Sphere gaps can be used to measure high voltages up to 2500 kV. They work by measuring the sparkover voltage between two conductive spheres. The standard diameters for the spheres are between 6.25 cm to 200 cm. Various factors like humidity, temperature, and pressure can influence the sparkover voltage. Sphere gaps are accurate to within 3% for measurements if the spacing between the spheres is less than half the sphere diameter.