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Environmental and
Energy Potential of
ATS Algal Systems
Algal Turf Scrubber
basal algal mesh           ready for harvest
        » C:Documents and.jpg

                    SettingsadeywDesktop3689
Florida ATS on Farm Canal
        (Fresh Water Algal Turf)

22 abundant species of:
       Green Algae
       Red Algae
       Brown Algae (diatoms)
       Blue Green Algae (Cyanobacteria)

Keystone Species
       Cladophora crispata
       Enteromorpha micrococca
       Compsopogon coeruleus
       Spirogyra rivularis
       Melosira spp.
       Eunotia pectinalis
Algal Turf Scrubbers (ATS)

   Attached algae/ Many species/ Several algal groups
   Applied biomimicry
   Multiple benefits:   environment/energy/materials
   Mature Technology:    Operating to 10acre systems today
                          Designed to 1440 acre systems for tomorrow
                          Modular: any size possible next year
S-154 System:
ATS test system of 2.5 acres, for processing
10-20 Mgpd of farm stream water
ATS Biomass Potential




      35g (dry)/m2/day




      3-6g (dry)/m2/day
Some diatoms are composed
of 60% triglycerides by mass
and grow in 3 days
Professor Steven Bertman
    Dept. of Chemistry
Western Michigan University




        “No more BTUs down the drain”
Lower N & P,
Nutrient-rich               Elevated DOC
   water                       in water
                     ATS




                                triglycerides
                Algae biomass                   biodiesel


      Starches and
        cellulose



                  Butanol
Biofuels: Investigation of Algal Turf at
     Taylor Creek as Biodiesel feedstock
                                                   Gas chromatograph of algal turf oils (fatty acid methyl esters)
                                                                                        FID1 A, (E07423.660A0035730.D)




                                                                                                  1.691




                                                                                                                                                                                          10.793
                                                                               pA
                                                                               18




                                                                                                                                                                                                                                13.953
                                                                                                                                                  7.534
                                                                               16


•   Analysis of algal turf ‘oil’




                                                                                                                                                                        10.215
                                                                               14



    composition                                                                12




                                                                                                                                                                                 10.486
     –   Fatty-acids are examined                                              10




                                                                                                                                                                                                                            13.822
                                                                                    8


         using ‘FAME’ analysis; Gas




                                                                                                                                                                                                                                                               16.902
                                                                                                                                                                   10.041 10.100




                                                                                                                                                                                                                       13.700
                                                                                                                                                                                                         11.574
                                                                                                                                                                        10.428




                                                                                                                                                                                                                      13.285
                                                                                    6




                                                                                                                                                                                                                                     14.141




                                                                                                                                                                                                                                                            16.768
                                                                                                                                                                                                11.221
         Chromatograph (FID)




                                                                                                                                                                                               11.072
                                                                                                                          4.463




                                                                                                                                                                                                                                                                                               20.289
                                                                                                                                                                                              10.966
                                                                                                                                                                    10.326




                                                                                                                                                                                                                   13.085




                                                                                                                                                                                                                                                                                      19.848
                                                                                                                                  4.945




                                                                                                                                                                                                                                              14.699
                                                                                                                                                                   10.639
                                                                                                                                                                   10.716
                                                                                                                                                           8.513




                                                                                                                                                                                                                  12.791


                                                                                                                                                                                                                  13.569
                                                                                                                                                                   9.768
                                                                                                                                                          8.227
                                                                                                                                          7.279
                                                                                                                                          7.013
                                                                                    4




     –   Results:
                                                                                                                                      5                              10                                                                                15                               20




           •   Major oil components in
                                                                                    Temporal Dynamics of Fatty Acid Composition of Algal Turf (components
               algal turf relatively stable                                                                        > 5.0%)
               over the three months                                      35


           •   Most fatty acids in C14-C18                                30




                                              FA composition percentage
               range                                                      25


           •   Often correspond to                                        20
                                                                                                                                                                                                                                                                                                        March
                                                                                                                                                                                                                                                                                                        April
               common animal and                                          15
                                                                                                                                                                                                                                                                                                        May

               vegetable oils                                             10

           •   Need to further                                             5

               characterize several peaks                                  0
                                                                               14:0-Myristic acid            Unknown (C12                  16:1 w7c                 16:0 (palmitic acid,                                   18:2 w6c (linoleic                           18:1 w8c/18:3 w3c
                                                                                                               alcohol?)                                                 palm oil)                                               acid)                                    (oleic, linolenic
                                                                                                                                                                                                                                                                               acids)


•   Small scale oil extraction
    performed
     –   Initial, small scale extraction
         methods successful at oil
         isolation
     –   targeted oils were recovered
         based on GC- ‘FAME’
         analysis
Climate Benefits of ATS
• Uptake of atmospheric CO2 at 16-30
  tons of C /ac/yr, or 60-110 tons of CO2
  ac/yr Can be engineered to sequester
  smokestack CO2 emissions
• Doesn’t require agro-industrial
  fertilizers, and thus side-steps the
  atmospheric/water pollution
  consequences of oil production from
  traditional agriculture
Water Quality Benefits of ATS
• Strips N & P from lakes, rivers and other
  waterbodies from eutrophic to ppb
  levels
• Removes heavy metals
• Breaks-down toxic organic compounds
• Supersaturates water with O2
• Creates conditions to increase
  biodiversity
ATS: Biofuel Potential
• 1 acre produces 140kg
  of dry biomass / day
• 10 - 50% diatoms
• Of this, 15-20gpd
  biofuel can be
  produced per acre
• Volatile solids average
  45-55%
• 40% conversion,
  biodiesel plus butanol
Presentación Algas
Presentación Algas
Presentación Algas
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Presentación Algas

  • 1. Environmental and Energy Potential of ATS Algal Systems
  • 2. Algal Turf Scrubber basal algal mesh ready for harvest » C:Documents and.jpg SettingsadeywDesktop3689
  • 3. Florida ATS on Farm Canal (Fresh Water Algal Turf) 22 abundant species of: Green Algae Red Algae Brown Algae (diatoms) Blue Green Algae (Cyanobacteria) Keystone Species Cladophora crispata Enteromorpha micrococca Compsopogon coeruleus Spirogyra rivularis Melosira spp. Eunotia pectinalis
  • 4. Algal Turf Scrubbers (ATS)  Attached algae/ Many species/ Several algal groups  Applied biomimicry  Multiple benefits: environment/energy/materials  Mature Technology: Operating to 10acre systems today Designed to 1440 acre systems for tomorrow Modular: any size possible next year
  • 5.
  • 6.
  • 7.
  • 8.
  • 9.
  • 10.
  • 11.
  • 12. S-154 System: ATS test system of 2.5 acres, for processing 10-20 Mgpd of farm stream water
  • 13. ATS Biomass Potential 35g (dry)/m2/day 3-6g (dry)/m2/day
  • 14. Some diatoms are composed of 60% triglycerides by mass and grow in 3 days
  • 15. Professor Steven Bertman Dept. of Chemistry Western Michigan University “No more BTUs down the drain”
  • 16. Lower N & P, Nutrient-rich Elevated DOC water in water ATS triglycerides Algae biomass biodiesel Starches and cellulose Butanol
  • 17. Biofuels: Investigation of Algal Turf at Taylor Creek as Biodiesel feedstock Gas chromatograph of algal turf oils (fatty acid methyl esters) FID1 A, (E07423.660A0035730.D) 1.691 10.793 pA 18 13.953 7.534 16 • Analysis of algal turf ‘oil’ 10.215 14 composition 12 10.486 – Fatty-acids are examined 10 13.822 8 using ‘FAME’ analysis; Gas 16.902 10.041 10.100 13.700 11.574 10.428 13.285 6 14.141 16.768 11.221 Chromatograph (FID) 11.072 4.463 20.289 10.966 10.326 13.085 19.848 4.945 14.699 10.639 10.716 8.513 12.791 13.569 9.768 8.227 7.279 7.013 4 – Results: 5 10 15 20 • Major oil components in Temporal Dynamics of Fatty Acid Composition of Algal Turf (components algal turf relatively stable > 5.0%) over the three months 35 • Most fatty acids in C14-C18 30 FA composition percentage range 25 • Often correspond to 20 March April common animal and 15 May vegetable oils 10 • Need to further 5 characterize several peaks 0 14:0-Myristic acid Unknown (C12 16:1 w7c 16:0 (palmitic acid, 18:2 w6c (linoleic 18:1 w8c/18:3 w3c alcohol?) palm oil) acid) (oleic, linolenic acids) • Small scale oil extraction performed – Initial, small scale extraction methods successful at oil isolation – targeted oils were recovered based on GC- ‘FAME’ analysis
  • 18. Climate Benefits of ATS • Uptake of atmospheric CO2 at 16-30 tons of C /ac/yr, or 60-110 tons of CO2 ac/yr Can be engineered to sequester smokestack CO2 emissions • Doesn’t require agro-industrial fertilizers, and thus side-steps the atmospheric/water pollution consequences of oil production from traditional agriculture
  • 19. Water Quality Benefits of ATS • Strips N & P from lakes, rivers and other waterbodies from eutrophic to ppb levels • Removes heavy metals • Breaks-down toxic organic compounds • Supersaturates water with O2 • Creates conditions to increase biodiversity
  • 20. ATS: Biofuel Potential • 1 acre produces 140kg of dry biomass / day • 10 - 50% diatoms • Of this, 15-20gpd biofuel can be produced per acre • Volatile solids average 45-55% • 40% conversion, biodiesel plus butanol