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Title here
Our mission is to enable and enhance freedom on land, sea, and air.
650 Wh/kg, 1400 Wh/L Rechargeable Batteries
for New Era of Electrified Mobility
Y. Mikhaylik*, I. Kovalev, C. Scordilis-Kelley, L. Liao, M. Laramie, U. Schoop, T. Kelley.
Licerion®
Topics
• Sion Power's New Licerion Technology Provides a Solution Beyond
Conventional Li-Ion
− Key elements of Licerion technology
− Road map to ultra high energy
• Sion Power/BASF Development of Licerion Batteries for Diverse Applications
− Current state of Energy Density
− Cycle Life
− Rate Capability
− Thermal Stability
− Low Temperature Performance
• Licerion Cells Availability
2
2018 NASA Aerospace Battery Workshop
Key Elements of Licerion®
Technology
§ Physical Protection of Lithium Metal Anode
with Thin, Chemically Stable and Ionically
Conductive Ceramic/Polymer Barriers
§ Spectra of Chemical Protections
– Electrolyte additives forming protective
film on the anode to extend cycle life
– Stabilized electrodes enhancing cycle
life and increasing energy
§ Cell Designs Which Maximize Energy and
Control Lithium Morphology During
Extended Cycling
§ 50% Reduction in Liquid Electrolyte Volume
Versus Conventional Li-Ion Technology
3
2018 NASA Aerospace Battery Workshop
Strategic Advancement
In 2015 Sion Power Made a
Strategic Decision to
Transition from Lithium-Sulfur
to Lithium-Metal Oxide
Rechargeable Battery
Technology.
4
Extending Licerion®
Technology
to Intercalation Cathodes
§ Intercalation Li-Metal Oxide Cathodes are Well Developed by Li-
Ion Battery Industry and Have Reached Technological Maturity.
§ High Quality Intercalation Cathodes are Available from Variety of
Sources including BASF Partners.
§ Licerion-Ion Battery Production is Compatible with Existing Li-ion
Manufacturing Processes.
5
2018 NASA Aerospace Battery Workshop
Roadmap to Ultra High Energy Density
Intercalation cathodes coupled with Licerion protected Li offer higher energy
density compared with other systems.
NiMH
Li-Ion
(Intercalation Anodes)
Li-S
400 Wh/kg
700 Wh/L
350 Cycles
2015
400 Wh/kg
800 Wh/L
350 Cycles
2016-2017
500 Wh/kg
1000 Wh/L
450 Cycles
2018
1000 cycles
2022
640 Wh/kg
1300 Wh/L
400 cycles
2022
1800 Cycles
2030
Licerion
® Batteries
6
2018 NASA Aerospace Battery Workshop
Licerion®
-Ion Progressing Rapidly
2018 Goal
500 Wh/kg
1000 Wh/L
450-500 Cycles
Protected lithium anode, electrolyte system and Ni-rich NCM cathode enable rapid
progress in energy densities and cycle life.
7
2018 NASA Aerospace Battery Workshop
What Cycle Life is Good Enough?
Car Life Expectancy = Driving Range x Cycle Life
200, 000 miles = 400 miles x 500 Cycles
Licerion®
500 Wh/kg
Licerion®
1000 Wh/L EV Applications
Driving
Range
400 miles
8
2018 NASA Aerospace Battery Workshop
• 2018
Licerion exceeded
500 Wh/kg, 1000 Wh/L, and >450 cycles
in 0.4 Ah development cells.
Projected specific energy and energy
density were confirmed in the actual large
cells.
• 2019
Scale-up and commercialize in large cell
format
− 26 Ah cell
− 10 cm x 10 cm x 1 cm
Licerion® Achieves 2018 Goal:
1000 Wh/L, 500 Wh/kg, > 450 Cycles
Specific energy and energy density projected to 10 cm x 10 cm x 1 cm cell design
using same active materials balance as 0.4 Ah cells and accounting for weight and
volume of all large cell components.
9
2018 NASA Aerospace Battery Workshop
Licerion® Li Anode Protection Leads to
Low Cell Electrical Resistance
Licerion protected Li anode
coupled with metal oxide
intercalation cathode has area
specific resistance of
18 Ohm*cm2
dV/dI x Electrodes Area = Area Specific Resistance
at steady state conditions
10
2018 NASA Aerospace Battery Workshop
Strategy to Improve Rate Capability
Area Specific Resistance
(ASR) – Temperature
Dependence Gives Insight
into What Controls Cell
Rate Capability at Low and
Elevated Temperatures
Area for Electrodes/Cell Design
Improvement
Area for Chemistry
Improvement
)
exp(
1
RT
E
Rate
ASR
a
-
»
»
Arrhenius plot of ASR as a function of temperature
11
2018 NASA Aerospace Battery Workshop
High Combination of Power and Energy
12
2018 NASA Aerospace Battery Workshop
• Licerion®
Cells Provide Good Power
and Energy Over Wide Range of Rates
• Higher temperatures yield higher
specific energy
High Specific Energy Over a Wide
Temperature Range
Specific Energy Delivered at Various Temperatures and Discharge Rates
13
2018 NASA Aerospace Battery Workshop
Stability of Licerion®
Technology in Abuse Testing
• Thermal Stability is Determined by the
Choice of Cathode Material (not Anode)
• Licerion®
Cell is Thermally Stable Until
Above 200°C
• Verified Licerion 1 and 2
• 6 Ah Licerion 1 Passed the Following
Abuse Tests:
• External Short, 100% SOC
• Over-charge
• Over-discharge
• Planned:
• Nail Penetration
• 3rd Party Validation
• 10 and 20 Ah Cell
• UN certification
Increase Ni
14
2018 NASA Aerospace Battery Workshop
200 mAh/g
cathode capacity
required for
>500 Wh/kg
Thermal Stability of 6 Ah Licerion Cells
Licerion®
Technology Variations
15
2018 NASA Aerospace Battery Workshop
500 Wh/kg
1000 Wh/L
Ultra High Energy
650 Wh/kg
1400 Wh/L
High Power
20C Rate Capability
>400 Wh/kg
>700 Wh/L
Ultra High Energy Licerion® Cells
16
2018 NASA Aerospace Battery Workshop
Energy up to 700 Wh/kg and 1400 Wh/L
Note: test in process, early results
High Power Licerion® Cells
Energy Over 70% at 20C Discharge Rate
17
2018 NASA Aerospace Battery Workshop
Capacity Over 75% at 20C Discharge Rate
High Power Licerion® Cells
Energy Over 400 Wh/kg
and 700 Wh/L
Discharge Rates up to 4 -10C
Charge Rates up to 1C
18
2018 NASA Aerospace Battery Workshop
19
Summary
• Licerion®
Technology Offers Extended Driving and Flying
Ranges for Diverse Electrified Mobility Applications through the
application of Advanced Metallic Lithium Protection Systems
• Specific Energy, Energy Density and Cycle Life Have Reached
500 Wh/kg and 1000 Wh/L and Over 450 Cycles
• High Energy Licerion Cells Offer up to 700 Wh/kg and 1400 Wh/L
• High Power Licerion Cells Offer Rate Capability up to 20C and
Specific Power up to 8 KW/kg at Continuous Discharge
• Sion Power is Developing Partnerships for Commercialization
and Volume Manufacturing to Supplement in-house Production
Capacities for a Variety of Markets
2018 NASA Aerospace Battery Workshop
Contact Us for More Information at
info@sionpower.com or Visit
www.sionpower.com Today

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silicon battery.pdf

  • 1. Title here Our mission is to enable and enhance freedom on land, sea, and air. 650 Wh/kg, 1400 Wh/L Rechargeable Batteries for New Era of Electrified Mobility Y. Mikhaylik*, I. Kovalev, C. Scordilis-Kelley, L. Liao, M. Laramie, U. Schoop, T. Kelley.
  • 2. Licerion® Topics • Sion Power's New Licerion Technology Provides a Solution Beyond Conventional Li-Ion − Key elements of Licerion technology − Road map to ultra high energy • Sion Power/BASF Development of Licerion Batteries for Diverse Applications − Current state of Energy Density − Cycle Life − Rate Capability − Thermal Stability − Low Temperature Performance • Licerion Cells Availability 2 2018 NASA Aerospace Battery Workshop
  • 3. Key Elements of Licerion® Technology § Physical Protection of Lithium Metal Anode with Thin, Chemically Stable and Ionically Conductive Ceramic/Polymer Barriers § Spectra of Chemical Protections – Electrolyte additives forming protective film on the anode to extend cycle life – Stabilized electrodes enhancing cycle life and increasing energy § Cell Designs Which Maximize Energy and Control Lithium Morphology During Extended Cycling § 50% Reduction in Liquid Electrolyte Volume Versus Conventional Li-Ion Technology 3 2018 NASA Aerospace Battery Workshop
  • 4. Strategic Advancement In 2015 Sion Power Made a Strategic Decision to Transition from Lithium-Sulfur to Lithium-Metal Oxide Rechargeable Battery Technology. 4
  • 5. Extending Licerion® Technology to Intercalation Cathodes § Intercalation Li-Metal Oxide Cathodes are Well Developed by Li- Ion Battery Industry and Have Reached Technological Maturity. § High Quality Intercalation Cathodes are Available from Variety of Sources including BASF Partners. § Licerion-Ion Battery Production is Compatible with Existing Li-ion Manufacturing Processes. 5 2018 NASA Aerospace Battery Workshop
  • 6. Roadmap to Ultra High Energy Density Intercalation cathodes coupled with Licerion protected Li offer higher energy density compared with other systems. NiMH Li-Ion (Intercalation Anodes) Li-S 400 Wh/kg 700 Wh/L 350 Cycles 2015 400 Wh/kg 800 Wh/L 350 Cycles 2016-2017 500 Wh/kg 1000 Wh/L 450 Cycles 2018 1000 cycles 2022 640 Wh/kg 1300 Wh/L 400 cycles 2022 1800 Cycles 2030 Licerion ® Batteries 6 2018 NASA Aerospace Battery Workshop
  • 7. Licerion® -Ion Progressing Rapidly 2018 Goal 500 Wh/kg 1000 Wh/L 450-500 Cycles Protected lithium anode, electrolyte system and Ni-rich NCM cathode enable rapid progress in energy densities and cycle life. 7 2018 NASA Aerospace Battery Workshop
  • 8. What Cycle Life is Good Enough? Car Life Expectancy = Driving Range x Cycle Life 200, 000 miles = 400 miles x 500 Cycles Licerion® 500 Wh/kg Licerion® 1000 Wh/L EV Applications Driving Range 400 miles 8 2018 NASA Aerospace Battery Workshop
  • 9. • 2018 Licerion exceeded 500 Wh/kg, 1000 Wh/L, and >450 cycles in 0.4 Ah development cells. Projected specific energy and energy density were confirmed in the actual large cells. • 2019 Scale-up and commercialize in large cell format − 26 Ah cell − 10 cm x 10 cm x 1 cm Licerion® Achieves 2018 Goal: 1000 Wh/L, 500 Wh/kg, > 450 Cycles Specific energy and energy density projected to 10 cm x 10 cm x 1 cm cell design using same active materials balance as 0.4 Ah cells and accounting for weight and volume of all large cell components. 9 2018 NASA Aerospace Battery Workshop
  • 10. Licerion® Li Anode Protection Leads to Low Cell Electrical Resistance Licerion protected Li anode coupled with metal oxide intercalation cathode has area specific resistance of 18 Ohm*cm2 dV/dI x Electrodes Area = Area Specific Resistance at steady state conditions 10 2018 NASA Aerospace Battery Workshop
  • 11. Strategy to Improve Rate Capability Area Specific Resistance (ASR) – Temperature Dependence Gives Insight into What Controls Cell Rate Capability at Low and Elevated Temperatures Area for Electrodes/Cell Design Improvement Area for Chemistry Improvement ) exp( 1 RT E Rate ASR a - » » Arrhenius plot of ASR as a function of temperature 11 2018 NASA Aerospace Battery Workshop
  • 12. High Combination of Power and Energy 12 2018 NASA Aerospace Battery Workshop
  • 13. • Licerion® Cells Provide Good Power and Energy Over Wide Range of Rates • Higher temperatures yield higher specific energy High Specific Energy Over a Wide Temperature Range Specific Energy Delivered at Various Temperatures and Discharge Rates 13 2018 NASA Aerospace Battery Workshop
  • 14. Stability of Licerion® Technology in Abuse Testing • Thermal Stability is Determined by the Choice of Cathode Material (not Anode) • Licerion® Cell is Thermally Stable Until Above 200°C • Verified Licerion 1 and 2 • 6 Ah Licerion 1 Passed the Following Abuse Tests: • External Short, 100% SOC • Over-charge • Over-discharge • Planned: • Nail Penetration • 3rd Party Validation • 10 and 20 Ah Cell • UN certification Increase Ni 14 2018 NASA Aerospace Battery Workshop 200 mAh/g cathode capacity required for >500 Wh/kg Thermal Stability of 6 Ah Licerion Cells
  • 15. Licerion® Technology Variations 15 2018 NASA Aerospace Battery Workshop 500 Wh/kg 1000 Wh/L Ultra High Energy 650 Wh/kg 1400 Wh/L High Power 20C Rate Capability >400 Wh/kg >700 Wh/L
  • 16. Ultra High Energy Licerion® Cells 16 2018 NASA Aerospace Battery Workshop Energy up to 700 Wh/kg and 1400 Wh/L Note: test in process, early results
  • 17. High Power Licerion® Cells Energy Over 70% at 20C Discharge Rate 17 2018 NASA Aerospace Battery Workshop Capacity Over 75% at 20C Discharge Rate
  • 18. High Power Licerion® Cells Energy Over 400 Wh/kg and 700 Wh/L Discharge Rates up to 4 -10C Charge Rates up to 1C 18 2018 NASA Aerospace Battery Workshop
  • 19. 19 Summary • Licerion® Technology Offers Extended Driving and Flying Ranges for Diverse Electrified Mobility Applications through the application of Advanced Metallic Lithium Protection Systems • Specific Energy, Energy Density and Cycle Life Have Reached 500 Wh/kg and 1000 Wh/L and Over 450 Cycles • High Energy Licerion Cells Offer up to 700 Wh/kg and 1400 Wh/L • High Power Licerion Cells Offer Rate Capability up to 20C and Specific Power up to 8 KW/kg at Continuous Discharge • Sion Power is Developing Partnerships for Commercialization and Volume Manufacturing to Supplement in-house Production Capacities for a Variety of Markets 2018 NASA Aerospace Battery Workshop
  • 20. Contact Us for More Information at info@sionpower.com or Visit www.sionpower.com Today