This document is the thesis of Eladio Teófilo Ocaña Anaya for the degree of Doctor of University at Université Blaise Pascal in Clermont-Ferrand, France. The thesis is titled "Un schéma de dualité pour les problèmes d'inéquations variationnelles" which translates to "A duality scheme for variational inequality problems". It discusses constructing a general duality scheme for monotone variational inequality problems that is analogous to the classical duality scheme in convex programming by adding perturbation variables. It also studies properties of monotone and maximal monotone multi-valued maps, monotonicity of affine subspaces, and applies the duality