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A. General
1. This booklet is your Question Paper. Do not break the seals of this boolket before being instructed to do so by the
invigilators.
2. The question paper CODE is printed on the right hand top corner of this page and on the back page (Page No. 28)
of this booklet.
3. Blank spaces and blank pages are provided in this booklet for your rough work. No additional sheets will be
provided for rough work.
4. Blank papers, clipboards , log tables, slide rules, calculators, cameras, cellular phones, pagers and electronic
gadgets are NOT allowed inside the examination hall.
5. Answer to the questions and personal details are to be filled on a two-part carbon-less paper, which is provided
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C Question Paper Format
The question paper consists of 3 parts (Physics, Chemistry and Mathematics)> Each part consists of three sec-
tions.
12. Section - I contains 8 multiple choice questions. Each question has four choice A,B,C and D out of which ONLY ONE
is correct.
13. Section - II contains 3 paragraph each describing theory, experiment, data etc. There are 6 multiple choice ques-
tions relating to three paragraphs with 2 questions on each paragraph. Each question of a particular paragraph has
four choice A,B,C and D out of which ONLY ONE is correct.
14. Section -III contains 6 multiple choice questions. Each question has four choice A,B,C and D out of which ONE or
MORE are correct.
D. Marking Scheme
15. For each question in Section I and Section II , you will be awarded 3 marks if you darken the bubble corresponding
to the correct answer ONLY and zero (0) marks if no bubbles are darkened. In all other cases, minus one (–1) mark
will be awarded in these sections.
16. For each question in Section III , you will be awarded 4 marks if you darken ALL the bubble(s) corresponding to
the correct answer(s) ONLY. In all other cases zero (0) marks will be awarded. No negative marks wil be awarded
for incorrect answer(s) in this section.
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PHYSICS
SECTION – I
( SINGLE CORRECT CHOICE TYPE )
This section contains 8 multiple choicse questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONLY ONE is correct
1. A student is performing the experiment of Resosance Column. The diameter of the column
tube is 4cm. The frequency of the tuning fork is 512Hz. The air temperature is 380
C in which
the speed of sound is 336 m/s. The zero of the meter scale coincides with the top end of the
Resonance Column tube. When the first resonance occurs, the reading of the water level in
the column is
a) 14.0 cm b) 15.2 cm c) 16.4 cm d) 17.6 cm
Ans :B
4
l e

  
0.3
4
l d

 
0.3
4
l d

 
Scale
Reading= cm
l
l
d
4

0
336
100( )
512
V
cm
F
   
16.4cm 
 16.4 0.3 4l  
15.2cm
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2. Two identical discs of same radius R are rotating about their axes in opposite directions with
the same constant angular speed  . The discs are in the same horizontal plane.At time t = 0,
the points Pand Qare facingeach otheras shown in thefigure. The relative speedbetween the
two points P and Q is rv . In one time period (T) of rotation of the discs, rv as a function of
time is best represented by
a) b)
c) d)
Ans :A

Q
1V R 2V R
 1/2 2 sinrV V R t  

Speed  2 sinrV R t  

T
2
T 3
4
T T0
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3. A loop carrying current I lies in the x – y plane as shown in the figure. The unit vector ˆk is
coming out of the plane of the paper. The magnetic moment of the current loop is
a) 2 ˆa Ik b)
2 ˆ1
2
a Ik
 
 
 
c)
2 ˆ1
2
a Ik
 
  
 
d)   2 ˆ2 1 a Ik 
Ans :B
Magnetic moment
2
2 21 ˆ ˆ4 1
2 2 2
a
I a k a Ik

 
    
        
     

4. An infinitely long hollow conductingcylinder with inner radius R/2 and outer radius Rcarries
a uniform current density along its length. The magnitude of the magnetic field, B

as a
function of the radial distance r from the axis is best represented by
a) b)
c) d)
Ans :D
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B=0(When / 2x R )
 
2
2
02
4
R
B x J x

  
 
  
 
2
0
8
R
B J x
x

 
  
 
/ 2R
x 0
2
0
2 8
x R
B J
x

 
  
 
at
2
R
x 
2
0 0
4 4
R R
B J
R

 
   
 
Where x R
1
B
x

5. Athin uniform cylinderical shell, closed at both ends, is partially filled with water. It is float-
ing vertically in water in half – submerged state. If c is the relative density of the material of
the shell with respect to water, then the correct statement is that the shell is
a) more than half–filled if c is less than 0.5
b) more than half – filled if c is more than 1.0
c) half – filled if c is more than 0.5
d) less than half – filled if c is less than 0.5
Ans :D
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l
/ 2l1V
Water
V1
=Value of water in cylinder. if half volume of cylinder is available in waterl; water can’t be
filled upto half level because cylinder is not mass less. What ever is the relative density of
material as cylinder volume as water in cylinder must be less than that volume as liquid
displeased.
6. In the given circuit, a charge of 80 C is given to the upper plate of the 4 F capacitor..
Then in the steady state, the charge on the upper plate of the 3 F capacitor is
a) 32 C b) 40 C c) 48 C d) 80 C
Ans :C
q c
2
3
5
q q
3
80
5
 
48 c
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7. Two moles of ideal helium gas are in a rubber balloon at 0
30 C . The balloon is fully expand-
able and can be assumed to require no energy in its expansion. The temperature of the gas in
the balloon is slowly changed to 0
35 C . The amount of heat required in raising the tempera-
ture is nearly (take R = 8.31 J/mol.K)
a) 62 J b) 104 J c) 124 J d) 208 J
Ans :D
n = 2 moles
0
30iT C
0
35fT C
Process can be assumed as isobaric
5
2.
2
Q R T  
5R T
5 8.31 5  
207.75
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8. Consider a disc rotating in the horizontal plane with a constant angular speed  about its
centre O. The disc has a shaded region on one side of the diameter and an unshaded region on
the other side as shownin the figure. When the disc is in the orientation as shown, two pebbles
P and Q are simultaneously projected at an angle towards R. The velocity of projection is in
the y – z plane and is same for both pebbles with respect to the disc. Assume that (i) they land
back on the disc before the disc has completed
1
8
rotation, (ii) their range is less than half the
disc radius, and (iii)  remains constant throughtout. Then
a) P lands in the shaded region and Q in the unshaded region
b) P lands in the unshaded region and Q in the shaded region
c) Both P and Q land in the unshaded region
d) Both P and Q land in the shaded region
Ans : C
t = 0
at
4
t



both will fall on disc simultaneously Q will be is unshaded area and P will be in shaded area
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SECTION – II
(COMPREHENSION TYPE)
This section contains 3 groups of questions. Each group has 2 multiple choice questions based on a paragraph.
Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is correct.
Paragraph for Questions 9 to 10
The  -decay process, discovered around 1900, is basically the decay of a neutron (n). In the
laboratory, a proton (p), and an electron (e-
) are observed as the decay products of the neu-
tron. Therefore, considering the decay of a neutron as a two-body decay process, it was predi-
cated theoretically that the kinetick energy of the electron sould be a constant. But experi-
mentally, it was observed that the electron kinetic energy has continuous spectrum. Consid-
ering a three-body decay process, i.e. en p e v
   , around 1930, Pauli explained the ob-
served electron energy spectrum. Assuming the anti-neutrino  ev to be massless and pos-
sessing negligible energy, and the neutron to be at rest, momentum and energy consevation
principles are applied. From this calculation, the maximum kinetic energy of the electron is
6
0.8 10 eV . The kinetic energy carried by the portion is only the recoil energy..
9. If the anti-neutrino had a mass of 2
3 /eV c (where c is the speed of the light) instead of zero
mass, what should be the range of the kinetic energy, K, of the electron?
a) 6
0 0.8 10K eV   b) 6
3.0 0.8 10eV K eV  
c) 6
3.0 0.8 10eV K eV   d) 6
0 0.8 10K eV  
Ans : D
1V 2V
P e
1 0P eP m V m V  ------ (1)
2 6
0
1
0.8 10
2
em V eV  -- (2)
KE as proton is too small.Q value is n
Rx little more than 6
0.8 10 eV .
Q value 6
0.8 10 eV
Now for least KE of e–
energy released is n
Rx will be shared between anti neutrino and
proton and linear momentum will be conserved. KE as e–
will be zero. For max KE as e–
KE
as antineutrino is zero all energy released in n
Rx will be shared between e–
and proton like
antineutrino is not available
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10. What is the maximum energy of the anti-neutrino?
a) Zero b) Much less than 6
0.8 10 eV
c) Nearly 6
0.8 10 eV d) Much larger than 6
0.8 10 eV
Ans:ADD
If information in Q. No.9 is not used in Q.No. 10. KEmax
for neutrino is 6
0.8 10 eV . Which is
not there in option.
Or
If information of Q.No. 9 is used for Q.No. 10 also max KE as antineutrino will be almost
equal ot Q value as n
Rx .
Paragraph for Questions 11 and 12
The general motion of a rigid body can be considered to be a combination of (i) a motion of
itscentre of mass about an axis, and (ii) its motionabout aninstantaneous axispassing through
the centre of mass. These axes need not be stationary. Consider, for example, a thin uniform
disc welded (rigidly fixed) horizontally at its rim to a massless stick, as shown in figure.
When the disc-stick system is rotated about the origin on a horizontal frictionless plane with
angular speed  , the motion at any instant can be taken as a combination of (i) a rotation of
the centre of mass of the disc about the z-axis, and (ii) a rotation of the disc through an
instantaneous vertical axis passing through its centre of mass (as is seen from the changed
orientation of points Pand Q. Both these motions have the same angular speed  in this case.
Now consider two similar systems as shown in the figure; Case(a) the disc with its face
vertical and parallel to x-z plane; Case(b) the disc with its face making an angle 0
45 with x-y
plane and its horizontal diameter parallel to x-axis. In both the cases, the disc is welded at
point P, and the systems are rotated with constant angular speed  about the z-axis.
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11. Which of the following statements regarding the angular speed about the instantaneous axis
(passing through the centre of mass) is correct?
a) It is 2 for the both the cases b) It is  for case (a); and
2

for case(b)
c) It is  for case(a); and 2 for case(b) d) It is  for both the cases
Ans :D
Angular speed about the instantaneous axis passing through centre of mass is  for both the
cases.
12. Which of the following statements about the instantaneous axis (passing through the centre
of mass) is correct?
a) It is vertical for the both the cases (a) and (b)
b) It is vertical for case (a); and it is 0
45 to the x-z plane and lies in the plane of the disc for
case (b)
c) It is horizontal for case (a); and is at 0
45 to the x-z plane and is normal to the plane of the
disc for case (b)
d) It is vertical for case (a); and is at 0
45 to the x-z plane and is normal to the plane of the disc
for case (b)
Ans :A
Instantaneous axis passing through c.m. is vertical in both the cases.
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Paragraph for Questions 13 and 14
Most materials have the refractive index, n>1. So, when a light ray from air entres a naturally
occuring material, then by Snell’s law, 1 1
2 2
sin
sin
n
n


 , it is understood that the refracted ray
bends towards the normal. But is never emerges on the same side of the normal as the inci-
dent ray. According to electromagnetism, the refractive index of the medium is given by the
relation, r r
c
n
v
 
 
  
 
, where c is the speed of the electromagnetic waves in vaccum, v its
speed in the medium, r and r are the relative permittivity and permeability of the medium
respectively. In normal materials, both r and r positive, implying positive n for the me-
dium. When both r and r are negative, one must choose the negative root of n. Such nega-
tive refractive index materials can now be artificially, prepared and are called meta-materials.
They exhibit significantly different optical behaviour, without violating any physical laws.
Since n is negative, it results in a change in the direction of propogation of the refracted light.
However, similar to normal materials, the frequency of light remains unchanged upon refrac-
tion even in meta-materials.
13. Choose the correct statement.
a) The speed of the light in the meta-material is v c n
b) The speed of the light in the meta-material is
c
v
n

c) The speed of the light in the meta-material is v=c
d) The wavelength of the light in the meta-material  m is given by m air n  , where air is
the wavelength of the light air
Ans :B
For meta materials n is -ve. Hence speed c
V
n

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14. For light from air on a meta-material, the appropriate ray diagram is
a) b)
c) d)
Ans :C
1
2
sin
sin
n


  where 2 is angle made by refracted ray with normal in anticlock wise sense.
1
2
sin
sin
n

 
  1
2
sin
sin
n

 
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SECTION – III
( MULTIPLE CORRECT CHOICE TYPE )
This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE is/ are correct
15. Six point charges are kept at the vertices of a regular hexagon of side L and centre O, as shown
in the figure. Given that 2
0
1
4
q
K
L
 , which of the following statement(s) is (are) correct ?
a) The electric field at O is 6K along OD
b) The potential at O is zero
c) The potential at all points on the line PR is same
d) The potential at all points on the line ST is same
Ans:ABC
0
1
4 12
q
E k

 
Due to F, C 2pE k (towards E

)
Due to B, E 2pE k (towards C

)
Due toA, D 4pE k (towards D

)
4 6PE k k k k    along  D

dv
E
dx

 0
cos90 0dv dx   
So ‘PR’ is equipotential surface to +q , –q
and 2 , 2q q 
and ,q q 
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16. Two spherical planets P and Q have the same uniform density  , mass PM and QM , and
surface area A and 4A, respectively.Aspherical planet R also has uniformly density  and its
mass is  P QM M . The escape velocities from the planets P, Q and R, are ,P QV V and RV
respectively. Then
a) Q R PV V V  b) R Q PV V V  c) / 3R PV V  d)
1
/
2
P QV V 
Ans : BD
2
e
qm
V
R

32 4
3
e
q
V R
R
   
eV A
D)
1
24
P
Q
V A
V A
 
B) R Q PV V V V A   
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17. The figure shows a system consisting of (i) a ring of outer radius 3R rolling clockwise with-
out slipping on a horizontal surface with angular speed  and (ii) an inner disc of radius 2R
rotating anti–clockwise with angular speed
2

. The ringand disc are separated by frictionless
ball bearings. The system is in the x–z plane. The point P on the inner disc is at a distance R
from the origin, where OP makes an angle of 300
with the horizontal. Then with respect to the
horizontal surface
a) the point O has a linear velocity ˆ3R i
b) the point P has a linear velocity
11 3 ˆˆ
4 4
R i R k 
c) the point P has a linear velocity
13 3 ˆˆ
4 4
R i R k 
d) the point P has a linear velocity
3 1 ˆˆ3
4 4
R i R k 
 
  
 
Ans : A,B
 0
ˆ3V R i /0
2
p
R
V


3 ˆˆ3
4 4
R
R i R k

 
 
  
 
11 3 ˆˆ
4 4
P
R
V i R k

 

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18. Two solid cylinders Pand Q of same mass and same radius start rollingdown a fixed inclined
plane from the same height at the same time. Cylinder P has most of its mass concentrated
near its surface, while Q has most of its mass concentrated near the axis. Which statement(s)
is(are) correct ?
a) Both cylinders P and Q reach the ground at the same time
b) Cylinder P has larger linear acceleration than cylinder Q.
c) Both cylinders reach the ground with same translational kinetic energy
d) Cylinder Q reaches the ground with larger angular speed
Ans : D
P QI I
sin
1
g
kv
Rv

 
 P Q 
P QK K
2l
t


 (A) is not event
 (B) is also not event
R  Q P  P QV V
Q P  V r
P Q 
 (D) only is correct
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19. A current carrying infinitely long wire is kept along the diameter of a circular wire loop,
without touching it. The correct statement(s) is(are)
a) The emf induced in the loop is zero if the current is constant
b) The emf induced in the loop is finite if the current is constnat
c) The emf induced in the loop is zero if the current decreases at a steady rate
d) The emf induced in the loop is finite if the current decreases at a steady rate
Ans :AC orABCD
Represents plane of loop
Current carrying wire
B
B
Net flux passing through loop will be zero, in all cases
So, emf induced in loop is zero.
20. In the given circuit, theAC source has 100 /rad s  .Considering the inductor and capaci-
tor to be ideal, the correct choice(s) is(are)
a) The current through the circuit , I is 0.3A
b) The current through the circuit , I is 0.3 2A
c) The voltage across 100 resistor 10 2 A
d) The voltage across 50 resistor = 10 V
Ans :B or AB
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For RL
1
100 0.5
1
50
L
TanQ
R
 
  
0
1 45Q 
v
 leads current 1i by 450
1 2 2
20 2
550 2L
v
i
x R
  

For RL
2
1
100
1
100
CTanQ
R
  
0
2 45Q 
2i leads VVapp
by 450
2 2 2
20 1
100 2 5 2L
V
i
x R
  

2 2
2 1i i i 
2 1 5 1
0.3
25 50 50 10
is A   
 100 2
100
100 10 2
5 2
V i V   
50
2
50 10 2
5
V V  
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CHEMISTRY
SECTION – I
( SINGLE CORRECT CHOICE TYPE )
This section contains 8 multiple choicse questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONLY ONE is correct
21. Using the data provided, calculate the multiple bond energy  1
kJ mol
of a C C bond in
2 2C H . That energy is (take the bond energy of a C – H bond as 1
350kJ mol
.)
     2 2 22C s H g C H g  1
225H kJ mol
 
   2 2C s C g 1
1410H kJ mol
 
   2 2H g H g 1
330H kJ mol
 
A) 1165 B) 837 C) 865 D) 815
Ans : D
     2 2 22C s H g C H g  1
225H kJ mol
 
   2 2C g C s 1
1410H kJ mol
  
   22H g H g 1
330H kJ mol
  
     2 22 2C S H g C H g  1
1515H kJ mol
  
H - C C H
350350
C C bond energy is 815 kJ/mole.
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22. The major product H of the given reaction sequence is
2 495%
3 2 3
H SOCN
Heat
CH CH CO CH G H    
A)
3CH CH C COOH  
CH3
B)
CH CH C CN  
CH3
C) 3 2CH CH C COOH  
CH3
OH
D)
3 2CH CH C CO NH   
CH3
Ans : B
CH3 - CH2 - C - CH3
O
CN
 CH3 - CH2 - C - CN
CH3
O-
2 495%.H SO


CH3 - CH2 - C - CN
CH3
OH

CH3 - CH = C - CH3
CN
23.     2 2 5 6 52 2
NiCl P C H C H exhibits temperaturedependent magneticbehaviour (paramagnetic
/ diamagnetic) . The coordination geometries of 2
Ni  in the paramagnetic and diamagnetic
states are respectively
A) tetrahedral and tetrahedral B) square planar and square planar
C) tetrahedral and square planar D) square planar and tetrahedral
Ans : C
Tetrahedral and square planar
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24. In the cyanide extraction process of silver from argentite ore, the oxidizing and reducing
agent used are
A) 2O and CO respectively B) 2O and Zn dust respectively
C) 3HNO and Zn dust respectively D) 3HNO and CO respectively
Ans : B
2O  oxidising agent
Zn  reducing agent
25. The reaction of white phosphorus with aqueous NaOH gives phosphine alongwith another
phosphorus containing compound. The reaction type; the oxidation states of phosphorus in
phosphine and the other product are respectively
A) redox reaction ; –3 and –5 B) redox reaction; +3 and +5
C) disproportionation reaction; –3 and +5 D) disproportionation reaction; –3 and +3
Ans : D
4 2 2 3P NaOH H PO PH
  

2 3 3Na HPO PH
26. The shape of 2 2XeO F molecule is
A) trigonal bipyramidal B) Square planar
C) tetrahedral D) see - saw
Ans : D
see-saw
O
O
Xe
F
F
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27. For a dilute solution containing 2.5 g of a non – volatile non – electrolyte solute in 100 g
of water, the elevation in boiling point at 1 atm pressure is 2 C .Assuming concentration
of solute is much lower than the concentration of solvent, the vapour pressure (mm of Hg)
of the solution is (take 1
0.76bK K kg mol
 )
A) 724 B) 740 C) 736 D) 718
Ans :A
0
0
55.5
solute
m p p
X
m p

 

760
55.5 760
m p

P = 724 mm of Hg
28. The compound that undergoes decarboxylation most readily under mild condition is
A) B) C) D)
Ans : B
 -keto acids readily undergo decarboxylation
SECTION – II
(COMPREHENSION TYPE)
This section contains 3 groups of questions. Each group has 2 multiple choice questions based on a paragraph.
Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is correct.
Paragraph for Questions 29 and 30
The electrochemical cell shown below is a concentration cell.
2
|M M 
(saturated solution of a sparingly soluble salt, 2MX ) 2
||M 
 3
0.001 |mol dm M
The emf of the cell depends on the difference in concentrations of 2
M  ions at the two
electrodes. The emf of the cell at 298 K is 0.059 V.
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29. The value of  1
G kJ mol
 for the given cell is (take 1
1 96500F C mol
 )
A) –5.7 B) 5.7 C) 11.4 D) –11.4
Ans : D
G nFE  
2 96500 0.059   
11.4 /kJ mol 
30. The solubility product  3 9
;spK mol dm
of 2MX at 298 K based on the information available
for the given concentration cell is (take 2.303 298/ 0.059R F V   )
A) 15
1 10
 B) 15
4 10
 C) 12
1 10
 D) 12
4 10

Ans : B
0.059 0.001
0.059 0 log
2
E
s
  
5
10S 

3 15
4 4 10SPK s 
  
Paragraph for Questions 31 and 32
In the following reaction sequence, the compound J is an intermediate.
 3 2 2
3 2
3
( ) , /
( )
( ) .
CH CO O i H Pd C
CH COONa ii SOCl
iii anhyd AlCl
I J K 
 9 8 2J C H O gives effervescence on treatment with 3NaHCO and a positive Baeyer’s test.
31. The compound K is
A) B) C) D)
Ans : C
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O
I
 3 2
3
CH CO O
CH COONa

O OH
J
2 / /H Pd C

O OH
2SOCl

O Cl
3anhyd AlCl

OK
32. The compound I is
A) B) C) D)
Ans :A
Paragraph for Questions 33 and 34
Bleaching powder and bleach solution are produced on a large scale and used in several
house hold products. The effectiveness of bleach solution is often measured by iodometry.
33. 25 mL of household bleach solution was mixed with 30 mL of 0.50 M KI and 10 mL of 4 N
acetic acid. In the titration of the liberated iodine, 48 mL of 0.25 N 2 2 3Na S O was used to
reach the end point. The molarity of the household bleach solution is
A) 0.48 M B) 0.96 M C) 0.24 M D) 0.024 M
Ans : C
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2 2 2 4 6
hypo
CaOCl I I NaI Na S O
    
12 meq. 30 ml 48 ml 0.25 N = 12 m eq
0.5 N
15 m eq
limitingreagent is beaching powder.
25 12N 
12
0.48
25
N N 
0.24M M
34. Bleaching powder contains a salt of an oxoacid as one of its components. The anhydride of
that oxoacid is
A) 2Cl O B) 2 7Cl O C) 2ClO D) 2 6Cl O
Ans :A
oxoacid is HOCl
2 22HOCl Cl O H O 
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SECTION – III
( MULTIPLE CORRECT CHOICE TYPE )
This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE is/ are correct
35. For the given aqueous reactions, which of the statement(s) is (are) true?
A) The first reaction is a redox reaction
B) White precipitate is  3 26
Zn Fe CN   .
C) Addition of filtrate to starch solution gives blue colour
D) White precipitate is soluble in NaOH solution.
Ans:ACD
   2 4/
3 4 26 6
di H SO
KI K Fe CN K Fe CN I        
ZnSO4
 3 2 3 6 2
I K Zn Fe CN
   
Brownish yellow ppt white ppt
Na2S2O3
(colourless solution)
NaI + Na2S4O6
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The whiteppt is soluble insodiumhydroxide
     
4 2
2 3 6 6 42
12 2 3 2K Zn Fe CN OH Fe CN Zn OH K
  
            
36. With reference to the scheme given, which of the given statement(s) about T, U, V and W
is(are) correct?
A) T is soluble in hot aqueous NaOH B) U is optically active
C) Molecular formula of W is 10 18 4C H O
D) V gives effervescence on treatment with aqueous 3NaHCO
Ans:ACD
OH OH
CH3
OAC OH
CH3
U
W
HOOC
CH3
COOH
V
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37. Which of the given statement (s) about N, O, P and Q with respect to M is (are) correct?
A) M and N are non–mirror image stereoisomers
B) M and O are identical C) M and P are enantiomers
D) M and Q are identical
Ans:ABC
38. With respect to graphiteand diamond, whichofthestatement(s) given below is(are)correct?
A) Graphite is harder than diamond.
B) Graphite has higher electrical conductivity than diamond.
C) Graphite has higher thermal conductivity than diamond.
D) Graphite has higher C – C bond order than diamond.
Ans : BD
39. The given graphs / data I, II, III and IV represent general trends observed for different
physisorption and chemisorption processes under mild conditions of temperature and
pressure. Which of the following choice(s) about I, II, III and IV is(are) correct?
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A) I is physisorption and II is chemisorption
B) I is physisorption and III is chemisorption
C) IV is chemisorption and II is chemisorption
D) IV is chemisorption and III is chemisorption
Ans :AC
40. The reversible expansion of an ideal gas under adiabatic and isothermal conditions is
shown in the figure. Which of the following statement(s) is (are) correct?
A) 1 2T T B) 3 1T T
C) isothermal adiabaticw w D) isothermal adiabaticU U  
Ans :AD
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MATHEMATICS
SECTION – I
( SINGLE CORRECT CHOICE TYPE )
This section contains 8 multiple choicse questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONLY ONE is correct
41. The value of the integral
/2
2
/2
ln cos
x
x x dx
x




 
 
 
 is
A) 0 B)
2
4
2

 C)
2
4
2

 D)
2
2

Ans. B
2
2
2
cos log
x
x xdx is an odd function
x




   
  
  
 
2
2
0
2 cosx xdx

 
=        2 2
0
2 sin 2 cos 2 sinx x x x x

     
=
2
2 2
4
 
 
 
=
2
4
2


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42. Let 1 2 3, , ,...a a a be in harmonic progression with 1 5a  and 20 25a  . The least positive inte-
ger n for which 0na  is
A) 22 B) 23 C) 24 D) 25
Ans. D
1
5,
a

1
25
19a d


1
5
a 
1
19
25
a d 
1 1
19
25 5
d  
=
4
25

 
4
25 19
d


 
 
 
 
1
0
1
1 0
1 4
1 0
5 5 19
na
a n d
a n d
n
 
 
   
 
    
 
95 - 4n + 4 < 0
99 < 4n
99
4
n 
3
24
4
n 
n = 25, 26, 27, .......
least n = 25
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43. The equation of a plane passing through the line of intersection of the planes 2 3 2x y z  
and 3x y z   and at a distance
2
3
from the point  3,1, 1 is
A) 5 11 17x y z   B) 2 3 2 1x y  
C) 3x y z   D) 2 1 2x y  
Ans. A
Required plane is
     
       
2 3 2 3 0 1
1 2 3 2 3 0
x y z x y z
x y z

   
        
         
Given
      
     
2 2 2
| 3 1 2 1 3 1 2 3 | 2
31 2 3
   
  
      

    
7
2



 1 5 11 17 0x y z    
44. Let PQR be a triangle of area  with
7
2,
2
a b  and
5
2
c  , where ,a b and c are the lengths
of the sides of the triangle opposite to the angles at ,P Q and R respectively. Then
2sin sin 2
2sin sin 2
P P
P P


equals
A)
3
4
B)
45
4
C)
2
3
4
 
 
 
D)
2
45
4
 
 
 
Ans. C
Hence 6 
29
1
2sin sin 2 1 cos 335
292sin sin 2 1 cos 321
35
p p p
p p p

 
  
  
P
Q R
C= 5/2
a = 2
7
2
b 
Clearly From (C) :
2
3 3
40 32
 
 
 
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45. If a

and b

are vectors such that 29a b 
 
and  
   
 2 3 4 2 3 4a i j k i j k b      
 
  , then a
possible value of    
 7 2 3a b i j k    
 
 is
A) 0 B) 3 C) 4 D) 8
Ans. C
 a r r b   , where 2 3 4r i j k  
0a r r b   
  0r a b  
 ˆˆ ˆ2 3 4a b i j k    
29a b 
4 9 16 29 1     
       7 2 3 2 3 4 7 2 3a b i j k i j k i j k            
 –14 + 6 + 12 = 4
46. If P is a 3 3 matrix such that 2T
P P I  , where T
P is the transpose of P and I is the 3 3
identity matrix, then there exists a column matrix
0
0
0
x
X y
z
   
       
      
such that
A)
0
0
0
PX
 
   
  
B) PX X C) 2PX X D) PX X 
Ans. D
2T
P P I 
2 T
P P I 
4 3P I 
P I  
PX X  
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47. Let  a and  a be the roots of the equation
     23 6
1 1 1 1 1 1 0a x a x a         where 1a   . Then  0
lim
a
a

and  0
lim
a
a

are
A)
5
2
 and 1 B)
1
2
 and -1 C)
7
2
 and 2 D)
9
2
 and 3
Ans. B
 
 
   
1 1
1/ 2
3 6
2
0
1 1 1 1 1 1
lim 0
1 1 1 1 1 1a
a a a
x x
a a a
     
  
     
21 1
1 0
3 2
x x  
2
2 3 1
0
6
x x 
 
2
2 2 1 0x x x    
   2 1 1 1 0x x x    
1
2
x   (or) –1.
48. Four fair dice 1 2 3, ,D D D and 4D , each having six faces numbered 1, 2, 3, 4, 5 and 6, are rolled
simultaneously. The probability that 4D shows a number appearingon one of 1 2,D D and 3D is
A)
91
216
B)
108
216
C)
125
216
D)
127
216
Ans. A
Required probability
= 1 – probability of D4
does not show a number appearing on any of D1
, D2
, D3
.
6 5 5 5
1
6 6 6 6
  
 
  
125
1
216
 
91
216

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SECTION – II
(COMPREHENSION TYPE)
This section contains 3 groups of questions. Each group has 2 multiple choice questions based on a paragraph.
Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is correct.
Paragraph for Questions 49 and 50
Let    
2 2 2
1 sinf x x x x   for all x IR , and let  
 
 
1
2 1
ln
1
x
t
g x t f t dt
t
 
  
 
 for all
 1,x 
49. Consider the statements:
P : There exists some x IR such that    2
2 2 1f x x x  
Q : There exists some x IR such that    2 1 2 1f x x x  
Then
A) Both P and Q are true B) P is true and Q is false
C) P is false and Q is true D) both P and Q are false
Ans. C
   
2 2 2
1 sinf x x x x   x R 
   2
2 2 1f x x x  
 
2 2 2 2
1 .sin 2 2 2x x x x x    
 
2 2 2
1 sin 2 1 1x x x x    
 
2 2 2
1 sin 2 1 1x x x x    
   
2 22
1 sin 1 1x x x   
 
2 2
1 sin 1 1x x    
 
2
2
1
sin 1
1
x
x
 

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But 2
sin 1 0x   x R 
and  
2
1
0
1x

 x R 
No such x exist satisfying P.
Q:   2
2 1 2 2f x x x  
 
2 2 2 2
2 1 sin 1 2 2x x x x x     
 
 
2 2 2 2
2 1 sin 2 1 2 2x x x x x    
 
2 2
2 1 sin 1 2x x x  
 
2 2
2 1 sin 2 1x x x  
   
2
2 2
2 1 2 1
sin 0
2 1 2 1
x x
x
x x
 
  
 
1
2
x 
Q is true.
50. Which of the following is true?
A) g is increasing on  1,
B) g is decreasing on  1,
C) g is increasing on  1,2 and decreasing on  2,
D) g is decreasing on  1,2 and increasing on  2,
Ans. B
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 
 
 
2 1
' ln
1
x
g x x f x
x
 
  
 
  0f x  x > 1
 
 2 1
ln
1
x
h x x
x

 

 
 
2
4 1
' 0
1
h x
xx
  
 1x 
h (x) is decreasing.
   1 1x h x h  
 2 1
ln 0
1
x
x
x

 

 ' 0 1g x x   
g is decreasing. on  1,
Paragraph for Questions 51 and 52
A tangent PT is drawn to the circle 2 2
4x y  at the point  3,1P . A straight line L ,
perpendicular to PT is a tangent to the circle  
2 2
3 1x y  
51. A common tangent of the two circles is
A) 4x  B) 2y  C) 3 4x y  D) 2 2 6x y 
Ans. D
Common tangent B Transversal

   
 
2 3,0 0,0
6,0
2 1
sI

 

Common tangent y–0 = m (x-6)
mx-y-6m=0
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2
| 3 |
1
1
m
m



1
2 2
m  

1
( 6)
2 2
y x  
2 2 6y x   
2 2 6x y 
52. A possible equation of L is
A) 3 1x y  B) 3 1x y  C) 3 1x y   D) 3 5x y 
Ans. A
3 0L x y k   
is tangent to 
2 2
3 1x y  
3
1
2
k
 
5, 1k k    
3 1x y  
Paragraph for Questions 53 and 54
Let na denote the number of all n  digit positive integers formed by the digits 0, 1 or both
such that no consecutive digits in them are 0. Let nb  the number of such n  digit integers
endingwithdigit1 and nc =the numberofsuch n  digit integersendingwithdigit0.
53. Which of the following is correct?
A) 17 16 15a a a  B) 17 16 15c c c  C) 17 16 16b b c  D) 17 17 16a c b 
Ans. A
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an
=
01 1
end with zero
2na 
+
1
end with one
1na 
1
 an
= an–2
+ an–1
a17
= a15
+ a16
54. The value of 6b is
A) 7 B) 8 C) 9 D) 11
Ans. B
6 digits the integer ending with one = b6
The no of cases
1 1
cases with 4 ones : 1 1 1 1 one
3 ones :
0 1 1 1
1 0 1 1
4
1 1 0 1
1 1 1 0






2 ones :
1 0 1 0
0 1 0 1 3
0 1 1 0





b6
= 8
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SECTION – III
( MULTIPLE CORRECT CHOICE TYPE )
This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE is/ are correct
55. If the straight lines
1 1
2 2
x y z
k
 
  and
1 1
5 2
x y z
k
 
  are coplanar, then the plane(s) con-
taining these two lines is(are)
A) 2 1y z   B) 1y z   C) 1y z   D) 2 1y z  
Ans. B,C
The lines are coplanar
2 0 0
2 2 0
5 2
k
k

 
2k  
Case (i) If
1 1
2 1 1 1 0
5 2 2
x y z
k then equation of plane is
 
 
       & 5 0 1 3 3 0x y z      
1y z 
1y z  
Case (ii) If
1 1
2 1 1 1 0
5 2 2
x y z
k then equation of plane is
 
   

       1 0 1 7 7 0x y z     
7 7 7 0y z  
1y z  
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56. If the adjoint of a 3 3 matrix P is
1 4 4
2 1 7
1 1 3
 
 
 
  
, then the possible value(s) of the determinant
of P is (are)
A) -2 B) -1 C) 1 D) 2
Ans. A,D
2
2
1 4 4
2 1 7 4
1 1 3
adjp P  
2P  
57. Let  : 1,1f IR  be such that   2
2
cos 4
2 sec
f 



for 0, ,
4 4 2
  

   
    
   
. Then the
value(s) of
1
3
f
 
 
 
is (are).
A)
3
1
2
 B)
3
1
2
 C)
2
1
3
 D)
2
1
3

Ans. A,B
 
2 2
1 cos 2
cos 4 1 sec2
cos 2
1 4 2
cos4 2cos 2 cos 2
3 3 3
3
sec2
2
1 3
1
3 2
,
f
f
A B

 

  


  
     
  
 
   
 

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58. Let X and Y be two events such that    
1 1
/ , /
2 3
P X Y P Y X  and  
1
6
P X Y  . Which
of the following is (are) correct?
A)  
2
3
P X Y  B) X and Y are independent
C) X and Y are not independent D)   1
3
c
P X Y 
Ans. A,B
 
 
 
 
 
 
1
3
1
2
p X YX
p p Y
Y p Y
p X YY
p p Y
X p X
 
   
 
 
   
 
     . ,p X Y p X p Y X Y independent   
 
     
1 1 1 4 2
3 2 6 6 3
1 1 3 1
2 6 6 2
,
p X Y
p X Y p X p X Y
A B
      
       

59. If     
2
0
2 3
x
t
f x e t t dt   for all  0,x  , then
A) f has a local maximum at 2x 
B) f is decreasing on  2,3
C) there exists some  0,c  such that  " 0f c 
D) f has a local minimum at 3x 
Ans. ABCD
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    
2
' 2 3x
f x e x x  
max . at x = 2
2 3
min. at x = 3
decreasing on (2, 3)
   
2
2
'' 5 6 2 5 0x
f x e x x x     
2
3 1 0x x   
 
3 5
0,
2
x

   
60. For every integer n , let na and nb be real numbers. Let function :f IR IR be given by
 
 
 
sin , for 2 ,2 1
cos , for 2 1,2
n
n
a x x n n
f x
b x x n n


   
 
  
, for all integers n .
If f is continuous, then which of the following hold(s) for all ?n
A) 1 1 0n na b   B) 1n na b  C) 1 1n na b   D) 1 1n na b   
Ans. B, D
continuous at x = 2n
1n nb a  
1n na b    (B)
continuous at x = 2 (n –1)
1 1 1n na b   
continuous at x = 2n – 1
1 1n na b   –––– (D)
continuous at x = 2n + 1
1 1n na b   

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IITJEE 2012 Paper2 solution

  • 1.
  • 2. INSTRUCTIONS A. General 1. This booklet is your Question Paper. Do not break the seals of this boolket before being instructed to do so by the invigilators. 2. The question paper CODE is printed on the right hand top corner of this page and on the back page (Page No. 28) of this booklet. 3. Blank spaces and blank pages are provided in this booklet for your rough work. No additional sheets will be provided for rough work. 4. Blank papers, clipboards , log tables, slide rules, calculators, cameras, cellular phones, pagers and electronic gadgets are NOT allowed inside the examination hall. 5. Answer to the questions and personal details are to be filled on a two-part carbon-less paper, which is provided separately. You should not separate these parts. The invigilator will separate them at the end of the examination. The upper sheet is a machine-gradable Objective Response Sheet (ORS) which will be taken back by the invigilator. You will be allowed to take away the bottom sheet at the end of the examination. 6. Using a black ball point pen, darken the bubbles on the upper original sheet. Apply sufficinet pressure so that the impression is created on the bottom sheet. 7. DO NOT TAMPER WITH / MUTILATE THE ORS OR THE BOOKLET. 8. On breaking the seals of the booklet check that it contains 28 pages and all the 60 questions and correspond- ing answer choices are legible. Read carefully the instructions printed at the beginining of each section. B. Filling the Right Part of the ORS 9. The ORS has CODES printed on its left and right parts. 10. Check that the same CODE is printed on the ORS and on this boolet. IF IS NOT THEN ASK FOR A CHANGE OF THE BOOKLET. Sign at the place provided on the ORS affirming that you have verified that all the codes are same. 11. Write your name , Registration Number and the name of examination centre and sign with pen in the boxes provided on the right part of the ORS. Do not write any of this information anywhere else. Darken the appropriate bubble UNDER each digit of your Registration Number in such a way that the impression is created on the bottom sheet. Also darken the paper CODE given on the right side of ORS (R4) C Question Paper Format The question paper consists of 3 parts (Physics, Chemistry and Mathematics)> Each part consists of three sec- tions. 12. Section - I contains 8 multiple choice questions. Each question has four choice A,B,C and D out of which ONLY ONE is correct. 13. Section - II contains 3 paragraph each describing theory, experiment, data etc. There are 6 multiple choice ques- tions relating to three paragraphs with 2 questions on each paragraph. Each question of a particular paragraph has four choice A,B,C and D out of which ONLY ONE is correct. 14. Section -III contains 6 multiple choice questions. Each question has four choice A,B,C and D out of which ONE or MORE are correct. D. Marking Scheme 15. For each question in Section I and Section II , you will be awarded 3 marks if you darken the bubble corresponding to the correct answer ONLY and zero (0) marks if no bubbles are darkened. In all other cases, minus one (–1) mark will be awarded in these sections. 16. For each question in Section III , you will be awarded 4 marks if you darken ALL the bubble(s) corresponding to the correct answer(s) ONLY. In all other cases zero (0) marks will be awarded. No negative marks wil be awarded for incorrect answer(s) in this section.
  • 3. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 3 Sri Chaitanya IIT Academy PHYSICS SECTION – I ( SINGLE CORRECT CHOICE TYPE ) This section contains 8 multiple choicse questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is correct 1. A student is performing the experiment of Resosance Column. The diameter of the column tube is 4cm. The frequency of the tuning fork is 512Hz. The air temperature is 380 C in which the speed of sound is 336 m/s. The zero of the meter scale coincides with the top end of the Resonance Column tube. When the first resonance occurs, the reading of the water level in the column is a) 14.0 cm b) 15.2 cm c) 16.4 cm d) 17.6 cm Ans :B 4 l e     0.3 4 l d    0.3 4 l d    Scale Reading= cm l l d 4  0 336 100( ) 512 V cm F     16.4cm   16.4 0.3 4l   15.2cm
  • 4. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 4 Sri Chaitanya IIT Academy 2. Two identical discs of same radius R are rotating about their axes in opposite directions with the same constant angular speed  . The discs are in the same horizontal plane.At time t = 0, the points Pand Qare facingeach otheras shown in thefigure. The relative speedbetween the two points P and Q is rv . In one time period (T) of rotation of the discs, rv as a function of time is best represented by a) b) c) d) Ans :A  Q 1V R 2V R  1/2 2 sinrV V R t    Speed  2 sinrV R t    T 2 T 3 4 T T0
  • 5. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 5 Sri Chaitanya IIT Academy 3. A loop carrying current I lies in the x – y plane as shown in the figure. The unit vector ˆk is coming out of the plane of the paper. The magnetic moment of the current loop is a) 2 ˆa Ik b) 2 ˆ1 2 a Ik       c) 2 ˆ1 2 a Ik        d)   2 ˆ2 1 a Ik  Ans :B Magnetic moment 2 2 21 ˆ ˆ4 1 2 2 2 a I a k a Ik                         4. An infinitely long hollow conductingcylinder with inner radius R/2 and outer radius Rcarries a uniform current density along its length. The magnitude of the magnetic field, B  as a function of the radial distance r from the axis is best represented by a) b) c) d) Ans :D
  • 6. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 6 Sri Chaitanya IIT Academy B=0(When / 2x R )   2 2 02 4 R B x J x            2 0 8 R B J x x         / 2R x 0 2 0 2 8 x R B J x         at 2 R x  2 0 0 4 4 R R B J R          Where x R 1 B x  5. Athin uniform cylinderical shell, closed at both ends, is partially filled with water. It is float- ing vertically in water in half – submerged state. If c is the relative density of the material of the shell with respect to water, then the correct statement is that the shell is a) more than half–filled if c is less than 0.5 b) more than half – filled if c is more than 1.0 c) half – filled if c is more than 0.5 d) less than half – filled if c is less than 0.5 Ans :D
  • 7. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 7 Sri Chaitanya IIT Academy l / 2l1V Water V1 =Value of water in cylinder. if half volume of cylinder is available in waterl; water can’t be filled upto half level because cylinder is not mass less. What ever is the relative density of material as cylinder volume as water in cylinder must be less than that volume as liquid displeased. 6. In the given circuit, a charge of 80 C is given to the upper plate of the 4 F capacitor.. Then in the steady state, the charge on the upper plate of the 3 F capacitor is a) 32 C b) 40 C c) 48 C d) 80 C Ans :C q c 2 3 5 q q 3 80 5   48 c
  • 8. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 8 Sri Chaitanya IIT Academy 7. Two moles of ideal helium gas are in a rubber balloon at 0 30 C . The balloon is fully expand- able and can be assumed to require no energy in its expansion. The temperature of the gas in the balloon is slowly changed to 0 35 C . The amount of heat required in raising the tempera- ture is nearly (take R = 8.31 J/mol.K) a) 62 J b) 104 J c) 124 J d) 208 J Ans :D n = 2 moles 0 30iT C 0 35fT C Process can be assumed as isobaric 5 2. 2 Q R T   5R T 5 8.31 5   207.75
  • 9. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 9 Sri Chaitanya IIT Academy 8. Consider a disc rotating in the horizontal plane with a constant angular speed  about its centre O. The disc has a shaded region on one side of the diameter and an unshaded region on the other side as shownin the figure. When the disc is in the orientation as shown, two pebbles P and Q are simultaneously projected at an angle towards R. The velocity of projection is in the y – z plane and is same for both pebbles with respect to the disc. Assume that (i) they land back on the disc before the disc has completed 1 8 rotation, (ii) their range is less than half the disc radius, and (iii)  remains constant throughtout. Then a) P lands in the shaded region and Q in the unshaded region b) P lands in the unshaded region and Q in the shaded region c) Both P and Q land in the unshaded region d) Both P and Q land in the shaded region Ans : C t = 0 at 4 t    both will fall on disc simultaneously Q will be is unshaded area and P will be in shaded area
  • 10. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 10 Sri Chaitanya IIT Academy SECTION – II (COMPREHENSION TYPE) This section contains 3 groups of questions. Each group has 2 multiple choice questions based on a paragraph. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is correct. Paragraph for Questions 9 to 10 The  -decay process, discovered around 1900, is basically the decay of a neutron (n). In the laboratory, a proton (p), and an electron (e- ) are observed as the decay products of the neu- tron. Therefore, considering the decay of a neutron as a two-body decay process, it was predi- cated theoretically that the kinetick energy of the electron sould be a constant. But experi- mentally, it was observed that the electron kinetic energy has continuous spectrum. Consid- ering a three-body decay process, i.e. en p e v    , around 1930, Pauli explained the ob- served electron energy spectrum. Assuming the anti-neutrino  ev to be massless and pos- sessing negligible energy, and the neutron to be at rest, momentum and energy consevation principles are applied. From this calculation, the maximum kinetic energy of the electron is 6 0.8 10 eV . The kinetic energy carried by the portion is only the recoil energy.. 9. If the anti-neutrino had a mass of 2 3 /eV c (where c is the speed of the light) instead of zero mass, what should be the range of the kinetic energy, K, of the electron? a) 6 0 0.8 10K eV   b) 6 3.0 0.8 10eV K eV   c) 6 3.0 0.8 10eV K eV   d) 6 0 0.8 10K eV   Ans : D 1V 2V P e 1 0P eP m V m V  ------ (1) 2 6 0 1 0.8 10 2 em V eV  -- (2) KE as proton is too small.Q value is n Rx little more than 6 0.8 10 eV . Q value 6 0.8 10 eV Now for least KE of e– energy released is n Rx will be shared between anti neutrino and proton and linear momentum will be conserved. KE as e– will be zero. For max KE as e– KE as antineutrino is zero all energy released in n Rx will be shared between e– and proton like antineutrino is not available
  • 11. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 11 Sri Chaitanya IIT Academy 10. What is the maximum energy of the anti-neutrino? a) Zero b) Much less than 6 0.8 10 eV c) Nearly 6 0.8 10 eV d) Much larger than 6 0.8 10 eV Ans:ADD If information in Q. No.9 is not used in Q.No. 10. KEmax for neutrino is 6 0.8 10 eV . Which is not there in option. Or If information of Q.No. 9 is used for Q.No. 10 also max KE as antineutrino will be almost equal ot Q value as n Rx . Paragraph for Questions 11 and 12 The general motion of a rigid body can be considered to be a combination of (i) a motion of itscentre of mass about an axis, and (ii) its motionabout aninstantaneous axispassing through the centre of mass. These axes need not be stationary. Consider, for example, a thin uniform disc welded (rigidly fixed) horizontally at its rim to a massless stick, as shown in figure. When the disc-stick system is rotated about the origin on a horizontal frictionless plane with angular speed  , the motion at any instant can be taken as a combination of (i) a rotation of the centre of mass of the disc about the z-axis, and (ii) a rotation of the disc through an instantaneous vertical axis passing through its centre of mass (as is seen from the changed orientation of points Pand Q. Both these motions have the same angular speed  in this case. Now consider two similar systems as shown in the figure; Case(a) the disc with its face vertical and parallel to x-z plane; Case(b) the disc with its face making an angle 0 45 with x-y plane and its horizontal diameter parallel to x-axis. In both the cases, the disc is welded at point P, and the systems are rotated with constant angular speed  about the z-axis.
  • 12. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 12 Sri Chaitanya IIT Academy 11. Which of the following statements regarding the angular speed about the instantaneous axis (passing through the centre of mass) is correct? a) It is 2 for the both the cases b) It is  for case (a); and 2  for case(b) c) It is  for case(a); and 2 for case(b) d) It is  for both the cases Ans :D Angular speed about the instantaneous axis passing through centre of mass is  for both the cases. 12. Which of the following statements about the instantaneous axis (passing through the centre of mass) is correct? a) It is vertical for the both the cases (a) and (b) b) It is vertical for case (a); and it is 0 45 to the x-z plane and lies in the plane of the disc for case (b) c) It is horizontal for case (a); and is at 0 45 to the x-z plane and is normal to the plane of the disc for case (b) d) It is vertical for case (a); and is at 0 45 to the x-z plane and is normal to the plane of the disc for case (b) Ans :A Instantaneous axis passing through c.m. is vertical in both the cases.
  • 13. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 13 Sri Chaitanya IIT Academy Paragraph for Questions 13 and 14 Most materials have the refractive index, n>1. So, when a light ray from air entres a naturally occuring material, then by Snell’s law, 1 1 2 2 sin sin n n    , it is understood that the refracted ray bends towards the normal. But is never emerges on the same side of the normal as the inci- dent ray. According to electromagnetism, the refractive index of the medium is given by the relation, r r c n v          , where c is the speed of the electromagnetic waves in vaccum, v its speed in the medium, r and r are the relative permittivity and permeability of the medium respectively. In normal materials, both r and r positive, implying positive n for the me- dium. When both r and r are negative, one must choose the negative root of n. Such nega- tive refractive index materials can now be artificially, prepared and are called meta-materials. They exhibit significantly different optical behaviour, without violating any physical laws. Since n is negative, it results in a change in the direction of propogation of the refracted light. However, similar to normal materials, the frequency of light remains unchanged upon refrac- tion even in meta-materials. 13. Choose the correct statement. a) The speed of the light in the meta-material is v c n b) The speed of the light in the meta-material is c v n  c) The speed of the light in the meta-material is v=c d) The wavelength of the light in the meta-material  m is given by m air n  , where air is the wavelength of the light air Ans :B For meta materials n is -ve. Hence speed c V n 
  • 14. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 14 Sri Chaitanya IIT Academy 14. For light from air on a meta-material, the appropriate ray diagram is a) b) c) d) Ans :C 1 2 sin sin n     where 2 is angle made by refracted ray with normal in anticlock wise sense. 1 2 sin sin n      1 2 sin sin n   
  • 15. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 15 Sri Chaitanya IIT Academy SECTION – III ( MULTIPLE CORRECT CHOICE TYPE ) This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONE OR MORE is/ are correct 15. Six point charges are kept at the vertices of a regular hexagon of side L and centre O, as shown in the figure. Given that 2 0 1 4 q K L  , which of the following statement(s) is (are) correct ? a) The electric field at O is 6K along OD b) The potential at O is zero c) The potential at all points on the line PR is same d) The potential at all points on the line ST is same Ans:ABC 0 1 4 12 q E k    Due to F, C 2pE k (towards E  ) Due to B, E 2pE k (towards C  ) Due toA, D 4pE k (towards D  ) 4 6PE k k k k    along  D  dv E dx   0 cos90 0dv dx    So ‘PR’ is equipotential surface to +q , –q and 2 , 2q q  and ,q q 
  • 16. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 16 Sri Chaitanya IIT Academy 16. Two spherical planets P and Q have the same uniform density  , mass PM and QM , and surface area A and 4A, respectively.Aspherical planet R also has uniformly density  and its mass is  P QM M . The escape velocities from the planets P, Q and R, are ,P QV V and RV respectively. Then a) Q R PV V V  b) R Q PV V V  c) / 3R PV V  d) 1 / 2 P QV V  Ans : BD 2 e qm V R  32 4 3 e q V R R     eV A D) 1 24 P Q V A V A   B) R Q PV V V V A   
  • 17. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 17 Sri Chaitanya IIT Academy 17. The figure shows a system consisting of (i) a ring of outer radius 3R rolling clockwise with- out slipping on a horizontal surface with angular speed  and (ii) an inner disc of radius 2R rotating anti–clockwise with angular speed 2  . The ringand disc are separated by frictionless ball bearings. The system is in the x–z plane. The point P on the inner disc is at a distance R from the origin, where OP makes an angle of 300 with the horizontal. Then with respect to the horizontal surface a) the point O has a linear velocity ˆ3R i b) the point P has a linear velocity 11 3 ˆˆ 4 4 R i R k  c) the point P has a linear velocity 13 3 ˆˆ 4 4 R i R k  d) the point P has a linear velocity 3 1 ˆˆ3 4 4 R i R k         Ans : A,B  0 ˆ3V R i /0 2 p R V   3 ˆˆ3 4 4 R R i R k           11 3 ˆˆ 4 4 P R V i R k    
  • 18. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 18 Sri Chaitanya IIT Academy 18. Two solid cylinders Pand Q of same mass and same radius start rollingdown a fixed inclined plane from the same height at the same time. Cylinder P has most of its mass concentrated near its surface, while Q has most of its mass concentrated near the axis. Which statement(s) is(are) correct ? a) Both cylinders P and Q reach the ground at the same time b) Cylinder P has larger linear acceleration than cylinder Q. c) Both cylinders reach the ground with same translational kinetic energy d) Cylinder Q reaches the ground with larger angular speed Ans : D P QI I sin 1 g kv Rv     P Q  P QK K 2l t    (A) is not event  (B) is also not event R  Q P  P QV V Q P  V r P Q   (D) only is correct
  • 19. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 19 Sri Chaitanya IIT Academy 19. A current carrying infinitely long wire is kept along the diameter of a circular wire loop, without touching it. The correct statement(s) is(are) a) The emf induced in the loop is zero if the current is constant b) The emf induced in the loop is finite if the current is constnat c) The emf induced in the loop is zero if the current decreases at a steady rate d) The emf induced in the loop is finite if the current decreases at a steady rate Ans :AC orABCD Represents plane of loop Current carrying wire B B Net flux passing through loop will be zero, in all cases So, emf induced in loop is zero. 20. In the given circuit, theAC source has 100 /rad s  .Considering the inductor and capaci- tor to be ideal, the correct choice(s) is(are) a) The current through the circuit , I is 0.3A b) The current through the circuit , I is 0.3 2A c) The voltage across 100 resistor 10 2 A d) The voltage across 50 resistor = 10 V Ans :B or AB
  • 20. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 20 Sri Chaitanya IIT Academy For RL 1 100 0.5 1 50 L TanQ R      0 1 45Q  v  leads current 1i by 450 1 2 2 20 2 550 2L v i x R     For RL 2 1 100 1 100 CTanQ R    0 2 45Q  2i leads VVapp by 450 2 2 2 20 1 100 2 5 2L V i x R     2 2 2 1i i i  2 1 5 1 0.3 25 50 50 10 is A     100 2 100 100 10 2 5 2 V i V    50 2 50 10 2 5 V V  
  • 21. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 21 Sri Chaitanya IIT Academy CHEMISTRY SECTION – I ( SINGLE CORRECT CHOICE TYPE ) This section contains 8 multiple choicse questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is correct 21. Using the data provided, calculate the multiple bond energy  1 kJ mol of a C C bond in 2 2C H . That energy is (take the bond energy of a C – H bond as 1 350kJ mol .)      2 2 22C s H g C H g  1 225H kJ mol      2 2C s C g 1 1410H kJ mol      2 2H g H g 1 330H kJ mol   A) 1165 B) 837 C) 865 D) 815 Ans : D      2 2 22C s H g C H g  1 225H kJ mol      2 2C g C s 1 1410H kJ mol       22H g H g 1 330H kJ mol         2 22 2C S H g C H g  1 1515H kJ mol    H - C C H 350350 C C bond energy is 815 kJ/mole.
  • 22. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 22 Sri Chaitanya IIT Academy 22. The major product H of the given reaction sequence is 2 495% 3 2 3 H SOCN Heat CH CH CO CH G H     A) 3CH CH C COOH   CH3 B) CH CH C CN   CH3 C) 3 2CH CH C COOH   CH3 OH D) 3 2CH CH C CO NH    CH3 Ans : B CH3 - CH2 - C - CH3 O CN  CH3 - CH2 - C - CN CH3 O- 2 495%.H SO   CH3 - CH2 - C - CN CH3 OH  CH3 - CH = C - CH3 CN 23.     2 2 5 6 52 2 NiCl P C H C H exhibits temperaturedependent magneticbehaviour (paramagnetic / diamagnetic) . The coordination geometries of 2 Ni  in the paramagnetic and diamagnetic states are respectively A) tetrahedral and tetrahedral B) square planar and square planar C) tetrahedral and square planar D) square planar and tetrahedral Ans : C Tetrahedral and square planar
  • 23. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 23 Sri Chaitanya IIT Academy 24. In the cyanide extraction process of silver from argentite ore, the oxidizing and reducing agent used are A) 2O and CO respectively B) 2O and Zn dust respectively C) 3HNO and Zn dust respectively D) 3HNO and CO respectively Ans : B 2O  oxidising agent Zn  reducing agent 25. The reaction of white phosphorus with aqueous NaOH gives phosphine alongwith another phosphorus containing compound. The reaction type; the oxidation states of phosphorus in phosphine and the other product are respectively A) redox reaction ; –3 and –5 B) redox reaction; +3 and +5 C) disproportionation reaction; –3 and +5 D) disproportionation reaction; –3 and +3 Ans : D 4 2 2 3P NaOH H PO PH     2 3 3Na HPO PH 26. The shape of 2 2XeO F molecule is A) trigonal bipyramidal B) Square planar C) tetrahedral D) see - saw Ans : D see-saw O O Xe F F
  • 24. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 24 Sri Chaitanya IIT Academy 27. For a dilute solution containing 2.5 g of a non – volatile non – electrolyte solute in 100 g of water, the elevation in boiling point at 1 atm pressure is 2 C .Assuming concentration of solute is much lower than the concentration of solvent, the vapour pressure (mm of Hg) of the solution is (take 1 0.76bK K kg mol  ) A) 724 B) 740 C) 736 D) 718 Ans :A 0 0 55.5 solute m p p X m p     760 55.5 760 m p  P = 724 mm of Hg 28. The compound that undergoes decarboxylation most readily under mild condition is A) B) C) D) Ans : B  -keto acids readily undergo decarboxylation SECTION – II (COMPREHENSION TYPE) This section contains 3 groups of questions. Each group has 2 multiple choice questions based on a paragraph. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is correct. Paragraph for Questions 29 and 30 The electrochemical cell shown below is a concentration cell. 2 |M M  (saturated solution of a sparingly soluble salt, 2MX ) 2 ||M   3 0.001 |mol dm M The emf of the cell depends on the difference in concentrations of 2 M  ions at the two electrodes. The emf of the cell at 298 K is 0.059 V.
  • 25. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 25 Sri Chaitanya IIT Academy 29. The value of  1 G kJ mol  for the given cell is (take 1 1 96500F C mol  ) A) –5.7 B) 5.7 C) 11.4 D) –11.4 Ans : D G nFE   2 96500 0.059    11.4 /kJ mol  30. The solubility product  3 9 ;spK mol dm of 2MX at 298 K based on the information available for the given concentration cell is (take 2.303 298/ 0.059R F V   ) A) 15 1 10  B) 15 4 10  C) 12 1 10  D) 12 4 10  Ans : B 0.059 0.001 0.059 0 log 2 E s    5 10S   3 15 4 4 10SPK s     Paragraph for Questions 31 and 32 In the following reaction sequence, the compound J is an intermediate.  3 2 2 3 2 3 ( ) , / ( ) ( ) . CH CO O i H Pd C CH COONa ii SOCl iii anhyd AlCl I J K   9 8 2J C H O gives effervescence on treatment with 3NaHCO and a positive Baeyer’s test. 31. The compound K is A) B) C) D) Ans : C
  • 26. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 26 Sri Chaitanya IIT Academy O I  3 2 3 CH CO O CH COONa  O OH J 2 / /H Pd C  O OH 2SOCl  O Cl 3anhyd AlCl  OK 32. The compound I is A) B) C) D) Ans :A Paragraph for Questions 33 and 34 Bleaching powder and bleach solution are produced on a large scale and used in several house hold products. The effectiveness of bleach solution is often measured by iodometry. 33. 25 mL of household bleach solution was mixed with 30 mL of 0.50 M KI and 10 mL of 4 N acetic acid. In the titration of the liberated iodine, 48 mL of 0.25 N 2 2 3Na S O was used to reach the end point. The molarity of the household bleach solution is A) 0.48 M B) 0.96 M C) 0.24 M D) 0.024 M Ans : C
  • 27. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 27 Sri Chaitanya IIT Academy 2 2 2 4 6 hypo CaOCl I I NaI Na S O      12 meq. 30 ml 48 ml 0.25 N = 12 m eq 0.5 N 15 m eq limitingreagent is beaching powder. 25 12N  12 0.48 25 N N  0.24M M 34. Bleaching powder contains a salt of an oxoacid as one of its components. The anhydride of that oxoacid is A) 2Cl O B) 2 7Cl O C) 2ClO D) 2 6Cl O Ans :A oxoacid is HOCl 2 22HOCl Cl O H O 
  • 28. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 28 Sri Chaitanya IIT Academy SECTION – III ( MULTIPLE CORRECT CHOICE TYPE ) This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONE OR MORE is/ are correct 35. For the given aqueous reactions, which of the statement(s) is (are) true? A) The first reaction is a redox reaction B) White precipitate is  3 26 Zn Fe CN   . C) Addition of filtrate to starch solution gives blue colour D) White precipitate is soluble in NaOH solution. Ans:ACD    2 4/ 3 4 26 6 di H SO KI K Fe CN K Fe CN I         ZnSO4  3 2 3 6 2 I K Zn Fe CN     Brownish yellow ppt white ppt Na2S2O3 (colourless solution) NaI + Na2S4O6
  • 29. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 29 Sri Chaitanya IIT Academy The whiteppt is soluble insodiumhydroxide       4 2 2 3 6 6 42 12 2 3 2K Zn Fe CN OH Fe CN Zn OH K                 36. With reference to the scheme given, which of the given statement(s) about T, U, V and W is(are) correct? A) T is soluble in hot aqueous NaOH B) U is optically active C) Molecular formula of W is 10 18 4C H O D) V gives effervescence on treatment with aqueous 3NaHCO Ans:ACD OH OH CH3 OAC OH CH3 U W HOOC CH3 COOH V
  • 30. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 30 Sri Chaitanya IIT Academy 37. Which of the given statement (s) about N, O, P and Q with respect to M is (are) correct? A) M and N are non–mirror image stereoisomers B) M and O are identical C) M and P are enantiomers D) M and Q are identical Ans:ABC 38. With respect to graphiteand diamond, whichofthestatement(s) given below is(are)correct? A) Graphite is harder than diamond. B) Graphite has higher electrical conductivity than diamond. C) Graphite has higher thermal conductivity than diamond. D) Graphite has higher C – C bond order than diamond. Ans : BD 39. The given graphs / data I, II, III and IV represent general trends observed for different physisorption and chemisorption processes under mild conditions of temperature and pressure. Which of the following choice(s) about I, II, III and IV is(are) correct?
  • 31. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 31 Sri Chaitanya IIT Academy A) I is physisorption and II is chemisorption B) I is physisorption and III is chemisorption C) IV is chemisorption and II is chemisorption D) IV is chemisorption and III is chemisorption Ans :AC 40. The reversible expansion of an ideal gas under adiabatic and isothermal conditions is shown in the figure. Which of the following statement(s) is (are) correct? A) 1 2T T B) 3 1T T C) isothermal adiabaticw w D) isothermal adiabaticU U   Ans :AD
  • 32. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 32 Sri Chaitanya IIT Academy MATHEMATICS SECTION – I ( SINGLE CORRECT CHOICE TYPE ) This section contains 8 multiple choicse questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is correct 41. The value of the integral /2 2 /2 ln cos x x x dx x            is A) 0 B) 2 4 2   C) 2 4 2   D) 2 2  Ans. B 2 2 2 cos log x x xdx is an odd function x                 2 2 0 2 cosx xdx    =        2 2 0 2 sin 2 cos 2 sinx x x x x        = 2 2 2 4       = 2 4 2  
  • 33. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 33 Sri Chaitanya IIT Academy 42. Let 1 2 3, , ,...a a a be in harmonic progression with 1 5a  and 20 25a  . The least positive inte- ger n for which 0na  is A) 22 B) 23 C) 24 D) 25 Ans. D 1 5, a  1 25 19a d   1 5 a  1 19 25 a d  1 1 19 25 5 d   = 4 25    4 25 19 d           1 0 1 1 0 1 4 1 0 5 5 19 na a n d a n d n                  95 - 4n + 4 < 0 99 < 4n 99 4 n  3 24 4 n  n = 25, 26, 27, ....... least n = 25
  • 34. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 34 Sri Chaitanya IIT Academy 43. The equation of a plane passing through the line of intersection of the planes 2 3 2x y z   and 3x y z   and at a distance 2 3 from the point  3,1, 1 is A) 5 11 17x y z   B) 2 3 2 1x y   C) 3x y z   D) 2 1 2x y   Ans. A Required plane is               2 3 2 3 0 1 1 2 3 2 3 0 x y z x y z x y z                         Given              2 2 2 | 3 1 2 1 3 1 2 3 | 2 31 2 3                     7 2     1 5 11 17 0x y z     44. Let PQR be a triangle of area  with 7 2, 2 a b  and 5 2 c  , where ,a b and c are the lengths of the sides of the triangle opposite to the angles at ,P Q and R respectively. Then 2sin sin 2 2sin sin 2 P P P P   equals A) 3 4 B) 45 4 C) 2 3 4       D) 2 45 4       Ans. C Hence 6  29 1 2sin sin 2 1 cos 335 292sin sin 2 1 cos 321 35 p p p p p p          P Q R C= 5/2 a = 2 7 2 b  Clearly From (C) : 2 3 3 40 32      
  • 35. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 35 Sri Chaitanya IIT Academy 45. If a  and b  are vectors such that 29a b    and        2 3 4 2 3 4a i j k i j k b           , then a possible value of      7 2 3a b i j k        is A) 0 B) 3 C) 4 D) 8 Ans. C  a r r b   , where 2 3 4r i j k   0a r r b      0r a b    ˆˆ ˆ2 3 4a b i j k     29a b  4 9 16 29 1             7 2 3 2 3 4 7 2 3a b i j k i j k i j k              –14 + 6 + 12 = 4 46. If P is a 3 3 matrix such that 2T P P I  , where T P is the transpose of P and I is the 3 3 identity matrix, then there exists a column matrix 0 0 0 x X y z                    such that A) 0 0 0 PX          B) PX X C) 2PX X D) PX X  Ans. D 2T P P I  2 T P P I  4 3P I  P I   PX X  
  • 36. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 36 Sri Chaitanya IIT Academy 47. Let  a and  a be the roots of the equation      23 6 1 1 1 1 1 1 0a x a x a         where 1a   . Then  0 lim a a  and  0 lim a a  are A) 5 2  and 1 B) 1 2  and -1 C) 7 2  and 2 D) 9 2  and 3 Ans. B         1 1 1/ 2 3 6 2 0 1 1 1 1 1 1 lim 0 1 1 1 1 1 1a a a a x x a a a                21 1 1 0 3 2 x x   2 2 3 1 0 6 x x    2 2 2 1 0x x x        2 1 1 1 0x x x     1 2 x   (or) –1. 48. Four fair dice 1 2 3, ,D D D and 4D , each having six faces numbered 1, 2, 3, 4, 5 and 6, are rolled simultaneously. The probability that 4D shows a number appearingon one of 1 2,D D and 3D is A) 91 216 B) 108 216 C) 125 216 D) 127 216 Ans. A Required probability = 1 – probability of D4 does not show a number appearing on any of D1 , D2 , D3 . 6 5 5 5 1 6 6 6 6         125 1 216   91 216 
  • 37. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 37 Sri Chaitanya IIT Academy SECTION – II (COMPREHENSION TYPE) This section contains 3 groups of questions. Each group has 2 multiple choice questions based on a paragraph. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is correct. Paragraph for Questions 49 and 50 Let     2 2 2 1 sinf x x x x   for all x IR , and let       1 2 1 ln 1 x t g x t f t dt t         for all  1,x  49. Consider the statements: P : There exists some x IR such that    2 2 2 1f x x x   Q : There exists some x IR such that    2 1 2 1f x x x   Then A) Both P and Q are true B) P is true and Q is false C) P is false and Q is true D) both P and Q are false Ans. C     2 2 2 1 sinf x x x x   x R     2 2 2 1f x x x     2 2 2 2 1 .sin 2 2 2x x x x x       2 2 2 1 sin 2 1 1x x x x       2 2 2 1 sin 2 1 1x x x x         2 22 1 sin 1 1x x x      2 2 1 sin 1 1x x       2 2 1 sin 1 1 x x   
  • 38. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 38 Sri Chaitanya IIT Academy But 2 sin 1 0x   x R  and   2 1 0 1x   x R  No such x exist satisfying P. Q:   2 2 1 2 2f x x x     2 2 2 2 2 1 sin 1 2 2x x x x x          2 2 2 2 2 1 sin 2 1 2 2x x x x x       2 2 2 1 sin 1 2x x x     2 2 2 1 sin 2 1x x x       2 2 2 2 1 2 1 sin 0 2 1 2 1 x x x x x        1 2 x  Q is true. 50. Which of the following is true? A) g is increasing on  1, B) g is decreasing on  1, C) g is increasing on  1,2 and decreasing on  2, D) g is decreasing on  1,2 and increasing on  2, Ans. B
  • 39. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 39 Sri Chaitanya IIT Academy       2 1 ' ln 1 x g x x f x x          0f x  x > 1    2 1 ln 1 x h x x x         2 4 1 ' 0 1 h x xx     1x  h (x) is decreasing.    1 1x h x h    2 1 ln 0 1 x x x      ' 0 1g x x    g is decreasing. on  1, Paragraph for Questions 51 and 52 A tangent PT is drawn to the circle 2 2 4x y  at the point  3,1P . A straight line L , perpendicular to PT is a tangent to the circle   2 2 3 1x y   51. A common tangent of the two circles is A) 4x  B) 2y  C) 3 4x y  D) 2 2 6x y  Ans. D Common tangent B Transversal        2 3,0 0,0 6,0 2 1 sI     Common tangent y–0 = m (x-6) mx-y-6m=0
  • 40. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 40 Sri Chaitanya IIT Academy 2 | 3 | 1 1 m m    1 2 2 m    1 ( 6) 2 2 y x   2 2 6y x    2 2 6x y  52. A possible equation of L is A) 3 1x y  B) 3 1x y  C) 3 1x y   D) 3 5x y  Ans. A 3 0L x y k    is tangent to  2 2 3 1x y   3 1 2 k   5, 1k k     3 1x y   Paragraph for Questions 53 and 54 Let na denote the number of all n  digit positive integers formed by the digits 0, 1 or both such that no consecutive digits in them are 0. Let nb  the number of such n  digit integers endingwithdigit1 and nc =the numberofsuch n  digit integersendingwithdigit0. 53. Which of the following is correct? A) 17 16 15a a a  B) 17 16 15c c c  C) 17 16 16b b c  D) 17 17 16a c b  Ans. A
  • 41. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 41 Sri Chaitanya IIT Academy an = 01 1 end with zero 2na  + 1 end with one 1na  1  an = an–2 + an–1 a17 = a15 + a16 54. The value of 6b is A) 7 B) 8 C) 9 D) 11 Ans. B 6 digits the integer ending with one = b6 The no of cases 1 1 cases with 4 ones : 1 1 1 1 one 3 ones : 0 1 1 1 1 0 1 1 4 1 1 0 1 1 1 1 0       2 ones : 1 0 1 0 0 1 0 1 3 0 1 1 0      b6 = 8
  • 42. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 42 Sri Chaitanya IIT Academy SECTION – III ( MULTIPLE CORRECT CHOICE TYPE ) This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONE OR MORE is/ are correct 55. If the straight lines 1 1 2 2 x y z k     and 1 1 5 2 x y z k     are coplanar, then the plane(s) con- taining these two lines is(are) A) 2 1y z   B) 1y z   C) 1y z   D) 2 1y z   Ans. B,C The lines are coplanar 2 0 0 2 2 0 5 2 k k    2k   Case (i) If 1 1 2 1 1 1 0 5 2 2 x y z k then equation of plane is            & 5 0 1 3 3 0x y z       1y z  1y z   Case (ii) If 1 1 2 1 1 1 0 5 2 2 x y z k then equation of plane is               1 0 1 7 7 0x y z      7 7 7 0y z   1y z  
  • 43. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 43 Sri Chaitanya IIT Academy 56. If the adjoint of a 3 3 matrix P is 1 4 4 2 1 7 1 1 3          , then the possible value(s) of the determinant of P is (are) A) -2 B) -1 C) 1 D) 2 Ans. A,D 2 2 1 4 4 2 1 7 4 1 1 3 adjp P   2P   57. Let  : 1,1f IR  be such that   2 2 cos 4 2 sec f     for 0, , 4 4 2                  . Then the value(s) of 1 3 f       is (are). A) 3 1 2  B) 3 1 2  C) 2 1 3  D) 2 1 3  Ans. A,B   2 2 1 cos 2 cos 4 1 sec2 cos 2 1 4 2 cos4 2cos 2 cos 2 3 3 3 3 sec2 2 1 3 1 3 2 , f f A B                              
  • 44. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 44 Sri Chaitanya IIT Academy 58. Let X and Y be two events such that     1 1 / , / 2 3 P X Y P Y X  and   1 6 P X Y  . Which of the following is (are) correct? A)   2 3 P X Y  B) X and Y are independent C) X and Y are not independent D)   1 3 c P X Y  Ans. A,B             1 3 1 2 p X YX p p Y Y p Y p X YY p p Y X p X                      . ,p X Y p X p Y X Y independent            1 1 1 4 2 3 2 6 6 3 1 1 3 1 2 6 6 2 , p X Y p X Y p X p X Y A B                 59. If      2 0 2 3 x t f x e t t dt   for all  0,x  , then A) f has a local maximum at 2x  B) f is decreasing on  2,3 C) there exists some  0,c  such that  " 0f c  D) f has a local minimum at 3x  Ans. ABCD
  • 45. Sri Chaitanya IIT Academy PAPER-2 KEY & SOLUTIONS Sri Chaitanya IIT Academy Admin Off : Plot No : 304, Kasetty Heights. Ayyappa Society - Madhapur , Pin : 500081 # 45 Sri Chaitanya IIT Academy      2 ' 2 3x f x e x x   max . at x = 2 2 3 min. at x = 3 decreasing on (2, 3)     2 2 '' 5 6 2 5 0x f x e x x x      2 3 1 0x x      3 5 0, 2 x      60. For every integer n , let na and nb be real numbers. Let function :f IR IR be given by       sin , for 2 ,2 1 cos , for 2 1,2 n n a x x n n f x b x x n n            , for all integers n . If f is continuous, then which of the following hold(s) for all ?n A) 1 1 0n na b   B) 1n na b  C) 1 1n na b   D) 1 1n na b    Ans. B, D continuous at x = 2n 1n nb a   1n na b    (B) continuous at x = 2 (n –1) 1 1 1n na b    continuous at x = 2n – 1 1 1n na b   –––– (D) continuous at x = 2n + 1 1 1n na b   