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Smoke Stream
Question:
 A glass jar is covered with cellophane.
A tightly folded paper tube of length 4-5
cm is inserted hermetically into the jar
through the cellophane cover. The tube
is oriented horizontally.
 If one burns out outside end of the tube
the dense smoke flows into the jar.
 Explore this phenomenon.
Introduction
 We conventionally see smoke rise.
 The tricky bit:
– Since smoke rises, how do can it flow
horizontally into
the jar?
– Smoke must sink
Introduction
 Why smoke rises:
– Convection
 Rising air column
carries the smoke particles up.
– Mass of particle ≈ 1.7 × 10-12 – 2.8 × 10-7 g
Theory
 Assuming smoke particles consist of
12C:
– ρ smoke particles ≈ 2200 kg/m3
– ρ air = 1.1839 kg/m3 @ 25°C
 ρ smoke particles > ρ air
– in the absence of convection, smoke
should sink naturally.
Evidence
Experimentation
Paper tube
Glass beaker
Retort stand
Cling wrap
Experimentation
 to record footage of the
phenomenon for analysis:
– Effect of the number of layers of paper.
– Effect of diameter / length of tube
– Mechanism driving smoke into the jar
– Theoretical vs. Actual flow speed in tube
Experimentation
 Variable:
– Number of layers of paper in each tube.
• 1, 2, 3 & 4
 Constants:
– Diameter of the paper tube (5.0mm).
– Type of paper used
– Length of paper tube (10.0cm)
• 6 cm protrusion outside the beaker
 At least 2 layers are required
– When layers > 2, inner layer burns slower
than outer layer
– Smoke in jar is from inner tube
Results: Variation in layers
Fast-burning
outer layer
Slow-burning
inner layer
Results: Smoke Flow
 Smoke flow in jar is
laminar
– Reynolds no. < 2000
– No vortices or eddies
Turbulent flow Laminar flow
Effect of length & ⌀
 15cm tube used in separate test
– Length of tube has no significant effect
– Smoke exits from opposite end almost
immediately
 Diameter of tube = 12.0 mm:
– smoke remains in tube, flow extremely
slow.
The really tricky bit:
What is the mechanism driving smoke
into the jar?
Patm air
Phot air
Pressure Gradient?
Smoke?
Proposed mechanism:
Patm air
Hot air expands
Inside tube
Expanded air
pushes both ways
Expanding air drives
Smoke into jar
smoke
Patm air
Proposed mechanism:
 Such a mechanism supports results.
– Flow speed not significantly affected by
length
– Larger diameter, less (slower) smoke flow
• Air has more room to expand
 Determine if theoretical flow speed
fits actual values.
Calculations
Volumetric flow
rate
 C6H10O5 + O2  5C + 5H2O + CO2
(incomplete combustion of cellulose)
 Find rate of combustion of paper
 Use eqn. to find rate of expulsion of CO2 &
H2O gas
 To find rate of expansion of gas
 Volumetric flow rate
of air into the tube.
Calculations (Cont’d)
 C6H10O5 + O2  5C + 5H2O + CO2
 Determine average flow speed
Average flow speed
Expanded air
pushes both ways smoke
Assumptions
 Expanded air splits equally on each side
 Paper is 100% cellulose; Incomplete
combustion
 Smoke is a suspension that travels
along with air
 Temperature of burning paper
is at 400°C
(slightly above flash point of paper)
Calculating rate of combustion
 Expt. to derive rate of combustion of paper:
 Avg. rate = 0.0186 gs-1
= 0.0186 gs-1 ∕ 162.0 gmol-1
= 0.000115 mols-1
Trial Initial mass/
g
Final mass/
g
Δ mass/
g
Time/ s Rate of
combustion/ gs-1
1 0.480 0.210 0.270 15.50 0.0174
2 0.461 0.259 0.202 11.16 0.0181
3 0.341 0.045 0.296 15.37 0.0192
4 0.336 0.201 0.165 8.41 0.0196
Calculating Volumetric Flow Rate
 C6H10O5 + O2  5C + 5H2O + CO2
 Rate of combustion of O2 =
0.000115mols-1
 Rate of formation of CO2 & H2O gas
= 0.000115 mols-1 × 6
= 0.000689 mols-1
initial temp. = 400°C , exit temp. = 50°C
 Ideal gas law: PV=nRT
Calculating Volumetric Flow Rate
 Volumetric flow rate into tube
= 0.0000380 m3s-1 ∕ 2
= 0.0000190 m3s-1
 Volumetric flow rate at exit
=0.00000913 m3s-1
 Average volumetric flow rate
= 0.0000141 m3s-1
Limitations
 Only expansion of combusted gas
considered
– (ignore heating of surrounding air)
 ‘Leakage’ of air not considered.
 Drops in pressure caused by drag not
factored.
 Only average flow speed is derived
– Instantaneous flow speed cannot be
calculated as we do not know how temp.
varies along tube
‘leaks’
Average Flow speed:
 Theoretical
– Vnarrow tube ≈ 0.7 ms-1
– Vwide tube ≈ 0.15ms-1
 Actual
– Vnarrow tube ≈ 0.5ms-1
– Vwide tube (N.A)
Computed Reynolds number
 Narrow tube (⌀ 5.0mm)
– Re ≈ 83
 Wide tube (⌀ 12.0mm)
– Re ≈ 34
 Reynolds no. are ultra-low, in the order
of 101
 Flow in tube fits laminar flow as
observed.
Conclusion:
 Mechanism has been proposed for the
phenomenon.
– Volumetric expansion of air
– Cooling of gas produced
 However, other factors are also
involved:
– ‘leakage of air’
– Change in pressure due to drag
 Hagen Poiseuille equation
Thank You

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Smoke Stream_edited

  • 2. Question:  A glass jar is covered with cellophane. A tightly folded paper tube of length 4-5 cm is inserted hermetically into the jar through the cellophane cover. The tube is oriented horizontally.  If one burns out outside end of the tube the dense smoke flows into the jar.  Explore this phenomenon.
  • 3. Introduction  We conventionally see smoke rise.  The tricky bit: – Since smoke rises, how do can it flow horizontally into the jar? – Smoke must sink
  • 4. Introduction  Why smoke rises: – Convection  Rising air column carries the smoke particles up. – Mass of particle ≈ 1.7 × 10-12 – 2.8 × 10-7 g
  • 5. Theory  Assuming smoke particles consist of 12C: – ρ smoke particles ≈ 2200 kg/m3 – ρ air = 1.1839 kg/m3 @ 25°C  ρ smoke particles > ρ air – in the absence of convection, smoke should sink naturally.
  • 8. Experimentation  to record footage of the phenomenon for analysis: – Effect of the number of layers of paper. – Effect of diameter / length of tube – Mechanism driving smoke into the jar – Theoretical vs. Actual flow speed in tube
  • 9. Experimentation  Variable: – Number of layers of paper in each tube. • 1, 2, 3 & 4  Constants: – Diameter of the paper tube (5.0mm). – Type of paper used – Length of paper tube (10.0cm) • 6 cm protrusion outside the beaker
  • 10.
  • 11.  At least 2 layers are required – When layers > 2, inner layer burns slower than outer layer – Smoke in jar is from inner tube Results: Variation in layers Fast-burning outer layer Slow-burning inner layer
  • 12. Results: Smoke Flow  Smoke flow in jar is laminar – Reynolds no. < 2000 – No vortices or eddies Turbulent flow Laminar flow
  • 13. Effect of length & ⌀  15cm tube used in separate test – Length of tube has no significant effect – Smoke exits from opposite end almost immediately  Diameter of tube = 12.0 mm: – smoke remains in tube, flow extremely slow.
  • 14. The really tricky bit: What is the mechanism driving smoke into the jar? Patm air Phot air Pressure Gradient? Smoke?
  • 15. Proposed mechanism: Patm air Hot air expands Inside tube Expanded air pushes both ways Expanding air drives Smoke into jar smoke Patm air
  • 16. Proposed mechanism:  Such a mechanism supports results. – Flow speed not significantly affected by length – Larger diameter, less (slower) smoke flow • Air has more room to expand  Determine if theoretical flow speed fits actual values.
  • 17. Calculations Volumetric flow rate  C6H10O5 + O2  5C + 5H2O + CO2 (incomplete combustion of cellulose)  Find rate of combustion of paper  Use eqn. to find rate of expulsion of CO2 & H2O gas  To find rate of expansion of gas  Volumetric flow rate of air into the tube.
  • 18. Calculations (Cont’d)  C6H10O5 + O2  5C + 5H2O + CO2  Determine average flow speed Average flow speed
  • 19. Expanded air pushes both ways smoke Assumptions  Expanded air splits equally on each side  Paper is 100% cellulose; Incomplete combustion  Smoke is a suspension that travels along with air  Temperature of burning paper is at 400°C (slightly above flash point of paper)
  • 20. Calculating rate of combustion  Expt. to derive rate of combustion of paper:  Avg. rate = 0.0186 gs-1 = 0.0186 gs-1 ∕ 162.0 gmol-1 = 0.000115 mols-1 Trial Initial mass/ g Final mass/ g Δ mass/ g Time/ s Rate of combustion/ gs-1 1 0.480 0.210 0.270 15.50 0.0174 2 0.461 0.259 0.202 11.16 0.0181 3 0.341 0.045 0.296 15.37 0.0192 4 0.336 0.201 0.165 8.41 0.0196
  • 21. Calculating Volumetric Flow Rate  C6H10O5 + O2  5C + 5H2O + CO2  Rate of combustion of O2 = 0.000115mols-1  Rate of formation of CO2 & H2O gas = 0.000115 mols-1 × 6 = 0.000689 mols-1 initial temp. = 400°C , exit temp. = 50°C  Ideal gas law: PV=nRT
  • 22. Calculating Volumetric Flow Rate  Volumetric flow rate into tube = 0.0000380 m3s-1 ∕ 2 = 0.0000190 m3s-1  Volumetric flow rate at exit =0.00000913 m3s-1  Average volumetric flow rate = 0.0000141 m3s-1
  • 23. Limitations  Only expansion of combusted gas considered – (ignore heating of surrounding air)  ‘Leakage’ of air not considered.  Drops in pressure caused by drag not factored.  Only average flow speed is derived – Instantaneous flow speed cannot be calculated as we do not know how temp. varies along tube ‘leaks’
  • 24. Average Flow speed:  Theoretical – Vnarrow tube ≈ 0.7 ms-1 – Vwide tube ≈ 0.15ms-1  Actual – Vnarrow tube ≈ 0.5ms-1 – Vwide tube (N.A)
  • 25. Computed Reynolds number  Narrow tube (⌀ 5.0mm) – Re ≈ 83  Wide tube (⌀ 12.0mm) – Re ≈ 34  Reynolds no. are ultra-low, in the order of 101  Flow in tube fits laminar flow as observed.
  • 26. Conclusion:  Mechanism has been proposed for the phenomenon. – Volumetric expansion of air – Cooling of gas produced  However, other factors are also involved: – ‘leakage of air’ – Change in pressure due to drag  Hagen Poiseuille equation