to prevent the escape of dust into the work area. Ensure that
dust-handling systems (such as exhaust ducts, dust collectors, vessels, and processing equipment) are designed in a manner to
prevent the escape of dust into the work area (i.e., there is no leakage from the equipment).
8.2.2. Personal protective equipment (PPE)
Eye/face protection
To minimize the risk of injury to face and eyes, always wear eye and face protection when working at sanding or grinding
operations or when near such operations. Select and use eye/face protection to prevent contact based on the results of an
exposure assessment. The following eye/face protection(s) are recommended:
Safety Glasses with side shields
Skin/hand protection
Wear appropriate gloves to minimize risk of injury to skin from contact with dust or physical abrasion from grinding or
sanding.
Respiratory protection
Assess exposure concentrations of all materials involved in the work process. Consider material being abraded when
determining the appropriate respiratory protection. Select and use appropriate respirators to prevent inhalation overexposure.
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
9.1. Information on basic physical and chemical properties
General Physical Form: Solid
Odor, Color, Grade: Solid Abrasive Product
SECTION 9: Physical and chemical properties
3M™ Abrasive Products, 362L, 372L, 382L 08/25/14
Page 5 of 10
Odor threshold Not Applicable
pH Not Applicable
Melting point Not Applicable
Boiling Point Not Applicable
Flash Point Not Applicable
Evaporation rate Not Applicable
Flammability (solid, gas) Not Classified
Flammable Limits(LEL) Not Applicable
Flammable Limits(UEL) Not Applicable
Vapor Pressure Not Applicable
Vapor Density Not Applicable
Density Not Applicable
Specific Gravity Not Applicable
Solubility In Water Not Applicable
Solubility- non-water Not Applicable
Partition coefficient: n-octanol/ water Not Applicable
Autoignitiontemperature Not Applicable
Decompositiontemperature Not Applicable
Viscosity Not Applicable
VOC Less H2O & Exempt Solvents No Data Available
10.1. Reactivity
This material is considered to be non reactive under normal use conditions.
10.2. Chemical stability
Stable.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
None known.
10.5. Incompatible materials
None known.
10.6. Hazardous decomposition products
Substance Condition
None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
SECTION 11: Toxicological information
SECTION 10: Stability and reactivity
3M™ Abrasive Products, 362L, 372L, 382L 08/25/14
Page 6 of 10
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
Dust from grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may include cough,
sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
Skin Contact:
Mechanical Skin irritation: Signs/symptoms may include abrasion, redness, pain, and itching.
Allergic Skin Reaction (non-photo induced) in sensitive people: Signs/symptoms may include redness, swelling, blistering,
and itching.
Eye Contact:
Mechanical eye irritation: Signs/symptoms may include pain, redness, tearing and corneal abrasion.
Dust created by grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness, swelling,
pain, tearing, and blurred or hazy vision.
Ingestion:
No health effects are expected.
Carcinogenicity:
Ingredient C.A.S. No. Class Description Regulation
SILICA, CRYS AIRRESP 14808-60-7 Known human carcinogen National Toxicology Program Carcinogens
Quartz Silica 14808-60-7 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer
Titanium Dioxide 13463-67-7 Grp. 2B: Possible human carc. International Agency for Research on Cancer
Additional Information:
This document covers only the 3M product. For complete assessment, when determining the degree of hazard, the material
being abraded must also be considered.
This product contains titanium dioxide and quartz (crystalline) silica. Cancer of the lungs has been associated with inhalation
of high levels of titanium dioxide in animal studies, and occupational exposure to inhaled quartz silica has been associated
with silicosis and lung cancer. No exposure to titanium dioxide or quartz silica is expected during the normal handling and
use of this product. Titanium dioxide and quartz silica were not detected when air sampling was conducted during simulated
use of similar products containing these substances. Therefore, the health effects associated with titanium dioxide and quartz
(crystalline) silica are not expected during the normal use of this product.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg
Film Backing Dermal LD50 estimated to be > 5,000 mg/kg
Film Backing Ingestion Rat LD50 > 5,000 mg/kg
Aluminum Oxide Mineral (non-fibrous) Dermal LD50 estimated to be > 5,000 mg/kg
Aluminum Oxide Mineral (non-fibrous) Inhalation-
Dust/Mist
(4 hours)
Rat LC50 > 2.3 mg/l
Aluminum Oxide Mineral (non-fibrous) Ingestion Rat LD50 > 5,000 mg/kg
Filler Dermal Rat LD50 > 2,000 mg/kg
Filler Inhalation-
Dust/Mist
Rat LC50 3.0 mg/l
3M™ Abrasive Products, 362L, 372L, 382L 08/25/14
Page 7 of 10
(4 hours)
Filler Ingestion Rat LD50 6,450 mg/kg
Filler Dermal LD50 estimated to be > 5,000 mg/kg
Filler Ingestion Human LD50 > 15,000 mg/kg
Crystalline Free Fumed Silica Dermal Rabbit LD50 > 5,000 mg/kg
Crystalline Free Fumed Silica Inhalation-
Dust/Mist
(4 hours)
Rat LC50 > 0.691 mg/l
Crystalline Free Fumed Silica Ingestion Rat LD50 > 5,110 mg/kg
Titanium Dioxide Dermal Rabbit LD50 > 10,000 mg/kg
Titanium Dioxide Inhalation-
Dust/Mist
(4 hours)
Rat LC50 > 6.82 mg/l
Titanium Dioxide Ingestion Rat LD50 > 10,000 mg/kg
Quartz Silica Dermal LD50 estimated to be > 5,000 mg/kg
Quartz Silica Ingestion LD50 estimated to be > 5,000 mg/kg
ATE = acute toxicity estimate
SkinCorrosion/Irritation
Name Species Value
Aluminum Oxide Mineral (non-fibrous) Rabbit No significant irritation
Filler Rabbit No significant irritation
Filler No significant irritation
Crystalline Free Fumed Silica Rabbit No significant irritation
Titanium Dioxide Rabbit No significant irritation
Quartz Silica No significant irritation
Serious Eye Damage/Irritation
Name Species Value
Aluminum Oxide Mineral (non-fibrous) Rabbit No significant irritation
Filler Rabbit No significant irritation
Filler No significant irritation
Crystalline Free Fumed Silica Rabbit No significant irritation
Titanium Dioxide Rabbit No significant irritation
Skin Sensitization
Name Species Value
Crystalline Free Fumed Silica Human
and
animal
Not sensitizing
Titanium Dioxide Human
and
animal
Not sensitizing
Respiratory Sensitization
Name Species Value
Germ Cell Mutagenicity
Name Route Value
Aluminum Oxide Mineral (non-fibrous) In Vitro Not mutagenic
Crystalline Free Fumed Silica In Vitro Not mutagenic
Titanium Dioxide In Vitro Not mutagenic
Titanium Dioxide In vivo Not mutagenic
Quartz Silica In Vitro Some positive data exist, but the data are not
sufficient for classification
Quartz Silica In vivo Some positive data exist, but the data are not
sufficient for classification
Carcinogenicity
Name Route Species Value
Aluminum Oxide Mineral (non-fibrous) Inhalation Rat Not carcinogenic
Filler Inhalation Multiple
animal
species
Not carcinogenic
3M™ Abrasive Products, 362L, 372L, 382L 08/25/14
Page 8 of 10
Crystalline Free Fumed Silica Not
Specified
Mouse Some positive data exist, but the data are not
sufficient for classification
Titanium Dioxide Ingestion Multiple
animal
species
Not carcinogenic
Titanium Dioxide Inhalation Rat Carcinogenic
Quartz Silica Inhalation Human
and
animal
Carcinogenic
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test Result Exposure
Duration
Filler Ingestion Not toxic to development Rat NOAEL 625
mg/kg/day
premating &
during
gestation
Crystalline Free Fumed Silica Ingestion Not toxic to female reproduction Rat NOAEL 509
mg/kg/day
1 generation
Crystalline Free Fumed Silica Ingestion Not toxic to male reproduction Rat NOAEL 497
mg/kg/day
1 generation
Crystalline Free Fumed Silica Ingestion Not toxic to development Rat NOAEL
1,350
mg/kg/day
during
organogenesi
s
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Filler Inhalation respiratory system All data are negative Rat NOAEL
0.812 mg/l
90 minutes
Specific Target Organ Toxicity - repeated exposure
Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Aluminum Oxide Mineral
(non-fibrous)
Inhalation pneumoconiosis |
pulmonary fibrosis
Some positive data exist, but the
data are not sufficient for
classification
Human NOAEL Not
available
occupational
exposure
Filler Inhalation respiratory system Some positive data exist, but the
data are not sufficient for
classification
Human NOAEL Not
available
occupational
exposure
Filler Inhalation pneumoconiosis Causes damage to organs
through prolonged or repeated
exposure
Human NOAEL NA occupational
exposure
Filler Inhalation pulmonary fibrosis Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL Not
available
Crystalline Free Fumed
Silica
Inhalation respiratory system |
silicosis
All data are negative Human NOAEL Not
available
occupational
exposure
Titanium Dioxide Inhalation respiratory system Some positive data exist, but the
data are not sufficient for
classification
Rat LOAEL
0.010 mg/l
2 years
Titanium Dioxide Inhalation pulmonary fibrosis All data are negative Human NOAEL Not
available
occupational
exposure
Quartz Silica Inhalation silicosis Causes damage to organs
through prolonged or repeated
exposure
Human NOAEL Not
available
occupational
exposure
Aspiration Hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
Name Value
3M™ Abrasive Products, 362L, 372L, 382L 08/25/14
Page 9 of 10
on this material and/or its components.
Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
The substrate that was abraded must be considered as a factor in the disposal method for this product. Dispose of waste
product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste incineration facility.
Proper destruction may require the use of additional fuel during incineration processes. Combustion products will include
halogen acid (HCl/HF/HBr). Facility must be capable of handling halogenated materials.
EPA Hazardous Waste Number (RCRA): Not regulated
Not regulated per U.S. DOT, IATA or IMO.
15.1. US Federal Regulations
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - No Delayed Hazard - No
15.2. State Regulations
Contact 3M for more information.
15.3. Chemical Inventories
This product is an article as defined by TSCA regulations, and is exempt from TSCA Inventory listing requirements.
Contact 3M for more information.
SECTION 15: Regulatory information
These transportation classifications are provided as a customer service. As the shipper YOU remain responsible for
complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M
transportation classifications are based on product formulation, packaging, 3M policies and 3M understanding of
applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information
applies only to transportation classification and not the packaging, labeling, or marking requirements. The original 3M
package is certified for U.S. ground shipment only. If you are shipping by air or ocean, the package may not meet
applicable regulatory requirements.
SECTION 14: Transport Information
SECTION 13: Disposal considerations
SECTION 12: Ecological information
3M™ Abrasive Products, 362L, 372L, 382L 08/25/14
Page 10 of 10
15.4. International Regulations
Contact 3M for more information.
NFPA Hazard Classification
Health: 0 Flammability: 1 Instability: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
HMIS Hazard Classification
Health: 0 Flammability: 1 Physical Hazard: 0 Personal Protection: X - See PPE section.
Hazardous Material Identification System (HMIS® III) hazard ratings are designed to inform employees of chemical hazards
in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use
and are not intended for use in emergency situations. HMIS® III ratings are to be used with a fully implemented HMIS® III
program. HMIS® is a registered mark of the American Coatings Association (ACA).
Document Group: 23-7173-0 Version Number: 2.12
Issue Date: 08/25/14 Supercedes Date: 03/21/14
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M
3M USA SDSs are available at www.3M.com
SECTION 16: Other information
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
3M Brand Fire Barrier CP-25WB+ 08/16/16
Page 1 of 11
SECTION 1: Identification
Safety Data Sheet
Copyright,2016,3MCompany.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group: 09-5451-1 Version Number: 26.01
Issue Date: 08/16/16 Supercedes Date: 06/20/14
1.1. Product identifier
3M Brand Fire Barrier CP-25WB+
Product Identification Numbers
ID Number UPC ID Number UPC
42-0016-4710-8 42-0016-4715-7
42-0016-4716-5 98-0400-5380-7 00-51115-11639-1
98-0400-5381-5 00-51115-11640-7 98-0400-5382-3 00-51115-11641-4
98-0400-5383-1 00-51115-11642-1 98-0400-5406-0 00-51115-16515-3
98-0400-5456-5 98-0400-5562-0 000-51115-11642-1
98-0400-5573-7 000-51115-16515-3 98-0400-5610-7
98-0400-5629-7
1.2. Recommended use and restrictions on use
Recommended use
Fire Protection, Used as Firestop in buildings.
1.3. Supplier’s details
MANUFACTURER: 3M
DIVISION: Industrial Adhesives and Tapes Division
ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA
Telephone: 1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
2.1. Hazard classification
Serious Eye Damage/Irritation: Category 2B.
2.2. Label elements
Signal word
Warning
Symbols
SECTION 2: Hazard identification
3M Brand Fire Barrier CP-25WB+ 08/16/16
Page 2 of 11
Not applicable
Pictograms
Not applicable
Hazard Statements
Causes eye irritation.
Precautionary Statements
General:
Keep out of reach of children.
Prevention:
Wash thoroughly after handling.
Response:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
2.3. Hazards not otherwise classified
None.
Ingredient C.A.S. No. % by Wt
Sodium Silicate 1344-09-8 10 - 30 Trade Secret *
Water 7732-18-5 10 - 30 Trade Secret *
Zinc Borate 2335 138265-88-0 10 - 30 Trade Secret *
Polymer (NJTS Reg. No. 04499600-7270) Trade Secret* 10 - 30 Trade Secret *
Ethylhexyldiphenylphosphate 1241-94-7 3 - 7 Trade Secret *
Iron oxide 1309-37-1 1 - 5 Trade Secret *
Oxide glass chemicals 65997-17-3 1 - 5 Trade Secret *
Polyethylene Glycol 25322-68-3 1 - 5 Trade Secret *
Di-2-ethylhexlphenylphosphate 16368-97-1 < 1.0 Trade Secret *
Polyoxyethylene monooctylphenyl ether 9036-19-5 < 1.0 Trade Secret *
Triphenyl phosphate 115-86-6 < 1.0 Trade Secret *
3(2H)-Isothiazolone, 5-chloro-2-methyl-, mixt. with 2-
methyl-3(2H)-isothiazolone
55965-84-9 < 0.001 Trade Secret *
NJTS or NJTSRN: New Jersey Trade Secret Registry Number.
*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.
4.1. Description of first aid measures
Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
Wash with soap and water. If signs/symptoms develop, get medical attention.
SECTION 4: First aid measures
SECTION 3: Composition/information on ingredients
3M Brand Fire Barrier CP-25WB+ 08/16/16
Page 3 of 11
Eye Contact:
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.
If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
5.1. Suitable extinguishing media
Non-combustible. Use a fire fighting agent suitable for surrounding fire.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
5.3. Special protective actions for fire-fighters
No special protective actions for fire-fighters are anticipated.
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation
to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for
information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmentalprecautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate
authorities. Clean up residue. Seal the container. Dispose of collected material as soon as possible.
7.1. Precautions for safe handling
Avoid eye contact. Keep out of reach of children. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not eat, drink or
smoke when using this product. Wash thoroughly after handling. Avoid release to the environment.
7.2. Conditions for safe storage including any incompatibilities
Keep cool. Store away from heat. Store away from areas where product may come into contact with food or
pharmaceuticals. Store in a dry place.
8.1. Control parameters
Occupational exposure limits
SECTION 8: Exposure controls/personal protection
SECTION 7: Handling and storage
SECTION 6: Accidental release measures
SECTION 5: Fire-fighting measures
3M Brand Fire Barrier CP-25WB+ 08/16/16
Page 4 of 11
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
Ingredient C.A.S. No. Agency Limit type Additional Comments
Triphenyl phosphate 115-86-6 ACGIH TWA:3 mg/m3 A4: Not class. as human
carcin
Triphenyl phosphate 115-86-6 OSHA TWA:3 mg/m3
Iron oxide 1309-37-1 OSHA TWA(as fume):10 mg/m3
ROUGE 1309-37-1 OSHA TWA(as total dust):15
mg/m3;TWA(respirable
fraction):5 mg/m3
Iron oxide 1309-37-1 ACGIH TWA(respirable fraction):5
mg/m3
A4: Not class. as human
carcin
Polyethylene Glycol 25322-68-3 AIHA TWA(as particulate):10
mg/m3
Oxide glass chemicals 65997-17-3 Manufacturer
determined
TWA(as dust):10 mg/m3
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect Vented Goggles
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing.
Gloves made from the following material(s) are recommended: Butyl Rubber
Neoprene
Nitrile Rubber
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
3M Brand Fire Barrier CP-25WB+ 08/16/16
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9.1. Information on basic physical and chemical properties
General Physical Form: Solid
Specific Physical Form: Paste
Odor, Color, Grade: Red with negligible odor
Odor threshold No Data Available
Melting point No Data Available
Flash Point No flash point
Flammability (solid, gas) Not Classified
Flammable Limits(LEL) Not Applicable
Flammable Limits(UEL) Not Applicable
Specific Gravity 1.35 [Ref Std: WATER=1]
Solubility in Water Complete
Solubility- non-water No Data Available
Autoignitiontemperature Not Applicable
Decompositiontemperature No Data Available
Molecular weight No Data Available
Volatile Organic Compounds <=0.5 % weight [Test Method: tested per EPA method 24]
VOC Less H2O & Exempt Solvents <=6 g/l [Test Method: tested per EPA method 24]
10.1. Reactivity
This material is considered to be non reactive under normal use conditions.
10.2. Chemical stability
Stable.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
None known.
10.5. Incompatible materials
None known.
10.6. Hazardous decomposition products
Substance Condition
Carbon monoxide Not Specified
Carbon dioxide Not Specified
Oxides of Phosphorus Not Specified
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
SECTION 11: Toxicological information
SECTION 10: Stability and reactivity
SECTION 9: Physical and chemical properties
3M Brand Fire Barrier CP-25WB+ 08/16/16
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Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
Skin Contact:
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Ingestion:
May be harmful if swallowed.
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
Overall product Dermal No data available; calculated ATE > 5,000 mg/kg
Overall product Ingestion No data available; calculated ATE 2,000 - 5,000
mg/kg
Polymer (NJTS Reg. No. 04499600-7270) Dermal LD50 estimated to be > 5,000 mg/kg
Polymer (NJTS Reg. No. 04499600-7270) Ingestion Rat LD50 > 2,000 mg/kg
Zinc Borate 2335 Dermal Rabbit LD50 > 10,000 mg/kg
Zinc Borate 2335 Ingestion Rat LD50 > 10,000 mg/kg
Sodium Silicate Dermal Rabbit LD50 > 4,640 mg/kg
Sodium Silicate Ingestion Rat LD50 500 mg/kg
Ethylhexyldiphenyl phosphate Dermal Rabbit LD50 > 7,940 mg/kg
Ethylhexyldiphenyl phosphate Ingestion Rat LD50 > 24,000 mg/kg
Iron oxide Dermal Not
available
LD50 3,100 mg/kg
Iron oxide Ingestion Not
available
LD50 3,700 mg/kg
Polyethylene Glycol Dermal Rabbit LD50 > 20,000 mg/kg
Polyethylene Glycol Ingestion Rat LD50 32,770 mg/kg
Oxide glass chemicals Dermal LD50 estimated to be > 5,000 mg/kg
Oxide glass chemicals Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg
Polyoxyethylene monooctylphenyl ether Dermal Rabbit LD50 > 3,000 mg/kg
Polyoxyethylene monooctylphenyl ether Ingestion Rat LD50 > 500 mg/kg
Triphenyl phosphate Dermal Rabbit LD50 > 7,900 mg/kg
Triphenyl phosphate Inhalation-
Dust/Mist
(4 hours)
Rat LC50 > 50 mg/l
Triphenyl phosphate Ingestion Rat LD50 > 3,000 mg/kg
3(2H)-Isothiazolone, 5-chloro-2-methyl-, mixt. with 2-methyl-
3(2H)-isothiazolone
Dermal Rabbit LD50 87 mg/kg
3(2H)-Isothiazolone, 5-chloro-2-methyl-, mixt. with 2-methyl-
3(2H)-isothiazolone
Inhalation-
Dust/Mist
(4 hours)
Rat LC50 0.33 mg/l
3(2H)-Isothiazolone, 5-chloro-2-methyl-, mixt. with 2-methyl-
3(2H)-isothiazolone
Ingestion Rat LD50 40 mg/kg
ATE = acute toxicity estimate
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SkinCorrosion/Irritation
Name Species Value
Polymer (NJTS Reg. No. 04499600-7270) Rabbit Minimal irritation
Sodium Silicate Rabbit Corrosive
Iron oxide Rabbit No significant irritation
Polyethylene Glycol Rabbit Minimal irritation
Oxide glass chemicals Professio
nal
judgeme
nt
No significant irritation
3(2H)-Isothiazolone, 5-chloro-2-methyl-, mixt. with 2-methyl-3(2H)-
isothiazolone
Rabbit Corrosive
Serious Eye Damage/Irritation
Name Species Value
Polymer (NJTS Reg. No. 04499600-7270) Professio
nal
judgeme
nt
Mild irritant
Sodium Silicate Rabbit Corrosive
Iron oxide Rabbit No significant irritation
Polyethylene Glycol Rabbit Mild irritant
Oxide glass chemicals Professio
nal
judgeme
nt
No significant irritation
3(2H)-Isothiazolone, 5-chloro-2-methyl-, mixt. with 2-methyl-3(2H)-
isothiazolone
Rabbit Corrosive
Skin Sensitization
Name Species Value
Sodium Silicate Mouse Not sensitizing
Iron oxide Human Some positive data exist, but the data are not
sufficient for classification
Polyethylene Glycol Guinea
pig
Not sensitizing
3(2H)-Isothiazolone, 5-chloro-2-methyl-, mixt. with 2-methyl-3(2H)-
isothiazolone
Human
and
animal
Sensitizing
Photosensitization
Name Species Value
3(2H)-Isothiazolone, 5-chloro-2-methyl-, mixt. with 2-methyl-3(2H)-
isothiazolone
Human
and
animal
Not sensitizing
Respiratory Sensitization
For the component/components, either no data are currently available or the data are not sufficient for classification.
Germ Cell Mutagenicity
Name Route Value
Sodium Silicate In Vitro Not mutagenic
Sodium Silicate In vivo Not mutagenic
Iron oxide In Vitro Not mutagenic
Polyethylene Glycol In Vitro Not mutagenic
Polyethylene Glycol In vivo Not mutagenic
Oxide glass chemicals In Vitro Some positive data exist, but the data are not
sufficient for classification
3(2H)-Isothiazolone, 5-chloro-2-methyl-, mixt. with 2-methyl-3(2H)- In vivo Not mutagenic
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Page 8 of 11
isothiazolone
3(2H)-Isothiazolone, 5-chloro-2-methyl-, mixt. with 2-methyl-3(2H)-
isothiazolone
In Vitro Some positive data exist, but the data are not
sufficient for classification
Carcinogenicity
Name Route Species Value
Iron oxide Inhalation Human Some positive data exist, but the data are not
sufficient for classification
Polyethylene Glycol Ingestion Rat Not carcinogenic
Oxide glass chemicals Inhalation Multiple
animal
species
Some positive data exist, but the data are not
sufficient for classification
3(2H)-Isothiazolone, 5-chloro-2-methyl-, mixt. with 2-methyl-
3(2H)-isothiazolone
Dermal Mouse Not carcinogenic
3(2H)-Isothiazolone, 5-chloro-2-methyl-, mixt. with 2-methyl-
3(2H)-isothiazolone
Ingestion Rat Not carcinogenic
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test Result Exposure
Duration
Sodium Silicate Ingestion Some positive developmental data exist,
but the data are not sufficient for
classification
Mouse NOAEL 200
mg/kg/day
during
gestation
Polyethylene Glycol Ingestion Not toxic to female reproduction Rat NOAEL 1,125
mg/kg/day
during
gestation
Polyethylene Glycol Ingestion Not toxic to male reproduction Rat NOAEL 5699
+/- 1341
mg/kg/day
5 days
Polyethylene Glycol Not
Specified
Some positive
reproductive/developmental data exist,
but the data are not sufficient for
classification
NOEL N/A
Polyethylene Glycol Ingestion Some positive developmental data exist,
but the data are not sufficient for
classification
Mouse NOAEL 562
mg/animal/da
y
during
gestation
3(2H)-Isothiazolone, 5-chloro-2-methyl-,
mixt. with 2-methyl-3(2H)-isothiazolone
Ingestion Not toxic to female reproduction Rat NOAEL 10
mg/kg/day
2 generation
3(2H)-Isothiazolone, 5-chloro-2-methyl-,
mixt. with 2-methyl-3(2H)-isothiazolone
Ingestion Not toxic to male reproduction Rat NOAEL 10
mg/kg/day
2 generation
3(2H)-Isothiazolone, 5-chloro-2-methyl-,
mixt. with 2-methyl-3(2H)-isothiazolone
Ingestion Not toxic to development Rat NOAEL 15
mg/kg/day
during
organogenesi
s
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Sodium Silicate Inhalation respiratory irritation May cause respiratory irritation official
classifica
tion
NOAEL Not
available
Polyethylene Glycol Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL
1.008 mg/l
2 weeks
3(2H)-Isothiazolone, 5-
chloro-2-methyl-, mixt.
with 2-methyl-3(2H)-
isothiazolone
Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
similar
health
hazards
NOAEL Not
available
Specific Target Organ Toxicity - repeated exposure
Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Sodium Silicate Ingestion kidney and/or Some positive data exist, but the Dog LOAEL 4 weeks
3M Brand Fire Barrier CP-25WB+ 08/16/16
Page 9 of 11
bladder data are not sufficient for
classification
2,400
mg/kg/day
Sodium Silicate Ingestion endocrine system Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 804
mg/kg/day
3 months
Sodium Silicate Ingestion blood All data are negative Rat NOAEL 804
mg/kg/day
3 months
Sodium Silicate Ingestion heart | liver All data are negative Rat NOAEL
1,259
mg/kg/day
8 weeks
Iron oxide Inhalation pulmonary fibrosis |
pneumoconiosis
Some positive data exist, but the
data are not sufficient for
classification
Human NOAEL Not
available
occupational
exposure
Polyethylene Glycol Inhalation respiratory system Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL
1.008 mg/l
2 weeks
Polyethylene Glycol Ingestion kidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL
5,640
mg/kg/day
13 weeks
Polyethylene Glycol Ingestion heart | endocrine
system |
hematopoietic
system | liver |
nervous system
All data are negative Rat NOAEL
5,640
mg/kg/day
13 weeks
Oxide glass chemicals Inhalation respiratory system Some positive data exist, but the
data are not sufficient for
classification
Human NOAEL not
available
occupational
exposure
Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification.
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
Ecotoxicological information
Test Organism Test Type Result
Water flea, Daphnia magna 48 hours Aquatic Toxicity - Acute 27 mg/l
Green algae, Pseudokirchneriella subcapitata 72 hours Aquatic Toxicity - Chronic 2.6 mg/l
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste
incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty
drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations
classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes
unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the
available treatment and disposal facilities.
SECTION 13: Disposal considerations
SECTION 12: Ecological information
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EPA Hazardous Waste Number (RCRA): Not regulated
15.1. US Federal Regulations
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt
Zinc Borate 2335 (ZINC COMPOUNDS) 138265-88-0 10 - 30
15.2. State Regulations
15.3. Chemical Inventories
The components of this material are in compliance with the provisions of Australia National Industrial Chemical Notification
and Assessment Scheme (NICNAS). Certain restrictions may apply. Contact the selling division for additional information.
The components of this product are in compliance with the new substance notification requirements of CEPA.
The components of this material are in compliance with the China "Measures on Environmental Management of New
Chemical Substance". Certain restrictions may apply. Contact the selling division for additional information.
The components of this material are in compliance with the provisions of the Korean Toxic Chemical Control Law. Certain
restrictions may apply. Contact the selling division for additional information.
The components of this product are in compliance with the chemical notification requirements of TSCA.
15.4. International Regulations
NFPA Hazard Classification
Health: 1 Flammability: 1 Instability: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
SECTION 16: Other information
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 15: Regulatory information
For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.
SECTION 14: Transport Information
3M Brand Fire Barrier CP-25WB+ 08/16/16
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HMIS Hazard Classification
Health: 2 Flammability: 1 Physical Hazard: 0 Personal Protection: X - See PPE section.
Hazardous Material Identification System (HMIS® IV) hazard ratings are designed to inform employees of chemical hazards
in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use
and are not intended for use in emergency situations. HMIS® IV ratings are to be used with a fully implemented HMIS® IV
program. HMIS® is a registered mark of the American Coatings Association (ACA).
Document Group: 09-5451-1 Version Number: 26.01
Issue Date: 08/16/16 Supercedes Date: 06/20/14
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or
accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M
3M USA SDSs are available at www.3M.com
3M™ Heavy Duty 20 Spray Adhesive 04/25/17
Page 1 of 13
SECTION 1: Identification
Safety Data Sheet
Copyright,2017,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group: 26-9520-3 Version Number: 6.00
Issue Date: 04/25/17 Supercedes Date: 04/15/17
1.1. Product identifier
3M™ Heavy Duty 20 Spray Adhesive
Product Identification Numbers
62-4915-4920-0, 62-4915-4925-9
1.2. Recommended use and restrictions on use
Recommended use
Adhesive aerosol, Industrial Use
1.3. Supplier’s details
MANUFACTURER: 3M
DIVISION: Industrial Adhesives and Tapes Division
ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA
Telephone: 1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
2.1. Hazard classification
Flammable Aerosol: Category 1.
Gas Under Pressure: Liquefied gas.
Serious Eye Damage/Irritation: Category 2B.
Reproductive Toxicity: Category 2.
Simple Asphyxiant.
Specific Target Organ Toxicity (single exposure): Category 1.
Specific Target Organ Toxicity (single exposure): Category 3.
Specific Target Organ Toxicity (repeated exposure): Category 1.
2.2. Label elements
Signal word
Danger
SECTION 2: Hazard identification
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Page 2 of 13
Symbols
Flame | Gas cylinder | Exclamation mark | Health Hazard |
Pictograms
Hazard Statements
Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes eye irritation.
May cause respiratory irritation.
May cause drowsiness or dizziness.
Suspected of damaging fertility or the unborn child.
May displace oxygen and cause rapid suffocation.
Causes damage to organs:
cardiovascular system |
Causes damage to organs through prolonged or repeated exposure:
nervous system |
Precautionary Statements
General:
Keep out of reach of children.
Prevention:
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Do not spray on an open flame or other ignition source.
Pressurized container: Do not pierce or burn, even after use.
Do not breathe dust/fume/gas/mist/vapors/spray.
Use only outdoors or in a well-ventilated area.
Wear protective gloves.
Do not eat, drink or smoke when using this product.
Wash thoroughly after handling.
Response:
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF exposed or concerned: Get medical advice/attention.
Specific treatment (see Notes to Physician on this label).
Storage:
Protect from sunlight. Do not expose to temperatures exceeding 50C/122F.
Keep container tightly closed.
Store locked up in a well-ventilated place.
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Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.
Notes to Physician:
Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary.
2.3. Hazards not otherwise classified
SupplementalInformation:
Intentional misuse by deliberately concentrating and inhaling contents can be harmful or fatal.
Ingredient C.A.S. No. % by Wt
Methyl acetate 79-20-9 25 - 35 Trade Secret *
Non-hazardous components (N.J.T.S. Reg No. 4499600-
6761)
Trade Secret* 20 - 30 Trade Secret *
Dimethyl ether 115-10-6 15 - 25 Trade Secret *
Hexane 110-54-3 10 - 20 Trade Secret *
Isobutane 75-28-5 5 - 10 Trade Secret *
Propane 74-98-6 5 - 10 Trade Secret *
*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.
4.1. Description of first aid measures
Inhalation:
Remove person to fresh air. Get medical attention.
Skin Contact:
Wash with soap and water. If signs/symptoms develop, get medical attention.
Eye Contact:
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.
If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.
4.3. Indication of any immediate medical attention and special treatment required
Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary.
5.1. Suitable extinguishing media
In case of fire: Use a carbon dioxide or dry chemical extinguisher to extinguish.
SECTION 5: Fire-fighting measures
SECTION 4: First aid measures
SECTION 3: Composition/information on ingredients
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5.2. Special hazards arising from the substance or mixture
Closed containers exposed to heat from fire may build pressure and explode.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Toxic Vapor, Gas, Particulate During Combustion
5.3. Special protective actions for fire-fighters
Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and
prevent explosive rupture.
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools.
Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or
exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and
could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for
information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmentalprecautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or
if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is
available. Place in a metal container approved for transportation by appropriate authorities. Seal the container. Dispose
of collected material as soon as possible.
7.1. Precautions for safe handling
Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from
heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not
pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing.
Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment.
Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Use personal protective equipment (gloves,
respirators, etc.) as required.
7.2. Conditions for safe storage including any incompatibilities
Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures
exceeding 50C/122F. Store away from heat. Store away from acids. Store away from oxidizing agents.
8.1. Control parameters
Occupational exposure limits
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
Ingredient C.A.S. No. Agency Limit type Additional Comments
SECTION 8: Exposure controls/personal protection
SECTION 7: Handling and storage
SECTION 6: Accidental release measures
3M™ Heavy Duty 20 Spray Adhesive 04/25/17
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Hexane 110-54-3 ACGIH TWA:50 ppm SKIN
Hexane 110-54-3 OSHA TWA:1800 mg/m3(500 ppm)
Dimethyl ether 115-10-6 AIHA TWA:1880 mg/m3(1000 ppm)
Propane 74-98-6 ACGIH Limit value not established:
Propane 74-98-6 OSHA TWA:1800 mg/m3(1000 ppm)
Isobutane 75-28-5 ACGIH STEL:1000 ppm
Methyl acetate 79-20-9 ACGIH TWA:200 ppm;STEL:250 ppm
Methyl acetate 79-20-9 OSHA TWA:610 mg/m3(200 ppm)
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Do not remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local exhaust
ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray.
If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect Vented Goggles
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing.
Gloves made from the following material(s) are recommended: Butyl Rubber
Nitrile Rubber
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part
of a full respiratory protection program. Based on the results of the exposure assessment, select from the following
respirator type(s) to reduce inhalation exposure:
Half facepiece or full facepiece supplied-air respirator
Organic vapor respirators may have short service life.
For questions about suitability for a specific application, consult with your respirator manufacturer.
9.1. Information on basic physical and chemical properties
General Physical Form: Liquid
Specific Physical Form: Aerosol
Odor, Color, Grade: Clear, Mild Solvent Odor
SECTION 9: Physical and chemical properties
3M™ Heavy Duty 20 Spray Adhesive 04/25/17
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Odor threshold No Data Available
pH No Data Available
Melting point No Data Available
Boiling Point [Details:Aerosol]Not Applicable
Flash Point -137 ºF [Details:Propellant]
Evaporation rate 1.9 [Ref Std:ETHER=1]
Flammability (solid, gas) Not Applicable
Flammable Limits(LEL) No Data Available
Flammable Limits(UEL) No Data Available
Vapor Pressure No Data Available
Vapor Density 2.97 [Ref Std:AIR=1]
Density 0.75 g/ml
Specific Gravity 0.73 - 0.77 [Ref Std:WATER=1]
Solubility in Water Nil
Solubility- non-water No Data Available
Partition coefficient: n-octanol/ water No Data Available
Autoignitiontemperature No Data Available
Decompositiontemperature Not Applicable
Viscosity Not Applicable
Hazardous Air Pollutants <=16.8 % weight [Test Method:Calculated]
Molecular weight No Data Available
Volatile Organic Compounds <=378 g/l [Test Method:calculated SCAQMD rule 443.1]
[Details:Material VOC]
Volatile Organic Compounds <=51.8 % [Test Method:calculated per CARB title 2]
10.1. Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.
10.2. Chemical stability
Stable.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
Heat
10.5. Incompatible materials
Strong oxidizing agents
10.6. Hazardous decomposition products
Substance Condition
None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
SECTION 11: Toxicological information
SECTION 10: Stability and reactivity
3M™ Heavy Duty 20 Spray Adhesive 04/25/17
Page 7 of 13
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
Intentional concentration and inhalation may be harmful or fatal.
Simple Asphyxiation: Signs/symptoms may include increased heart rate, rapid respirations, drowsiness, headache,
incoordination, altered judgement, nausea, vomiting, lethargy, seizures, coma, and may be fatal.
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and
nose and throat pain.
May cause additional health effects (see below).
Skin Contact:
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May cause additional health effects (see below).
Additional Health Effects:
Single exposure may cause target organ effects:
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination,
nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.
Single exposure, above recommended guidelines, may cause:
Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may
be fatal.
Prolonged or repeated exposure may cause target organ effects:
Peripheral Neuropathy: Signs/symptoms may include tingling or numbness of the extremities, incoordination, weakness of the
hands and feet, tremors and muscle atrophy.
Reproductive/DevelopmentalToxicity:
Contains a chemical or chemicals which can cause birth defects or other reproductive harm.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
3M™ Heavy Duty 20 Spray Adhesive 04/25/17
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Overall product Inhalation-
Vapor(4 hr)
No data available; calculated ATE >50 mg/l
Overall product Ingestion No data available; calculated ATE >5,000 mg/kg
Methyl acetate Dermal Rat LD50 > 2,000 mg/kg
Methyl acetate Inhalation-
Vapor (4
hours)
Rat LC50 > 49 mg/l
Methyl acetate Ingestion Rat LD50 > 5,000 mg/kg
Hexane Dermal Rabbit LD50 > 2,000 mg/kg
Hexane Inhalation-
Vapor (4
hours)
Rat LC50 170 mg/l
Hexane Ingestion Rat LD50 > 28,700 mg/kg
Dimethyl ether Inhalation-
Gas (4
hours)
Rat LC50 164,000 ppm
Isobutane Inhalation-
Gas (4
hours)
Rat LC50 276,000 ppm
Propane Inhalation-
Gas (4
hours)
Rat LC50 > 200,000 ppm
Non-hazardous components (N.J.T.S. Reg No. 4499600-6761) Dermal Not
available
LD50 > 2,000 mg/kg
Non-hazardous components (N.J.T.S. Reg No. 4499600-6761) Ingestion Not
available
LD50 > 2,000 mg/kg
ATE = acute toxicity estimate
SkinCorrosion/Irritation
Name Species Value
Methyl acetate Rabbit No significant irritation
Hexane Human
and
animal
Mild irritant
Isobutane Professio
nal
judgeme
nt
No significant irritation
Propane Rabbit Minimal irritation
Non-hazardous components (N.J.T.S. Reg No. 4499600-6761) Professio
nal
judgeme
nt
No significant irritation
Serious Eye Damage/Irritation
Name Species Value
Methyl acetate Rabbit Moderate irritant
Hexane Rabbit Mild irritant
Isobutane Professio
nal
judgeme
nt
No significant irritation
Propane Rabbit Mild irritant
Non-hazardous components (N.J.T.S. Reg No. 4499600-6761) Professio
nal
judgeme
nt
No significant irritation
Skin Sensitization
Name Species Value
Methyl acetate Human Not sensitizing
Hexane Human Not sensitizing
3M™ Heavy Duty 20 Spray Adhesive 04/25/17
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Non-hazardous components (N.J.T.S. Reg No. 4499600-6761) Not sensitizing
Respiratory Sensitization
For the component/components, either no data are currently available or the data are not sufficient for classification.
Germ Cell Mutagenicity
Name Route Value
Methyl acetate In Vitro Not mutagenic
Methyl acetate In vivo Not mutagenic
Hexane In Vitro Not mutagenic
Hexane In vivo Not mutagenic
Dimethyl ether In Vitro Not mutagenic
Dimethyl ether In vivo Not mutagenic
Isobutane In Vitro Not mutagenic
Propane In Vitro Not mutagenic
Carcinogenicity
Name Route Species Value
Hexane Dermal Mouse Not carcinogenic
Hexane Inhalation Mouse Some positive data exist, but the data are not
sufficient for classification
Dimethyl ether Inhalation Rat Not carcinogenic
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test Result Exposure
Duration
Hexane Ingestion Not toxic to development Mouse NOAEL 2,200
mg/kg/day
during
organogenesi
s
Hexane Inhalation Some positive developmental data exist,
but the data are not sufficient for
classification
Rat NOAEL 0.7
mg/l
during
gestation
Hexane Ingestion Toxic to male reproduction Rat NOAEL 1,140
mg/kg/day
90 days
Hexane Inhalation Toxic to male reproduction Rat LOAEL 3.52
mg/l
28 days
Dimethyl ether Inhalation Not toxic to development Rat NOAEL
40,000 ppm
during
organogenesi
s
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Methyl acetate Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Human
and
animal
NOAEL Not
available
Methyl acetate Inhalation respiratory irritation May cause respiratory irritation Human
and
animal
NOAEL Not
available
Methyl acetate Inhalation blindness Some positive data exist, but the
data are not sufficient for
classification
NOAEL Not
available
Methyl acetate Ingestion central nervous
system depression
May cause drowsiness or
dizziness
NOAEL Not
available
Hexane Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Human NOAEL Not
available
not available
Hexane Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
Rabbit NOAEL Not
available
8 hours
3M™ Heavy Duty 20 Spray Adhesive 04/25/17
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classification
Hexane Inhalation respiratory system Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 24.6
mg/l
8 hours
Dimethyl ether Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Rat LOAEL
10,000 ppm
30 minutes
Dimethyl ether Inhalation cardiac sensitization Some positive data exist, but the
data are not sufficient for
classification
Dog NOAEL
100,000 ppm
5 minutes
Isobutane Inhalation cardiac sensitization Causes damage to organs Multiple
animal
species
NOAEL Not
available
Isobutane Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Human
and
animal
NOAEL Not
available
Isobutane Inhalation respiratory irritation All data are negative Mouse NOAEL Not
available
Propane Inhalation cardiac sensitization Causes damage to organs Human NOAEL Not
available
Propane Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Human NOAEL Not
available
Propane Inhalation respiratory irritation All data are negative Human NOAEL Not
available
Specific Target Organ Toxicity - repeated exposure
Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Methyl acetate Inhalation respiratory system Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 1.1
mg/l
28 days
Methyl acetate Inhalation endocrine system |
hematopoietic
system | liver |
immune system |
kidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 6.1
mg/l
28 days
Hexane Inhalation peripheral nervous
system
Causes damage to organs through
prolonged or repeated exposure
Human NOAEL Not
available
occupational
exposure
Hexane Inhalation respiratory system Some positive data exist, but the
data are not sufficient for
classification
Mouse LOAEL 1.76
mg/l
13 weeks
Hexane Inhalation liver Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL Not
available
6 months
Hexane Inhalation kidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
Rat LOAEL 1.76
mg/l
6 months
Hexane Inhalation hematopoietic
system
Some positive data exist, but the
data are not sufficient for
classification
Mouse NOAEL 35.2
mg/l
13 weeks
Hexane Inhalation auditory system |
immune system |
eyes
Some positive data exist, but the
data are not sufficient for
classification
Human NOAEL Not
available
occupational
exposure
Hexane Inhalation heart | skin |
endocrine system
All data are negative Rat NOAEL 1.76
mg/l
6 months
Hexane Ingestion peripheral nervous
system
Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL
1,140
mg/kg/day
90 days
Hexane Ingestion endocrine system |
hematopoietic
system | liver |
immune system |
kidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL Not
available
13 weeks
Dimethyl ether Inhalation hematopoietic
system
Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL
25,000 ppm
2 years
3M™ Heavy Duty 20 Spray Adhesive 04/25/17
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Dimethyl ether Inhalation liver Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL
20,000 ppm
30 weeks
Isobutane Inhalation kidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL
4,500 ppm
13 weeks
Aspiration Hazard
Name Value
Hexane Aspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
Ecotoxicologicalinformation
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Incinerate in a permitted waste incineration facility. Facility must be capable of handling aerosol cans. As a disposal
alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and
handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable
regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable
waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal
facilities.
EPA Hazardous Waste Number (RCRA): D001 (Ignitable)
15.1. US Federal Regulations
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed
Hazard - Yes
EPCRA 311/312 Hazard Classifications (effective January 1, 2018):
SECTION 15: Regulatory information
For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.
SECTION 14: Transport Information
SECTION 13: Disposal considerations
SECTION 12: Ecological information
3M™ Heavy Duty 20 Spray Adhesive 04/25/17
Page 12 of 13
Physical Hazards
Flammable (gases, aerosols, liquids, or solids)
Gas under pressure
Health Hazards
Reproductive toxicity
Serious eye damage or eye irritation
Specific target organ toxicity (single or repeated exposure)
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt
Hexane 110-54-3 Trade Secret 10 - 20
Hexane (Hexane) 110-54-3 10 - 20
15.2. State Regulations
Contact 3M for more information.
15.3. Chemical Inventories
The components of this product are in compliance with the chemical notification requirements of TSCA.
Contact 3M for more information.
15.4. International Regulations
Contact 3M for more information.
NFPA Hazard Classification
Health: 2 Flammability: 4 Instability: 0 Special Hazards: None
Aerosol Storage Code: 3
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
Document Group: 26-9520-3 Version Number: 6.00
Issue Date: 04/25/17 Supercedes Date: 04/15/17
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued.3MMAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE.User is responsible for determining whether the3Mproduct is fit for a particular purpose and suitable for
user's method of use or application.Given the variety of factors that can affect the use and application of a3Mproduct, some of
which are uniquely within the user's knowledge and control,it is essential that the user evaluate the3Mproduct to determine
whether it is fit for a particular purpose and suitable for user's method of use or application.
3Mprovides information in electronic form as a service to its customers. Due to the remote possibility that electronic
SECTION 16: Other information
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
3M™ Heavy Duty 20 Spray Adhesive 04/25/17
Page 13 of 13
transfer may have resulted in errors, omissions or alterations in this information,3Mmakes no representations as to its
completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the
SDS available directly from3M
3M USA SDSs are available at www.3M.com
3M™ Hi-Strength Spray Adhesive 90 (aerosol) 04/28/17
Page 1 of 12
SECTION 1: Identification
Safety Data Sheet
Copyright,2017,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group: 16-4935-9 Version Number: 11.00
Issue Date: 04/28/17 Supercedes Date: 09/23/16
1.1. Product identifier
3M™ Hi-Strength Spray Adhesive 90 (aerosol)
Product Identification Numbers
62-4942-4730-7, 62-4942-4920-4, 62-4942-4921-2, 62-4942-4922-0, 62-4942-4925-3, 62-4942-4927-9, 62-4942-4930-3, 62-
4942-4935-2, 62-4942-4950-1, 62-4942-4955-0, 62-4942-4970-9, 62-4942-4975-8, CS-0406-7111-0
1.2. Recommended use and restrictions on use
Recommended use
Aerosol adhesive. Recommended for industrial and professional use., hi-strength aerosol adhesive
1.3. Supplier’s details
MANUFACTURER: 3M
DIVISION: Industrial Adhesives and Tapes Division
ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA
Telephone: 1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
2.1. Hazard classification
Flammable Aerosol: Category 1.
Gas Under Pressure: Liquefied gas.
Serious Eye Damage/Irritation: Category 2B.
Simple Asphyxiant.
Specific Target Organ Toxicity (single exposure): Category 1.
Specific Target Organ Toxicity (single exposure): Category 3.
2.2. Label elements
Signal word
Danger
Symbols
SECTION 2: Hazard identification
3M™ Hi-Strength Spray Adhesive 90 (aerosol) 04/28/17
Page 2 of 12
Flame | Gas cylinder | Exclamation mark | Health Hazard |
Pictograms
Hazard Statements
Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes eye irritation.
May cause respiratory irritation.
May cause drowsiness or dizziness.
May displace oxygen and cause rapid suffocation.
Causes damage to organs:
cardiovascular system |
Precautionary Statements
General:
Keep out of reach of children.
Prevention:
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Do not spray on an open flame or other ignition source.
Pressurized container: Do not pierce or burn, even after use.
Do not breathe dust/fume/gas/mist/vapors/spray.
Use only outdoors or in a well-ventilated area.
Do not eat, drink or smoke when using this product.
Wash thoroughly after handling.
Response:
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF exposed: Call a POISON CENTER or doctor/physician.
Specific treatment (see Notes to Physician on this label).
Storage:
Protect from sunlight. Do not expose to temperatures exceeding 50C/122F.
Keep container tightly closed.
Store locked up in a well-ventilated place.
Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.
Notes to Physician:
Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary.
2.3. Hazards not otherwise classified
3M™ Hi-Strength Spray Adhesive 90 (aerosol) 04/28/17
Page 3 of 12
SupplementalInformation:
Intentional misuse by deliberately concentrating and inhaling contents can be harmful or fatal.
Ingredient C.A.S. No. % by Wt
Dimethyl ether 115-10-6 35 - 45 Trade Secret *
Methyl acetate 79-20-9 25 - 35 Trade Secret *
Nonvolatile components (N.J.T.S. Reg. No. 0449960-
6448P)
Trade Secret* 10 - 20 Trade Secret *
Cyclohexane 110-82-7 7 - 13 Trade Secret *
1,1-Difluoroethane 75-37-6 1 - 5 Trade Secret *
Pentane 109-66-0 1 - 5 Trade Secret *
*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.
4.1. Description of first aid measures
Inhalation:
Remove person to fresh air. Get medical attention.
Skin Contact:
Wash with soap and water. If signs/symptoms develop, get medical attention.
Eye Contact:
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.
If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.
4.3. Indication of any immediate medical attention and special treatment required
Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary.
5.1. Suitable extinguishing media
Use a fire fighting agent suitable for the surrounding fire.
5.2. Special hazards arising from the substance or mixture
Closed containers exposed to heat from fire may build pressure and explode.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Irritant Vapors or Gases During Combustion
SECTION 5: Fire-fighting measures
SECTION 4: First aid measures
SECTION 3: Composition/information on ingredients
3M™ Hi-Strength Spray Adhesive 90 (aerosol) 04/28/17
Page 4 of 12
5.3. Special protective actions for fire-fighters
No special protective actions for fire-fighters are anticipated.
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools.
Ventilate the area with fresh air. Warning! A motor could be an ignition source and could cause flammable gases or vapors
in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health
hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmentalprecautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or
if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is
available. Close cylinder. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal
container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible.
7.1. Precautions for safe handling
Keep out of reach of children. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an
open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe
dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this
product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidizing agents (eg.
chlorine, chromic acid etc.)
7.2. Conditions for safe storage including any incompatibilities
Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures
exceeding 50C/122F. Store away from heat. Store away from acids. Store away from oxidizing agents.
8.1. Control parameters
Occupational exposure limits
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
Ingredient C.A.S. No. Agency Limit type Additional Comments
Pentane 109-66-0 OSHA TWA:2950 mg/m3(1000 ppm)
Pentane 109-66-0 ACGIH TWA:1000 ppm
Cyclohexane 110-82-7 OSHA TWA:1050 mg/m3(300 ppm)
Cyclohexane 110-82-7 ACGIH TWA:100 ppm
Dimethyl ether 115-10-6 AIHA TWA:1880 mg/m3(1000 ppm)
1,1-Difluoroethane 75-37-6 AIHA TWA:2700 mg/m3(1000 ppm)
Methyl acetate 79-20-9 ACGIH TWA:200 ppm;STEL:250 ppm
Methyl acetate 79-20-9 OSHA TWA:610 mg/m3(200 ppm)
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
SECTION 8: Exposure controls/personal protection
SECTION 7: Handling and storage
SECTION 6: Accidental release measures
3M™ Hi-Strength Spray Adhesive 90 (aerosol) 04/28/17
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OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Do not remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local exhaust
ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray.
If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect Vented Goggles
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing.
Gloves made from the following material(s) are recommended: Butyl Rubber
Nitrile Rubber
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part
of a full respiratory protection program. Based on the results of the exposure assessment, select from the following
respirator type(s) to reduce inhalation exposure:
Half facepiece or full facepiece supplied-air respirator
Organic vapor respirators may have short service life.
For questions about suitability for a specific application, consult with your respirator manufacturer.
9.1. Information on basic physical and chemical properties
General Physical Form: Gas
Specific Physical Form: Aerosol
Odor, Color, Grade: clear, sweet fruity odor
Odor threshold No Data Available
pH No Data Available
Melting point Not Applicable
Boiling Point Not Applicable
Flash Point -42.00 ºF [Test Method:Tagliabue Closed Cup]
Evaporation rate 1.9 [Ref Std:ETHER=1]
Flammability (solid, gas) Flammable Aerosol: Category 1.
Flammable Limits(LEL) No Data Available
Flammable Limits(UEL) No Data Available
Vapor Density 2.97 [Ref Std:AIR=1]
Density 0.726 g/ml
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Specific Gravity 0.726 [Ref Std:WATER=1]
Solubility in Water Nil
Solubility- non-water No Data Available
Partition coefficient: n-octanol/ water No Data Available
Autoignitiontemperature No Data Available
Decompositiontemperature Not Applicable
Viscosity Not Applicable
Hazardous Air Pollutants <=0 % weight [Test Method:Calculated]
Molecular weight No Data Available
VOC Less H2O & Exempt Solvents <=55 % [Test Method:calculated per CARB title 2]
10.1. Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.
10.2. Chemical stability
Stable.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
Heat
10.5. Incompatible materials
Strong oxidizing agents
10.6. Hazardous decomposition products
Substance Condition
None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
Intentional concentration and inhalation may be harmful or fatal.
Simple Asphyxiation: Signs/symptoms may include increased heart rate, rapid respirations, drowsiness, headache,
SECTION 11: Toxicological information
SECTION 10: Stability and reactivity
3M™ Hi-Strength Spray Adhesive 90 (aerosol) 04/28/17
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incoordination, altered judgement, nausea, vomiting, lethargy, seizures, coma, and may be fatal.
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and
nose and throat pain.
May cause additional health effects (see below).
Skin Contact:
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May cause additional health effects (see below).
Additional Health Effects:
Single exposure may cause target organ effects:
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination,
nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.
Single exposure, above recommended guidelines, may cause:
Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may
be fatal.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
Overall product Dermal No data available; calculated ATE >5,000 mg/kg
Overall product Inhalation-
Vapor(4 hr)
No data available; calculated ATE >50 mg/l
Overall product Ingestion No data available; calculated ATE >5,000 mg/kg
Dimethyl ether Inhalation-
Gas (4
hours)
Rat LC50 164,000 ppm
Methyl acetate Dermal Rat LD50 > 2,000 mg/kg
Methyl acetate Inhalation-
Vapor (4
hours)
Rat LC50 > 49 mg/l
Methyl acetate Ingestion Rat LD50 > 5,000 mg/kg
Cyclohexane Dermal Rat LD50 > 2,000 mg/kg
Cyclohexane Inhalation-
Vapor (4
hours)
Rat LC50 > 32.9 mg/l
Cyclohexane Ingestion Rat LD50 6,200 mg/kg
Nonvolatile components (N.J.T.S. Reg. No. 0449960-6448P) Dermal LD50 estimated to be > 5,000 mg/kg
Nonvolatile components (N.J.T.S. Reg. No. 0449960-6448P) Ingestion Rat LD50 > 34,000 mg/kg
Pentane Dermal Rabbit LD50 3,000 mg/kg
Pentane Inhalation-
Vapor (4
hours)
Rat LC50 > 18 mg/l
Pentane Ingestion Rat LD50 > 2,000 mg/kg
1,1-Difluoroethane Inhalation- Rat LC50 > 437,000 ppm
3M™ Hi-Strength Spray Adhesive 90 (aerosol) 04/28/17
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Gas (4
hours)
1,1-Difluoroethane Ingestion Rat LD50 > 1,500 mg/kg
ATE = acute toxicity estimate
SkinCorrosion/Irritation
Name Species Value
Methyl acetate Rabbit No significant irritation
Cyclohexane Rabbit Mild irritant
Pentane Rabbit Minimal irritation
Serious Eye Damage/Irritation
Name Species Value
Methyl acetate Rabbit Moderate irritant
Cyclohexane Rabbit Mild irritant
Pentane Rabbit Mild irritant
Skin Sensitization
Name Species Value
Methyl acetate Human Not classified
Pentane Guinea
pig
Not classified
Respiratory Sensitization
For the component/components, either no data are currently available or the data are not sufficient for classification.
Germ Cell Mutagenicity
Name Route Value
Dimethyl ether In Vitro Not mutagenic
Dimethyl ether In vivo Not mutagenic
Methyl acetate In Vitro Not mutagenic
Methyl acetate In vivo Not mutagenic
Cyclohexane In Vitro Not mutagenic
Cyclohexane In vivo Some positive data exist, but the data are not
sufficient for classification
Pentane In vivo Not mutagenic
Pentane In Vitro Some positive data exist, but the data are not
sufficient for classification
1,1-Difluoroethane In Vitro Some positive data exist, but the data are not
sufficient for classification
1,1-Difluoroethane In vivo Some positive data exist, but the data are not
sufficient for classification
Carcinogenicity
Name Route Species Value
Dimethyl ether Inhalation Rat Not carcinogenic
1,1-Difluoroethane Inhalation Rat Some positive data exist, but the data are not
sufficient for classification
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test Result Exposure
Duration
Dimethyl ether Inhalation Not classified for development Rat NOAEL
40,000 ppm
during
organogenesi
s
Cyclohexane Inhalation Not classified for female reproduction Rat NOAEL 24 2 generation
3M™ Hi-Strength Spray Adhesive 90 (aerosol) 04/28/17
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mg/l
Cyclohexane Inhalation Not classified for male reproduction Rat NOAEL 24
mg/l
2 generation
Cyclohexane Inhalation Not classified for development Rat NOAEL 6.9
mg/l
2 generation
Pentane Ingestion Not classified for development Rat NOAEL 1,000
mg/kg/day
during
organogenesi
s
Pentane Inhalation Not classified for development Rat NOAEL 30
mg/l
during
organogenesi
s
1,1-Difluoroethane Inhalation Not classified for development Rat NOAEL
50,000 ppm
during
organogenesi
s
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Dimethyl ether Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Rat LOAEL
10,000 ppm
30 minutes
Dimethyl ether Inhalation cardiac sensitization Some positive data exist, but the
data are not sufficient for
classification
Dog NOAEL
100,000 ppm
5 minutes
Methyl acetate Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Human
and
animal
NOAEL Not
available
Methyl acetate Inhalation respiratory irritation May cause respiratory irritation Human
and
animal
NOAEL Not
available
Methyl acetate Inhalation blindness Not classified NOAEL Not
available
Methyl acetate Ingestion central nervous
system depression
May cause drowsiness or
dizziness
NOAEL Not
available
Cyclohexane Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Human
and
animal
NOAEL Not
available
Cyclohexane Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
Human
and
animal
NOAEL Not
available
Cyclohexane Ingestion central nervous
system depression
May cause drowsiness or
dizziness
Professio
nal
judgeme
nt
NOAEL Not
available
Pentane Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Multiple
animal
species
NOAEL Not
available
not available
Pentane Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
Not
available
NOAEL Not
available
not available
Pentane Inhalation cardiac sensitization Not classified Dog NOAEL Not
available
not available
Pentane Ingestion central nervous
system depression
May cause drowsiness or
dizziness
Professio
nal
judgeme
nt
NOAEL Not
available
not available
1,1-Difluoroethane Inhalation cardiac sensitization Causes damage to organs Human
and
animal
NOAEL Not
available
poisoning
and/or abuse
1,1-Difluoroethane Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Human
and
animal
NOAEL
100,000 ppm
1,1-Difluoroethane Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
Not
available
NOAEL Not
available
not available
3M™ Hi-Strength Spray Adhesive 90 (aerosol) 04/28/17
Page 10 of 12
Specific Target Organ Toxicity - repeated exposure
Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Dimethyl ether Inhalation hematopoietic
system
Not classified Rat NOAEL
25,000 ppm
2 years
Dimethyl ether Inhalation liver Not classified Rat NOAEL
20,000 ppm
30 weeks
Methyl acetate Inhalation respiratory system Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 1.1
mg/l
28 days
Methyl acetate Inhalation endocrine system |
hematopoietic
system | liver |
immune system |
kidney and/or
bladder
Not classified Rat NOAEL 6.1
mg/l
28 days
Cyclohexane Inhalation liver Not classified Rat NOAEL 24
mg/l
90 days
Cyclohexane Inhalation auditory system Not classified Rat NOAEL 1.7
mg/l
90 days
Cyclohexane Inhalation kidney and/or
bladder
Not classified Rabbit NOAEL 2.7
mg/l
10 weeks
Cyclohexane Inhalation hematopoietic
system
Not classified Mouse NOAEL 24
mg/l
14 weeks
Cyclohexane Inhalation peripheral nervous
system
Not classified Rat NOAEL 8.6
mg/l
30 weeks
Pentane Inhalation peripheral nervous
system
Not classified Human NOAEL Not
available
occupational
exposure
Pentane Inhalation heart | skin |
endocrine system |
bone, teeth, nails,
and/or hair |
hematopoietic
system | liver |
immune system |
muscles | nervous
system | eyes |
kidney and/or
bladder | respiratory
system
Not classified Rat NOAEL 20
mg/l
13 weeks
Pentane Ingestion kidney and/or
bladder
Not classified Rat NOAEL
2,000
mg/kg/day
28 days
1,1-Difluoroethane Inhalation hematopoietic
system | kidney
and/or bladder |
respiratory system
Not classified Rat NOAEL
25,000 ppm
2 years
Aspiration Hazard
Name Value
Cyclohexane Aspiration hazard
Pentane Aspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
Ecotoxicologicalinformation
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
SECTION 12: Ecological information
3M™ Hi-Strength Spray Adhesive 90 (aerosol) 04/28/17
Page 11 of 12
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste
incineration facility. Facility must be capable of handling aerosol cans. The facility should be equipped to handle gaseous
waste. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical
substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated
& disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective
regulating authorities to determine the available treatment and disposal facilities.
EPA Hazardous Waste Number (RCRA): D001 (Ignitable)
15.1. US Federal Regulations
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed
Hazard - No
EPCRA 311/312 Hazard Classifications (effective January 1, 2018):
Physical Hazards
Flammable (gases, aerosols, liquids, or solids)
Gas under pressure
Health Hazards
Serious eye damage or eye irritation
Simple Asphyxiant
Specific target organ toxicity (single or repeated exposure)
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt
Cyclohexane 110-82-7 Trade Secret 7 - 13
15.2. State Regulations
Contact 3M for more information.
SECTION 15: Regulatory information
For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.
SECTION 14: Transport Information
SECTION 13: Disposal considerations
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ADOBE DRYWALL SDS.pdf

  • 1. TABLE OF CONTENTS 1 3M ADHESIVE PRODUCTS 2 3M FIRE CAULKING 3 3M HEAVY DUTY 20 SPRAY ADEHSIVE 4 3M SPRAY ADHESIVE 90 5 BLACK CHALK 6 BLUE CHALK 7 CLARKDIETRICH METAL PRODUCTS 8 CLINCH ON CORNER BEAD 9 DAP DYNAGRIP ALL PURPOSE ADHESIVE 10 FRP FAST GRAB 11 HILTI GAS GC41 12 HOMAX WALL TEXTURE 13 IPG MASKING TAPE 14 NATURES SWEEPEING COMPOUND 15 PABCO DRYWALL 16 PLS 180 17 PLS 3 18 PLS 360 19 PYRO-GUARD WOOD PRODUCTS 20 RAMSET BATTERY 21 RAMSET FUEL CELL 22 RAMSET POWDER LOADS 23 RED CHALK 24 RTV SILICONE 25 SEYMOUR CLEAR SPRAY 26 SEYMOUR COLOR SPRAY
  • 2. 27 UGS ACOUSTICAL SEALANT 28 UNITED METALS 29 WD-40 30 WHITE LIGHTNING ACRYLIC LATEX 31 WESTPAC PAPER TAPE 32 WESTPAC POWDERED JOINT COMP. 33 WESTPAC PREP COAT 34 WESTPAC READY-MIX 35 WESTPAC SETTING COMPOUNDS 36 W ES T WESTPAC SMOOTH COAT
  • 3. 3M™ Abrasive Products, 362L, 372L, 382L 08/25/14 Page 1 of 10 SECTION 1: Identification Safety Data Sheet Copyright,2014,3MCompany. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 23-7173-0 Version Number: 2.12 Issue Date: 08/25/14 Supercedes Date: 03/21/14 1.1. Product identifier 3M™ Abrasive Products, 362L, 372L, 382L 1.2. Recommended use and restrictions on use Recommended use Abrasive Product 1.3. Supplier’s details MANUFACTURER: 3M DIVISION: Abrasive Systems Division ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) 2.1. Hazard classification Not classified as hazardous according to OSHA Hazard Communication Standard, 29 CFR 1910.1200. 2.2. Label elements Signal word Not applicable. Symbols Not applicable. Pictograms Not applicable. 2.3. Hazards not otherwise classified None. 29% of the mixture consists of ingredients of unknown acute oral toxicity. SECTION 3: Composition/information on ingredients SECTION 2: Hazard identification
  • 4. 3M™ Abrasive Products, 362L, 372L, 382L 08/25/14 Page 2 of 10 Ingredient C.A.S. No. % by Wt Aluminum Oxide Mineral (non-fibrous) 1344-28-1 3 - 35 Filler 1317-65-3 3 - 20 Filler 1332-58-7 0 - 5 Crystalline Free Fumed Silica 112945-52-5 0 - 5 Titanium Dioxide 13463-67-7 0.2 - 2.5 Quartz Silica 14808-60-7 0.001 - 0.4 Cured Resin Mixture 5 - 30 Film Backing Mixture 20 - 75 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Wash with soap and water. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: No need for first aid is anticipated. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Condition Aldehydes During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures SECTION 5: Fire-fighting measures SECTION 4: First aid measures
  • 5. 3M™ Abrasive Products, 362L, 372L, 382L 08/25/14 Page 3 of 10 6.1. Personal precautions, protective equipment and emergency procedures Observe precautions from other sections. 6.2. Environmentalprecautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Not applicable. 7.1. Precautions for safe handling For industrial or professional use only. Avoid breathing of dust created by sanding, grinding or machining. Damaged product can break apart during use and cause serious injury to face or eyes. Check product for damage such as cracks or nicks prior to use. Replace if damaged. Always wear eye and face protection when working at sanding or grinding operations or when near such operations. Avoid release to the environment. Combustible dust may form by action of this product on another material (substrate). Dust generated from the substrate during use of this product may be explosive if in sufficient concentration with an ignition source. Dust deposits should not be allowed to accumulate on surfaces because of the potential for secondary explosions. 7.2. Conditions for safe storage including any incompatibilities No special storage requirements. 8.1. Control parameters Occupational exposure limits Ingredient C.A.S. No. Agency Limit type Additional Comments SILICA, AMORPHOUS 112945-52- 5 OSHA TWA concentration:0.8 mg/m3;TWA:20 millions of particles/cu. ft. Filler 1317-65-3 OSHA TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 KAOLIN, TOTAL DUST 1332-58-7 OSHA TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 Filler 1332-58-7 ACGIH TWA(respirable fraction):2 mg/m3 A4: Not class. as human carcin Aluminum Oxide Mineral (non- fibrous) 1344-28-1 CMRG TWA:1 fiber/cc Aluminum, insoluble compounds 1344-28-1 ACGIH TWA(respirable fraction):1 mg/m3 A4: Not class. as human carcin Aluminum Oxide Mineral (non- fibrous) 1344-28-1 OSHA TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 Titanium Dioxide 13463-67-7 OSHA TWA(as total dust):15 mg/m3 Titanium Dioxide 13463-67-7 ACGIH TWA:10 mg/m3 A4: Not class. as human carcin Titanium Dioxide 13463-67-7 CMRG TWA(as respirable dust):5 mg/m3 Quartz Silica 14808-60-7 OSHA TWA concentration(as total SECTION 8: Exposure controls/personal protection SECTION 7: Handling and storage
  • 6. 3M™ Abrasive Products, 362L, 372L, 382L 08/25/14 Page 4 of 10 dust):0.3 mg/m3;TWA concentration(respirable):0.1 mg/m3(2.4 millions of particles/cu. ft.) Quartz Silica 14808-60-7 ACGIH TWA(respirable fraction):0.025 mg/m3 A2: Suspected human carcin. Film Backing Mixture CMRG TWA(as respirable dust):5 mg/m3;TWA(as total dust):10 mg/m3 ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Provide appropriate local exhaust ventilation for sanding, grinding or machining. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Provide local exhaust at process emission sources to control exposure near the source and to prevent the escape of dust into the work area. Ensure that dust-handling systems (such as exhaust ducts, dust collectors, vessels, and processing equipment) are designed in a manner to prevent the escape of dust into the work area (i.e., there is no leakage from the equipment). 8.2.2. Personal protective equipment (PPE) Eye/face protection To minimize the risk of injury to face and eyes, always wear eye and face protection when working at sanding or grinding operations or when near such operations. Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Safety Glasses with side shields Skin/hand protection Wear appropriate gloves to minimize risk of injury to skin from contact with dust or physical abrasion from grinding or sanding. Respiratory protection Assess exposure concentrations of all materials involved in the work process. Consider material being abraded when determining the appropriate respiratory protection. Select and use appropriate respirators to prevent inhalation overexposure. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for particulates For questions about suitability for a specific application, consult with your respirator manufacturer. 9.1. Information on basic physical and chemical properties General Physical Form: Solid Odor, Color, Grade: Solid Abrasive Product SECTION 9: Physical and chemical properties
  • 7. 3M™ Abrasive Products, 362L, 372L, 382L 08/25/14 Page 5 of 10 Odor threshold Not Applicable pH Not Applicable Melting point Not Applicable Boiling Point Not Applicable Flash Point Not Applicable Evaporation rate Not Applicable Flammability (solid, gas) Not Classified Flammable Limits(LEL) Not Applicable Flammable Limits(UEL) Not Applicable Vapor Pressure Not Applicable Vapor Density Not Applicable Density Not Applicable Specific Gravity Not Applicable Solubility In Water Not Applicable Solubility- non-water Not Applicable Partition coefficient: n-octanol/ water Not Applicable Autoignitiontemperature Not Applicable Decompositiontemperature Not Applicable Viscosity Not Applicable VOC Less H2O & Exempt Solvents No Data Available 10.1. Reactivity This material is considered to be non reactive under normal use conditions. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid None known. 10.5. Incompatible materials None known. 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects SECTION 11: Toxicological information SECTION 10: Stability and reactivity
  • 8. 3M™ Abrasive Products, 362L, 372L, 382L 08/25/14 Page 6 of 10 Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Dust from grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Skin Contact: Mechanical Skin irritation: Signs/symptoms may include abrasion, redness, pain, and itching. Allergic Skin Reaction (non-photo induced) in sensitive people: Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Mechanical eye irritation: Signs/symptoms may include pain, redness, tearing and corneal abrasion. Dust created by grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: No health effects are expected. Carcinogenicity: Ingredient C.A.S. No. Class Description Regulation SILICA, CRYS AIRRESP 14808-60-7 Known human carcinogen National Toxicology Program Carcinogens Quartz Silica 14808-60-7 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer Titanium Dioxide 13463-67-7 Grp. 2B: Possible human carc. International Agency for Research on Cancer Additional Information: This document covers only the 3M product. For complete assessment, when determining the degree of hazard, the material being abraded must also be considered. This product contains titanium dioxide and quartz (crystalline) silica. Cancer of the lungs has been associated with inhalation of high levels of titanium dioxide in animal studies, and occupational exposure to inhaled quartz silica has been associated with silicosis and lung cancer. No exposure to titanium dioxide or quartz silica is expected during the normal handling and use of this product. Titanium dioxide and quartz silica were not detected when air sampling was conducted during simulated use of similar products containing these substances. Therefore, the health effects associated with titanium dioxide and quartz (crystalline) silica are not expected during the normal use of this product. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg Film Backing Dermal LD50 estimated to be > 5,000 mg/kg Film Backing Ingestion Rat LD50 > 5,000 mg/kg Aluminum Oxide Mineral (non-fibrous) Dermal LD50 estimated to be > 5,000 mg/kg Aluminum Oxide Mineral (non-fibrous) Inhalation- Dust/Mist (4 hours) Rat LC50 > 2.3 mg/l Aluminum Oxide Mineral (non-fibrous) Ingestion Rat LD50 > 5,000 mg/kg Filler Dermal Rat LD50 > 2,000 mg/kg Filler Inhalation- Dust/Mist Rat LC50 3.0 mg/l
  • 9. 3M™ Abrasive Products, 362L, 372L, 382L 08/25/14 Page 7 of 10 (4 hours) Filler Ingestion Rat LD50 6,450 mg/kg Filler Dermal LD50 estimated to be > 5,000 mg/kg Filler Ingestion Human LD50 > 15,000 mg/kg Crystalline Free Fumed Silica Dermal Rabbit LD50 > 5,000 mg/kg Crystalline Free Fumed Silica Inhalation- Dust/Mist (4 hours) Rat LC50 > 0.691 mg/l Crystalline Free Fumed Silica Ingestion Rat LD50 > 5,110 mg/kg Titanium Dioxide Dermal Rabbit LD50 > 10,000 mg/kg Titanium Dioxide Inhalation- Dust/Mist (4 hours) Rat LC50 > 6.82 mg/l Titanium Dioxide Ingestion Rat LD50 > 10,000 mg/kg Quartz Silica Dermal LD50 estimated to be > 5,000 mg/kg Quartz Silica Ingestion LD50 estimated to be > 5,000 mg/kg ATE = acute toxicity estimate SkinCorrosion/Irritation Name Species Value Aluminum Oxide Mineral (non-fibrous) Rabbit No significant irritation Filler Rabbit No significant irritation Filler No significant irritation Crystalline Free Fumed Silica Rabbit No significant irritation Titanium Dioxide Rabbit No significant irritation Quartz Silica No significant irritation Serious Eye Damage/Irritation Name Species Value Aluminum Oxide Mineral (non-fibrous) Rabbit No significant irritation Filler Rabbit No significant irritation Filler No significant irritation Crystalline Free Fumed Silica Rabbit No significant irritation Titanium Dioxide Rabbit No significant irritation Skin Sensitization Name Species Value Crystalline Free Fumed Silica Human and animal Not sensitizing Titanium Dioxide Human and animal Not sensitizing Respiratory Sensitization Name Species Value Germ Cell Mutagenicity Name Route Value Aluminum Oxide Mineral (non-fibrous) In Vitro Not mutagenic Crystalline Free Fumed Silica In Vitro Not mutagenic Titanium Dioxide In Vitro Not mutagenic Titanium Dioxide In vivo Not mutagenic Quartz Silica In Vitro Some positive data exist, but the data are not sufficient for classification Quartz Silica In vivo Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Aluminum Oxide Mineral (non-fibrous) Inhalation Rat Not carcinogenic Filler Inhalation Multiple animal species Not carcinogenic
  • 10. 3M™ Abrasive Products, 362L, 372L, 382L 08/25/14 Page 8 of 10 Crystalline Free Fumed Silica Not Specified Mouse Some positive data exist, but the data are not sufficient for classification Titanium Dioxide Ingestion Multiple animal species Not carcinogenic Titanium Dioxide Inhalation Rat Carcinogenic Quartz Silica Inhalation Human and animal Carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Filler Ingestion Not toxic to development Rat NOAEL 625 mg/kg/day premating & during gestation Crystalline Free Fumed Silica Ingestion Not toxic to female reproduction Rat NOAEL 509 mg/kg/day 1 generation Crystalline Free Fumed Silica Ingestion Not toxic to male reproduction Rat NOAEL 497 mg/kg/day 1 generation Crystalline Free Fumed Silica Ingestion Not toxic to development Rat NOAEL 1,350 mg/kg/day during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Filler Inhalation respiratory system All data are negative Rat NOAEL 0.812 mg/l 90 minutes Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Aluminum Oxide Mineral (non-fibrous) Inhalation pneumoconiosis | pulmonary fibrosis Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Filler Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Filler Inhalation pneumoconiosis Causes damage to organs through prolonged or repeated exposure Human NOAEL NA occupational exposure Filler Inhalation pulmonary fibrosis Some positive data exist, but the data are not sufficient for classification Rat NOAEL Not available Crystalline Free Fumed Silica Inhalation respiratory system | silicosis All data are negative Human NOAEL Not available occupational exposure Titanium Dioxide Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 0.010 mg/l 2 years Titanium Dioxide Inhalation pulmonary fibrosis All data are negative Human NOAEL Not available occupational exposure Quartz Silica Inhalation silicosis Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure Aspiration Hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information Name Value
  • 11. 3M™ Abrasive Products, 362L, 372L, 382L 08/25/14 Page 9 of 10 on this material and/or its components. Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. The substrate that was abraded must be considered as a factor in the disposal method for this product. Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Combustion products will include halogen acid (HCl/HF/HBr). Facility must be capable of handling halogenated materials. EPA Hazardous Waste Number (RCRA): Not regulated Not regulated per U.S. DOT, IATA or IMO. 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - No Delayed Hazard - No 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories This product is an article as defined by TSCA regulations, and is exempt from TSCA Inventory listing requirements. Contact 3M for more information. SECTION 15: Regulatory information These transportation classifications are provided as a customer service. As the shipper YOU remain responsible for complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M transportation classifications are based on product formulation, packaging, 3M policies and 3M understanding of applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to transportation classification and not the packaging, labeling, or marking requirements. The original 3M package is certified for U.S. ground shipment only. If you are shipping by air or ocean, the package may not meet applicable regulatory requirements. SECTION 14: Transport Information SECTION 13: Disposal considerations SECTION 12: Ecological information
  • 12. 3M™ Abrasive Products, 362L, 372L, 382L 08/25/14 Page 10 of 10 15.4. International Regulations Contact 3M for more information. NFPA Hazard Classification Health: 0 Flammability: 1 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. HMIS Hazard Classification Health: 0 Flammability: 1 Physical Hazard: 0 Personal Protection: X - See PPE section. Hazardous Material Identification System (HMIS® III) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS® III ratings are to be used with a fully implemented HMIS® III program. HMIS® is a registered mark of the American Coatings Association (ACA). Document Group: 23-7173-0 Version Number: 2.12 Issue Date: 08/25/14 Supercedes Date: 03/21/14 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com SECTION 16: Other information This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
  • 13. 3M Brand Fire Barrier CP-25WB+ 08/16/16 Page 1 of 11 SECTION 1: Identification Safety Data Sheet Copyright,2016,3MCompany. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 09-5451-1 Version Number: 26.01 Issue Date: 08/16/16 Supercedes Date: 06/20/14 1.1. Product identifier 3M Brand Fire Barrier CP-25WB+ Product Identification Numbers ID Number UPC ID Number UPC 42-0016-4710-8 42-0016-4715-7 42-0016-4716-5 98-0400-5380-7 00-51115-11639-1 98-0400-5381-5 00-51115-11640-7 98-0400-5382-3 00-51115-11641-4 98-0400-5383-1 00-51115-11642-1 98-0400-5406-0 00-51115-16515-3 98-0400-5456-5 98-0400-5562-0 000-51115-11642-1 98-0400-5573-7 000-51115-16515-3 98-0400-5610-7 98-0400-5629-7 1.2. Recommended use and restrictions on use Recommended use Fire Protection, Used as Firestop in buildings. 1.3. Supplier’s details MANUFACTURER: 3M DIVISION: Industrial Adhesives and Tapes Division ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) 2.1. Hazard classification Serious Eye Damage/Irritation: Category 2B. 2.2. Label elements Signal word Warning Symbols SECTION 2: Hazard identification
  • 14. 3M Brand Fire Barrier CP-25WB+ 08/16/16 Page 2 of 11 Not applicable Pictograms Not applicable Hazard Statements Causes eye irritation. Precautionary Statements General: Keep out of reach of children. Prevention: Wash thoroughly after handling. Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. 2.3. Hazards not otherwise classified None. Ingredient C.A.S. No. % by Wt Sodium Silicate 1344-09-8 10 - 30 Trade Secret * Water 7732-18-5 10 - 30 Trade Secret * Zinc Borate 2335 138265-88-0 10 - 30 Trade Secret * Polymer (NJTS Reg. No. 04499600-7270) Trade Secret* 10 - 30 Trade Secret * Ethylhexyldiphenylphosphate 1241-94-7 3 - 7 Trade Secret * Iron oxide 1309-37-1 1 - 5 Trade Secret * Oxide glass chemicals 65997-17-3 1 - 5 Trade Secret * Polyethylene Glycol 25322-68-3 1 - 5 Trade Secret * Di-2-ethylhexlphenylphosphate 16368-97-1 < 1.0 Trade Secret * Polyoxyethylene monooctylphenyl ether 9036-19-5 < 1.0 Trade Secret * Triphenyl phosphate 115-86-6 < 1.0 Trade Secret * 3(2H)-Isothiazolone, 5-chloro-2-methyl-, mixt. with 2- methyl-3(2H)-isothiazolone 55965-84-9 < 0.001 Trade Secret * NJTS or NJTSRN: New Jersey Trade Secret Registry Number. *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Wash with soap and water. If signs/symptoms develop, get medical attention. SECTION 4: First aid measures SECTION 3: Composition/information on ingredients
  • 15. 3M Brand Fire Barrier CP-25WB+ 08/16/16 Page 3 of 11 Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable 5.1. Suitable extinguishing media Non-combustible. Use a fire fighting agent suitable for surrounding fire. 5.2. Special hazards arising from the substance or mixture None inherent in this product. 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmentalprecautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue. Seal the container. Dispose of collected material as soon as possible. 7.1. Precautions for safe handling Avoid eye contact. Keep out of reach of children. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. 7.2. Conditions for safe storage including any incompatibilities Keep cool. Store away from heat. Store away from areas where product may come into contact with food or pharmaceuticals. Store in a dry place. 8.1. Control parameters Occupational exposure limits SECTION 8: Exposure controls/personal protection SECTION 7: Handling and storage SECTION 6: Accidental release measures SECTION 5: Fire-fighting measures
  • 16. 3M Brand Fire Barrier CP-25WB+ 08/16/16 Page 4 of 11 If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Triphenyl phosphate 115-86-6 ACGIH TWA:3 mg/m3 A4: Not class. as human carcin Triphenyl phosphate 115-86-6 OSHA TWA:3 mg/m3 Iron oxide 1309-37-1 OSHA TWA(as fume):10 mg/m3 ROUGE 1309-37-1 OSHA TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 Iron oxide 1309-37-1 ACGIH TWA(respirable fraction):5 mg/m3 A4: Not class. as human carcin Polyethylene Glycol 25322-68-3 AIHA TWA(as particulate):10 mg/m3 Oxide glass chemicals 65997-17-3 Manufacturer determined TWA(as dust):10 mg/m3 ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Butyl Rubber Neoprene Nitrile Rubber Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for particulates For questions about suitability for a specific application, consult with your respirator manufacturer.
  • 17. 3M Brand Fire Barrier CP-25WB+ 08/16/16 Page 5 of 11 9.1. Information on basic physical and chemical properties General Physical Form: Solid Specific Physical Form: Paste Odor, Color, Grade: Red with negligible odor Odor threshold No Data Available Melting point No Data Available Flash Point No flash point Flammability (solid, gas) Not Classified Flammable Limits(LEL) Not Applicable Flammable Limits(UEL) Not Applicable Specific Gravity 1.35 [Ref Std: WATER=1] Solubility in Water Complete Solubility- non-water No Data Available Autoignitiontemperature Not Applicable Decompositiontemperature No Data Available Molecular weight No Data Available Volatile Organic Compounds <=0.5 % weight [Test Method: tested per EPA method 24] VOC Less H2O & Exempt Solvents <=6 g/l [Test Method: tested per EPA method 24] 10.1. Reactivity This material is considered to be non reactive under normal use conditions. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid None known. 10.5. Incompatible materials None known. 10.6. Hazardous decomposition products Substance Condition Carbon monoxide Not Specified Carbon dioxide Not Specified Oxides of Phosphorus Not Specified The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects SECTION 11: Toxicological information SECTION 10: Stability and reactivity SECTION 9: Physical and chemical properties
  • 18. 3M Brand Fire Barrier CP-25WB+ 08/16/16 Page 6 of 11 Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: May be harmful if swallowed. Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE > 5,000 mg/kg Overall product Ingestion No data available; calculated ATE 2,000 - 5,000 mg/kg Polymer (NJTS Reg. No. 04499600-7270) Dermal LD50 estimated to be > 5,000 mg/kg Polymer (NJTS Reg. No. 04499600-7270) Ingestion Rat LD50 > 2,000 mg/kg Zinc Borate 2335 Dermal Rabbit LD50 > 10,000 mg/kg Zinc Borate 2335 Ingestion Rat LD50 > 10,000 mg/kg Sodium Silicate Dermal Rabbit LD50 > 4,640 mg/kg Sodium Silicate Ingestion Rat LD50 500 mg/kg Ethylhexyldiphenyl phosphate Dermal Rabbit LD50 > 7,940 mg/kg Ethylhexyldiphenyl phosphate Ingestion Rat LD50 > 24,000 mg/kg Iron oxide Dermal Not available LD50 3,100 mg/kg Iron oxide Ingestion Not available LD50 3,700 mg/kg Polyethylene Glycol Dermal Rabbit LD50 > 20,000 mg/kg Polyethylene Glycol Ingestion Rat LD50 32,770 mg/kg Oxide glass chemicals Dermal LD50 estimated to be > 5,000 mg/kg Oxide glass chemicals Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg Polyoxyethylene monooctylphenyl ether Dermal Rabbit LD50 > 3,000 mg/kg Polyoxyethylene monooctylphenyl ether Ingestion Rat LD50 > 500 mg/kg Triphenyl phosphate Dermal Rabbit LD50 > 7,900 mg/kg Triphenyl phosphate Inhalation- Dust/Mist (4 hours) Rat LC50 > 50 mg/l Triphenyl phosphate Ingestion Rat LD50 > 3,000 mg/kg 3(2H)-Isothiazolone, 5-chloro-2-methyl-, mixt. with 2-methyl- 3(2H)-isothiazolone Dermal Rabbit LD50 87 mg/kg 3(2H)-Isothiazolone, 5-chloro-2-methyl-, mixt. with 2-methyl- 3(2H)-isothiazolone Inhalation- Dust/Mist (4 hours) Rat LC50 0.33 mg/l 3(2H)-Isothiazolone, 5-chloro-2-methyl-, mixt. with 2-methyl- 3(2H)-isothiazolone Ingestion Rat LD50 40 mg/kg ATE = acute toxicity estimate
  • 19. 3M Brand Fire Barrier CP-25WB+ 08/16/16 Page 7 of 11 SkinCorrosion/Irritation Name Species Value Polymer (NJTS Reg. No. 04499600-7270) Rabbit Minimal irritation Sodium Silicate Rabbit Corrosive Iron oxide Rabbit No significant irritation Polyethylene Glycol Rabbit Minimal irritation Oxide glass chemicals Professio nal judgeme nt No significant irritation 3(2H)-Isothiazolone, 5-chloro-2-methyl-, mixt. with 2-methyl-3(2H)- isothiazolone Rabbit Corrosive Serious Eye Damage/Irritation Name Species Value Polymer (NJTS Reg. No. 04499600-7270) Professio nal judgeme nt Mild irritant Sodium Silicate Rabbit Corrosive Iron oxide Rabbit No significant irritation Polyethylene Glycol Rabbit Mild irritant Oxide glass chemicals Professio nal judgeme nt No significant irritation 3(2H)-Isothiazolone, 5-chloro-2-methyl-, mixt. with 2-methyl-3(2H)- isothiazolone Rabbit Corrosive Skin Sensitization Name Species Value Sodium Silicate Mouse Not sensitizing Iron oxide Human Some positive data exist, but the data are not sufficient for classification Polyethylene Glycol Guinea pig Not sensitizing 3(2H)-Isothiazolone, 5-chloro-2-methyl-, mixt. with 2-methyl-3(2H)- isothiazolone Human and animal Sensitizing Photosensitization Name Species Value 3(2H)-Isothiazolone, 5-chloro-2-methyl-, mixt. with 2-methyl-3(2H)- isothiazolone Human and animal Not sensitizing Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Sodium Silicate In Vitro Not mutagenic Sodium Silicate In vivo Not mutagenic Iron oxide In Vitro Not mutagenic Polyethylene Glycol In Vitro Not mutagenic Polyethylene Glycol In vivo Not mutagenic Oxide glass chemicals In Vitro Some positive data exist, but the data are not sufficient for classification 3(2H)-Isothiazolone, 5-chloro-2-methyl-, mixt. with 2-methyl-3(2H)- In vivo Not mutagenic
  • 20. 3M Brand Fire Barrier CP-25WB+ 08/16/16 Page 8 of 11 isothiazolone 3(2H)-Isothiazolone, 5-chloro-2-methyl-, mixt. with 2-methyl-3(2H)- isothiazolone In Vitro Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Iron oxide Inhalation Human Some positive data exist, but the data are not sufficient for classification Polyethylene Glycol Ingestion Rat Not carcinogenic Oxide glass chemicals Inhalation Multiple animal species Some positive data exist, but the data are not sufficient for classification 3(2H)-Isothiazolone, 5-chloro-2-methyl-, mixt. with 2-methyl- 3(2H)-isothiazolone Dermal Mouse Not carcinogenic 3(2H)-Isothiazolone, 5-chloro-2-methyl-, mixt. with 2-methyl- 3(2H)-isothiazolone Ingestion Rat Not carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Sodium Silicate Ingestion Some positive developmental data exist, but the data are not sufficient for classification Mouse NOAEL 200 mg/kg/day during gestation Polyethylene Glycol Ingestion Not toxic to female reproduction Rat NOAEL 1,125 mg/kg/day during gestation Polyethylene Glycol Ingestion Not toxic to male reproduction Rat NOAEL 5699 +/- 1341 mg/kg/day 5 days Polyethylene Glycol Not Specified Some positive reproductive/developmental data exist, but the data are not sufficient for classification NOEL N/A Polyethylene Glycol Ingestion Some positive developmental data exist, but the data are not sufficient for classification Mouse NOAEL 562 mg/animal/da y during gestation 3(2H)-Isothiazolone, 5-chloro-2-methyl-, mixt. with 2-methyl-3(2H)-isothiazolone Ingestion Not toxic to female reproduction Rat NOAEL 10 mg/kg/day 2 generation 3(2H)-Isothiazolone, 5-chloro-2-methyl-, mixt. with 2-methyl-3(2H)-isothiazolone Ingestion Not toxic to male reproduction Rat NOAEL 10 mg/kg/day 2 generation 3(2H)-Isothiazolone, 5-chloro-2-methyl-, mixt. with 2-methyl-3(2H)-isothiazolone Ingestion Not toxic to development Rat NOAEL 15 mg/kg/day during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Sodium Silicate Inhalation respiratory irritation May cause respiratory irritation official classifica tion NOAEL Not available Polyethylene Glycol Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.008 mg/l 2 weeks 3(2H)-Isothiazolone, 5- chloro-2-methyl-, mixt. with 2-methyl-3(2H)- isothiazolone Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification similar health hazards NOAEL Not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Sodium Silicate Ingestion kidney and/or Some positive data exist, but the Dog LOAEL 4 weeks
  • 21. 3M Brand Fire Barrier CP-25WB+ 08/16/16 Page 9 of 11 bladder data are not sufficient for classification 2,400 mg/kg/day Sodium Silicate Ingestion endocrine system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 804 mg/kg/day 3 months Sodium Silicate Ingestion blood All data are negative Rat NOAEL 804 mg/kg/day 3 months Sodium Silicate Ingestion heart | liver All data are negative Rat NOAEL 1,259 mg/kg/day 8 weeks Iron oxide Inhalation pulmonary fibrosis | pneumoconiosis Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Polyethylene Glycol Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.008 mg/l 2 weeks Polyethylene Glycol Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 5,640 mg/kg/day 13 weeks Polyethylene Glycol Ingestion heart | endocrine system | hematopoietic system | liver | nervous system All data are negative Rat NOAEL 5,640 mg/kg/day 13 weeks Oxide glass chemicals Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Human NOAEL not available occupational exposure Aspiration Hazard For the component/components, either no data are currently available or the data are not sufficient for classification. Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. Ecotoxicological information Test Organism Test Type Result Water flea, Daphnia magna 48 hours Aquatic Toxicity - Acute 27 mg/l Green algae, Pseudokirchneriella subcapitata 72 hours Aquatic Toxicity - Chronic 2.6 mg/l Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 13: Disposal considerations SECTION 12: Ecological information
  • 22. 3M Brand Fire Barrier CP-25WB+ 08/16/16 Page 10 of 11 EPA Hazardous Waste Number (RCRA): Not regulated 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Zinc Borate 2335 (ZINC COMPOUNDS) 138265-88-0 10 - 30 15.2. State Regulations 15.3. Chemical Inventories The components of this material are in compliance with the provisions of Australia National Industrial Chemical Notification and Assessment Scheme (NICNAS). Certain restrictions may apply. Contact the selling division for additional information. The components of this product are in compliance with the new substance notification requirements of CEPA. The components of this material are in compliance with the China "Measures on Environmental Management of New Chemical Substance". Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of the Korean Toxic Chemical Control Law. Certain restrictions may apply. Contact the selling division for additional information. The components of this product are in compliance with the chemical notification requirements of TSCA. 15.4. International Regulations NFPA Hazard Classification Health: 1 Flammability: 1 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. SECTION 16: Other information This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 15: Regulatory information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 14: Transport Information
  • 23. 3M Brand Fire Barrier CP-25WB+ 08/16/16 Page 11 of 11 HMIS Hazard Classification Health: 2 Flammability: 1 Physical Hazard: 0 Personal Protection: X - See PPE section. Hazardous Material Identification System (HMIS® IV) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS® IV ratings are to be used with a fully implemented HMIS® IV program. HMIS® is a registered mark of the American Coatings Association (ACA). Document Group: 09-5451-1 Version Number: 26.01 Issue Date: 08/16/16 Supercedes Date: 06/20/14 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com
  • 24. 3M™ Heavy Duty 20 Spray Adhesive 04/25/17 Page 1 of 13 SECTION 1: Identification Safety Data Sheet Copyright,2017,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 26-9520-3 Version Number: 6.00 Issue Date: 04/25/17 Supercedes Date: 04/15/17 1.1. Product identifier 3M™ Heavy Duty 20 Spray Adhesive Product Identification Numbers 62-4915-4920-0, 62-4915-4925-9 1.2. Recommended use and restrictions on use Recommended use Adhesive aerosol, Industrial Use 1.3. Supplier’s details MANUFACTURER: 3M DIVISION: Industrial Adhesives and Tapes Division ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) 2.1. Hazard classification Flammable Aerosol: Category 1. Gas Under Pressure: Liquefied gas. Serious Eye Damage/Irritation: Category 2B. Reproductive Toxicity: Category 2. Simple Asphyxiant. Specific Target Organ Toxicity (single exposure): Category 1. Specific Target Organ Toxicity (single exposure): Category 3. Specific Target Organ Toxicity (repeated exposure): Category 1. 2.2. Label elements Signal word Danger SECTION 2: Hazard identification
  • 25. 3M™ Heavy Duty 20 Spray Adhesive 04/25/17 Page 2 of 13 Symbols Flame | Gas cylinder | Exclamation mark | Health Hazard | Pictograms Hazard Statements Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of damaging fertility or the unborn child. May displace oxygen and cause rapid suffocation. Causes damage to organs: cardiovascular system | Causes damage to organs through prolonged or repeated exposure: nervous system | Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF exposed or concerned: Get medical advice/attention. Specific treatment (see Notes to Physician on this label). Storage: Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Keep container tightly closed. Store locked up in a well-ventilated place.
  • 26. 3M™ Heavy Duty 20 Spray Adhesive 04/25/17 Page 3 of 13 Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Notes to Physician: Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. 2.3. Hazards not otherwise classified SupplementalInformation: Intentional misuse by deliberately concentrating and inhaling contents can be harmful or fatal. Ingredient C.A.S. No. % by Wt Methyl acetate 79-20-9 25 - 35 Trade Secret * Non-hazardous components (N.J.T.S. Reg No. 4499600- 6761) Trade Secret* 20 - 30 Trade Secret * Dimethyl ether 115-10-6 15 - 25 Trade Secret * Hexane 110-54-3 10 - 20 Trade Secret * Isobutane 75-28-5 5 - 10 Trade Secret * Propane 74-98-6 5 - 10 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. 4.1. Description of first aid measures Inhalation: Remove person to fresh air. Get medical attention. Skin Contact: Wash with soap and water. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. 5.1. Suitable extinguishing media In case of fire: Use a carbon dioxide or dry chemical extinguisher to extinguish. SECTION 5: Fire-fighting measures SECTION 4: First aid measures SECTION 3: Composition/information on ingredients
  • 27. 3M™ Heavy Duty 20 Spray Adhesive 04/25/17 Page 4 of 13 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion Toxic Vapor, Gas, Particulate During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmentalprecautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Place in a metal container approved for transportation by appropriate authorities. Seal the container. Dispose of collected material as soon as possible. 7.1. Precautions for safe handling Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Use personal protective equipment (gloves, respirators, etc.) as required. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store away from heat. Store away from acids. Store away from oxidizing agents. 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments SECTION 8: Exposure controls/personal protection SECTION 7: Handling and storage SECTION 6: Accidental release measures
  • 28. 3M™ Heavy Duty 20 Spray Adhesive 04/25/17 Page 5 of 13 Hexane 110-54-3 ACGIH TWA:50 ppm SKIN Hexane 110-54-3 OSHA TWA:1800 mg/m3(500 ppm) Dimethyl ether 115-10-6 AIHA TWA:1880 mg/m3(1000 ppm) Propane 74-98-6 ACGIH Limit value not established: Propane 74-98-6 OSHA TWA:1800 mg/m3(1000 ppm) Isobutane 75-28-5 ACGIH STEL:1000 ppm Methyl acetate 79-20-9 ACGIH TWA:200 ppm;STEL:250 ppm Methyl acetate 79-20-9 OSHA TWA:610 mg/m3(200 ppm) ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Do not remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Butyl Rubber Nitrile Rubber Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece supplied-air respirator Organic vapor respirators may have short service life. For questions about suitability for a specific application, consult with your respirator manufacturer. 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Aerosol Odor, Color, Grade: Clear, Mild Solvent Odor SECTION 9: Physical and chemical properties
  • 29. 3M™ Heavy Duty 20 Spray Adhesive 04/25/17 Page 6 of 13 Odor threshold No Data Available pH No Data Available Melting point No Data Available Boiling Point [Details:Aerosol]Not Applicable Flash Point -137 ºF [Details:Propellant] Evaporation rate 1.9 [Ref Std:ETHER=1] Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure No Data Available Vapor Density 2.97 [Ref Std:AIR=1] Density 0.75 g/ml Specific Gravity 0.73 - 0.77 [Ref Std:WATER=1] Solubility in Water Nil Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignitiontemperature No Data Available Decompositiontemperature Not Applicable Viscosity Not Applicable Hazardous Air Pollutants <=16.8 % weight [Test Method:Calculated] Molecular weight No Data Available Volatile Organic Compounds <=378 g/l [Test Method:calculated SCAQMD rule 443.1] [Details:Material VOC] Volatile Organic Compounds <=51.8 % [Test Method:calculated per CARB title 2] 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat 10.5. Incompatible materials Strong oxidizing agents 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be SECTION 11: Toxicological information SECTION 10: Stability and reactivity
  • 30. 3M™ Heavy Duty 20 Spray Adhesive 04/25/17 Page 7 of 13 reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Intentional concentration and inhalation may be harmful or fatal. Simple Asphyxiation: Signs/symptoms may include increased heart rate, rapid respirations, drowsiness, headache, incoordination, altered judgement, nausea, vomiting, lethargy, seizures, coma, and may be fatal. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Single exposure, above recommended guidelines, may cause: Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal. Prolonged or repeated exposure may cause target organ effects: Peripheral Neuropathy: Signs/symptoms may include tingling or numbness of the extremities, incoordination, weakness of the hands and feet, tremors and muscle atrophy. Reproductive/DevelopmentalToxicity: Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value
  • 31. 3M™ Heavy Duty 20 Spray Adhesive 04/25/17 Page 8 of 13 Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE >50 mg/l Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Methyl acetate Dermal Rat LD50 > 2,000 mg/kg Methyl acetate Inhalation- Vapor (4 hours) Rat LC50 > 49 mg/l Methyl acetate Ingestion Rat LD50 > 5,000 mg/kg Hexane Dermal Rabbit LD50 > 2,000 mg/kg Hexane Inhalation- Vapor (4 hours) Rat LC50 170 mg/l Hexane Ingestion Rat LD50 > 28,700 mg/kg Dimethyl ether Inhalation- Gas (4 hours) Rat LC50 164,000 ppm Isobutane Inhalation- Gas (4 hours) Rat LC50 276,000 ppm Propane Inhalation- Gas (4 hours) Rat LC50 > 200,000 ppm Non-hazardous components (N.J.T.S. Reg No. 4499600-6761) Dermal Not available LD50 > 2,000 mg/kg Non-hazardous components (N.J.T.S. Reg No. 4499600-6761) Ingestion Not available LD50 > 2,000 mg/kg ATE = acute toxicity estimate SkinCorrosion/Irritation Name Species Value Methyl acetate Rabbit No significant irritation Hexane Human and animal Mild irritant Isobutane Professio nal judgeme nt No significant irritation Propane Rabbit Minimal irritation Non-hazardous components (N.J.T.S. Reg No. 4499600-6761) Professio nal judgeme nt No significant irritation Serious Eye Damage/Irritation Name Species Value Methyl acetate Rabbit Moderate irritant Hexane Rabbit Mild irritant Isobutane Professio nal judgeme nt No significant irritation Propane Rabbit Mild irritant Non-hazardous components (N.J.T.S. Reg No. 4499600-6761) Professio nal judgeme nt No significant irritation Skin Sensitization Name Species Value Methyl acetate Human Not sensitizing Hexane Human Not sensitizing
  • 32. 3M™ Heavy Duty 20 Spray Adhesive 04/25/17 Page 9 of 13 Non-hazardous components (N.J.T.S. Reg No. 4499600-6761) Not sensitizing Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Methyl acetate In Vitro Not mutagenic Methyl acetate In vivo Not mutagenic Hexane In Vitro Not mutagenic Hexane In vivo Not mutagenic Dimethyl ether In Vitro Not mutagenic Dimethyl ether In vivo Not mutagenic Isobutane In Vitro Not mutagenic Propane In Vitro Not mutagenic Carcinogenicity Name Route Species Value Hexane Dermal Mouse Not carcinogenic Hexane Inhalation Mouse Some positive data exist, but the data are not sufficient for classification Dimethyl ether Inhalation Rat Not carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Hexane Ingestion Not toxic to development Mouse NOAEL 2,200 mg/kg/day during organogenesi s Hexane Inhalation Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 0.7 mg/l during gestation Hexane Ingestion Toxic to male reproduction Rat NOAEL 1,140 mg/kg/day 90 days Hexane Inhalation Toxic to male reproduction Rat LOAEL 3.52 mg/l 28 days Dimethyl ether Inhalation Not toxic to development Rat NOAEL 40,000 ppm during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Methyl acetate Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Methyl acetate Inhalation respiratory irritation May cause respiratory irritation Human and animal NOAEL Not available Methyl acetate Inhalation blindness Some positive data exist, but the data are not sufficient for classification NOAEL Not available Methyl acetate Ingestion central nervous system depression May cause drowsiness or dizziness NOAEL Not available Hexane Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available not available Hexane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for Rabbit NOAEL Not available 8 hours
  • 33. 3M™ Heavy Duty 20 Spray Adhesive 04/25/17 Page 10 of 13 classification Hexane Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 24.6 mg/l 8 hours Dimethyl ether Inhalation central nervous system depression May cause drowsiness or dizziness Rat LOAEL 10,000 ppm 30 minutes Dimethyl ether Inhalation cardiac sensitization Some positive data exist, but the data are not sufficient for classification Dog NOAEL 100,000 ppm 5 minutes Isobutane Inhalation cardiac sensitization Causes damage to organs Multiple animal species NOAEL Not available Isobutane Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Isobutane Inhalation respiratory irritation All data are negative Mouse NOAEL Not available Propane Inhalation cardiac sensitization Causes damage to organs Human NOAEL Not available Propane Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Propane Inhalation respiratory irritation All data are negative Human NOAEL Not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Methyl acetate Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.1 mg/l 28 days Methyl acetate Inhalation endocrine system | hematopoietic system | liver | immune system | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 6.1 mg/l 28 days Hexane Inhalation peripheral nervous system Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure Hexane Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Mouse LOAEL 1.76 mg/l 13 weeks Hexane Inhalation liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL Not available 6 months Hexane Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat LOAEL 1.76 mg/l 6 months Hexane Inhalation hematopoietic system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 35.2 mg/l 13 weeks Hexane Inhalation auditory system | immune system | eyes Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Hexane Inhalation heart | skin | endocrine system All data are negative Rat NOAEL 1.76 mg/l 6 months Hexane Ingestion peripheral nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1,140 mg/kg/day 90 days Hexane Ingestion endocrine system | hematopoietic system | liver | immune system | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL Not available 13 weeks Dimethyl ether Inhalation hematopoietic system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 25,000 ppm 2 years
  • 34. 3M™ Heavy Duty 20 Spray Adhesive 04/25/17 Page 11 of 13 Dimethyl ether Inhalation liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 20,000 ppm 30 weeks Isobutane Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 4,500 ppm 13 weeks Aspiration Hazard Name Value Hexane Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. Ecotoxicologicalinformation Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. Facility must be capable of handling aerosol cans. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. EPA Hazardous Waste Number (RCRA): D001 (Ignitable) 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes EPCRA 311/312 Hazard Classifications (effective January 1, 2018): SECTION 15: Regulatory information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 14: Transport Information SECTION 13: Disposal considerations SECTION 12: Ecological information
  • 35. 3M™ Heavy Duty 20 Spray Adhesive 04/25/17 Page 12 of 13 Physical Hazards Flammable (gases, aerosols, liquids, or solids) Gas under pressure Health Hazards Reproductive toxicity Serious eye damage or eye irritation Specific target organ toxicity (single or repeated exposure) Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Hexane 110-54-3 Trade Secret 10 - 20 Hexane (Hexane) 110-54-3 10 - 20 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. NFPA Hazard Classification Health: 2 Flammability: 4 Instability: 0 Special Hazards: None Aerosol Storage Code: 3 National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 26-9520-3 Version Number: 6.00 Issue Date: 04/25/17 Supercedes Date: 04/15/17 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued.3MMAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE.User is responsible for determining whether the3Mproduct is fit for a particular purpose and suitable for user's method of use or application.Given the variety of factors that can affect the use and application of a3Mproduct, some of which are uniquely within the user's knowledge and control,it is essential that the user evaluate the3Mproduct to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3Mprovides information in electronic form as a service to its customers. Due to the remote possibility that electronic SECTION 16: Other information This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
  • 36. 3M™ Heavy Duty 20 Spray Adhesive 04/25/17 Page 13 of 13 transfer may have resulted in errors, omissions or alterations in this information,3Mmakes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from3M 3M USA SDSs are available at www.3M.com
  • 37. 3M™ Hi-Strength Spray Adhesive 90 (aerosol) 04/28/17 Page 1 of 12 SECTION 1: Identification Safety Data Sheet Copyright,2017,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 16-4935-9 Version Number: 11.00 Issue Date: 04/28/17 Supercedes Date: 09/23/16 1.1. Product identifier 3M™ Hi-Strength Spray Adhesive 90 (aerosol) Product Identification Numbers 62-4942-4730-7, 62-4942-4920-4, 62-4942-4921-2, 62-4942-4922-0, 62-4942-4925-3, 62-4942-4927-9, 62-4942-4930-3, 62- 4942-4935-2, 62-4942-4950-1, 62-4942-4955-0, 62-4942-4970-9, 62-4942-4975-8, CS-0406-7111-0 1.2. Recommended use and restrictions on use Recommended use Aerosol adhesive. Recommended for industrial and professional use., hi-strength aerosol adhesive 1.3. Supplier’s details MANUFACTURER: 3M DIVISION: Industrial Adhesives and Tapes Division ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) 2.1. Hazard classification Flammable Aerosol: Category 1. Gas Under Pressure: Liquefied gas. Serious Eye Damage/Irritation: Category 2B. Simple Asphyxiant. Specific Target Organ Toxicity (single exposure): Category 1. Specific Target Organ Toxicity (single exposure): Category 3. 2.2. Label elements Signal word Danger Symbols SECTION 2: Hazard identification
  • 38. 3M™ Hi-Strength Spray Adhesive 90 (aerosol) 04/28/17 Page 2 of 12 Flame | Gas cylinder | Exclamation mark | Health Hazard | Pictograms Hazard Statements Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. May displace oxygen and cause rapid suffocation. Causes damage to organs: cardiovascular system | Precautionary Statements General: Keep out of reach of children. Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF exposed: Call a POISON CENTER or doctor/physician. Specific treatment (see Notes to Physician on this label). Storage: Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Keep container tightly closed. Store locked up in a well-ventilated place. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Notes to Physician: Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. 2.3. Hazards not otherwise classified
  • 39. 3M™ Hi-Strength Spray Adhesive 90 (aerosol) 04/28/17 Page 3 of 12 SupplementalInformation: Intentional misuse by deliberately concentrating and inhaling contents can be harmful or fatal. Ingredient C.A.S. No. % by Wt Dimethyl ether 115-10-6 35 - 45 Trade Secret * Methyl acetate 79-20-9 25 - 35 Trade Secret * Nonvolatile components (N.J.T.S. Reg. No. 0449960- 6448P) Trade Secret* 10 - 20 Trade Secret * Cyclohexane 110-82-7 7 - 13 Trade Secret * 1,1-Difluoroethane 75-37-6 1 - 5 Trade Secret * Pentane 109-66-0 1 - 5 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. 4.1. Description of first aid measures Inhalation: Remove person to fresh air. Get medical attention. Skin Contact: Wash with soap and water. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. 5.1. Suitable extinguishing media Use a fire fighting agent suitable for the surrounding fire. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion Irritant Vapors or Gases During Combustion SECTION 5: Fire-fighting measures SECTION 4: First aid measures SECTION 3: Composition/information on ingredients
  • 40. 3M™ Hi-Strength Spray Adhesive 90 (aerosol) 04/28/17 Page 4 of 12 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmentalprecautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Close cylinder. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. 7.1. Precautions for safe handling Keep out of reach of children. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store away from heat. Store away from acids. Store away from oxidizing agents. 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Pentane 109-66-0 OSHA TWA:2950 mg/m3(1000 ppm) Pentane 109-66-0 ACGIH TWA:1000 ppm Cyclohexane 110-82-7 OSHA TWA:1050 mg/m3(300 ppm) Cyclohexane 110-82-7 ACGIH TWA:100 ppm Dimethyl ether 115-10-6 AIHA TWA:1880 mg/m3(1000 ppm) 1,1-Difluoroethane 75-37-6 AIHA TWA:2700 mg/m3(1000 ppm) Methyl acetate 79-20-9 ACGIH TWA:200 ppm;STEL:250 ppm Methyl acetate 79-20-9 OSHA TWA:610 mg/m3(200 ppm) ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines SECTION 8: Exposure controls/personal protection SECTION 7: Handling and storage SECTION 6: Accidental release measures
  • 41. 3M™ Hi-Strength Spray Adhesive 90 (aerosol) 04/28/17 Page 5 of 12 OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Do not remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Butyl Rubber Nitrile Rubber Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece supplied-air respirator Organic vapor respirators may have short service life. For questions about suitability for a specific application, consult with your respirator manufacturer. 9.1. Information on basic physical and chemical properties General Physical Form: Gas Specific Physical Form: Aerosol Odor, Color, Grade: clear, sweet fruity odor Odor threshold No Data Available pH No Data Available Melting point Not Applicable Boiling Point Not Applicable Flash Point -42.00 ºF [Test Method:Tagliabue Closed Cup] Evaporation rate 1.9 [Ref Std:ETHER=1] Flammability (solid, gas) Flammable Aerosol: Category 1. Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Density 2.97 [Ref Std:AIR=1] Density 0.726 g/ml SECTION 9: Physical and chemical properties
  • 42. 3M™ Hi-Strength Spray Adhesive 90 (aerosol) 04/28/17 Page 6 of 12 Specific Gravity 0.726 [Ref Std:WATER=1] Solubility in Water Nil Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignitiontemperature No Data Available Decompositiontemperature Not Applicable Viscosity Not Applicable Hazardous Air Pollutants <=0 % weight [Test Method:Calculated] Molecular weight No Data Available VOC Less H2O & Exempt Solvents <=55 % [Test Method:calculated per CARB title 2] 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat 10.5. Incompatible materials Strong oxidizing agents 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Intentional concentration and inhalation may be harmful or fatal. Simple Asphyxiation: Signs/symptoms may include increased heart rate, rapid respirations, drowsiness, headache, SECTION 11: Toxicological information SECTION 10: Stability and reactivity
  • 43. 3M™ Hi-Strength Spray Adhesive 90 (aerosol) 04/28/17 Page 7 of 12 incoordination, altered judgement, nausea, vomiting, lethargy, seizures, coma, and may be fatal. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Single exposure, above recommended guidelines, may cause: Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE >5,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE >50 mg/l Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Dimethyl ether Inhalation- Gas (4 hours) Rat LC50 164,000 ppm Methyl acetate Dermal Rat LD50 > 2,000 mg/kg Methyl acetate Inhalation- Vapor (4 hours) Rat LC50 > 49 mg/l Methyl acetate Ingestion Rat LD50 > 5,000 mg/kg Cyclohexane Dermal Rat LD50 > 2,000 mg/kg Cyclohexane Inhalation- Vapor (4 hours) Rat LC50 > 32.9 mg/l Cyclohexane Ingestion Rat LD50 6,200 mg/kg Nonvolatile components (N.J.T.S. Reg. No. 0449960-6448P) Dermal LD50 estimated to be > 5,000 mg/kg Nonvolatile components (N.J.T.S. Reg. No. 0449960-6448P) Ingestion Rat LD50 > 34,000 mg/kg Pentane Dermal Rabbit LD50 3,000 mg/kg Pentane Inhalation- Vapor (4 hours) Rat LC50 > 18 mg/l Pentane Ingestion Rat LD50 > 2,000 mg/kg 1,1-Difluoroethane Inhalation- Rat LC50 > 437,000 ppm
  • 44. 3M™ Hi-Strength Spray Adhesive 90 (aerosol) 04/28/17 Page 8 of 12 Gas (4 hours) 1,1-Difluoroethane Ingestion Rat LD50 > 1,500 mg/kg ATE = acute toxicity estimate SkinCorrosion/Irritation Name Species Value Methyl acetate Rabbit No significant irritation Cyclohexane Rabbit Mild irritant Pentane Rabbit Minimal irritation Serious Eye Damage/Irritation Name Species Value Methyl acetate Rabbit Moderate irritant Cyclohexane Rabbit Mild irritant Pentane Rabbit Mild irritant Skin Sensitization Name Species Value Methyl acetate Human Not classified Pentane Guinea pig Not classified Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Dimethyl ether In Vitro Not mutagenic Dimethyl ether In vivo Not mutagenic Methyl acetate In Vitro Not mutagenic Methyl acetate In vivo Not mutagenic Cyclohexane In Vitro Not mutagenic Cyclohexane In vivo Some positive data exist, but the data are not sufficient for classification Pentane In vivo Not mutagenic Pentane In Vitro Some positive data exist, but the data are not sufficient for classification 1,1-Difluoroethane In Vitro Some positive data exist, but the data are not sufficient for classification 1,1-Difluoroethane In vivo Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Dimethyl ether Inhalation Rat Not carcinogenic 1,1-Difluoroethane Inhalation Rat Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Dimethyl ether Inhalation Not classified for development Rat NOAEL 40,000 ppm during organogenesi s Cyclohexane Inhalation Not classified for female reproduction Rat NOAEL 24 2 generation
  • 45. 3M™ Hi-Strength Spray Adhesive 90 (aerosol) 04/28/17 Page 9 of 12 mg/l Cyclohexane Inhalation Not classified for male reproduction Rat NOAEL 24 mg/l 2 generation Cyclohexane Inhalation Not classified for development Rat NOAEL 6.9 mg/l 2 generation Pentane Ingestion Not classified for development Rat NOAEL 1,000 mg/kg/day during organogenesi s Pentane Inhalation Not classified for development Rat NOAEL 30 mg/l during organogenesi s 1,1-Difluoroethane Inhalation Not classified for development Rat NOAEL 50,000 ppm during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Dimethyl ether Inhalation central nervous system depression May cause drowsiness or dizziness Rat LOAEL 10,000 ppm 30 minutes Dimethyl ether Inhalation cardiac sensitization Some positive data exist, but the data are not sufficient for classification Dog NOAEL 100,000 ppm 5 minutes Methyl acetate Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Methyl acetate Inhalation respiratory irritation May cause respiratory irritation Human and animal NOAEL Not available Methyl acetate Inhalation blindness Not classified NOAEL Not available Methyl acetate Ingestion central nervous system depression May cause drowsiness or dizziness NOAEL Not available Cyclohexane Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Cyclohexane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human and animal NOAEL Not available Cyclohexane Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available Pentane Inhalation central nervous system depression May cause drowsiness or dizziness Multiple animal species NOAEL Not available not available Pentane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Not available NOAEL Not available not available Pentane Inhalation cardiac sensitization Not classified Dog NOAEL Not available not available Pentane Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available not available 1,1-Difluoroethane Inhalation cardiac sensitization Causes damage to organs Human and animal NOAEL Not available poisoning and/or abuse 1,1-Difluoroethane Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL 100,000 ppm 1,1-Difluoroethane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Not available NOAEL Not available not available
  • 46. 3M™ Hi-Strength Spray Adhesive 90 (aerosol) 04/28/17 Page 10 of 12 Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Dimethyl ether Inhalation hematopoietic system Not classified Rat NOAEL 25,000 ppm 2 years Dimethyl ether Inhalation liver Not classified Rat NOAEL 20,000 ppm 30 weeks Methyl acetate Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.1 mg/l 28 days Methyl acetate Inhalation endocrine system | hematopoietic system | liver | immune system | kidney and/or bladder Not classified Rat NOAEL 6.1 mg/l 28 days Cyclohexane Inhalation liver Not classified Rat NOAEL 24 mg/l 90 days Cyclohexane Inhalation auditory system Not classified Rat NOAEL 1.7 mg/l 90 days Cyclohexane Inhalation kidney and/or bladder Not classified Rabbit NOAEL 2.7 mg/l 10 weeks Cyclohexane Inhalation hematopoietic system Not classified Mouse NOAEL 24 mg/l 14 weeks Cyclohexane Inhalation peripheral nervous system Not classified Rat NOAEL 8.6 mg/l 30 weeks Pentane Inhalation peripheral nervous system Not classified Human NOAEL Not available occupational exposure Pentane Inhalation heart | skin | endocrine system | bone, teeth, nails, and/or hair | hematopoietic system | liver | immune system | muscles | nervous system | eyes | kidney and/or bladder | respiratory system Not classified Rat NOAEL 20 mg/l 13 weeks Pentane Ingestion kidney and/or bladder Not classified Rat NOAEL 2,000 mg/kg/day 28 days 1,1-Difluoroethane Inhalation hematopoietic system | kidney and/or bladder | respiratory system Not classified Rat NOAEL 25,000 ppm 2 years Aspiration Hazard Name Value Cyclohexane Aspiration hazard Pentane Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. Ecotoxicologicalinformation Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information SECTION 12: Ecological information
  • 47. 3M™ Hi-Strength Spray Adhesive 90 (aerosol) 04/28/17 Page 11 of 12 Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste incineration facility. Facility must be capable of handling aerosol cans. The facility should be equipped to handle gaseous waste. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. EPA Hazardous Waste Number (RCRA): D001 (Ignitable) 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No EPCRA 311/312 Hazard Classifications (effective January 1, 2018): Physical Hazards Flammable (gases, aerosols, liquids, or solids) Gas under pressure Health Hazards Serious eye damage or eye irritation Simple Asphyxiant Specific target organ toxicity (single or repeated exposure) Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Cyclohexane 110-82-7 Trade Secret 7 - 13 15.2. State Regulations Contact 3M for more information. SECTION 15: Regulatory information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 14: Transport Information SECTION 13: Disposal considerations