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MATERIAL SAFETY DATA SHEET
DATE: 2014-05-01
1. Chemical Product and Company Information
Chemical Name: Xanthan Gum
Chemical Family: Polysaccharide Gum
2. Composition/Information on Ingredients
Component CAS NO.
Xanthan Gum 11138-66-2
3. Hazards Identification
EMERGENCY OVERVIEW
Appearance and Odor: White to Tan powder with slight odor
WARNING! COMBUSTIBLE DUST
POTENTIAL HEALTH EFFECTS
Likely Routes of Exposure: Skin contact and inhalation
Eye Contact: No more than slightly irritating based on toxicity studies. Prolonged contact
with the dry powder may cause drying or chapping of the skin.
Inhalation: Inhalation of the dust may cause coughing and sneezing.
Ingestion: Is not toxic if swallowed toxicity studies. No significant adverse health effects are
expected to develop if only small amounts (less than a mouthful) are swallowed.
Refer to Section 11 for toxicological information.
4. First Aid Measures
If in Eyes or on Skin: Immediate first aid is not likely to be required. However, this material
can be removed with water. Wash heavily contaminated clothing before reuse.
If Inhaled: Immediate first aid is not likely to be required. However, if symptoms occur,
remove to fresh air. Remove material from eyes, skin and clothing.
If Swallowed: Immediate first aid is not likely to be required. A physician or Poison Control
Center can be contcted for advice. Wash heavily contaminated clothing before reuse.
5. Fire Fighting Measures
Flashpoint: Not applicable
Extinguishing Media: In case of fire, use water, dry chemical, CO2, or alcohol foam.
Hazardous Products of Combustion: Carbon Dioxide, Carbon Monoxide
Unusual Fire and Explosion Hazards: This material as normally packaged and handled can
contain sufficient fines to form an explosive mixture if dispersed in a sufficient quantity of air.
Surfaces that may be covered with this product will become extremely slippery upon
application of water.
Fire Fighting Equipment: Fire Fighters and others exposed to products of combustion should
wear self-contained breathing apparatus. Equipment should be thoroughly decontaminated
after use.
6. Accidental Release Measures
In case of spill, do not blow material. Use vacuum equipment designed specifically for
handling combustible dusts.
Note: The use of water wash down is not recommended unless the spilled material is
already wet. Wet material on a walking surface will be extremely slippery. Wet spills should
be thoroughly flushed with water until non-slippery.
Refer to Section 13 for disposal information and Section 15 for reportable quantity
information.
7. Handling and Storage
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICES. THESE
PRACTICES INCLUDE AVOIDING UNNECESSARY EXPOSURE AND REMOVAL OF MATERIAL
FROM EYES, SKIN, AND CLOTHING.
Keep away from heat, sparks and flame. Avoid creating dust cloud in handling transfer and
clean up.
8. Exposure Controls/Personal Protection
Eye Protection: This product does not cause significant eye irritation or eye toxicity requiring
special protection. Use good industrial practice to avoid eye contact.
Skin Protection: Although this product does not present a significant skin concern, minimize
skin contamination by following good industrial practice. wearing protective gloves is
recommended. Wash hands and contaminated skin thoroughly after handling.
Respiratory Protection: Avoid breathing dust. Use NIOSH/MSHA approved respiratory
protection equipment when airborne exposure limits are exceeded (see below). Consult the
respirator manufacturer to determine appropriate type equipment for a given application.
Observe respirator use limitations specified by NIOSH/MSHA or the manufacturer
Respiratory protection programs must comply with 29 C.F.R. 1910.134.
Ventilation: Provide natural or mechanical ventilation to control exposure levels below
airborne exposure limits (see below). The use of local mechanical exhaust ventilation is
preferred at sources of air contamination such as open process equipment. Consult NFPA
Standard 91 for design of exhaust systems.
AIRBORNE EXPOSURE LIMITS:
OSHA and ACGIH have not established specific exposure limits for this material. However,
OSHA and ACGIH have established limits for particulates not otherwise regulated (PNOR)
and particulates not otherwise classified (PNOC) respectively, which are the least stringent
exposure limits applicable to dusts.
OSHA PEL ACGIH TLV
15mg/m3 (total dust) 8-hr TWA 10mg/m3 (inhalable) 8-hr TWA
5mg/m3 (respirable) 8-hr TWA 3mg/m3 (respirable) 8-hr TWA
9. Physical and Chemical Properties
Molecular Weight: Approximately 1,000,000
Appearance: White to tan powder
Odor: Slight
pH: Approximately neutral (as a 1% solution)
Bulk Density: Approximately 50 lb./cu. ft.
Solubility in Water: Soluble, forming a viscous solutions, becoming a paste at concentrations
greater than about 5%
NOTE: These physical data are typical values based on material tested but may vary from
sample to sample. Typical values should not be construed as a guaranteed analysis of any
specific lot or as specifications for the product.
10. Stability and Reactivity
Stability: Product is stable under normal conditions of storage and handling. Store in a cool,
dry place to maintain product performance.
Materials To Avoid: Strong oxidizers
Hazardous Decomposition Products: Thermal decomposition products may include carbon
dioxide and carbon monoxide.
Hazardous Polymerization: Will not occur.
11. Toxicological Information
The dry powder may cause foreign body irritation in some individuals. Prolonged contact
with the dry powder may cause drying or chapping of the skin. Excessive inhalation of dust
may be annoying and can mechanically impede respiration. Due to the hygroscopic
properties of the gums, they can form a paste or gel in the airway.
Data from laboratory studies conducted by The NutraSweet Kelco Company and from the
scientific literature with this material are summarized.
Oral - rat LD50: >5,000 mg/kg
Eye Irritation - rabbit: not irritating
Skin Irritation - rabbit: not irritating
No skin allergy was observed in guinea pigs following skin exposure.
No adverse effects were observed in long-term feeding studies with rats (up to 1,000
mg/kg/day) and dogs (up to 1,000 mg/kg/day). No adverse effects were observed in a 3
generation reproduction study with rats (up to 500 mg/kg/day).
12. Ecological Information
The following data have been classified using the criteria adopted by the European Economic
Community (EEC) for aquatic organism toxicity. A legend summarizing the classification
scheme appears below.
96 - hr LC50; rainbow trout: 490 mg/L; practically nontoxic
48 - hr LC50; Daphnia Magna: 980 mg/L; practically nontoxic
96 - hr LC50; Mysid shrimp, using 2 lb./bbl. xanthan gum in standard drilling mud: >500,000
ppm suspended particulate phase.
Legend for Aquatic Organism Toxicity (Journal of the European Communities, Annex VII A,
Section 5.2.1)
Values
Classifications
LC50 or EC50 < or = 1.0 mg/L
Very Toxic
LC50 or EC50 > 1.0 mg/L and < or = 10 mg/L
Toxic
LC50 or EC50 > 10 mg/L < or = 100 mg/L
Harmful
LC50 or EC50 > 100 mg/L
Practically Nontoxic
BOD5 is approx. 200 mg O2/gram. COD is approx. 1600 mg O2/g.
13. Disposal Considerations
Discarded material is not considered a hazardous waste under California regulations (Title 22,
CAC). also, the NutraSweet Kelco Company is unaware of any local, state, or federal
regulations which define this product or its ingredients as hazardous. Dispose of in
accordance with local, state, or federal regulations. Dry or wet solid material can be
landfilled in accordance with local, state, and federal regulations. Liquids may be sewered in
accordance with local, state, and federal regulations if care id taken to avoid pluggage or
blockage of sewer systems recognizing that these materials are intended to increase
viscosity and form gels. As a carbohydrate, this material should be readily biodegradable,
when at low concentrations, in a biological wastewater treatment plant.
14. Transport Information
UN proper shipping name: Not regulated
UN Lable: None
UN Identitication number: None
Hazardous Ingredients: None
Placard: None
Reportable quantity: None
The product is not hazardous under the applicable DOT, OCAO/IATA, or IMDG regulations.
15. Regulatory Information
TSCA Listed: Yes
SARA Title III Section 302 No
SARA Title III Section 311/312 No
SARA Title III Section 313 No
The ingredients of this product are on the TSCA Chemical Substances Inventory, the
Canadian Domestic Substances List, and are included in the European Inventory of Existing
Commercial Chemical Substances (EINECS).
Sara Hazard Notification
Hazard Categories Under Title III Rules (40 CFR 370): fire
Section 302 Extremely Hazardous Substances: not applicable
Section 313 Toxic Chemical(s): not applicable
Cercla Reportable Quantity: not applicable

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MSDS XANTHAN

  • 1. MATERIAL SAFETY DATA SHEET DATE: 2014-05-01 1. Chemical Product and Company Information Chemical Name: Xanthan Gum Chemical Family: Polysaccharide Gum 2. Composition/Information on Ingredients Component CAS NO. Xanthan Gum 11138-66-2 3. Hazards Identification EMERGENCY OVERVIEW Appearance and Odor: White to Tan powder with slight odor WARNING! COMBUSTIBLE DUST POTENTIAL HEALTH EFFECTS Likely Routes of Exposure: Skin contact and inhalation Eye Contact: No more than slightly irritating based on toxicity studies. Prolonged contact with the dry powder may cause drying or chapping of the skin. Inhalation: Inhalation of the dust may cause coughing and sneezing. Ingestion: Is not toxic if swallowed toxicity studies. No significant adverse health effects are expected to develop if only small amounts (less than a mouthful) are swallowed. Refer to Section 11 for toxicological information. 4. First Aid Measures If in Eyes or on Skin: Immediate first aid is not likely to be required. However, this material can be removed with water. Wash heavily contaminated clothing before reuse. If Inhaled: Immediate first aid is not likely to be required. However, if symptoms occur, remove to fresh air. Remove material from eyes, skin and clothing. If Swallowed: Immediate first aid is not likely to be required. A physician or Poison Control Center can be contcted for advice. Wash heavily contaminated clothing before reuse. 5. Fire Fighting Measures Flashpoint: Not applicable Extinguishing Media: In case of fire, use water, dry chemical, CO2, or alcohol foam. Hazardous Products of Combustion: Carbon Dioxide, Carbon Monoxide Unusual Fire and Explosion Hazards: This material as normally packaged and handled can contain sufficient fines to form an explosive mixture if dispersed in a sufficient quantity of air. Surfaces that may be covered with this product will become extremely slippery upon application of water. Fire Fighting Equipment: Fire Fighters and others exposed to products of combustion should wear self-contained breathing apparatus. Equipment should be thoroughly decontaminated after use.
  • 2. 6. Accidental Release Measures In case of spill, do not blow material. Use vacuum equipment designed specifically for handling combustible dusts. Note: The use of water wash down is not recommended unless the spilled material is already wet. Wet material on a walking surface will be extremely slippery. Wet spills should be thoroughly flushed with water until non-slippery. Refer to Section 13 for disposal information and Section 15 for reportable quantity information. 7. Handling and Storage HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICES. THESE PRACTICES INCLUDE AVOIDING UNNECESSARY EXPOSURE AND REMOVAL OF MATERIAL FROM EYES, SKIN, AND CLOTHING. Keep away from heat, sparks and flame. Avoid creating dust cloud in handling transfer and clean up. 8. Exposure Controls/Personal Protection Eye Protection: This product does not cause significant eye irritation or eye toxicity requiring special protection. Use good industrial practice to avoid eye contact. Skin Protection: Although this product does not present a significant skin concern, minimize skin contamination by following good industrial practice. wearing protective gloves is recommended. Wash hands and contaminated skin thoroughly after handling. Respiratory Protection: Avoid breathing dust. Use NIOSH/MSHA approved respiratory protection equipment when airborne exposure limits are exceeded (see below). Consult the respirator manufacturer to determine appropriate type equipment for a given application. Observe respirator use limitations specified by NIOSH/MSHA or the manufacturer Respiratory protection programs must comply with 29 C.F.R. 1910.134. Ventilation: Provide natural or mechanical ventilation to control exposure levels below airborne exposure limits (see below). The use of local mechanical exhaust ventilation is preferred at sources of air contamination such as open process equipment. Consult NFPA Standard 91 for design of exhaust systems. AIRBORNE EXPOSURE LIMITS: OSHA and ACGIH have not established specific exposure limits for this material. However, OSHA and ACGIH have established limits for particulates not otherwise regulated (PNOR) and particulates not otherwise classified (PNOC) respectively, which are the least stringent exposure limits applicable to dusts. OSHA PEL ACGIH TLV 15mg/m3 (total dust) 8-hr TWA 10mg/m3 (inhalable) 8-hr TWA 5mg/m3 (respirable) 8-hr TWA 3mg/m3 (respirable) 8-hr TWA 9. Physical and Chemical Properties Molecular Weight: Approximately 1,000,000 Appearance: White to tan powder Odor: Slight pH: Approximately neutral (as a 1% solution) Bulk Density: Approximately 50 lb./cu. ft.
  • 3. Solubility in Water: Soluble, forming a viscous solutions, becoming a paste at concentrations greater than about 5% NOTE: These physical data are typical values based on material tested but may vary from sample to sample. Typical values should not be construed as a guaranteed analysis of any specific lot or as specifications for the product. 10. Stability and Reactivity Stability: Product is stable under normal conditions of storage and handling. Store in a cool, dry place to maintain product performance. Materials To Avoid: Strong oxidizers Hazardous Decomposition Products: Thermal decomposition products may include carbon dioxide and carbon monoxide. Hazardous Polymerization: Will not occur. 11. Toxicological Information The dry powder may cause foreign body irritation in some individuals. Prolonged contact with the dry powder may cause drying or chapping of the skin. Excessive inhalation of dust may be annoying and can mechanically impede respiration. Due to the hygroscopic properties of the gums, they can form a paste or gel in the airway. Data from laboratory studies conducted by The NutraSweet Kelco Company and from the scientific literature with this material are summarized. Oral - rat LD50: >5,000 mg/kg Eye Irritation - rabbit: not irritating Skin Irritation - rabbit: not irritating No skin allergy was observed in guinea pigs following skin exposure. No adverse effects were observed in long-term feeding studies with rats (up to 1,000 mg/kg/day) and dogs (up to 1,000 mg/kg/day). No adverse effects were observed in a 3 generation reproduction study with rats (up to 500 mg/kg/day). 12. Ecological Information The following data have been classified using the criteria adopted by the European Economic Community (EEC) for aquatic organism toxicity. A legend summarizing the classification scheme appears below. 96 - hr LC50; rainbow trout: 490 mg/L; practically nontoxic 48 - hr LC50; Daphnia Magna: 980 mg/L; practically nontoxic 96 - hr LC50; Mysid shrimp, using 2 lb./bbl. xanthan gum in standard drilling mud: >500,000 ppm suspended particulate phase. Legend for Aquatic Organism Toxicity (Journal of the European Communities, Annex VII A, Section 5.2.1) Values Classifications LC50 or EC50 < or = 1.0 mg/L Very Toxic LC50 or EC50 > 1.0 mg/L and < or = 10 mg/L Toxic LC50 or EC50 > 10 mg/L < or = 100 mg/L
  • 4. Harmful LC50 or EC50 > 100 mg/L Practically Nontoxic BOD5 is approx. 200 mg O2/gram. COD is approx. 1600 mg O2/g. 13. Disposal Considerations Discarded material is not considered a hazardous waste under California regulations (Title 22, CAC). also, the NutraSweet Kelco Company is unaware of any local, state, or federal regulations which define this product or its ingredients as hazardous. Dispose of in accordance with local, state, or federal regulations. Dry or wet solid material can be landfilled in accordance with local, state, and federal regulations. Liquids may be sewered in accordance with local, state, and federal regulations if care id taken to avoid pluggage or blockage of sewer systems recognizing that these materials are intended to increase viscosity and form gels. As a carbohydrate, this material should be readily biodegradable, when at low concentrations, in a biological wastewater treatment plant. 14. Transport Information UN proper shipping name: Not regulated UN Lable: None UN Identitication number: None Hazardous Ingredients: None Placard: None Reportable quantity: None The product is not hazardous under the applicable DOT, OCAO/IATA, or IMDG regulations. 15. Regulatory Information TSCA Listed: Yes SARA Title III Section 302 No SARA Title III Section 311/312 No SARA Title III Section 313 No The ingredients of this product are on the TSCA Chemical Substances Inventory, the Canadian Domestic Substances List, and are included in the European Inventory of Existing Commercial Chemical Substances (EINECS). Sara Hazard Notification Hazard Categories Under Title III Rules (40 CFR 370): fire Section 302 Extremely Hazardous Substances: not applicable Section 313 Toxic Chemical(s): not applicable Cercla Reportable Quantity: not applicable