Castillian Inc. is a Canadian gold exploration company advancing its flagship Hope Brook Gold Project in Newfoundland. In 2011, Castillian announced a maiden NI 43-101 resource of 740,000 ounces of inferred gold and 290,000 ounces of indicated gold. Castillian plans to expand on this resource through a 5,000 meter drill program targeting extensions along the 8+ kilometer mineralized structure. The company also aims to increase its resource base through acquisitions to become a multi-million ounce gold producer.

1. TSX-V: CT
OTCQX: CTIIF
Growing Gold Deposits and
Advancing Projects in Canada
June 2012

2. Forward Looking Statements
The information presented contains “forward-looking statements”, within the meaning of the United States Private Securities Litigation Reform Act of 1995, and
“forward-looking information” under similar Canadian legislation, concerning the business, operations and financial performance and condition of the Company.
Forward-looking statements and forward-looking information include, but are not limited to, statements with respect to estimated production, the estimation of
mineral reserves and mineral resources; the realization of mineral reserve estimates; the timing and amount of estimated future production; costs of production;
capital expenditures; success of exploration activities; permitting time lines and permitting, mining or processing issues; government regulation of mining
operations; environmental risks; unanticipated reclamation expenses; title disputes or claims; litigation liabilities; and limitations on insurance coverage.
Generally, forward-looking statements and forward-looking information can be identified by the use of forward-looking terminology such as “plans”, “expects” or
“does not expect”, “is expected”, “budget”, “scheduled”, “estimates”, “forecasts”, “intends”, “anticipates” or “does not anticipate”, or believes”, or variations of
such words and phrases or state that certain actions, events or results “may”, “could”, “would”, “might” or “will be taken”, “occur” or “be achieved”. Forward-
looking statements and forward-looking information are based on the opinions and estimates of management as of the date such statements are made, and
they are subject to known and unknown risks, uncertainties and other factors that may cause the actual results, level of activity, performance or achievements
of the Company to be materially different from those expressed or implied by such forward-looking statements or forward-looking information. Although
management of the Company has attempted to identify important factors that could cause actual results to differ materially from those contained in forward-
looking statements or forward-looking information, there may be other factors that cause results not to be as anticipated, estimated or intended. There can be
no assurance that such statements will prove to be accurate, as actual results and future events could differ materially from those anticipated in such
statements. Accordingly, readers should not place undue reliance on forward-looking statements and forward-looking information. The Company does not
undertake to update any forward-looking statements or forward-looking information that are incorporated by reference herein, except in accordance with
applicable securities laws.
Dr. Bill Pearson, P.Geo. who is a Qualified Person as defined by National Instrument NI 43-101 and reviewed and approved the scientific and technical
information contained in this presentation.
Cautionary Note to U.S. Investors Concerning Estimates of Measured, Indicated or Inferred Resources.
The information presented uses the terms “measured”, “indicated” and “inferred” mineral resources. United States investors are advised that while such terms
are recognized and required by Canadian regulations, the United States Securities and Exchange Commission does not recognize these terms. “Inferred
mineral resources” have a great amount of uncertainty as to their existence, and as to their economic and legal feasibility. It cannot be assumed that all or any
part of an inferred mineral resource will ever be upgraded to a higher category. Under Canadian rules, estimates of inferred mineral resources may not form the
basis of feasibility or other economic studies. United States investors are cautioned not to assume that all or any part of measured or indicated mineral
resources will ever be converted into mineral reserves. United States investors are also cautioned not to assume that all or any part of an inferred mineral
resource exists, or is economically or legally mineable.
In connection with the recently announced private placement financing, this presentation shall not constitute an offer to sell or the solicitation of an offer to buy
nor shall there be any sale of the securities in any State in which such offer, solicitation or sale would be unlawful. The securities that are subject to the recently
announced private placement financing have not been registered under the United States Securities Act of 1933, as amended, and may not be offered or sold
in the United States absent registration or an applicable exemption from the registration requirements.
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3. 2011: Accomplishments
 Castillian has significantly advanced its flagship Hope Brook Gold Project in Newfoundland
• First NI 43 -101 mineral resource announced February 14, 2012 (filed April 5, 2012), meeting guidance
at 740,000 inferred ounces of gold and 290,000 indicated ounces of gold and in just 16 months of
exploration
• Discovery cost of approximately $10 per resource ounce
• Positive tailing results have the potential to increase current mineral resource estimate
o Average grade of 58 tailings samples tested is 0.96 g Au/t and 0.10% Cu (see April 24, 2012 press
release).
 Substantially advanced Canadian Creek project in Yukon, outlining a 7.5 km long gold-in-
soil anomaly that is associated with a major structure
 In Bolivia, continue to evaluate options related to Achachucani
 Working on completing the sale of other non-core assets
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4. Advancing Hope Brook
2010 2010 2011
February December September
Acquired Hope Intersected Intersected
Brook Gold 2.41 g Au/t 4.09 g Au/t over
Project over 26.5 metres 29.3 metres in Mine
in Pit Zone Zone Extension
2010 2011 2012
August March February
Started Intersected First NI 43 -101
Exploration 4.56 g Au/t Mineral Resource
Program over 8.9 metres Exploration Drilling
in Hanging Wall Recommenced
Zone at Hope Brook
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5. 2012: Moving Castillian Forward
 5000 metre drill program designed to test potential
major extensions is in progress at Hope Brook
• Testing priority targets that have been identified
• Continuing to look for new zones along extensive
mineralized structure
 Continue to test tailings
 Complete technical work for PEA
 Complete metallurgical testing
 Sell or joint venture non core assets
 Deliver mineral resource estimate update by end of
2012
 Create a multi-million ounce resource company via
drilling and acquisitions
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6. $100
$125
$150
$175
$200
$0
$25
$50
$75
Torex Gold
Premier Gold
Trelawney
Romarco Minerals
Maudore Minerals
TSX-V: CT OTCQX: CTIIF
Detour Gold
Guyana Goldfields
Upside Potential
Rainy River Resources
Prodigy Gold
Exploreco Avg
Midway Gold
Belo Sun Mining
Amarillo Gold
Castillian adjusted market capitalization
Carlisle Goldfields
Northern Gold
Rio Novo
Castillian
CT Undervalued with Tremendous
Magellan Minerals
RBC Capital Markets , JR. Golds – Explorers and Developers, AMC/oz Valuations, January 2012
Probe Mines
Rye Patch Gold
Chesapeake Gold
Gryphon Gold
Mega Precious Metals
Average adjusted market capitalization for junior gold companies
Victoria Gold
Temex Resources
Sandspring Resources
$20/oz
$60/oz
PC Gold
Aurvista Gold
Coral Gold
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7. Hope Brook Gold: The Flagship Project
 Option to purchase 100%
interest in 993 claims covering
approximately 25,000 ha
 Historical production (1987 –
1997) of 752,163 ounces gold in
time of low gold prices
(<US$400/oz)
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8. Major Gold Mineralized Structure
more than 8 km in Length
Structure likely
continues under
granite sheet
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9. Large Scale Mineralized System
Altered &
Mineralized
Shear Zone
 Alteration zone 500+m wide
Open Pit
extends 8+ km along (behind hill)
Helicopter
strike with a number of
for scale
gold occurrences
 Mineralized zone open
along strike in both
directions and at depth
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10. Hope Brook Gold Resource Model
740,000 inferred and 290,000 indicated ounces of gold are located within this model
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11. NI 43-101 Mineral Resource
NI 43-101 MINERAL RESOURCE ESTIMATE, HOPE BROOK GOLD PROJECT *
Within constraining shell Below constraining shell
Total
@ 0.50 g Au/t cutoff @ 2.0 g Au/t cutoff
Tonnes Gold Gold Tonnes Gold Gold Tonnes Gold Gold
Category
(millions) (g/t) (oz) (millions) (g/t) (oz) (millions) (g/t) (oz)
Indicated 4.0 1.11 140,000 1.5 3.04 150,000 5.5 1.65 290,000
Inferred 11.2 1.57 570,000 2.0 2.65 170,000 13.2 1.73 740,000
 Constraining shell incorporates essentially all of the remaining historic resources in the former
Hope Brook mine in addition to new areas of resource as defined by Castillian, including the Pit
Zone, Hanging Wall Zone and Mine Zone Extension.
 There is a possible copper credit that is not included in the mineral resource due to
missing copper assays in historical drill holes.
• NI 43-101 Technical Report “Mineral Resource Estimate Technical Report, Hope Brook Gold Project, Newfoundland and Labrador, Canada”
February 14th 2012. Prepared by Pierre Desautels, P. Eng., Jay Melnyk, P.Eng., and Mr. Mike Cullen, P.Geo.
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12. Major Targets and Planned Drilling Areas
at Hope Brook
 5000 metre exploration drilling program in progress
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13. Applying Technology: Titan 24 Survey at
Hope Brook
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14. Hope Brook Gold’s Infrastructure Advantages
 Power from Provincial
Electrical Power Grid
 Wharf on Tide Water
Modern Winterized Camp
 Existing Tailings Ponds
Wharf
 1.2km Long Air Strip Air Strip
 Ramp to 350m below surface
Good Road Network
 Excellent Local Labour Force
Ramp Portal
 Highly rated mining jurisdiction
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15. Corporate Summary
June 1, 2012
CAPITALIZATION
Symbol TSX-V: CT $0.20
OTCQX: CTIIF
Frankfurt: Cy4 $0.15
52 Week Trading Range $0.04-0.20 $0.10
Price (June 1, 2012) $0.04 $0.05
Average Volume (3 mth) 525,565 per day $0.00
April July October January
Market Cap $13 M
MAJOR SHAREHOLDERS
Shares Issued 332 M*
Management and Insiders
Fully Diluted 389 M Pyramis
Ned Goodman Investment Management
Cash at March 2012 $2.4 M
Mayo Investments
* At the May 9th AGM, a proposed consolidation of RBC Asset Management
Castillian’s issued and outstanding common shares Pinetree Capital
on the basis of one (1) post-consolidation common Aberdeen International
share for every five (5) pre-consolidation common
shares issued and outstanding was passed. Howson Tattersall
TD Asset Management
Source: Bloomberg 15
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16. Management
Bill Pearson, Ph.D., P.Geo., President & CEO, Director
– Over 37 years of exploration experience from grassroots through to advanced projects and mine
development; former VP Exploration for Desert Sun Mining.
Greg Duras, CGA, CPA, CFO
– Over 14 years of corporate and project finance experience in the resource sector.
Colinda Parent, CFA, Corporate Development
– Extensive capital markets experience having spent more than 15 years in institutional equity sales
and five years in investment banking.
Josh Van Deurzen, JD, MDA, Corporate Secretary
– Corporate and securities lawyer who works as a legal consultant to various public and private
companies in the resource-based sectors.
Kevin Brewer, P.Geo., Manager, Yukon
– Professional geoscientist with over 25 years of mining industry experience.
Chris Hale, Ph.D., P.Geo., Chief Geophysicist
– Exploration geophysicist with more than 35 years experience worldwide.
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17. Board of Directors
David Gower, P.Geo., Chairman
– Over 20 years’ experience with Falconbridge & Noranda (now Xstrata), most recently as GM of
Global Nickel & PGM Exploration.
Bill Pearson, Ph.D., P.Geo., President & CEO, Director
Mike Hoffman, P.Eng., Director
– Professional mining engineer with over 25 years of experience in mine operations, projects,
engineering and corporate development.
Brian Penney, P.Eng., Director
– Twenty years of experience in the mining sector also includes senior operating and environmental
positions in the gold industry, current COO of Alderon Iron Ore Corp.
David S. Warner, MBA, Independent Director
– Accounting professional with 30 year career spent at KPMG LLP, most recently as Partner.
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18. Contact Information
Bill Pearson
President & CEO
president@castillian.ca
416 861 2968
www.castillian.ca
Bulgan Orgilsaikhan
Communications Coordinator
borgilsaikhan@castillian.ca
416 309 2895
www.castillian.ca
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