Is vehicle cabin air now dirtier than what comes
out of the tailpipe?
Nick Molden
12 October 2021
CONFIDENTIAL © Emissions Analytics 2020
When it comes to the pursuit for improved air quality, we believe in the power of
clarity, transparency and integrity. With real-world data we can meet emissions
challenges – instilling trust and confidence in our industry partners and public.
It’s with our commitment and independence we are able to make a significant
contribution toward positive change and to achieve enduring results.
Our Belief
65
CONFIDENTIAL © Emissions Analytics 2021
• Founded in 2011
• Headquartered in the UK
• Operations in Germany, USA and South Korea
• Independent testing house specialising in real-world emissions testing
• Over 2,500 vehicles/machines PEMS tested across passenger, commercial and off-road
• Largest commercially available database of real-world emissions data
• We work with regulators, OEMs, Tier 1/2 suppliers, fuel and chemical companies, fleets,
consumer media
• Leads standardisation of new methods through CEN
Introduction
66
Test methodologies
CONFIDENTIAL © Emissions Analytics 2021
• Core: CO2, CO, NO, NO2, NOx, exhaust temperature
• Using regulatory-grade PEMS from Sensors, Inc
• Measurements at 1Hz
• Weather station: temperature, humidity, pressure
• OBD: typically speed, rpm, coolant temperature, engine load,
throttle position, manifold pressure
• PN, particularly for EU gasoline and hybrids
• Custom integrated NH3 sensor
Measurements – PEMS
68
CONFIDENTIAL © Emissions Analytics 2021
Measurements – volatile organic compounds
69
• Two-dimensional gas chromatography with mass
spectrometry
• INSIGHT flow modulator from SepSolve Analytical
for separation
• BENCH-TOF time-of flight mass spectrometer
• Thermal desorption tube sampling from Markes
International
CONFIDENTIAL © Emissions Analytics 2021
Portable in-cabin measurement system
70
• Particle number (down to 15nm), CO2, CO, NO2
Tailpipe emissions
CONFIDENTIAL © Emissions Analytics 2021
• Diesel NOx under control
since RDE around 2018
• Both diesel and gasoline
NOx tending to very low
levels
• PN emissions in decline and
always well under 6x1011
#/km limit
• What about unregulated
pollutants?
How low are tailpipe emissions now?
72
CONFIDENTIAL © Emissions Analytics 2021
• 8 gasoline vehicles
• Mix of hybridisation levels
• PHEV in engine mode
• 2020 or 2021 model year
• EQUA test cycle
• Tested May-July 2021
 Three-way catalysts can produce N2O, CH2O
 VOCs including aldehydes, ketones, alcohols and PAHs may also be generated
 What else should Euro 7 consider?
Test programme
73
CONFIDENTIAL © Emissions Analytics 2021
• xx
Regulated pollutant test results
74
Model Year Make Model Fuel/powertrain CO2 (g/km) CO
(mg/km)
NOx
(mg/km)
PN
(x10^11)
2021 Renault Clio Gasoline 124.6 61 6 0.015
2021 Volkswagen Polo Gasoline 130.2 14 6 0.083
2021 Kia Rio Gasoline MHEV 139.9 39 7 0.575
2021 Ford Focus Gasoline MHEV 126.5 194 3 0.620
2021 Skoda Octavia Gasoline 116.6 11 14 0.003
2020 Mini Countryman Gasoline PHEV 176.9 113 1 0.122
2021 Subaru Forester Gasoline FHEV 184.3 143 6 2.198
2021 Peugeot 208 Gasoline 134.1 251 8 0.685
Average 141.6 103 6 0.538
Average exceedance factor 1.5 0.1 0.1 0.1
CONFIDENTIAL © Emissions Analytics 2021
• Powerful greenhouse gas
• Quantified using N2O standard
Nitrous oxide results
75
Model Year Make Model Fuel/powertrain N2O (mg/km)
Urban Rural Motorway
2021 Renault Clio Gasoline 0.256 4.794 3.177
2021 Volkswagen Polo Gasoline 0.927 3.933 0.389
2021 Kia Rio Gasoline MHEV 0.678 2.335 1.742
2021 Ford Focus Gasoline MHEV 0.727 3.199 3.504
2021 Skoda Octavia Gasoline 1.085 4.588 3.978
2020 Mini Countryman Gasoline PHEV 0.718 2.778 1.753
2021 Subaru Forester Gasoline FHEV 0.141 2.194 1.624
2021 Peugeot 208 Gasoline 0.781 2.077 1.898
Average 0.664 3.237 2.258
CONFIDENTIAL © Emissions Analytics 2021
• Carcinogen, serious irritant
• Quantified using CH2O standard
Formaldehyde results
76
Model Year Make Model Fuel/powertrain CH2O (mg/km)
Urban Rural Motorway
2021 Renault Clio Gasoline 0.380 0.400 0.340
2021 Volkswagen Polo Gasoline 0.160 0.250 0.200
2021 Kia Rio Gasoline MHEV 0.130 0.110 0.110
2021 Ford Focus Gasoline MHEV 0.180 0.240 0.150
2021 Skoda Octavia Gasoline 0.170 0.330 0.260
2020 Mini Countryman Gasoline PHEV 0.110 0.210 0.110
2021 Subaru Forester Gasoline FHEV 0.190 0.430 0.170
2021 Peugeot 208 Gasoline 0.160 0.250 0.140
Average 0.185 0.278 0.185
CONFIDENTIAL © Emissions Analytics 2021
• Affect lungs, liver, kidney, brain +
headaches, dizziness
• Quantified using toluene equivalence
Alkanes, alkenes‚ alkynes and
cyclo- results
77
Model Year Make Model Fuel/powertrain Alkanes etc (ng/km)
Urban Rural Motorway
2021 Renault Clio Gasoline 1627.2 5817.1 3333.7
2021 Volkswagen Polo Gasoline 2872.2 6309.3 4564.0
2021 Kia Rio Gasoline MHEV 3250.6 3877.2 3448.7
2021 Ford Focus Gasoline MHEV 4873.7 5515.1 3232.6
2021 Skoda Octavia Gasoline 2890.9 2891.6 1775.5
2020 Mini Countryman Gasoline PHEV 972.4 2774.5 1193.8
2021 Subaru Forester Gasoline FHEV 4089.4 14287.7 8111.6
2021 Peugeot 208 Gasoline 6142.8 6834.5 5997.0
Average 3339.9 6038.4 3957.1
CONFIDENTIAL © Emissions Analytics 2021
• Often carcinogenic
• Quantified using toluene equivalence
PAH and N-compounds
78
Model Year Make Model Fuel/powertrain PAH and N-compounds (ng/km)
Urban Rural Motorway
2021 Renault Clio Gasoline 15.8 71.6 31.5
2021 Volkswagen Polo Gasoline 266.0 292.1 210.5
2021 Kia Rio Gasoline MHEV 294.0 227.2 205.0
2021 Ford Focus Gasoline MHEV 281.1 333.5 121.1
2021 Skoda Octavia Gasoline 428.1 322.4 205.0
2020 Mini Countryman Gasoline PHEV 214.3 285.0 126.3
2021 Subaru Forester Gasoline FHEV 287.8 259.0 182.4
2021 Peugeot 208 Gasoline 211.6 469.6 206.6
Average 249.9 282.6 161.0
Other sources of emissions
CONFIDENTIAL © Emissions Analytics 2020
Tyre wear testing
80
CONFIDENTIAL © Emissions Analytics 2021
• Most mass is shed at 10μm end of distribution
• Large number of ultrafine particles down to 10nm
• Concentration >400,000 #/cm3 at the low size end
• Ultrafine peaks when tyre surface hotter
• Contribute to both air and marine pollution
• 64 mg/km for new tyres, averaging 32 mg/km
• <1 mg/km tailpipe for new vehicles
Tyre wear emissions
81
Filtration effectiveness
CONFIDENTIAL © Emissions Analytics 2021
• Euro 6 diesel, with DPF
• Matching CPCs in front of and
behind vehicle
• Canisters deployed in front of
air intake
• Neutralised by engine and
DPF
• Underlying effect of cleaning
air
• Can be offset during high load
and filter regeneration
Measuring tailpipe filtration
83
1
10
100
1000
10000
100000
1000000
10000000
1
47
93
139
185
231
277
323
369
415
461
507
553
599
645
691
737
783
829
875
921
967
1013
1059
1105
1151
1197
1243
1289
1335
1381
1427
1473
1519
1565
1611
1657
1703
1749
1795
1841
1887
1933
1979
2025
2071
2117
2163
2209
2255
2301
Particle
number
concentration,
#/cm3
Time, seconds
Front of vehicle Rear of vehicle
Canister2
Canister1
Vehicle on
CONFIDENTIAL © Emissions Analytics 2021
• Real-world methodology
• Being standardised with CEN Workshop 103
Measuring in-cabin pollution
84
0
50000
100000
150000
200000
250000
1
71
141
211
281
351
421
491
561
631
701
771
841
911
981
1051
1121
1191
1261
1331
1401
1471
1541
1611
1681
1751
1821
1891
1961
2031
2101
2171
2241
2311
2381
2451
2521
2591
2661
2731
2801
2871
2941
3011
3081
3151
3221
3291
3361
3431
3501
3571
3641
3711
3781
3851
3921
3991
4061
Particle
number
concentration,
#/cm
3
Time, seconds
Inside vehicle Outside vehicle
Recirculationon Recirculationoff
CONFIDENTIAL © Emissions Analytics 2021
• xx
Tyre wear emissions
85
0
50000
100000
150000
200000
250000
300000
350000
400000
450000
500000
1
94
187
280
373
466
559
652
745
838
931
1024
1117
1210
1303
1396
1489
1582
1675
1768
1861
1954
2047
2140
2233
2326
2419
2512
2605
2698
2791
2884
2977
3070
3163
3256
3349
3442
3535
3628
3721
3814
3907
4000
4093
4186
4279
4372
4465
4558
4651
4744
4837
4930
Particle
number
concentration
(#/cm3)
Time(seconds)
Inside
Outside
0
100000
200000
300000
400000
500000
600000
700000
800000
900000
1000000
1
96
191
286
381
476
571
666
761
856
951
1046
1141
1236
1331
1426
1521
1616
1711
1806
1901
1996
2091
2186
2281
2376
2471
2566
2661
2756
2851
2946
3041
3136
3231
3326
3421
3516
3611
3706
3801
3896
3991
4086
4181
4276
4371
4466
4561
4656
4751
4846
4941
Particle
number
concentration
(#/cm3)
Time(seconds)
Inside
Outside
Good filtration:
Hyundai Kona
CAQI = 0.36
Poor filtration:
Lexus ES
CAQI = 4.32
Recirculation on Recirculation off Recirculation on Recirculation off
CONFIDENTIAL © Emissions Analytics 2021
• 97 vehicles
• Recent US models
• Tested in California
• CAQI results averaged by
manufacturer
• Fresh air vs recirculation
mode
• Moderate correlation
suggests importance of
filtration strategy
Comparative test programme
86
Acura
BMW
Chevrolet
Chrysler
Dodge
Ford
GMC
Honda
Hyundai
Infiniti
Jaguar
Jeep
Kia
Lexus
Lincoln
Mazda
Mercedes-Benz
Mitsubishi
Nissan
Ram
Subaru
Tesla
Toyota
Volkswagen
Volvo
0.00
0.05
0.10
0.15
0.20
0.25
0.30
0.35
0.40
0.45
0.50
0.00 0.50 1.00 1.50 2.00 2.50
PN
filtration
rate
-
recirculation
on
PN filtration rate - recirculation off
CONFIDENTIAL © Emissions Analytics 2021
Putting tailpipe and cabin together…
87
CONFIDENTIAL © Emissions Analytics 2021
• Average CAQI is 1.2
• Cabin slightly more polluted than outside on average
• Ambient sees big particulate spikes, which can persist when inside
• Before regulation, measurement and rating necessary
• Potential for a quick win, as better filtration is relatively inexpensive
• Better than Euro 7, which may just regulate existing low emissions even further?
• Let’s stand back and consider the holistic environmental and health impacts of vehicles to
prioritise action
Should we regulate in-cabin air?
88
Thank you.
Nick Molden
Chief Executive Officer
nick@emissionsanalytics.com
+44 (0)20 7193 0489

[RTCA21] Is vehicle cabin air now dirtier than what comes out of the tailpipe?, Nick Moden, Emmisions Analytics Ltd.

  • 1.
    Is vehicle cabinair now dirtier than what comes out of the tailpipe? Nick Molden 12 October 2021
  • 2.
    CONFIDENTIAL © EmissionsAnalytics 2020 When it comes to the pursuit for improved air quality, we believe in the power of clarity, transparency and integrity. With real-world data we can meet emissions challenges – instilling trust and confidence in our industry partners and public. It’s with our commitment and independence we are able to make a significant contribution toward positive change and to achieve enduring results. Our Belief 65
  • 3.
    CONFIDENTIAL © EmissionsAnalytics 2021 • Founded in 2011 • Headquartered in the UK • Operations in Germany, USA and South Korea • Independent testing house specialising in real-world emissions testing • Over 2,500 vehicles/machines PEMS tested across passenger, commercial and off-road • Largest commercially available database of real-world emissions data • We work with regulators, OEMs, Tier 1/2 suppliers, fuel and chemical companies, fleets, consumer media • Leads standardisation of new methods through CEN Introduction 66
  • 4.
  • 5.
    CONFIDENTIAL © EmissionsAnalytics 2021 • Core: CO2, CO, NO, NO2, NOx, exhaust temperature • Using regulatory-grade PEMS from Sensors, Inc • Measurements at 1Hz • Weather station: temperature, humidity, pressure • OBD: typically speed, rpm, coolant temperature, engine load, throttle position, manifold pressure • PN, particularly for EU gasoline and hybrids • Custom integrated NH3 sensor Measurements – PEMS 68
  • 6.
    CONFIDENTIAL © EmissionsAnalytics 2021 Measurements – volatile organic compounds 69 • Two-dimensional gas chromatography with mass spectrometry • INSIGHT flow modulator from SepSolve Analytical for separation • BENCH-TOF time-of flight mass spectrometer • Thermal desorption tube sampling from Markes International
  • 7.
    CONFIDENTIAL © EmissionsAnalytics 2021 Portable in-cabin measurement system 70 • Particle number (down to 15nm), CO2, CO, NO2
  • 8.
  • 9.
    CONFIDENTIAL © EmissionsAnalytics 2021 • Diesel NOx under control since RDE around 2018 • Both diesel and gasoline NOx tending to very low levels • PN emissions in decline and always well under 6x1011 #/km limit • What about unregulated pollutants? How low are tailpipe emissions now? 72
  • 10.
    CONFIDENTIAL © EmissionsAnalytics 2021 • 8 gasoline vehicles • Mix of hybridisation levels • PHEV in engine mode • 2020 or 2021 model year • EQUA test cycle • Tested May-July 2021  Three-way catalysts can produce N2O, CH2O  VOCs including aldehydes, ketones, alcohols and PAHs may also be generated  What else should Euro 7 consider? Test programme 73
  • 11.
    CONFIDENTIAL © EmissionsAnalytics 2021 • xx Regulated pollutant test results 74 Model Year Make Model Fuel/powertrain CO2 (g/km) CO (mg/km) NOx (mg/km) PN (x10^11) 2021 Renault Clio Gasoline 124.6 61 6 0.015 2021 Volkswagen Polo Gasoline 130.2 14 6 0.083 2021 Kia Rio Gasoline MHEV 139.9 39 7 0.575 2021 Ford Focus Gasoline MHEV 126.5 194 3 0.620 2021 Skoda Octavia Gasoline 116.6 11 14 0.003 2020 Mini Countryman Gasoline PHEV 176.9 113 1 0.122 2021 Subaru Forester Gasoline FHEV 184.3 143 6 2.198 2021 Peugeot 208 Gasoline 134.1 251 8 0.685 Average 141.6 103 6 0.538 Average exceedance factor 1.5 0.1 0.1 0.1
  • 12.
    CONFIDENTIAL © EmissionsAnalytics 2021 • Powerful greenhouse gas • Quantified using N2O standard Nitrous oxide results 75 Model Year Make Model Fuel/powertrain N2O (mg/km) Urban Rural Motorway 2021 Renault Clio Gasoline 0.256 4.794 3.177 2021 Volkswagen Polo Gasoline 0.927 3.933 0.389 2021 Kia Rio Gasoline MHEV 0.678 2.335 1.742 2021 Ford Focus Gasoline MHEV 0.727 3.199 3.504 2021 Skoda Octavia Gasoline 1.085 4.588 3.978 2020 Mini Countryman Gasoline PHEV 0.718 2.778 1.753 2021 Subaru Forester Gasoline FHEV 0.141 2.194 1.624 2021 Peugeot 208 Gasoline 0.781 2.077 1.898 Average 0.664 3.237 2.258
  • 13.
    CONFIDENTIAL © EmissionsAnalytics 2021 • Carcinogen, serious irritant • Quantified using CH2O standard Formaldehyde results 76 Model Year Make Model Fuel/powertrain CH2O (mg/km) Urban Rural Motorway 2021 Renault Clio Gasoline 0.380 0.400 0.340 2021 Volkswagen Polo Gasoline 0.160 0.250 0.200 2021 Kia Rio Gasoline MHEV 0.130 0.110 0.110 2021 Ford Focus Gasoline MHEV 0.180 0.240 0.150 2021 Skoda Octavia Gasoline 0.170 0.330 0.260 2020 Mini Countryman Gasoline PHEV 0.110 0.210 0.110 2021 Subaru Forester Gasoline FHEV 0.190 0.430 0.170 2021 Peugeot 208 Gasoline 0.160 0.250 0.140 Average 0.185 0.278 0.185
  • 14.
    CONFIDENTIAL © EmissionsAnalytics 2021 • Affect lungs, liver, kidney, brain + headaches, dizziness • Quantified using toluene equivalence Alkanes, alkenes‚ alkynes and cyclo- results 77 Model Year Make Model Fuel/powertrain Alkanes etc (ng/km) Urban Rural Motorway 2021 Renault Clio Gasoline 1627.2 5817.1 3333.7 2021 Volkswagen Polo Gasoline 2872.2 6309.3 4564.0 2021 Kia Rio Gasoline MHEV 3250.6 3877.2 3448.7 2021 Ford Focus Gasoline MHEV 4873.7 5515.1 3232.6 2021 Skoda Octavia Gasoline 2890.9 2891.6 1775.5 2020 Mini Countryman Gasoline PHEV 972.4 2774.5 1193.8 2021 Subaru Forester Gasoline FHEV 4089.4 14287.7 8111.6 2021 Peugeot 208 Gasoline 6142.8 6834.5 5997.0 Average 3339.9 6038.4 3957.1
  • 15.
    CONFIDENTIAL © EmissionsAnalytics 2021 • Often carcinogenic • Quantified using toluene equivalence PAH and N-compounds 78 Model Year Make Model Fuel/powertrain PAH and N-compounds (ng/km) Urban Rural Motorway 2021 Renault Clio Gasoline 15.8 71.6 31.5 2021 Volkswagen Polo Gasoline 266.0 292.1 210.5 2021 Kia Rio Gasoline MHEV 294.0 227.2 205.0 2021 Ford Focus Gasoline MHEV 281.1 333.5 121.1 2021 Skoda Octavia Gasoline 428.1 322.4 205.0 2020 Mini Countryman Gasoline PHEV 214.3 285.0 126.3 2021 Subaru Forester Gasoline FHEV 287.8 259.0 182.4 2021 Peugeot 208 Gasoline 211.6 469.6 206.6 Average 249.9 282.6 161.0
  • 16.
  • 17.
    CONFIDENTIAL © EmissionsAnalytics 2020 Tyre wear testing 80
  • 18.
    CONFIDENTIAL © EmissionsAnalytics 2021 • Most mass is shed at 10μm end of distribution • Large number of ultrafine particles down to 10nm • Concentration >400,000 #/cm3 at the low size end • Ultrafine peaks when tyre surface hotter • Contribute to both air and marine pollution • 64 mg/km for new tyres, averaging 32 mg/km • <1 mg/km tailpipe for new vehicles Tyre wear emissions 81
  • 19.
  • 20.
    CONFIDENTIAL © EmissionsAnalytics 2021 • Euro 6 diesel, with DPF • Matching CPCs in front of and behind vehicle • Canisters deployed in front of air intake • Neutralised by engine and DPF • Underlying effect of cleaning air • Can be offset during high load and filter regeneration Measuring tailpipe filtration 83 1 10 100 1000 10000 100000 1000000 10000000 1 47 93 139 185 231 277 323 369 415 461 507 553 599 645 691 737 783 829 875 921 967 1013 1059 1105 1151 1197 1243 1289 1335 1381 1427 1473 1519 1565 1611 1657 1703 1749 1795 1841 1887 1933 1979 2025 2071 2117 2163 2209 2255 2301 Particle number concentration, #/cm3 Time, seconds Front of vehicle Rear of vehicle Canister2 Canister1 Vehicle on
  • 21.
    CONFIDENTIAL © EmissionsAnalytics 2021 • Real-world methodology • Being standardised with CEN Workshop 103 Measuring in-cabin pollution 84 0 50000 100000 150000 200000 250000 1 71 141 211 281 351 421 491 561 631 701 771 841 911 981 1051 1121 1191 1261 1331 1401 1471 1541 1611 1681 1751 1821 1891 1961 2031 2101 2171 2241 2311 2381 2451 2521 2591 2661 2731 2801 2871 2941 3011 3081 3151 3221 3291 3361 3431 3501 3571 3641 3711 3781 3851 3921 3991 4061 Particle number concentration, #/cm 3 Time, seconds Inside vehicle Outside vehicle Recirculationon Recirculationoff
  • 22.
    CONFIDENTIAL © EmissionsAnalytics 2021 • xx Tyre wear emissions 85 0 50000 100000 150000 200000 250000 300000 350000 400000 450000 500000 1 94 187 280 373 466 559 652 745 838 931 1024 1117 1210 1303 1396 1489 1582 1675 1768 1861 1954 2047 2140 2233 2326 2419 2512 2605 2698 2791 2884 2977 3070 3163 3256 3349 3442 3535 3628 3721 3814 3907 4000 4093 4186 4279 4372 4465 4558 4651 4744 4837 4930 Particle number concentration (#/cm3) Time(seconds) Inside Outside 0 100000 200000 300000 400000 500000 600000 700000 800000 900000 1000000 1 96 191 286 381 476 571 666 761 856 951 1046 1141 1236 1331 1426 1521 1616 1711 1806 1901 1996 2091 2186 2281 2376 2471 2566 2661 2756 2851 2946 3041 3136 3231 3326 3421 3516 3611 3706 3801 3896 3991 4086 4181 4276 4371 4466 4561 4656 4751 4846 4941 Particle number concentration (#/cm3) Time(seconds) Inside Outside Good filtration: Hyundai Kona CAQI = 0.36 Poor filtration: Lexus ES CAQI = 4.32 Recirculation on Recirculation off Recirculation on Recirculation off
  • 23.
    CONFIDENTIAL © EmissionsAnalytics 2021 • 97 vehicles • Recent US models • Tested in California • CAQI results averaged by manufacturer • Fresh air vs recirculation mode • Moderate correlation suggests importance of filtration strategy Comparative test programme 86 Acura BMW Chevrolet Chrysler Dodge Ford GMC Honda Hyundai Infiniti Jaguar Jeep Kia Lexus Lincoln Mazda Mercedes-Benz Mitsubishi Nissan Ram Subaru Tesla Toyota Volkswagen Volvo 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.00 0.50 1.00 1.50 2.00 2.50 PN filtration rate - recirculation on PN filtration rate - recirculation off
  • 24.
    CONFIDENTIAL © EmissionsAnalytics 2021 Putting tailpipe and cabin together… 87
  • 25.
    CONFIDENTIAL © EmissionsAnalytics 2021 • Average CAQI is 1.2 • Cabin slightly more polluted than outside on average • Ambient sees big particulate spikes, which can persist when inside • Before regulation, measurement and rating necessary • Potential for a quick win, as better filtration is relatively inexpensive • Better than Euro 7, which may just regulate existing low emissions even further? • Let’s stand back and consider the holistic environmental and health impacts of vehicles to prioritise action Should we regulate in-cabin air? 88
  • 26.
    Thank you. Nick Molden ChiefExecutive Officer nick@emissionsanalytics.com +44 (0)20 7193 0489