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What EH&S Managers Need to Know
        About Vapor Intrusion
                              By

Khaled Chekiri, Ph.D., P.E. and Jeffrey A. Bolin, M.S., CHMM



                 Dragun Corporation - April 18, 2011
2
   Regulatory concerns

   Property transaction concerns

   Legal liability

   Health concerns

                                    3
USEPA VI Path
November 2002: EPA Draft VI Guidance
                 (not applicable to petroleum)


March 2011: EPA solicited (more) comments
September 2011: Petroleum guidance
February 2012:   Technical updates
November 2012: Final VI Guidance (expected)
                                                 4
2004 – 7 States (Including Michigan)

2010 – 32 States

2012 – 32 +

                                       5
Re-openers?
 What do you mean it’s not closed?




                                     6
   Anywhere there is “potential” from a previous
    release.
   Notable VI sites include
     Love Canal in Niagara Falls, NY - 70's

     Hillside school in Needham, MA - 80's

     Redfield site in Denver, CO. - 90's

     Bishop St. site in Cambridge, ON. - 00's
                                                    7
 Buying/Selling   Property
 Merger/Acquisition

 Confusion   = Delays = $$$


                               8
 All Appropriate   Inquiries (AAI)
  ASTM 1527-05

 Vapor   Encroachment Condition (VEC)
  ASTM 2600-10




                                      9
   Where is your site relative
    to a known plume?

   …or just within an AOC?

   Non-petroleum hydrocarbon
       1/3 mile (1,760 feet)

   Petroleum hydrocarbon
       1/10 mile (528 feet)

                                10
   AAI Continuing Obligations

   Michigan Due Care




                                 11
   Employee Exposure?

   What is an “okay” exposure?

     ACGIH, PEL,

     Something Else?



                                  12
   Diffusion
    ~ slow vs. advection

   Fick’s Law:
    Movement of molecules from
    a high concentration to a low
    concentration

       Mass Movement (Flux) = D dC/dx
                                        13
α= Cindoor air
   Csoil vapor


                 14
   Safety
   Economics
   Social
   Time constraints
   Defensible results

                         15
   Critical thinking
   Conceptual site model
   Multiple lines of evidence
   Other considerations
   Sampling methods

                                 16
   Does it make sense?

   Data validation

   Screening levels


                          17
   Geology

   Water table

   Contaminant

   Underground utilities

   Sensitive receptors

   Existing and potential future buildings
                                              18
   Indoor air
   Soil vapor (deep and shallow)
   Groundwater
   Background concentrations (ambient air)
   Building construction
   Soil stratigraphy
   Chemicals (presence, ratios)
   Temporal patterns (heating and cooling)
                                              19
   Access agreements

   Regulator involved?

   Risk communication

   Potential litigation

                           20
   Background sources
   Sample custody
   Temporal variability
   Multiple home visits


                           21
Passive   Active

                   22
Sub-slab probes   Soil vapor points

                                      23
24
25
   Source remediation

   Mitigation

   Institutional controls


                             26
   Sebawaing, MI

   Port Huron, MI

   Salina, KS


                     27
Soil Vapor Points




                    28
   Properly assessing VI is complicated; it requires
    well thought-out strategy and execution – as with
    all data GIGO.

   VI may or may not be part of environmental due
    diligence or other environmental assessments – it
    should be on your checklist to ask if it has been
    evaluated.

   Don’t rush to remediate or mitigate based on VI
    data; do the data make sense?

                                                        29
   Contact Information:

   Khaled Chekiri, Ph.D., PE
     (kchekiri@dragun.com)


   Jeffrey A. Bolin, M.S., CHMM
     (jbolin@dragun.com)




                                   30

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Is There Something In The Air April 18 2012

  • 1. What EH&S Managers Need to Know About Vapor Intrusion By Khaled Chekiri, Ph.D., P.E. and Jeffrey A. Bolin, M.S., CHMM Dragun Corporation - April 18, 2011
  • 2. 2
  • 3. Regulatory concerns  Property transaction concerns  Legal liability  Health concerns 3
  • 4. USEPA VI Path November 2002: EPA Draft VI Guidance (not applicable to petroleum) March 2011: EPA solicited (more) comments September 2011: Petroleum guidance February 2012: Technical updates November 2012: Final VI Guidance (expected) 4
  • 5. 2004 – 7 States (Including Michigan) 2010 – 32 States 2012 – 32 + 5
  • 6. Re-openers? What do you mean it’s not closed? 6
  • 7. Anywhere there is “potential” from a previous release.  Notable VI sites include  Love Canal in Niagara Falls, NY - 70's  Hillside school in Needham, MA - 80's  Redfield site in Denver, CO. - 90's  Bishop St. site in Cambridge, ON. - 00's 7
  • 8.  Buying/Selling Property  Merger/Acquisition  Confusion = Delays = $$$ 8
  • 9.  All Appropriate Inquiries (AAI)  ASTM 1527-05  Vapor Encroachment Condition (VEC)  ASTM 2600-10 9
  • 10. Where is your site relative to a known plume?  …or just within an AOC?  Non-petroleum hydrocarbon  1/3 mile (1,760 feet)  Petroleum hydrocarbon  1/10 mile (528 feet) 10
  • 11. AAI Continuing Obligations  Michigan Due Care 11
  • 12. Employee Exposure?  What is an “okay” exposure?  ACGIH, PEL,  Something Else? 12
  • 13. Diffusion ~ slow vs. advection  Fick’s Law: Movement of molecules from a high concentration to a low concentration Mass Movement (Flux) = D dC/dx 13
  • 14. α= Cindoor air Csoil vapor 14
  • 15. Safety  Economics  Social  Time constraints  Defensible results 15
  • 16. Critical thinking  Conceptual site model  Multiple lines of evidence  Other considerations  Sampling methods 16
  • 17. Does it make sense?  Data validation  Screening levels 17
  • 18. Geology  Water table  Contaminant  Underground utilities  Sensitive receptors  Existing and potential future buildings 18
  • 19. Indoor air  Soil vapor (deep and shallow)  Groundwater  Background concentrations (ambient air)  Building construction  Soil stratigraphy  Chemicals (presence, ratios)  Temporal patterns (heating and cooling) 19
  • 20. Access agreements  Regulator involved?  Risk communication  Potential litigation 20
  • 21. Background sources  Sample custody  Temporal variability  Multiple home visits 21
  • 22. Passive Active 22
  • 23. Sub-slab probes Soil vapor points 23
  • 24. 24
  • 25. 25
  • 26. Source remediation  Mitigation  Institutional controls 26
  • 27. Sebawaing, MI  Port Huron, MI  Salina, KS 27
  • 29. Properly assessing VI is complicated; it requires well thought-out strategy and execution – as with all data GIGO.  VI may or may not be part of environmental due diligence or other environmental assessments – it should be on your checklist to ask if it has been evaluated.  Don’t rush to remediate or mitigate based on VI data; do the data make sense? 29
  • 30. Contact Information:  Khaled Chekiri, Ph.D., PE  (kchekiri@dragun.com)  Jeffrey A. Bolin, M.S., CHMM  (jbolin@dragun.com) 30