Cray Valley's line of Krasol resins are low molecular weight, hydroxyl-terminated diols based on homopolymers of butadiene. As hydroxyl-terminated polybutadiene (HTPB) resins, Cray Valley dissects the product to provide key insights into its features, applications and properties.

1. Krasol® Polybutadiene Monol
Features and Attributes of Krasol® Resins

2. Overview
• Physical Properties, Polybutadiene Monol
• Derivatives
• Attributes
• Applications
• About Cray Valley
2 Cray Valley HSC

3. Polybutadiene Monol
Physical Properties
• Extremely long chain alcohols with carbon counts > > 140
Extremely long chain alcohols with carbon counts 140
x y
• Linear Chains
• Linear chains • 2000-5000 g/molg/mol Mn
2,000-5,000 Mn
• • Mono-functional, chain end 65% vinyl, 35% cis/trans
Mono-functional, chain end • 65% vinyl, 36% cis/trans
Tg ~ -35˚C to -45˚C
• • Secondaryhydroxyl
Secondary hydroxl
• 10 - 50 Pas to -45°C
Tg ~ -35°C
• • Liquid physical form
Liquid physical form
• 10 – 50 Pas
3
2 Cray Valley HSC

4. Derivatives
• Creating functional derivatives increases
Derivatives
the application scope.
• Creating functional derivatives increases the application scope
x y
where X =
1. hydrogenation
x y
2. -OH transformation
x y
3 Cray Valley HSC
4 Cray Valley HSC

5. Attributes
• Polybutadiene monol
- Hydrophobicity, acid/base resistance
- Compatibility with hydrocarbon additives
- Capability of curing (peroxide, UV, sulfur)
- Reactivity of terminal group
• Hydrogenated monol
- Oleophilic
- Fully saturated
- Compatibility with olefinic polymers
- Reactivity of terminal group
5 Cray Valley HSC

6. Potential Applications
Possible Applications
Potential Applications
• Potential Applications
• MACROMONOMERS
MACROMONOMERS
• MACROMONOMERS
- Olefinic macromonomers for the synthesis of
- Olefinic macromonomers for the synthesis
- Olefinic macromonomers for the synthesis
• MACROMONOMERS
polymers.
combof comb polymers
of comb polymers
- Olefinic macromonomers for the synthesis
ADDITIVES
ADDITIVES
of comb polymers
• ADDITIVES modification
ADDITIVES
•• Surface
Surface modification
• Adhesion
- •Surface modification
Adhesion
• Surface modification
• Hydrophobic coatings additives
- •Adhesion
• Adhesion Hydrophobic coatings additives
• Rheological coatings additives
- Hydrophobic modification
• Rheological modification
• Hydrophobic coatings additives
- Rheological modification
• Rheological modification
DISPERSION / COMPATIBILIZATION
DISPERSION of COMPATIBILIZATION
• Dispersion / fillers
• DISPERSION/COMPATIBILIZATION
DISPERSION / COMPATIBILIZATION
• Dispersion of fillers
• Reactive compatibilizers
- • Dispersion of fillers
Dispersion of fillers
• Reactive compatibilizers
- • Reactivecompatibilizers
Reactive compatibilizers
5 Cray Valley HSC
5 5 Cray Valley HSC
Cray Valley HSC
6 Cray Valley HSC

7. Cray Valley HSC
A Division of Total SA
Upstream Downstream Chemicals
• Oil & gas exploration • Trading & shipping • Base chemicals
• Production • Refining & marketing • Industrial & consumer
Focus
• Gas & power • Commodity & specialty market specialty
• Alternative energy fluids chemicals
Sales
$24.6 $163.4 $23.2
(billion)
Employees 17,192 32,631 41,658
Total, a partner in your challenges
7 Cray Valley HSC

8. Cray Valley HSC
Focus Markets
• Performance • Pressure • Printed
Growth Markets
additives sensitive circuit
boards
Adhesives
• Tire & hose • Reactive
Rubber
applications adhesives • Pigment
Dispersants
• Co-curing • Insulated
agents Glass • Mineral
Sealants Dispersants
8 Cray Valley HSC

9. Cray Valley HSC
Global Presence
9 Cray Valley HSC

10. Cray Valley HSC
• For additional information about Cray Valley, its products
or its work in Hydrocarbon Specialty Chemicals,
visit www.CVPolymerAdditives.com.
10 Cray Valley HSC