The roles of process parameters on structures and mechanical properties of po...Bambang Afrinaldi
Process parameters are crucial to produce targeted qualities in polypropylene (PP)/clay nanocomposites, due to their roles on the generation of shear and diffusion. Thus, this research aims to observe their effects on structures and properties of PP/clay nanocomposites. Samples were produced by mixing PP, PP grafting maleic anhydride (PP-gMA), and Cloisite 20A at fixed compositions, 88/9/3 wt%, respectively, in an internal mixer with variations on temperatures (210, 220, 230 °C) and speeds (60, 80, 100 rpm). Effect of mixing parameters on nanocomposite structures and properties were investigated from XRD, SEM and flexural properties. The results showed that all samples had intercalated as well as agglomerated structures. Further analysis on XRD and SEM showed that samples produced at
high conditions (230C or 100 rpm) had similar structures. In contrast, low setting sample (210C and 60 rpm), despite its similarity on dispersion level, had longer agglomerates than that of mixed at high settings. Correlated both increase of d-spacing and agglomerates length to flexural properties suggested that modulus was more influenced by dispersion level, while strength
was affected by agglomerates. However, it was worth to note that improvement on dspacing, with availability of long agglomerates might not guarantee modulus and strength improvement due to low interfacial bonding.
Effect of multi wall carbon nanotube content on the electrical and rheologica...Bambang Afrinaldi
Incorporating multi wall carbon nanotube (MWCNT) into the
polymer can improve the electrical properties of the nanocomposites. The effects of MWCNT on the electrical and rheological properties of polypropylene/MWCNT (PP/MWCNT) nanocomposites are investigated. The nanocomposites were prepared using melt mixing technique at chamber temperature of 180ºC and rotor rotation of 100 rpm for 10 minutes. Addition of MWCNT increases the electrical surface conductivity
up to 10-7 S. The electrical percolation threshold of the nanocomposites is found to occur at 1.3 wt% MWCNT content. Viscosity of the nanocomposites increased with the addition of MWCNT. The rheological percolation threshold of the PP/MWCNT is found occur at 1.4 wt% MWCNT content. Well dispersion is observed by mean Scanning Electron Microscope (SEM) analysis.
The roles of process parameters on structures and mechanical properties of po...Bambang Afrinaldi
Process parameters are crucial to produce targeted qualities in polypropylene (PP)/clay nanocomposites, due to their roles on the generation of shear and diffusion. Thus, this research aims to observe their effects on structures and properties of PP/clay nanocomposites. Samples were produced by mixing PP, PP grafting maleic anhydride (PP-gMA), and Cloisite 20A at fixed compositions, 88/9/3 wt%, respectively, in an internal mixer with variations on temperatures (210, 220, 230 °C) and speeds (60, 80, 100 rpm). Effect of mixing parameters on nanocomposite structures and properties were investigated from XRD, SEM and flexural properties. The results showed that all samples had intercalated as well as agglomerated structures. Further analysis on XRD and SEM showed that samples produced at
high conditions (230C or 100 rpm) had similar structures. In contrast, low setting sample (210C and 60 rpm), despite its similarity on dispersion level, had longer agglomerates than that of mixed at high settings. Correlated both increase of d-spacing and agglomerates length to flexural properties suggested that modulus was more influenced by dispersion level, while strength
was affected by agglomerates. However, it was worth to note that improvement on dspacing, with availability of long agglomerates might not guarantee modulus and strength improvement due to low interfacial bonding.
Effect of multi wall carbon nanotube content on the electrical and rheologica...Bambang Afrinaldi
Incorporating multi wall carbon nanotube (MWCNT) into the
polymer can improve the electrical properties of the nanocomposites. The effects of MWCNT on the electrical and rheological properties of polypropylene/MWCNT (PP/MWCNT) nanocomposites are investigated. The nanocomposites were prepared using melt mixing technique at chamber temperature of 180ºC and rotor rotation of 100 rpm for 10 minutes. Addition of MWCNT increases the electrical surface conductivity
up to 10-7 S. The electrical percolation threshold of the nanocomposites is found to occur at 1.3 wt% MWCNT content. Viscosity of the nanocomposites increased with the addition of MWCNT. The rheological percolation threshold of the PP/MWCNT is found occur at 1.4 wt% MWCNT content. Well dispersion is observed by mean Scanning Electron Microscope (SEM) analysis.
Pengaruh konsentrasi inisiator dan komposisi styrene dan maleic anhydride ter...Bambang Afrinaldi
Pengaruh konsentrasi inisiator dan komposisi styrene dan maleic anhydride terhadap berat molekul pada sintesis kopolimer poly(styrene maleic anhydride)
Pengaruh konsentrasi inisiator dan komposisi styrene dan maleic anhydride ter...Bambang Afrinaldi
Pengaruh konsentrasi inisiator dan komposisi styrene dan maleic anhydride terhadap berat molekul pada sintesis kopolimer poly(styrene maleic anhydride)
