2. Question:
A glass jar is covered with cellophane.
A tightly folded paper tube of length 4-5
cm is inserted hermetically into the jar
through the cellophane cover. The tube
is oriented horizontally.
If one burns out outside end of the tube
the dense smoke flows into the jar.
Explore this phenomenon.
3. Introduction
We conventionally see smoke rise.
The tricky bit:
– Since smoke rises, how do can it flow
horizontally into
the jar?
– Smoke must sink
4. Introduction
Why smoke rises:
– Convection
Rising air column
carries the smoke particles up.
– Mass of particle ≈ 1.7 × 10-12 – 2.8 × 10-7 g
5. Theory
Assuming smoke particles consist of
12C:
– ρ smoke particles ≈ 2200 kg/m3
– ρ air = 1.1839 kg/m3 @ 25°C
ρ smoke particles > ρ air
– in the absence of convection, smoke
should sink naturally.
8. Experimentation
to record footage of the
phenomenon for analysis:
– Effect of the number of layers of paper.
– Effect of diameter / length of tube
– Mechanism driving smoke into the jar
– Theoretical vs. Actual flow speed in tube
9. Experimentation
Variable:
– Number of layers of paper in each tube.
• 1, 2, 3 & 4
Constants:
– Diameter of the paper tube (5.0mm).
– Type of paper used
– Length of paper tube (10.0cm)
• 6 cm protrusion outside the beaker
10.
11. At least 2 layers are required
– When layers > 2, inner layer burns slower
than outer layer
– Smoke in jar is from inner tube
Results: Variation in layers
Fast-burning
outer layer
Slow-burning
inner layer
12. Results: Smoke Flow
Smoke flow in jar is
laminar
– Reynolds no. < 2000
– No vortices or eddies
Turbulent flow Laminar flow
13. Effect of length & ⌀
15cm tube used in separate test
– Length of tube has no significant effect
– Smoke exits from opposite end almost
immediately
Diameter of tube = 12.0 mm:
– smoke remains in tube, flow extremely
slow.
14. The really tricky bit:
What is the mechanism driving smoke
into the jar?
Patm air
Phot air
Pressure Gradient?
Smoke?
15. Proposed mechanism:
Patm air
Hot air expands
Inside tube
Expanded air
pushes both ways
Expanding air drives
Smoke into jar
smoke
Patm air
16. Proposed mechanism:
Such a mechanism supports results.
– Flow speed not significantly affected by
length
– Larger diameter, less (slower) smoke flow
• Air has more room to expand
Determine if theoretical flow speed
fits actual values.
17. Calculations
Volumetric flow
rate
C6H10O5 + O2 5C + 5H2O + CO2
(incomplete combustion of cellulose)
Find rate of combustion of paper
Use eqn. to find rate of expulsion of CO2 &
H2O gas
To find rate of expansion of gas
Volumetric flow rate
of air into the tube.
19. Expanded air
pushes both ways smoke
Assumptions
Expanded air splits equally on each side
Paper is 100% cellulose; Incomplete
combustion
Smoke is a suspension that travels
along with air
Temperature of burning paper
is at 400°C
(slightly above flash point of paper)
20. Calculating rate of combustion
Expt. to derive rate of combustion of paper:
Avg. rate = 0.0186 gs-1
= 0.0186 gs-1 ∕ 162.0 gmol-1
= 0.000115 mols-1
Trial Initial mass/
g
Final mass/
g
Δ mass/
g
Time/ s Rate of
combustion/ gs-1
1 0.480 0.210 0.270 15.50 0.0174
2 0.461 0.259 0.202 11.16 0.0181
3 0.341 0.045 0.296 15.37 0.0192
4 0.336 0.201 0.165 8.41 0.0196
21. Calculating Volumetric Flow Rate
C6H10O5 + O2 5C + 5H2O + CO2
Rate of combustion of O2 =
0.000115mols-1
Rate of formation of CO2 & H2O gas
= 0.000115 mols-1 × 6
= 0.000689 mols-1
initial temp. = 400°C , exit temp. = 50°C
Ideal gas law: PV=nRT
23. Limitations
Only expansion of combusted gas
considered
– (ignore heating of surrounding air)
‘Leakage’ of air not considered.
Drops in pressure caused by drag not
factored.
Only average flow speed is derived
– Instantaneous flow speed cannot be
calculated as we do not know how temp.
varies along tube
‘leaks’
25. Computed Reynolds number
Narrow tube (⌀ 5.0mm)
– Re ≈ 83
Wide tube (⌀ 12.0mm)
– Re ≈ 34
Reynolds no. are ultra-low, in the order
of 101
Flow in tube fits laminar flow as
observed.
26. Conclusion:
Mechanism has been proposed for the
phenomenon.
– Volumetric expansion of air
– Cooling of gas produced
However, other factors are also
involved:
– ‘leakage of air’
– Change in pressure due to drag
Hagen Poiseuille equation