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c                            C.
                                     I                           I
                        C-C-C-c-c:-c                        -C-C-C-c
             chance               =ti- Yl'1dro'jetlS       YYa-th                  ~xUJ          i~   Lireness
                                                                                           -1SL
    3°              5                      2-                0                             br'<o
    2°             3.~                    2                4S.1.o                           4-S.b
                                                                                             b'.b
    1°
                                          12.
V                                                     I~     2

                                                            Col.~

             C')U(Ct          :t: hJd V"OC ens        ffiQ+n             ) nbo.b l 1.J           ut.e'AeS&
    '3°1      1(000                       2                 32DO                         ~200               -,1.0°/'0
                                                                                         ~qo
    2°             82                 11                    C184-                        --ft¥Lf=            23°/u
    IV                                                                                   4QIo
                    I
             _.-   ---                2
                                                      + 12                   ,           _ '2-
                                                                                          ltlq(o
                                                                                                             .3/0
                                                           41'1lp
         *brofnH'O'ho             410   o.l~~        -t~X+io.¥j 30) ~'.
                                                                 (


         c
                   -c

         .B : Br          -">     ~r· ·Br

         c                                                            C.
                                                                      
                                                           C -        C - C              +    t1 : Br .
                                                                      •
                                                             free          rGdCD...
Br· + 'Br. ~   '&"' :   ~r

                                          C
                                            
                                    c.- C -
                                        ,         C
                                       B~
      ~c
~/         I                               C
 /'    C- c - c   +. 5r         ~    C
                                            1
                                         -c, -        C
          •
                                           Br-

          C           C
          I                                      c c..
                      
      c..-C-C+                                           
                  c-c-c ~                 C-     c.: c. -     c..
          •                                       I       l
                                                 C C
-Sn1
 ~




                                                 +120-

                                                                       c.-~CH-3>

                                                                    1-10$   C.l3    Cl
                                                                      lCH£hC-f?>




                               c.thC.H~
                                I    __
                   -~C - C:       0 Hi-             : C - ~                       Cl
                                I
                               ( 0-2.) 2. Qt~
·cc                      -c -
                 .C-C-c-c-c. - G -G-c....
                                       "                          I

                  •                t                              ,
                   frobo.r;l~
                  ~OSSibt;~                  ,      ~~~~en                           ~o:tn   nro. ctibn                  ~/••
                           5                  .Jl             ::.L:            'l.     10              'C/S2...}         lC. I   °10
                       3.8                    ~                                .. BO."+-        ;}c·'f(S2.4           Gi3'~
                           l                  «                                ~       12..            1'l./S2..'+         ').'29.7>/"

                           I                                "--                      52.4-                                                J
                      -c                                                                         ~                   ~-t.P
                           "~/G-                                      ~                                    ~~u."d~/(fvvi..
                   -c.--C-C-C-c.-c.,                                                                                  ~             ~~
                                                                                                               r=;: ::r
                                                                                                                                                              0Wt"--


     ~                         I              -q _                                                                                                   t'~




            I&ctrlll-i~                   "" I ~                    CU'Itj ~

                                                            :;H.4             -::4t at
    ",_~                                   ~bi((':J                            ~~0                ~a.m                                        0/",
                   3   0                            5                     IC
                                                                                                                                          G·~oD
                                                                                                                                           (,7 'J/o
           ~~     2-                                3.~                    ~                                                                   110.
    &              ,.                                   I                                     '. -4-    I.                                      '3q.lf7-:J/ p




                                                                                                  +s.            to
-   -   ---.---,-~----------------------:--




                 CH4  t cl 2 .:»              C'H3C l      $

                   CW.5 C ( ~ Cl 2. ~       CH 2 Cl   2

                     CI-b C! 2 +- Cl    2    ~    c.H Cl ~
                        CH   er ~   + C!    2 ~   ~   er   <..(.




             +

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Mono chlorination and bromination

  • 1. c C. I I C-C-C-c-c:-c -C-C-C-c chance =ti- Yl'1dro'jetlS YYa-th ~xUJ i~ Lireness -1SL 3° 5 2- 0 br'<o 2° 3.~ 2 4S.1.o 4-S.b b'.b 1° 12. V I~ 2 Col.~ C')U(Ct :t: hJd V"OC ens ffiQ+n ) nbo.b l 1.J ut.e'AeS& '3°1 1(000 2 32DO ~200 -,1.0°/'0 ~qo 2° 82 11 C184- --ft¥Lf= 23°/u IV 4QIo I _.- --- 2 + 12 , _ '2- ltlq(o .3/0 41'1lp *brofnH'O'ho 410 o.l~~ -t~X+io.¥j 30) ~'. ( c -c .B : Br -"> ~r· ·Br c C. C - C - C + t1 : Br . • free rGdCD...
  • 2. Br· + 'Br. ~ '&"' : ~r C c.- C - , C B~ ~c ~/ I C /' C- c - c +. 5r ~ C 1 -c, - C • Br- C C I c c.. c..-C-C+ c-c-c ~ C- c.: c. - c.. • I l C C -Sn1 ~ +120- c.-~CH-3> 1-10$ C.l3 Cl lCH£hC-f?> c.thC.H~ I __ -~C - C: 0 Hi- : C - ~ Cl I ( 0-2.) 2. Qt~
  • 3. ·cc -c - .C-C-c-c-c. - G -G-c.... " I • t , frobo.r;l~ ~OSSibt;~ , ~~~~en ~o:tn nro. ctibn ~/•• 5 .Jl ::.L: 'l. 10 'C/S2...} lC. I °10 3.8 ~ .. BO."+- ;}c·'f(S2.4 Gi3'~ l « ~ 12.. 1'l./S2..'+ ').'29.7>/" I "-- 52.4- J -c ~ ~-t.P "~/G- ~ ~~u."d~/(fvvi.. -c.--C-C-C-c.-c., ~ ~~ r=;: ::r 0Wt"-- ~ I -q _ t'~ I&ctrlll-i~ "" I ~ CU'Itj ~ :;H.4 -::4t at ",_~ ~bi((':J ~~0 ~a.m 0/", 3 0 5 IC G·~oD (,7 'J/o ~~ 2- 3.~ ~ 110. & ,. I '. -4- I. '3q.lf7-:J/ p +s. to
  • 4. - - ---.---,-~----------------------:-- CH4 t cl 2 .:» C'H3C l $ CW.5 C ( ~ Cl 2. ~ CH 2 Cl 2 CI-b C! 2 +- Cl 2 ~ c.H Cl ~ CH er ~ + C! 2 ~ ~ er <..(. +