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This document summarizes a presentation on factors that define the economics of sandstone uranium mines, with a focus on grade. It states that grade and tonnage are the main economic factors, and minimum requirements are an average grade of 500ppm U3O8 and reserves over 300Mt. Capital costs are roughly $100-150 per pound of annual U3O8 production. Several examples of mines are discussed where actual costs exceeded initial estimates. The presentation recommends improving grade or tonnage before advancing projects beyond exploration.
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Sandstone uranium deposits were discussed at a meeting on their origin, with half of identified deposits being of this type. Maps of Kazakh sandstone uranium deposits were presented. The JV Inkai deposit in Kazakhstan was mentioned, and its uranium resource numbers from a 2010 CAMECO report were referenced.
This document summarizes the proceedings of a conference on sandstone uranium deposits. It notes that 105 participants from various countries attended and 45 papers were presented over 3.5 days covering major uranium districts around the world. Key points from the discussions include the control of uranium deposition in specific climatic conditions and basins, the role of migrated organic matter in uranium reduction, advances in exploration methods using geophysics and isotopes, and an overview of major uranium provinces and resources. The proposed organization of a technical document on sandstone uranium deposits is also included, structured to provide an overview of the systems and deposits, case studies on key regions, and summaries of exploration advances, production, and resources.
This document discusses using refractory sandstone ores and waste as alternative sources of uranium in Poland. It describes how uranium exploration was historically conducted in southwest Poland and how biotechnology can be used to extract uranium and other rare elements from waste. The document outlines studies that showed organic compounds in shale are the main carriers of uranium in certain deposits. It also details how microbial consortia were isolated that are able to leach uranium from ores and wastes under neutral and acidic conditions, extracting up to 95% of the uranium content. The document concludes by discussing different "green" nanosynthesis methods using fungi, bacteria and plants to produce metal nanoparticles.
This document provides the program for an IAEA technical meeting on sandstone uranium deposits from a global perspective, being held from May 29-June 1, 2012 in Vienna. The meeting will include 8 sessions over 4 days covering the geology and exploration of major sandstone-hosted uranium deposit regions around the world, including Central Asia, Australia, Europe, North America, South America, Southeast Asia, Africa, and case studies of in-situ leach production. Presentations will address the mineralization controls, regional geology, exploration techniques, processing, markets and environmental issues related to these important uranium deposit types. The meeting aims to advance scientific understanding of sandstone uranium deposits worldwide.
This document summarizes a study of uranium mineralization in Lower Triassic sandstones in North Poland. Geochemical analysis found strong correlations between uranium and other trace elements like vanadium, lead, and mercury. Mineralogical analysis using SEM-EDS found that uranium mineralization occurs mainly in an amorphous form filling pores and cracks between grains. Key uranium-bearing minerals identified include nasturan, coffinite, and associations with titanium and silica minerals. Uranium was also observed replacing pyrite along veinlets. The mineralization has a mainly amorphous character and fills spaces in feldspar, mica, dolomite, and replaces clay minerals.
1. Dave Princep, Matthew Owers
How to sort the mineralisation from the background
– Processing of radiometric logging data
IAEA Sandstone Conference
May 2012
2. • Introduction
• Modification factors
• Deconvolution
• Disequilibrium
• Comparison to Assays
• Calibration
• Data processing
1
3. Paladin
• Top 10 Uranium producer, currently 8th
• 2 producing mines, Namibia and Malawi
• Significant investment in exploration on 3 continents
• Approximately 566Mlb U3O8 attributable mineral resources
• Logging in excess of 1,000,000m per year
2
4. Background
• The background is considered to be the counts per
second read in the absence of uranium mineralisation
• Instrument will register counts as a result of small but
widespread concentrations of various radioelements,
cosmic rays and radon in the atmosphere
• The local background is dependent on the local
geology (soil, basalt, granite etc.) and may vary down
the hole
• Background effects need to be removed prior to the
conversion of counts per second to an equivalent
uranium grade
6. Casing
• The effect of drill casing on logged counts per second, the blue trace has
been logged open hole, the red trace has been logged in rods.
•Casing factors need to be determined at the start of every drilling programme
and when the rod string is changed.
7. Radon
• The effect of either gaseous or dissolved Radon within a drill hole can be both variable
down the hole and arbitrary in value.
• The red trace shows the drill hole as originally logged showing highly variable apparent
background (both locally and along the length of the hole), the blue trace shows the hole
logged at a later date.
•Some drill holes are known to exhibit a diurnal variation in apparent Radon effect
8. Radon
• Detailed view of the previous trace showing background shift due to
Radon, in the red trace, at the interface with the water table.
• In this case the contribution to counts per second due to Radon is between
60 and 250 additional cps.
9. Deconvolution
• The downhole radiometric log is deconvolved prior to use in order to confine
the mineralised intervals to the correct spatial position in regards to thickness .
• Whilst in normal practice, radiometric logs output information in small down
hole increments (usually 5 or 10cm) the gamma rays being counted come from
a significantly larger area.
• The result of this is that the apparent peak of mineralisation will be wider than
occurs in reality. This can be seen most easily in the slope in the sides of the
calibration logs – in this instance there is a very sharp, perpendicular boundary
between mineralised and barren material which is not accurately honoured.
•Deconvolution is a mathematical process performed on the down hole logs in
order to ensure that the transitions from mineralised to un-mineralised material
(and vice-versa) results in the true thickness of the mineralisation being
determined.
10. Disequilibrium
• The difference between the radiometrically derived grade and the assay grade.
• Due to separation of uranium and it’s daughter products, normally due to removal of
either uranium or daughters in solution.
• Is considered positive when there is a higher concentration of uranium present compared
to daughters.
• Is considered negative when there is a lower concentration of uranium present compared
to daughters.
• Is spatially variable within deposits that exhibit disequilibrium.
• Is normally only present where there is active re-distribution of uranium or daughter
products and effect diminishes over geological time once re-distribution ceases.
• Not all secondary uranium deposits exhibit disequilibrium as mineralisation may be
geologically old and have reached equilibrium.
9
11. Disequilibrium
URANIUM DECAY SERIES Soluble and transportable
240
238 U238
primary element
4.5 x 109 y
URANIUM GROUP
236 1.2 m
(Relatively Soluble)
Pa234
234 Th 234 U234
24 d 250,000 y
232
230 Th230
80,000 y
228
226
Gaseous and easily
RADIUM GROUP Ra226
MASS NUMBER
224
(98% of Gamma 1602 y removable daughter
Radiation) Gas
ROAC, Track Etch, Alpha Card,
222 Rn222 Alpha Tube and Emanometers
3.8 d
220
218 Po218 As218 LEGEND Stable majority gamma
3m 2s Type of Decay
emitters detected by
m
20
216 2 14
Bi Scintillometers,
scintillometers
214 Pb214 Po214 Spectrometers,
27 m 160 s Borehole Probes
y
21
212 21
0
21
0
Pb Bi Principal Gamma
d
5
Emitters
210 Tl210 Po210
1m 138 d
24 d - Half lives
208
Scintillometers
206 Pb206 Instruments used
Tl 206 for Detection
stable
4m
204
80 81 82 83 84 85 86 87 88 89 90 91 92 93 94
ATOMIC NUMBER
10
12. Comparison to Assays
• In order to both confirm the validity of the downhole radiometrically derived grades as
well as determine if any disequilibrium is present within the mineralised body a comparison
to conventionally derived assay grades is normally undertaken.
• During the drilling programme a statistically representative number of samples are taken
from drill cuttings (these may be RC chips, cut drill core or similar).
• The samples are processed through a laboratory with all appropriate QAQC procedures
maintained (duplicates, blanks, certified standards etc) in order to maintain the accuracy
and precision of the results for the final comparison.
• During this process material is sampled from the mineralised zones as well as the non
mineralised areas either side of mineralisation (at least 2-3m).
• Whilst comparisons to radiometric grades (following application of all correction factors)
can be undertaken on a metre by metre basis, variations in sampled down hole position
normally means this method is unreliable.
• Radiometric grades and sampled intervals should be composited to the entire
mineralised interval plus 2-3m either side to allow for any variation in actual down hole
position.
13. Comparison to Assays
5,000
Comparison of gamma data
4,500
against assay values on a
4,000
metre by metre
y = 0.964x basis, deposit and rock
3,500 type are known to exhibit a
level of disequilibrium.
3,000
Note the scatter of data
Assay
2,500
points and the lack of
2,000 correlation. Based on 511
samples.
1,500
1,000
500
0
0 500 1,000 1,500 2,000 2,500 3,000 3,500 4,000 4,500 5,000
Gamma
12
14. Comparison to Assays
5,000
The same base data but now
4,500 composited to mineralised
4,000
intervals (as deposit is
layered normal additional un-
3,500 mineralised areas cannot be
included in this example).
3,000
Note the correlation of data
Assay
2,500
points. Minimum thickness for
2,000 a composite is 3m, average is
y = 1.137x
6.39m and is based on 71
1,500
drill holes.
1,000
Additional analysis of the data
500 points to an effective
disequilibrium factor of
0
approximately 1.17
0 500 1,000 1,500 2,000 2,500 3,000 3,500 4,000 4,500 5,000
Gamma
13
15. Comparison to Assays
• It is unlikely that the comparison between radiometrically derived grades will be
exact, however, in the absence of significant disequilibrium the basic comparison should
be within 5% between the two.
• This basic discrepancy may be due to a number of factors (formation factor, drill hole
size issues etc) but can be normally collected together as a residual factor.
• It should be noted that the comparison is between two processes that derive their values
from fundamentally different sources – the drilling derived sample and the radiometric
value for everything else except the drilling sample. There is a significant volume
difference (and therefore potential variability) between the sampling methods – drilling is
usually in the region of 10cm diameter and radiometric logging is up to 1m diameter and
specifically excludes the drilled portion.
14
16. Calibration
Probe Calibration at Kayelekera
3500
Probes are calibrated
3150 Kayelekera Pit
against known thicknesses
Active Layer Thickness = 1.02 m
Hole Diameter = 110 mm and grades of
2800 Hole Fluid = air
mineralisation in order to
2450
Probe T360 determine a K-factor, a
Run 1 constant value to convert
2100 Run 2
logged counts per second
Run 3
Run 4
to an equivalent uranium
1750
grade.
1400
The log to the left shows 4
1050
logging runs at the newly
commissioned primary
700
calibration facility at the
350 Kayelekera Minesite.
0
0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6 1.8 2 2.2 2.4 2.6 2.8
Depth (metres)
17. Calibration (Pelindaba, South Africa)
Probe Calibration at Pelindaba
4500
Calibration pits are constructed
Calibration Pit: Pelindaba
4000 as a layer of barren material at
Grade = 1440 ppm
Thickness = 0.86 m the base, a layer of mineralised
Hole Diameter = 100 mm
3500
Hole Fluid = air material with a known grade
and thickness, and another
Probe A775
3000
layer of barren material at the
Probe T244
Probe S093 top.
2500
Probe T362
2000
Probe 005 The diameter of the
Probe T279 construction is such that an
1500
apparent ‘infinite’ width can be
seen by the logging equipment.
1000
The recent transportation of the
500
test pits at Pelindaba has
resulted in damage as indicated
0
0.2 0.4 0.6 0.8 1 1.2 1.4 1.6 1.8 2 2.2 2.4 2.6 2.8 by the accompanying log.
Depth (metres)
18. Calibration
Recently constructed full
calibration facility at the
Kayelekera mine, the
photograph shows the top
surface of the facility with
cased holes of various
diameter.
The covered pipe at the
rear of the pad is a
temporary termination for
the moisture monitoring
equipment.
19. Calibration check facility, LHU
Individual historic test pits
at LHU refurbished to allow
for more frequent
calibration checks.
A full calibration
facility, similar to that at
Kayelekera, is currently
being constructed at LHU
to replace the Gencor pits.
18
20. Sensitivity Checks
Probes are checked for instrument
drift using a standardised rig and
radioactive source.
All probes are checked before use
for exploration, before each shift
for mining and at least once a
week when not in normal use.
If excessive drift is identified the
probe is sent for re-calibration or
repair.
Probe status is monitored by
dedicated staff at all sites (mining
and exploration), in addition a
report is issued by the geophysical
department in Perth each month
detailing the calibration and
standardisation status of all probes
19
21. Sensitivity checks
Probe returned to service
Probe re-calibrated Probe damaged and sent for
following excessive repair and calibration
drift
20
22. Logging equipment
Logging
equipment, standard
Auslog winch and DLS
with custom made boom
and winch enclosure
mounted on Yamaha
Rhino 4x4 base. Electrics
currently upgraded to
Solar power for battery re-
charge.
Gamma probes, 33mm
slimline, with primary
calibration at Pelindaba.
23. Rhino service facility
All Rhino based
equipment is
serviced and
maintained on site.
Service facility also
contains a low
background area
for shift based
probe sensitivity
checks.
22
24. Data Processing
Data from the
logging process is
downloaded at the
end of each shift or
drill hole and
processed to las
files.
Data is then
combined in a
custom Access
database where all
calibrations and
corrections are
applied
23
Paladin is amongst the worlds top ten uranium producers and is currently positioned at number 8, production is expected to increase over the coming year with the ramp up of stage 3 of Langer Heinrich and the optimisation of Kayelekera. Paladin has active exploration projects in Africa, primarily around the Kayelekera minesite and in Niger, in Australia at Mount Isa and the Manyingee ISR project, and in Canada at the Michelin project. Paladin currently has projects around the world containing about 608Mlb U3O8 of total resources of which approximately 566Mlb U3O8 are attributable to Paladin. All exploration drill holes are downhole logged along with production blast holes at both Langer Heinrich and Kayelekera, this amounts to in excess of a million metres of logging each year.
The local background radiation, from whatever source, is extremely important in relation to down hole logging as it adds directly to the apparent counts per second used in the determination of equivalent grades. The background is always additive to total counts and so will lead to an overestimation of equivalent grade if not treated appropriately. The local background should always be determined on a hole by hole basis as the values are likely to be inconsistent between holes on any project and will be influenced by local conditions. No attempt should be made to account for down hole backgrounds after the determination of an equivalent grade, particularly on multiple drill holes.
As can be seen in this slide, from a single project with the holes positioned approximately 200m from each other, there is considerable local variation in apparent background values. The green trace has a background of approximately 75 cps, the red trace a background of approximately 12 cps and the blue trace a background of approximately 7 cps. An overall subtraction of background on a project wide would most likely result in the under estimation of equivalent grades on the red and blue holes and an over estimation of the green hole. Using the minimum value for background would result in over estimations for the red and green holes. In this case the holes were logged in rods so cps is approximately equivalent to uranium grade. The risk is that non removal of background will result in the generation of apparent, significant, mineralisation, both in terms of thickness and grade. It should be noted that background radiation due to Radon can be extreme (examples from Kayelekera are in the order of 500-1000cps).
A significant amount of down hole logging will take place within the drill rod string, whilst the optimum process is to log in the open hole ground conditions will frequently make this unwise. Whilst there are tables available to calculate the attenuation of gamma rays due to the presence of varying thicknesses of steel it is recommended to perform a calibration of the actual casing factor on the drill rod string in use. Paladin calculates casing factors for drill rod strings, in various combinations, at the start of each drilling programme, with the rod strings in use, and whenever a rod string is changed (ie on rod change out or commencement of a new drill rig). As the casing factor will vary with down hole depth (due to the combinations of rods used) noting of the down hole position of each casing is extremely important. As the factor is a direct multiplier of cps it is very important to get the correct value.
Radon is a frequently ignored, variable, background additive component within down hole logs. The effect of Radon is likely to be hole specific, though may often be associated with faulting and water table on a more project wide basis.
Close up of the refurbished test pit, the original holes were carefully reamed out and full length PVC tubing cemented in place. Following the work the upgraded pits were monitored for Radon loss and repeatedly logged to confirm stability. In the background can be seen one of the scintillometer check pads.
The mine currently uses 6 Yamaha Rhino 4 wheel drive vehicles modified for mine use with radio, marker lights etc, and a specially manufactured boom enclosure for the winch and logging system. The Rhino is set up for single person operation with all electronics housed in dust and waterproof enclosures. Some of the Rhino’s have now been converted to have solar panels on the roof cover to allow for continuous charging of the batteries used to power the logging system, previous battery charging at shift changeover having proved inefficient. At present software used for logging is the Auslog program Alog with all binary and las output files downloaded to the main mine system at the end of each shift. The Rhino was chosen for its ease of operation, low maintenance requirements and small size as it is able to fit between rows of blast holes without damaging drill collars.
The site has constructed an extensive service and storage facility for both Rhino’s and logging equipment with the majority of repairs to any equipment able to be completed on site. The service bay also has an area specifically designated as low background where shift based probe sensitivity checks are carried out. Should a probe need extensive repair the on site calibration pits can be used to re-certify the K-factor for the probe provided that it is close to the original primary calibration. Should this not be the case the probe is returned to Pelindaba for a full re-calibration. As the site will log over 400,000m this year the additional investment in these systems and facilities is fully justified.
Al the end of each shift all the data logged during the shift is downloaded onto the minesite main computer system. To speed up data processing and allow for the generation of ore markouts the las files are batch processed though an in house Microsoft Access database. This processing incorporates a dead time correction, background removal, deconvolution and application of K and other factors. At Langer Heinrich, due to the low overall background values, the background for each hole is calculated automatically from a minimum 1m moving average value (up to a pre-set maximum). Included for comparison is the same Microsoft Access database in use at the Kayelekera Mine site where, due to variable elevated backgrounds caused by Radon, each log has to be individually assessed. Up to 1000 las files can be processed at any one time, however the usual processing batch is 200-500 holes.