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John V. Fontana, PG
       JFontana@VistaGeoScience.com

   David M. Seneshen, PhD
      DSeneshen@VistaGeoScience com
      DSeneshen@VistaGeoScience.com
Vista GeoScience, Golden, Colorado, USA
Outline
Industry’s Image 
Domestic Water Well Facts
 Domestic Water Well Facts
Leading up to the Complaint
       g p            p
The Water Well Symptoms & Causes
How to Prepare for and Handle the 
 Complaints that Will Come.
 Complaints that Will Come
           AAPG International Conference & Exhibition: Singapore     
               DEG & EMD Luncheon; September 18, 2012
                                                                        2
The Environmental Rules

 Environmental Problems are Emotional
  Environmental Problems are Emotional
 Environmental Solutions are Technical
 Environmental Decisions are Political

                                                               Author Unknown

           AAPG International Conference & Exhibition: Singapore    
               DEG & EMD Luncheon; September 18, 2012                           3
The Public Image of Oil and Gas
The Public Image of Oil and Gas 
Development




         AAPG International Conference & Exhibition: Singapore     
             DEG & EMD Luncheon; September 18, 2012                   4
Google Images (1st page)
Google Images (1
Fracking, Water
Fracking, Water




        AAPG International Conference & Exhibition: Singapore     DEG & EMD 
                          Luncheon; September 18, 2012                         5
GASLAND Debunked
 Several cases in Piceance & 
    Denver Basins, Colorado, USA
   Colorado Oil & Gas 
    Conservation Commission 
               i         i i
    publishes a letter correcting 
    inaccuracies in Gasland.  
   Only one case related to oil & 
    O l              l t d t il &
    gas operations,  (but not 
    shown to be from fracking.)
   Others all showed biogenic 
    Others all showed biogenic
    shallow or coal bed gas. 
   How many people who saw 
    the movie heard about that?
    the movie heard about that?
                     AAPG International Conference & Exhibition: Singapore     
                         DEG & EMD Luncheon; September 18, 2012                   6
Results of Misinformation?
 Bans on Hydraulic 
  Fracturing
 Countries
    France
    Bulgaria
 Many States, Provinces 
 & Cities
                AAPG International Conference & Exhibition: Singapore     
                    DEG & EMD Luncheon; September 18, 2012                   7
W     W ll O     F
Water Well Owner Facts
 About 95% of all rural Americans get their drinking
  About 95% of all rural Americans get their drinking 
  water from a groundwater source
 42 million depend on wells for their water
 Groundwater provides:
   37% of public water supplies
   95% of self‐supplied household water
 Well Owner Associations Recommend Annual 
  Maintenance and Testing
  Maintenance and Testing
    Most Owners Don’t Do Any!
 Few Test for Methane
  Few Test for Methane
                AAPG International Conference & Exhibition: Singapore    
                    DEG & EMD Luncheon; September 18, 2012                  8
Colorado
 25,700 Active Wells                         270,000 Water Wells
 40,000  P&A Wells                           203,000 Residential/Household




                 AAPG International Conference & Exhibition: Singapore     
                     DEG & EMD Luncheon; September 18, 2012                    9
Common Well Problems
Common Well Problems
Common Well Problems
1. Poor Water Production (Quantity)
   Well Goes Dry or has Low Yield Rates
2. General Water Quality
2 General Water Quality
   Odors, Taste, Color, Staining, etc. 
      di
   Sediment
   Bacteria ‐ Slime
3. Gases in the Water

             AAPG International Conference & Exhibition: Singapore    
                  DEG & EMD Luncheon; September 18, 2012                 10
Reasons for Problems are Many
   Lack of Routine Testing & Maintenance
   Poor Installation & Construction Practices
   Poor Aquifer Conditions
    Poor Aquifer Conditions




                                                                   Photos Courtesy Anthony Gorody
             AAPG International Conference & Exhibition: Singapore    
                  DEG & EMD Luncheon; September 18, 2012                                            11
Private Wells Exceed EPA Standards
Private Wells Exceed EPA Standards
 Private water wells are not required 
 to meet US‐EPA drinking water standards. 
 Many exceed primary or secondary standards.
     y        p     y            y
 Most Domestic Water Wells Contain Measurable 
 Dissolved Hydrocarbons (Mostly Methane)
 Dissolved Hydrocarbons (Mostly Methane)
   Majority Contain Bacterial Gas
   Some Contain Gas From Natural Seeps or 
                                l
   Historic Production Activities

               AAPG International Conference & Exhibition: Singapore    
                   DEG & EMD Luncheon; September 18, 2012                  12
l     l       '         l          l
U.S. Geological Survey's National Water‐Quality
U.S. Geological Survey's National Water‐
Assessment Program
USGS News Release, 2011
 About 20% of untreated water samples from public, private, and 
  monitoring wells across the nation contain concentrations of at least 
  one trace element, such as arsenic, manganese and uranium, at 
  one trace element such as arsenic manganese and uranium at
  levels of potential health concern, according to a new study by the 
  U.S. Geological Survey.
 10% actually contained two or more trace elements exceeding
  10% actually contained two or more trace elements exceeding 
  human health benchmarks.
 Trace elements in groundwater exceed human health benchmarks at 
  a rate that far outpaces most other groundwater contaminants, such 
  as nitrate, pesticides, and volatile organic compounds (VOCs).
      i           i id      d l il          i          d (VOC )
    5,000 well sample set in USGS NWQAP
    http://www.usgs.gov/newsroom/article.asp
    http://water.usgs.gov/nawqa/trace/pubs/sir2011‐5059
     http://water.usgs.gov/nawqa/trace/pubs/sir2011 5059

                      AAPG International Conference & Exhibition: Singapore     
                          DEG & EMD Luncheon; September 18, 2012                   13
The Complaint Sequence
The Complaint Sequence
1. CBM, Tight Sand, or Shale Play Develops 
2. + Hydraulic Fracturing Well Stimulation
     No Previous Production History, or…
     Previous History Drilling – Possibly Old, or….
     Severed Mineral Rights
3 L i A        i iti
3. Leasing Acquisition
4. Owners Google “Fracking” and see the images
   Operator Begins Drilling Program, then…
5. O        B i D illi P              h
6. A Landowner’s Water Well Develops a Problem….
7. The Land Owner Calls and Complains
                 AAPG International Conference & Exhibition: Singapore   
                      DEG & EMD Luncheon; September 18, 2012                14
h C    l i
The Complaint
 After they drilled that oil/gas well my water
  After they drilled that oil/gas well, my water 
 well _________!!!!!  (Fill in the Blank)
 well _________!!!!!  (Fill in the Blank)
   … Stopped Working
      Stopped Working
   … Went Dry
      Has Sediment or Slimy Stuff
   … Has Sediment, or Slimy Stuff
   … Has Gas Bubbles, or Methane 
   … Tastes Awful, Salty
      Tastes Awful Salty
   … Smells
   … Blew Up!
    … Blew Up!
                 AAPG International Conference & Exhibition: Singapore    
                      DEG & EMD Luncheon; September 18, 2012                 15
Common Aquifer Types


                        W t T bl
                        Water Table
                                                                         Alluvial
                                                                         Aquifer

    Bedrock Aquifer
(Confined or Unconfined)
               AAPG International Conference & Exhibition: Singapore  
                    DEG & EMD Luncheon; September 18, 2012                          16
Reasons for Low Yield
Reasons for Low Yield
“My well now goes dry!”
 Yield i h
   i ld is the Rate the Well Flows Water (gpm)
                     h    ll l           (   )
 Day 1 will be your best yield ever!
 P t ti l C
  Potential Causes:
     Tight or Low‐Flowing Aquifer
     Dry Season – Low Water Table
      Dry Season  Low Water Table
     Drawdown (over‐pumping)
     Fouling of the Well Screen or Pump ‐ Sediment 
     Pump Damage, Small Size, Bad Installation
                           ll       d      ll
     Poor Well Design or Construction
     Lifespan: Yield Declines with Age of Water Well
      Lifespan: Yield Declines with Age of Water Well
                  AAPG International Conference & Exhibition: Singapore     
                      DEG & EMD Luncheon; September 18, 2012                   17
Seasonal Fluctuation or Drought
 Spring/Summer                                               Fall/Winter
  High water level                                           Low water level




          AAPG International Conference & Exhibition: Singapore     DEG & EMD 
                            Luncheon; September 18, 2012                         18
Localized Drawdown 
Over‐
Over‐Use of the Aquifer




          AAPG International Conference & Exhibition: Singapore     DEG & EMD 
                            Luncheon; September 18, 2012                         19
Fouling (blockage) of the
Fouling (blockage) of the 
Well Screen or Pump
 Silts and Clays                                                          AFTER
 Encrustation
   “Hard” Water
                                                  BEFORE
   Iron
 Corrosion                                                FOULED PUMP
                                                           FOULED PUMP
 Bio‐Fouling
   Bacteria Growth
    Bacteria Growth
                AAPG International Conference & Exhibition: Singapore   
                                                                                   20
                     DEG & EMD Luncheon; September 18, 2012
Poor Well Design or Construction
Poor Well Design or Construction
                       Minimum Construction 
                           Requirements & Rules 
                                      g
                           – Good Enough?  
                       Maybe Not…..
                         Sand/Gravel Filter or Open Bore?
                                                   p
                         Post‐drilling well cleaning?
                         Adequate Bore‐Hole Diameter & 
                          Depth?
                          D th?
                         Is the casing too small or too big?
                         Well Casing Size & Screen Type?
                          Well Casing Size & Screen Type?
                         Pump Size & Location?
         AAPG International Conference & Exhibition: Singapore     
             DEG & EMD Luncheon; September 18, 2012                   21
if       f           ll
Lifespan of a Water Well
                     Years to decades based on:
                              d d b d
                      The Geology/Environment 
                      Well Design/Construction
                                  /
                      Maintenance 
                      Normal Corrosion/Wear & 
                             l         /
                       Tear
                      Water Chemistry 
                              h
                      Amount of Use

       AAPG International Conference & Exhibition: Singapore   
            DEG & EMD Luncheon; September 18, 2012                22
Water Quality Complaints:: 
Water Quality Complaints


 Odor


     Taste


          Color & Sediment
           AAPG International Conference & Exhibition: Singapore    
                DEG & EMD Luncheon; September 18, 2012                 23
Causes of Poor Quality
Causes of Poor Quality
Dissolved Minerals & Salts (High TDS)
 Dissolved Minerals & Salts (High TDS)
Excessive Bacteria Activity 
                           y
Dislodged Sediment or Slime




                                                             Photos Courtesy Anthony Gorody

          AAPG International Conference & Exhibition: Singapore    
               DEG & EMD Luncheon; September 18, 2012                                         24
Gas Bubbles
Gas Bubbles
My water fizzes like soda!
 y       f
 Causes
     Dissolved Air or Natural Gas ‐
    Dissolved Air or Natural Gas
     Methane and/or Carbon Dioxide
 Sources
    Natural Bacteria Gas
    Natural Gas ‐ Coal Bed Methane
 Radon – Uranium is potential 

              AAPG International Conference & Exhibition: Singapore    
                   DEG & EMD Luncheon; September 18, 2012                 25
N t lS
Natural Seeps Do Exist – A k J d!
              D E it
Natural Seeps Do Exist – Ask Jed!




         AAPG International Conference & Exhibition: Singapore    
              DEG & EMD Luncheon; September 18, 2012                 26
How Common is Methane in 
Ground Water?
 Is Methane Present in the Well?
 Not Regulated by EPA, So There is No Specific 
  Method Detection Limit Requirements
     “Reportable Quantities” Vary by Lab
              y                     g
     Varies by several orders of magnitude 
       (.1ug/L – 1mg/L)
 Laboratory Methods Vary
    FID‐GC vs. TCD‐GC Analysis
    RSKSOP‐175  (Rev. No. 2, 2004)
                  (         ,     )
      (Robert S. Kerr Lab Std. Op. Procedure #175)
     USEPA Region 1 (Rev. 1, 2002): Technical 
      Guidance for the Natural Attenuation Indicators: 
      Methane, Ethane, and Ethene
 Proper Collection Method is IMPORTANT
  Proper Collection Method is IMPORTANT

      RSK METHOD:   “This standard operating procedure has been prepared for the use of the Ground Water and 
      Ecosystems Restoration Division of the U.S. Environmental Protection Agency and may not be specifically applicable 
      to the activities of other organizations. THIS IS NOT AN OFFICIAL EPA APPROVED METHOD. This document has 
          h   i i i   f  h            i i       THIS IS NOT AN OFFICIAL EPA APPROVED METHOD  Thi  d                   h  
      not been through the Agency’s peer review process or ORD clearance process.”

                                 AAPG International Conference & Exhibition: Singapore     
                                     DEG & EMD Luncheon; September 18, 2012                                            27
Potential Impacts to Water Wells
            p
                                                                             Barn 
  Home with                                                Fuel                                   Garage
                                                                            Animals
  Septic Field
  Septic Field                                           Storage
                                                         S




                 AAPG International Conference & Exhibition: Singapore     DEG & EMD Luncheon; 
                                             September 18, 2012                                            28
Livestock Pen Water Well & Cistern
Livestock Pen, Water Well & Cistern




         AAPG International Conference & Exhibition: Singapore    
                                                                     29
              DEG & EMD Luncheon; September 18, 2012
Ci         S i       k?
Cistern or Septic Tank?




         AAPG International Conference & Exhibition: Singapore   
              DEG & EMD Luncheon; September 18, 2012                30
Preparing for Complaints
 Establish a Baseline Program
  Establish a Baseline Program 
    Conduct Sampling 
 Ed
  Educate Water Well Owners on Your Efforts 
        t W t W ll O            Y   Eff t
 and Water Well Testing & Maintenance
  Promote it as a Valuable Community Service
   Promote it as a Valuable Community Service
   “How Well Do You Know Your Water Well”
    http://cogcc.state.co.us/Library/WaterWellBooklet.pdf
    htt //        t t       /Lib    /W t W llB kl t df
 Use as Opportunity for Stakeholder 
 Engagement
                 AAPG International Conference & Exhibition: Singapore     
                     DEG & EMD Luncheon; September 18, 2012                   31
E bli h B li W           Q li
Establish Baseline Water Quality
 Voluntary Programs
 Regulated Programs
 Sampling & Analysis Plan (SAP)
       l         l     l (     )
   Establish Data Quality Objectives
   Quality Assurance & Quality
    Quality Assurance & Quality 
    Control
   Field Protocol
    Analytical Protocol
   Analytical Protocol
 Expertise & Experience


                 AAPG International Conference & Exhibition: Singapore   
                      DEG & EMD Luncheon; September 18, 2012                32
Baseline Water Quality & Dissolved
Baseline Water Quality & Dissolved 
Gas Parameters
   Fingerprint of Water and Gas Chemistry
   Major Anions and Cations ‐ Balance
                (               )
    Trace Metals (EPA Toxic Lists)
   pH, eH, Conductivity, Temp, DO
   Dissolved Hydrocarbons
     Methane, Ethane, Propane
      Methane, Ethane, Propane  
      C1‐C6 recommended
     BTEX or VOCs (EPA ‐ SW846 8260 GC‐MS) + TPH
 Stable Isotopes
  Stable Isotopes
     Methane ‐ δ13C and δD
     C2+, CO2 and Water Isotopes (O & H)
     Other Stable Isotopes 
                        p

                    AAPG International Conference & Exhibition: Singapore   
                         DEG & EMD Luncheon; September 18, 2012                33
Establish Baseline Water Quality 
                         Q     y
Parameters (continued)
 Uranium/Radon, other NORMs
 Arsenic
 Nitrates
 Coliform B t i
  C lif     Bacteria
 Bacteria Activity Reaction Test (BART)
    Iron Related (IRB)
    Sulfate Related (SRB)
      Sulfate Related (SRB)
    Slime Forming  (SLYM)
 Design for Local Geochemistry Issues
 How Many Pre‐Drill Events?
  How Many Pre Drill Events?
    Natural Variability can be Significant
         Seasonal Changes
         Mixed Aquifers
         Water Demand/Usage
          Water Demand/Usage


                       AAPG International Conference & Exhibition: Singapore     
                           DEG & EMD Luncheon; September 18, 2012                   34
Methane in Fox Hills Aquifer
Methane in Fox Hills Aquifer
D      B i C l d USA
Denver Basin, Colorado, USA




             AAPG International Conference & Exhibition: Singapore     
                 DEG & EMD Luncheon; September 18, 2012                   35
Denver Basin Baseline Survey, 
C l d USA
Colorado, USA
                      Period




                                                                          TYPE WELL M. Segelke # 1
ERA




                                     GEOLOGIC            FORMATION         NENE Sec. 27 T11N R53W
                                     EPOCH/AGE             NAME                API 05-075-09050
                                       Holocene         Alluvial & Dune
Recent                                                                             0 - 50 ft
                                      Pleistocene            Sand
                                       Pliocene            Ogallaha                0 - 180 ft
                                                                                                       Ogallala Aquifer (80 m)
           TERTIARY




                                                                                    0 - 80 ft
                                       Miocene             Arikaree
                                                                             (Not present in area)
                                                                             (    p              )
                                   Lower Oligocene       White River              25 - 100 ft

                                                           Laramie
                                   Late Maestrichtian
                                                           Fox Hills
                                                                                  400 - 550 ft
                                                                                                        Fox Hills Aquifer (300 m)
                                     Maestrichtian
                                      Campanian
                                                            Pierre                  3150 ft
                                                                                                        Anomalous dissolved CH4
                      CRETACEOUS




                                      Campanian           Niobrara &
                                                                                    350 ft
                                      Coniacian           Fort Hays
 ESOZOIC




                                                            Carlile                 195 ft
                                       Turonian
                                                          Greenhorn
                                                                           250 ft (Storage Caprock)
ME

                      C




                                     Cenomanian         Graneros Shale

                                        Albian
                                                          Dakota "D"
                                                          Huntsman
                                                                              50 ft (Storage Zone)
                                                                                       65 ft
                                                                                                       O&G Reservoir (2,100 m)
                                                          Dakota "J"         104 ft (Storage Zone)
                                        Aptian            Skull Creek                 115 ft
                                                             Lytle                    104 ft
                                     Jurassic              Morrison                 420 ft


                                                                       AAPG International Conference & Exhibition: Singapore     
                                                                           DEG & EMD Luncheon; September 18, 2012                   36
No Mixing of Groundwater & Produced Water
        g

 Ogallala Aquifer 
   g       q
 (Ca/Mg HCO3 Water)
 Fox Hills Aquifer 
 Fox Hills Aquifer                                                             Produced Water
 (NaHCO3 Water)                  Ogallala
                                 Aquifer
 Produced Water
 Produced Water                                                           Fox Hills Aquifer

 (NaCl Water)
                            Magnesium                                            Sulfate
                               type                                               type



                                                             Bicarbonat
                                     Sodium or                                         Chloride
                      Calcium                                  e type
                                     potassium                                          type
                       type             type




                  AAPG International Conference & Exhibition: Singapore     
                      DEG & EMD Luncheon; September 18, 2012                                      37
Biogenic Methane in Aquifer Easily 
Distinguished from Produced Gas
Distinguished from Produced Gas
                      -80                                               -80
                                                                                    BIOGENIC GAS

                                         BIOGENIC
                                                                                  Water Well
                      -70
                                            GAS
                                                                        -70       Fox Hills Aquifer (300 m)

                      -60                                               -60       MIXED
                                           MIXED
    C13Methane (‰)




                                                                                    GAS
                                            GAS
                      -50                                               -50
                                                                                        Produced Gas (2,100 m)
                               MATURE THERMOGENIC GAS                          MATURE THERMOGENIC GAS

                                   FORMED WITH OIL                                     FORMED WITH OIL
                      -40                                               -40

                                                          POST-                POST-
                                                         MATURE               MATURE
                      -30       POST-MATURE                             -30
                                                         DRY GAS              DRY GAS                 POST-MATURE
                                  WET GAS
                                                                                                        WET GAS

                      -20
                       20                                               20
                                                                       -20
                        -300     -250       -200       -150       -100    0        5      10     15     20   25     30
                                        DMethane (‰)                              Gas Wetness (% C2+)
                                           AAPG International Conference & Exhibition: Singapore     
                                               DEG & EMD Luncheon; September 18, 2012                                    38
Caveat: Mixing & Alteration can
Caveat: Mixing & Alteration can 
Create a Complex Picture




                                                                      Courtesy Isotech Labs
         AAPG International Conference & Exhibition: Singapore     
             DEG & EMD Luncheon; September 18, 2012                                           39
Assess Nearby Wells (and Mines) 
 for Leakage
 Old Wells or Open Annulus Can Create 
  Cross‐Communication with Aquifers
  C     C     i i      i h A if




         Courtesy Anthony Gorody
                 AAPG International Conference & Exhibition: Singapore     DEG & EMD 
                                   Luncheon; September 18, 2012                         40
Some Symptoms May Be 
Related to Ancillary Activities
Related to Ancillary Activities
Vibrations from Construction & 
Hydraulic Fracturing Activities
 Ground motion impacts on 
 water wells can ….
  Disturb bottom sediment
  Dislodge scale & bacterial 
         g
   slime
  Temporarily increase 
   suspended material
  = Immediate complaint

                 AAPG International Conference & Exhibition: Singapore    
                      DEG & EMD Luncheon; September 18, 2012                 41
Exploration Activity
 Seismic exploration may disturb the sediments in a
  Seismic exploration may disturb the sediments in a 
 water well temporarily 




               AAPG International Conference & Exhibition: Singapore     
                   DEG & EMD Luncheon; September 18, 2012                   42
Regulated & Voluntary Baseline 
  g                 y
Program Are a Good Start…. 
A Use Them as a Minimum Set of Standards
A Use Them as a Minimum Set of Standards




     2012, Richard Hirsch, Section of Douglas County Rural Water Providers Map
                         AAPG International Conference & Exhibition: Singapore     
                             DEG & EMD Luncheon; September 18, 2012                   43
….. But it May not be Enough
             y            g
Multiple Confined Aquifers & High Density Water Wells Requires More Samples




         2012, Richard Hirsch, Ponderosa Summit Subdivision

                  AAPG International Conference & Exhibition: Singapore     DEG & EMD Luncheon; 
                                              September 18, 2012                                   44
Assess Variability
Ground Water & Well Headspace Methane:  
17 Sampling Events in 8 Month Period 




    Courtesy: Chuck Whisman (GES),  Debby McElreath (Chesapeake); 2012 Stray Gas Incident & Response Forum

                              AAPG International Conference & Exhibition: Singapore     
                                  DEG & EMD Luncheon; September 18, 2012                                     45
A      V i bilit
Assess Variability
Well Headspace Methane vs. Water Level (Drawdown)




   Courtesy: Chuck Whisman (GES),  Debby McElreath (Chesapeake); 2012 Stray Gas Incident & Response Forum

                              AAPG International Conference & Exhibition: Singapore     
                                  DEG & EMD Luncheon; September 18, 2012                                    46
Fight Misinformation with Good 
Information & Education  
 Many Water Well Organizations 
  Provide Good Public Service 
  Information
    NGWA
    AGWT
    GWPC
     State Water Well 
    State Water Well
     Organizations
 Industry Information Websites

                AAPG International Conference & Exhibition: Singapore     
                    DEG & EMD Luncheon; September 18, 2012                   47
Summary
 Complaints Happen!
 Water Well Problems or Contaminants are a Result of:
   Lack of Maintenance & Testing (most common)
   Poor Construction, Poor Aquifer or Lifespan of a Well
   Historic Drilling or Mining Activities
   Natural In Place Gas, Migration or Seepage
   Naturally Occurring Bacteria, Minerals, Etc.
   New Releases, Casing Leaks, Spills (least common)
                ,      g      , p      (            )
 A Proper Designed Baseline & Monitoring Program can:
   Educate Stakeholders
   Establishes Pre-Drill Baseline Conditions
   Monitor Variability
   Prepare you with    Answers to the Complaints!
   Mitigate Risk


                    AAPG International Conference & Exhibition: Singapore     
                        DEG & EMD Luncheon; September 18, 2012                   48
Thanks

JFontana@VistaGeoScience.com
DSeneshen@VistaGeoScience.com
Vista GeoScience, Golden, Colorado, USA
www.VistaGeoScience.com




                                          49

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Addressing Water Well ‘Problems’ and Complaints in Areas of Unconventional Resource Development

  • 1. John V. Fontana, PG JFontana@VistaGeoScience.com David M. Seneshen, PhD DSeneshen@VistaGeoScience com DSeneshen@VistaGeoScience.com Vista GeoScience, Golden, Colorado, USA
  • 2. Outline Industry’s Image  Domestic Water Well Facts Domestic Water Well Facts Leading up to the Complaint g p p The Water Well Symptoms & Causes How to Prepare for and Handle the  Complaints that Will Come. Complaints that Will Come AAPG International Conference & Exhibition: Singapore      DEG & EMD Luncheon; September 18, 2012 2
  • 3. The Environmental Rules  Environmental Problems are Emotional Environmental Problems are Emotional  Environmental Solutions are Technical  Environmental Decisions are Political Author Unknown AAPG International Conference & Exhibition: Singapore     DEG & EMD Luncheon; September 18, 2012 3
  • 4. The Public Image of Oil and Gas The Public Image of Oil and Gas  Development AAPG International Conference & Exhibition: Singapore      DEG & EMD Luncheon; September 18, 2012 4
  • 5. Google Images (1st page) Google Images (1 Fracking, Water Fracking, Water AAPG International Conference & Exhibition: Singapore     DEG & EMD  Luncheon; September 18, 2012 5
  • 6. GASLAND Debunked  Several cases in Piceance &  Denver Basins, Colorado, USA  Colorado Oil & Gas  Conservation Commission  i i i publishes a letter correcting  inaccuracies in Gasland.    Only one case related to oil &  O l l t d t il & gas operations,  (but not  shown to be from fracking.)  Others all showed biogenic  Others all showed biogenic shallow or coal bed gas.   How many people who saw  the movie heard about that? the movie heard about that? AAPG International Conference & Exhibition: Singapore      DEG & EMD Luncheon; September 18, 2012 6
  • 7. Results of Misinformation?  Bans on Hydraulic  Fracturing  Countries  France  Bulgaria  Many States, Provinces  & Cities AAPG International Conference & Exhibition: Singapore      DEG & EMD Luncheon; September 18, 2012 7
  • 8. W W ll O F Water Well Owner Facts  About 95% of all rural Americans get their drinking About 95% of all rural Americans get their drinking  water from a groundwater source  42 million depend on wells for their water  Groundwater provides:  37% of public water supplies  95% of self‐supplied household water  Well Owner Associations Recommend Annual  Maintenance and Testing Maintenance and Testing  Most Owners Don’t Do Any!  Few Test for Methane Few Test for Methane AAPG International Conference & Exhibition: Singapore     DEG & EMD Luncheon; September 18, 2012 8
  • 9. Colorado  25,700 Active Wells  270,000 Water Wells  40,000  P&A Wells  203,000 Residential/Household AAPG International Conference & Exhibition: Singapore      DEG & EMD Luncheon; September 18, 2012 9
  • 10. Common Well Problems Common Well Problems Common Well Problems 1. Poor Water Production (Quantity)  Well Goes Dry or has Low Yield Rates 2. General Water Quality 2 General Water Quality  Odors, Taste, Color, Staining, etc.  di  Sediment  Bacteria ‐ Slime 3. Gases in the Water AAPG International Conference & Exhibition: Singapore     DEG & EMD Luncheon; September 18, 2012 10
  • 11. Reasons for Problems are Many  Lack of Routine Testing & Maintenance  Poor Installation & Construction Practices  Poor Aquifer Conditions Poor Aquifer Conditions Photos Courtesy Anthony Gorody AAPG International Conference & Exhibition: Singapore     DEG & EMD Luncheon; September 18, 2012 11
  • 12. Private Wells Exceed EPA Standards Private Wells Exceed EPA Standards  Private water wells are not required  to meet US‐EPA drinking water standards.   Many exceed primary or secondary standards. y p y y  Most Domestic Water Wells Contain Measurable  Dissolved Hydrocarbons (Mostly Methane) Dissolved Hydrocarbons (Mostly Methane)  Majority Contain Bacterial Gas  Some Contain Gas From Natural Seeps or  l Historic Production Activities AAPG International Conference & Exhibition: Singapore     DEG & EMD Luncheon; September 18, 2012 12
  • 13. l l ' l l U.S. Geological Survey's National Water‐Quality U.S. Geological Survey's National Water‐ Assessment Program USGS News Release, 2011  About 20% of untreated water samples from public, private, and  monitoring wells across the nation contain concentrations of at least  one trace element, such as arsenic, manganese and uranium, at  one trace element such as arsenic manganese and uranium at levels of potential health concern, according to a new study by the  U.S. Geological Survey.  10% actually contained two or more trace elements exceeding 10% actually contained two or more trace elements exceeding  human health benchmarks.  Trace elements in groundwater exceed human health benchmarks at  a rate that far outpaces most other groundwater contaminants, such  as nitrate, pesticides, and volatile organic compounds (VOCs). i i id d l il i d (VOC )  5,000 well sample set in USGS NWQAP  http://www.usgs.gov/newsroom/article.asp  http://water.usgs.gov/nawqa/trace/pubs/sir2011‐5059 http://water.usgs.gov/nawqa/trace/pubs/sir2011 5059 AAPG International Conference & Exhibition: Singapore      DEG & EMD Luncheon; September 18, 2012 13
  • 14. The Complaint Sequence The Complaint Sequence 1. CBM, Tight Sand, or Shale Play Develops  2. + Hydraulic Fracturing Well Stimulation  No Previous Production History, or…  Previous History Drilling – Possibly Old, or….  Severed Mineral Rights 3 L i A i iti 3. Leasing Acquisition 4. Owners Google “Fracking” and see the images Operator Begins Drilling Program, then… 5. O B i D illi P h 6. A Landowner’s Water Well Develops a Problem…. 7. The Land Owner Calls and Complains AAPG International Conference & Exhibition: Singapore    DEG & EMD Luncheon; September 18, 2012 14
  • 15. h C l i The Complaint  After they drilled that oil/gas well my water After they drilled that oil/gas well, my water  well _________!!!!!  (Fill in the Blank) well _________!!!!!  (Fill in the Blank)  … Stopped Working Stopped Working  … Went Dry Has Sediment or Slimy Stuff  … Has Sediment, or Slimy Stuff  … Has Gas Bubbles, or Methane   … Tastes Awful, Salty Tastes Awful Salty  … Smells  … Blew Up! … Blew Up! AAPG International Conference & Exhibition: Singapore     DEG & EMD Luncheon; September 18, 2012 15
  • 16. Common Aquifer Types W t T bl Water Table Alluvial Aquifer Bedrock Aquifer (Confined or Unconfined) AAPG International Conference & Exhibition: Singapore   DEG & EMD Luncheon; September 18, 2012 16
  • 17. Reasons for Low Yield Reasons for Low Yield “My well now goes dry!”  Yield i h i ld is the Rate the Well Flows Water (gpm) h ll l ( )  Day 1 will be your best yield ever!  P t ti l C Potential Causes:  Tight or Low‐Flowing Aquifer  Dry Season – Low Water Table Dry Season  Low Water Table  Drawdown (over‐pumping)  Fouling of the Well Screen or Pump ‐ Sediment   Pump Damage, Small Size, Bad Installation ll d ll  Poor Well Design or Construction  Lifespan: Yield Declines with Age of Water Well Lifespan: Yield Declines with Age of Water Well AAPG International Conference & Exhibition: Singapore      DEG & EMD Luncheon; September 18, 2012 17
  • 18. Seasonal Fluctuation or Drought Spring/Summer Fall/Winter High water level Low water level AAPG International Conference & Exhibition: Singapore     DEG & EMD  Luncheon; September 18, 2012 18
  • 19. Localized Drawdown  Over‐ Over‐Use of the Aquifer AAPG International Conference & Exhibition: Singapore     DEG & EMD  Luncheon; September 18, 2012 19
  • 20. Fouling (blockage) of the Fouling (blockage) of the  Well Screen or Pump  Silts and Clays AFTER  Encrustation  “Hard” Water BEFORE  Iron  Corrosion FOULED PUMP FOULED PUMP  Bio‐Fouling  Bacteria Growth Bacteria Growth AAPG International Conference & Exhibition: Singapore    20 DEG & EMD Luncheon; September 18, 2012
  • 21. Poor Well Design or Construction Poor Well Design or Construction  Minimum Construction  Requirements & Rules  g – Good Enough?    Maybe Not…..  Sand/Gravel Filter or Open Bore? p  Post‐drilling well cleaning?  Adequate Bore‐Hole Diameter &  Depth? D th?  Is the casing too small or too big?  Well Casing Size & Screen Type? Well Casing Size & Screen Type?  Pump Size & Location? AAPG International Conference & Exhibition: Singapore      DEG & EMD Luncheon; September 18, 2012 21
  • 22. if f ll Lifespan of a Water Well Years to decades based on: d d b d  The Geology/Environment   Well Design/Construction /  Maintenance   Normal Corrosion/Wear &  l / Tear  Water Chemistry  h  Amount of Use AAPG International Conference & Exhibition: Singapore    DEG & EMD Luncheon; September 18, 2012 22
  • 23. Water Quality Complaints::  Water Quality Complaints  Odor  Taste  Color & Sediment AAPG International Conference & Exhibition: Singapore     DEG & EMD Luncheon; September 18, 2012 23
  • 24. Causes of Poor Quality Causes of Poor Quality Dissolved Minerals & Salts (High TDS) Dissolved Minerals & Salts (High TDS) Excessive Bacteria Activity  y Dislodged Sediment or Slime Photos Courtesy Anthony Gorody AAPG International Conference & Exhibition: Singapore     DEG & EMD Luncheon; September 18, 2012 24
  • 25. Gas Bubbles Gas Bubbles My water fizzes like soda! y f  Causes Dissolved Air or Natural Gas ‐  Dissolved Air or Natural Gas Methane and/or Carbon Dioxide  Sources  Natural Bacteria Gas  Natural Gas ‐ Coal Bed Methane  Radon – Uranium is potential  AAPG International Conference & Exhibition: Singapore     DEG & EMD Luncheon; September 18, 2012 25
  • 26. N t lS Natural Seeps Do Exist – A k J d! D E it Natural Seeps Do Exist – Ask Jed! AAPG International Conference & Exhibition: Singapore     DEG & EMD Luncheon; September 18, 2012 26
  • 27. How Common is Methane in  Ground Water?  Is Methane Present in the Well?  Not Regulated by EPA, So There is No Specific  Method Detection Limit Requirements  “Reportable Quantities” Vary by Lab y g  Varies by several orders of magnitude  (.1ug/L – 1mg/L)  Laboratory Methods Vary  FID‐GC vs. TCD‐GC Analysis  RSKSOP‐175  (Rev. No. 2, 2004) ( , ) (Robert S. Kerr Lab Std. Op. Procedure #175)  USEPA Region 1 (Rev. 1, 2002): Technical  Guidance for the Natural Attenuation Indicators:  Methane, Ethane, and Ethene  Proper Collection Method is IMPORTANT Proper Collection Method is IMPORTANT RSK METHOD:   “This standard operating procedure has been prepared for the use of the Ground Water and  Ecosystems Restoration Division of the U.S. Environmental Protection Agency and may not be specifically applicable  to the activities of other organizations. THIS IS NOT AN OFFICIAL EPA APPROVED METHOD. This document has    h   i i i   f  h   i i  THIS IS NOT AN OFFICIAL EPA APPROVED METHOD  Thi  d  h   not been through the Agency’s peer review process or ORD clearance process.” AAPG International Conference & Exhibition: Singapore      DEG & EMD Luncheon; September 18, 2012 27
  • 28. Potential Impacts to Water Wells p Barn  Home with  Fuel  Garage Animals Septic Field Septic Field Storage S AAPG International Conference & Exhibition: Singapore     DEG & EMD Luncheon;  September 18, 2012 28
  • 29. Livestock Pen Water Well & Cistern Livestock Pen, Water Well & Cistern AAPG International Conference & Exhibition: Singapore     29 DEG & EMD Luncheon; September 18, 2012
  • 30. Ci S i k? Cistern or Septic Tank? AAPG International Conference & Exhibition: Singapore    DEG & EMD Luncheon; September 18, 2012 30
  • 31. Preparing for Complaints  Establish a Baseline Program Establish a Baseline Program   Conduct Sampling   Ed Educate Water Well Owners on Your Efforts  t W t W ll O Y Eff t and Water Well Testing & Maintenance  Promote it as a Valuable Community Service Promote it as a Valuable Community Service  “How Well Do You Know Your Water Well” http://cogcc.state.co.us/Library/WaterWellBooklet.pdf htt // t t /Lib /W t W llB kl t df  Use as Opportunity for Stakeholder  Engagement AAPG International Conference & Exhibition: Singapore      DEG & EMD Luncheon; September 18, 2012 31
  • 32. E bli h B li W Q li Establish Baseline Water Quality  Voluntary Programs  Regulated Programs  Sampling & Analysis Plan (SAP) l l l ( )  Establish Data Quality Objectives  Quality Assurance & Quality Quality Assurance & Quality  Control  Field Protocol Analytical Protocol  Analytical Protocol  Expertise & Experience AAPG International Conference & Exhibition: Singapore    DEG & EMD Luncheon; September 18, 2012 32
  • 33. Baseline Water Quality & Dissolved Baseline Water Quality & Dissolved  Gas Parameters  Fingerprint of Water and Gas Chemistry  Major Anions and Cations ‐ Balance  ( ) Trace Metals (EPA Toxic Lists)  pH, eH, Conductivity, Temp, DO  Dissolved Hydrocarbons  Methane, Ethane, Propane Methane, Ethane, Propane   C1‐C6 recommended  BTEX or VOCs (EPA ‐ SW846 8260 GC‐MS) + TPH  Stable Isotopes Stable Isotopes  Methane ‐ δ13C and δD  C2+, CO2 and Water Isotopes (O & H)  Other Stable Isotopes  p AAPG International Conference & Exhibition: Singapore    DEG & EMD Luncheon; September 18, 2012 33
  • 34. Establish Baseline Water Quality  Q y Parameters (continued)  Uranium/Radon, other NORMs  Arsenic  Nitrates  Coliform B t i C lif Bacteria  Bacteria Activity Reaction Test (BART)  Iron Related (IRB)  Sulfate Related (SRB) Sulfate Related (SRB)  Slime Forming  (SLYM)  Design for Local Geochemistry Issues  How Many Pre‐Drill Events? How Many Pre Drill Events?  Natural Variability can be Significant  Seasonal Changes  Mixed Aquifers  Water Demand/Usage Water Demand/Usage AAPG International Conference & Exhibition: Singapore      DEG & EMD Luncheon; September 18, 2012 34
  • 35. Methane in Fox Hills Aquifer Methane in Fox Hills Aquifer D B i C l d USA Denver Basin, Colorado, USA AAPG International Conference & Exhibition: Singapore      DEG & EMD Luncheon; September 18, 2012 35
  • 36. Denver Basin Baseline Survey,  C l d USA Colorado, USA Period TYPE WELL M. Segelke # 1 ERA GEOLOGIC FORMATION NENE Sec. 27 T11N R53W EPOCH/AGE NAME API 05-075-09050 Holocene Alluvial & Dune Recent 0 - 50 ft Pleistocene Sand Pliocene Ogallaha 0 - 180 ft Ogallala Aquifer (80 m) TERTIARY 0 - 80 ft Miocene Arikaree (Not present in area) ( p ) Lower Oligocene White River 25 - 100 ft Laramie Late Maestrichtian Fox Hills 400 - 550 ft Fox Hills Aquifer (300 m) Maestrichtian Campanian Pierre 3150 ft Anomalous dissolved CH4 CRETACEOUS Campanian Niobrara & 350 ft Coniacian Fort Hays ESOZOIC Carlile 195 ft Turonian Greenhorn 250 ft (Storage Caprock) ME C Cenomanian Graneros Shale Albian Dakota "D" Huntsman 50 ft (Storage Zone) 65 ft O&G Reservoir (2,100 m) Dakota "J" 104 ft (Storage Zone) Aptian Skull Creek 115 ft Lytle 104 ft Jurassic Morrison 420 ft AAPG International Conference & Exhibition: Singapore      DEG & EMD Luncheon; September 18, 2012 36
  • 37. No Mixing of Groundwater & Produced Water g Ogallala Aquifer  g q (Ca/Mg HCO3 Water) Fox Hills Aquifer  Fox Hills Aquifer Produced Water (NaHCO3 Water) Ogallala Aquifer Produced Water Produced Water  Fox Hills Aquifer (NaCl Water) Magnesium Sulfate type type Bicarbonat Sodium or Chloride Calcium e type potassium type type type AAPG International Conference & Exhibition: Singapore      DEG & EMD Luncheon; September 18, 2012 37
  • 38. Biogenic Methane in Aquifer Easily  Distinguished from Produced Gas Distinguished from Produced Gas -80 -80 BIOGENIC GAS BIOGENIC Water Well -70 GAS -70 Fox Hills Aquifer (300 m) -60 -60 MIXED MIXED C13Methane (‰) GAS GAS -50 -50 Produced Gas (2,100 m) MATURE THERMOGENIC GAS MATURE THERMOGENIC GAS FORMED WITH OIL FORMED WITH OIL -40 -40 POST- POST- MATURE MATURE -30 POST-MATURE -30 DRY GAS DRY GAS POST-MATURE WET GAS WET GAS -20 20 20 -20 -300 -250 -200 -150 -100 0 5 10 15 20 25 30 DMethane (‰) Gas Wetness (% C2+) AAPG International Conference & Exhibition: Singapore      DEG & EMD Luncheon; September 18, 2012 38
  • 39. Caveat: Mixing & Alteration can Caveat: Mixing & Alteration can  Create a Complex Picture Courtesy Isotech Labs AAPG International Conference & Exhibition: Singapore      DEG & EMD Luncheon; September 18, 2012 39
  • 40. Assess Nearby Wells (and Mines)  for Leakage  Old Wells or Open Annulus Can Create  Cross‐Communication with Aquifers C C i i i h A if Courtesy Anthony Gorody AAPG International Conference & Exhibition: Singapore     DEG & EMD  Luncheon; September 18, 2012 40
  • 41. Some Symptoms May Be  Related to Ancillary Activities Related to Ancillary Activities Vibrations from Construction &  Hydraulic Fracturing Activities  Ground motion impacts on  water wells can ….  Disturb bottom sediment  Dislodge scale & bacterial  g slime  Temporarily increase  suspended material  = Immediate complaint AAPG International Conference & Exhibition: Singapore     DEG & EMD Luncheon; September 18, 2012 41
  • 42. Exploration Activity  Seismic exploration may disturb the sediments in a Seismic exploration may disturb the sediments in a  water well temporarily  AAPG International Conference & Exhibition: Singapore      DEG & EMD Luncheon; September 18, 2012 42
  • 43. Regulated & Voluntary Baseline  g y Program Are a Good Start….  A Use Them as a Minimum Set of Standards A Use Them as a Minimum Set of Standards 2012, Richard Hirsch, Section of Douglas County Rural Water Providers Map AAPG International Conference & Exhibition: Singapore      DEG & EMD Luncheon; September 18, 2012 43
  • 44. ….. But it May not be Enough y g Multiple Confined Aquifers & High Density Water Wells Requires More Samples 2012, Richard Hirsch, Ponderosa Summit Subdivision AAPG International Conference & Exhibition: Singapore     DEG & EMD Luncheon;  September 18, 2012 44
  • 45. Assess Variability Ground Water & Well Headspace Methane:   17 Sampling Events in 8 Month Period  Courtesy: Chuck Whisman (GES),  Debby McElreath (Chesapeake); 2012 Stray Gas Incident & Response Forum AAPG International Conference & Exhibition: Singapore      DEG & EMD Luncheon; September 18, 2012 45
  • 46. A V i bilit Assess Variability Well Headspace Methane vs. Water Level (Drawdown) Courtesy: Chuck Whisman (GES),  Debby McElreath (Chesapeake); 2012 Stray Gas Incident & Response Forum AAPG International Conference & Exhibition: Singapore      DEG & EMD Luncheon; September 18, 2012 46
  • 47. Fight Misinformation with Good  Information & Education    Many Water Well Organizations  Provide Good Public Service  Information  NGWA  AGWT  GWPC State Water Well   State Water Well Organizations  Industry Information Websites AAPG International Conference & Exhibition: Singapore      DEG & EMD Luncheon; September 18, 2012 47
  • 48. Summary  Complaints Happen!  Water Well Problems or Contaminants are a Result of:  Lack of Maintenance & Testing (most common)  Poor Construction, Poor Aquifer or Lifespan of a Well  Historic Drilling or Mining Activities  Natural In Place Gas, Migration or Seepage  Naturally Occurring Bacteria, Minerals, Etc.  New Releases, Casing Leaks, Spills (least common) , g , p ( )  A Proper Designed Baseline & Monitoring Program can:  Educate Stakeholders  Establishes Pre-Drill Baseline Conditions  Monitor Variability  Prepare you with Answers to the Complaints!  Mitigate Risk AAPG International Conference & Exhibition: Singapore      DEG & EMD Luncheon; September 18, 2012 48