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  REACH 中高度关注物质及解决方案、 ECHA 最新快报 Sunny Chen 东莞标检 化学、食品及药物部 2 Dec  2009
[object Object],[object Object],[object Object],[object Object],[object Object],REACH 概要
REACH  管控范围 ,[object Object],范围以内 : 单一化学物质、配制品和物品。包括电子、玩具、纺织品、化学品…… 范围以外 : 放射性物质、不可分离中间体、废物、受海关监督的物质、运输过程中危险物质、某些应国防需豁免的物质、 Annex IV 本质特性决定了其风险极低的物质、 Annex V 不适合或不必要注册的物质。医药、食品、食品接触材料有另外的法规要求。
REACH 重要术语 ,[object Object],物质 :自然状态下或通过生产得到的 化学元素及其化合物 。如邻  苯二甲酸盐、苯、镍、蒽…… 配制品 :由两种或以上物质组成的 混合物 。如洗发水、洗衣粉、油漆…… 物品 :由一种或多种物质和 / 或配制品组成的物体,比它的化学成分有更高的最终功能。如电脑、打印机、鞋子……
REACH 流程 版權屬標檢集團 Copyright owned by STC Group
高度关注物质( SVHC ) 2008 年 10 月 28 首批 SVHC 清单 ,[object Object]
[object Object],2009 年 6 月 1 号 ECHA 第一次对 annex XIV 建议 ECHA 建议以下这 7 个 SVHC 如果没有具体授权将不能使用   «  二甲苯麝香 «  短链氯化石蜡 «  六溴环十二烷及异构体  «   4,4’-  二氨基二苯基甲烷 «  邻苯二甲酸二 (2- 乙基己 ) 酯 «  邻苯二甲酸丁苄酯 «  邻苯二甲酸二丁酯
15 种 SVHC 性质及用途  ,[object Object],蒽 : 无色片状晶体,有蓝紫色荧光,易挥发。 用于制造蒽醌和染  料等 。也用作杀虫剂、杀菌剂、汽油阻凝剂等。是 EPA 16 种  PAHs 中一种,橡胶、油漆、石油产品中都可能存在。 4,4‘- 二氨基二苯基甲烷 :结晶状,在空气中 易氧化 ,颜色变深,  对肝脏有毒害作。染料原料,生产 偶氮染料 ;硫化剂及硫化  促进剂,用于合成 橡胶 ;树脂固化剂,用于 环氧树脂 ,有机  合成中间体。 邻苯二甲酸二丁酯( DBP )、邻苯二甲酸二 (2- 乙基已醇 ) 酯( DEHP )、邻苯二甲酸丁芐酯( BBP ) :是塑料、合成橡胶、  人造革等的常用增塑剂。 氯化钴 :极易溶于水,水溶液为桃红色。氯化钴一般用作硅胶干 燥剂的吸湿 指示剂 。也可用于 电镀工业,玻璃和陶瓷的着色 剂、油漆催干剂 ,制造 隐显墨水 ,还可用作饲料添加剂。可 用作啤酒泡沫稳定剂。还用作氨的吸收剂。
15 种 SVHC 性质及用途  ,[object Object],五氧化二砷 : 白色无定形固体。有剧毒。在 315℃ 分解成三氧化 二砷和氧。在空气中潮解。用于制药物、 杀虫剂 、 金属焊接  剂 、 有色金属玻璃,染料、还用于印刷。 三氧化二砷 :用于 玻璃工业 玻璃的去氧剂和高温澄清剂和制备药 物、杀虫剂、除草剂、用于浸洗羊毛,提炼金属砷, 制造砷 合金和制备半导体 。也用于生产含砷农药。还可用作 物品防 腐剂 、锅炉防垢剂、化学分析试剂。此外,用于 陶挠、搪瓷、 涂料、皮革保存剂、染料 等工业中。有剧毒。 重铬酸钠 :橙红色单斜棱晶体或针状晶体。极易溶于水。供 鞣革、 电镀、制铬颜料 、制火柴,并用作酶染剂、氧化剂等。还用 于镀锌后钝化处理和金属表面处理,生产碱性湖蓝染料,糖 精,合成樟脑,合成纤维,合成香料。 二甲苯麝香 :淡黄色针状晶体。是一种人造麝香,用于化妆品 香 精 和皂用香精的 定香剂 。
15 种 SVHC 性质及用途  ,[object Object],六溴环十二烷及其非对映异构体 : 白色结晶。有两种异构体。对 热和紫外光和稳定性好。用作 阻燃整理剂 ,  可用于涤纶织 物阻燃后整理和维纶涂塑双面革的阻燃。也用于聚苯乙烯、 不饱和聚酯、聚碳酸酯、聚丙烯、合成橡胶等。 C10-13 短链氯化石蜡 :短链氯化石蜡( C10-13 )按含氯量可分为: 42% 、 48% 、 50-52% 、 65-70% 四种。前三种可 代替部分主要  增塑剂 ,而且使制品具有 阻燃性 ,相容性也好。广泛使用在  电缆 中,也可用于 制水管、地板、薄膜、人造革、塑料制品  和日用品 等。 三丁基氧化锡 :无色液体。不溶于水,溶于一般有机溶剂。农业 上用作杀菌剂,杀菌性强。在 木材、造纸、纺织、粉刷 等工 业用作防护剂。也用作 聚合 反应中的催化剂。 砷酸氢铅 :杀虫剂、木材 三乙基砷酸酯 :木材,纺织品用防腐剂。
  高度关注物质 2009 年 6 月公布的可能被列入 SVHC 候选清单的  化学物质
  高度关注物质 2009 年 9 月 1 日公布的 15 项潜在 SVHC
15 种潜在 SVHC 性质及用途  ,[object Object],蒽油等 1-6 项 : 煤产品、工业电极、路面和焦油沥青纸上的粘合胶 上; 碳纤维 的生产中;防风雨 涂料 和封闭涂层上; 木材 防腐  剂;在药膏和消毒产品中的医疗器械。 磷酸三 2- 氯乙酯 : 阻燃剂和增塑剂 ;被应用于泡沫 塑料 、地毯垫  面、阻燃剂 涂层 、 粘合剂 、浇铸 压克力板 和 木 / 树脂 复合材料。 2,4- 二硝基甲苯 :被用作炸药和无烟粉末的凝胶剂和防水剂;用 作推进剂里的增塑剂;用于 橡胶 行业和 塑料 生产当中;用作  染料生产过程中的媒介物。 邻苯二甲酸二异丁酯( DIBP ) : 增塑剂 ;被用于 涂料 、涂漆和油 漆行业里; 纸张 、纸浆和夹板行业;在 粘合剂、软化剂 和粘  度调节剂里。 铬酸铅、钼红、铬橙 :在 涂料、颜料、橡胶和塑胶 中用作着色剂。 丙烯酸胺 :石油、化学品、药品和染料的介质 矽酸铝耐火纤维、氧化锆耐火纤维 :用于冶金、陶瓷、石油、化工。
  SVHC 的测试方案 版權屬標檢集團 Copyright owned by STC Group
     11 月份主要更新 2009 年 11 月 3 号 ECHA 出版了关于化学安全评估的简要指南。 2009 年 11 月 4 号 ECHA 出版了两种化学物质(六溴环十二烷和氟铝酸钠)统一分类和标识的公众咨询。 2009 年 11 月 5 号 ECHA 出版了 9 月 16 号收到的第一次上诉的内容摘要:主要是反对 ECHA 拒收上诉者注册(资料不全)的决议。 2009 年 11 月 5 号和 13 号分别开通可以直接在网上进行限制查询和提交注册档案的网站。 2009 年 11 月 19 号再一次要求对新物质的研究尽量避免动物实验。 2009 年 11 月 25 号后可在网上查找 REACH 中物质的性质讨论的资料。
产品召回实例 ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
产品召回实例 ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
产品召回实例 ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
产品召回实例 ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
REACH 相关网站 ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Q & A ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]

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REACH 2009 New Standard

  • 1.   REACH 中高度关注物质及解决方案、 ECHA 最新快报 Sunny Chen 东莞标检 化学、食品及药物部 2 Dec 2009
  • 2.
  • 3.
  • 4.
  • 5. REACH 流程 版權屬標檢集團 Copyright owned by STC Group
  • 6.
  • 7.
  • 8.
  • 9.
  • 10.
  • 11. 高度关注物质 2009 年 6 月公布的可能被列入 SVHC 候选清单的 化学物质
  • 12. 高度关注物质 2009 年 9 月 1 日公布的 15 项潜在 SVHC
  • 13.
  • 14. SVHC 的测试方案 版權屬標檢集團 Copyright owned by STC Group
  • 15.      11 月份主要更新 2009 年 11 月 3 号 ECHA 出版了关于化学安全评估的简要指南。 2009 年 11 月 4 号 ECHA 出版了两种化学物质(六溴环十二烷和氟铝酸钠)统一分类和标识的公众咨询。 2009 年 11 月 5 号 ECHA 出版了 9 月 16 号收到的第一次上诉的内容摘要:主要是反对 ECHA 拒收上诉者注册(资料不全)的决议。 2009 年 11 月 5 号和 13 号分别开通可以直接在网上进行限制查询和提交注册档案的网站。 2009 年 11 月 19 号再一次要求对新物质的研究尽量避免动物实验。 2009 年 11 月 25 号后可在网上查找 REACH 中物质的性质讨论的资料。
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