parm d students guide

1. IONIZATION

2.  pH is the negative logarithm of the hydrogen ion (H+) activity
in a given solution.
 The range of the pH scale is from 0 to 14
pH = -log [H+ ]--------------------(1)
where H+ = activity of hydronium ion
pH

3.  Sorenson defined:
◦ pH as the logarithm of the reciprocal of the hydrogen ion
concentration.
 Mathematically pH is expressed as:
 pH = log 1 /H3O+
-------- (1)
Equation (1) may be rearranged as:
 pH = log 1- log H3O+
----------------(2)

4.  Since log 1 is zero, equation (2) is written as :
pH = -log H3O+
------------------(3)
 Thus , pH defined as negative logarithm of hydrogen
ion concentration. Sorensen established the term pH ,
to represent hydrogen ion potential. The term p used to
express the negative logarithm .The concentration of
the H30+ is expressed in molarity, moles/liter etc.

5.  The pH values and different concentration of H30+ ions, a scale is
devised and named after Sorenson, who had developed it.
 The scale starts with a zero pH, i.e., hydrogen ion concentration is
1(100
). It means the solution is strongly acidic.
 At the other end of the scale , pH is 14 i.e., hydrogen ion concentration is
10-14
.It means the solution is strongly alkaline.
 The central point pH in the scale is 7.0, because [H3O+] is equal to
[OH].
Sorensen’s pH Scale

6.  The p in pH stands for "potenz" meaning "power" in
Danish. Since the scale was given by a Danish Chemist
Sorensen. H stands for Hydrogen and is its symbol.
Hence H is written in capital letter.
Why in pH symbol p is small and H is capital?

7. “It is a substance which is used to indicate the end point or
completion of a reaction by it’s colour change.”
OR
“A pH indicator is a halochromic chemical compound added in
small amounts to a solution so the pH (acidity or basicity) of the
solution or end point of titration can be determined visually by
color change. “
pH indicator

8.  pH stripes (litmus paper)
 pH meter
Types of pH indicator

9.  Litmus dye is a natural pH indicator . Litmus paper is a
small strip of paper that has dyes in it. When it touches
a base or a dye then the litmus paper changes colors
depending on , either it is a base or it is an acid.
 If a litmus paper is exposed to an acid it either changes
its colour to pink or red. If a strip of litmus paper
touches a base then the paper changes to a shade of
blue.
pH strip

11.  A pH meter is an electronic instrument used for
measuring the pH (acidity or alkalinity) of a liquid
(though special probes are sometimes used to measure
the pH of semi-solid substances).
 A typical pH meter consists of special measuring
probes (a glass electrode and a reference electrode)
connected to an electronic meter that measures and
displays the pH reading.
pH meter

13.  Calibration should be performed with at least two
standard buffer solutions that span the range of pH values
to be measured.
 For general purposes buffers at pH 4 and pH 10 are
acceptable.
 The pH meter has one control (calibrate) to set the meter
reading equal to the value of the first standard buffer and
a second control (slope) which is used to adjust the meter
reading to the value of the second buffer.
 A third control allows the temperature to be set.
Calibration