2. Bl I I.I
R~ • · .,~,ilain c Elements
1 • block
r-,
r:·- · 1 l 2
P- 0,b,
~----_j I
3 4
I III 1.01( I OR'1 ,u m u n
5
GROUPS
Transition ilfctals
d · block
6 7 8 9 10
)I( 'lBI IOI I.I I ,11,1-.,
I
11 12 13
Repn•~cnta tic Elemcnh
p - block
14 15
Active mctalc,
16
:ohlc ga~c~
p-blod,
r-i
17 18
,__,
' ' i-! Q Ato1rnc nurnber ~ C State
Symbol
Carbon
D Solid
(A lkali metals & Alkaline eanh metals)
Heavy metals
Mctallo,d,
If I
HeQ
I I 11
Hd1um
C
0
Liquid
Gas
VB
Name
"18 VIIB
250
Mn
Non-metal',
Non-metal, (Halogen;)
Non-metals (lnen gas)
.----- VIII m
260 270 230 290
Fe Co Ni Cu
IIB
300
Zn
5,0 6 0
i3 C
8(•nm Carbon
13 D 14 D
Al . Si
Alumiruum S1hwn
31 0 3:! D
Ga Ge
7 8 9 10
N Q oQ FQ Ne Q
'uroren 0,H;1..-n fluonn< '.C'011
15 D 16 0 17 111
p s Cl Q Ar Q
Pho,phoru, Sulphur Chlonnc .r)'.•n
33 D 34 D 35 36
A, Se Br 0 Kr Q
Manganese Iron Cobalt Nickel Copper Zinc Gallium G~1um A.r~mc Sdcmum BnlfTIH'lc: M)ri.~n
42 0 43 0 44 □ 45 □ 46 0 47 0 48 □ 49 □ 50 D 51 D s:! D 53 D 54
Tc Ru Rh Pd Ag Cd In Sn
echoctium Rulhcnium Rhodium Palladium Sih,cr Cadnllum lNhwn Tin
Sb Te Xe Q
onmoo~ Tellunurn fo,d1n,.• ,.:111,n
75 0 760 n □ 780 790 80 0 81 D 8:! D 83 D s4 D 85 D ~6
Re Os Ir Pt Au Hg 11 Pb Bi Po At Rn Q
Tanpw, Rheoiwn Osmium Indium Platinum Gold M<muy 1ball1um Le.Hi 81<.muth ro,.....,mum .,t.,un~ R,.,J.,n
106 107 108 109 110 Ill 112 113 114 115 11 6 117
Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv T,
llohrium Has."ium Mritrcnum D~ud- ROCIII• q,p:c- Nihomum Fkro,,um ;.,o,.._"'"ium
~1;'.
- NC>um
/-block
61 D 62 0 63 0 64 D 65 D 660 67 D 68 0 09 D 70 0
Pm Sm Eu Gd 1b Dy Ho Er Tm Yb
- Sarunum Emcpwn Gadoltntum Terbium D)'l"""Uffl H...,.um Erbium Thuhum lklindll luldhtlll
93 94 95 96 97 98 99 100 IOI 102 103
Np Pu Am Cm Bk Cf Es Fm Mtl No Lr
- Omum Bak.chum Cabfomuam em.u;n,um tcmuum M.:.nJdn11111 ?-.,~l"th·,1m la.,.11:"n..11Jm
Nlpo.-
-
7. (
,.,,
II u um Br:r:lhum
Na. 1 4
.... t<.! pm u.=. pm
KL ~l
2 I .!. 2
~ @
.
•
ln th...· lh1rd pe n li..i. ~xlmm ..
,u~ .mu ..:-hlonn... ..h m 1, th, ,
'otr th r •"-- or
, .in c,..·.:pthm. c- ,11:~ o uc
men g. ,.:, .1 ~ b1~_;.~r th.m h~11'.)f.1..•th ,f the ~
pc_nod nu, ,, tx,-.ill-...' the out.:-r lnl.''l ,hell of men
g.L~, 1
, compktr Ill{·~ ha,.:~ nw.umwn number
of ek..,·tron, m th...··- olll1..'mh),t 1.lrbit tbu, the
d~.:lmm..• rept.ll,10 1, -~ mi,umun The effe"., of
nuc-kar pllll P l?r th.: , ~kn.:-.;' ~k.'.tn.'n, i, not
,1..,·n. Hcn..·1..•. lh.: , ii~ 0f the at,m 1..'f .m men ga., '"
bil!.~er. ~ut lh.
'l t-1i::~t>r than the .1U...tl1 metal of
~..., -"'
th1..' ,.un.: ~riod
Tn.•nd, in utomk ).Jll' :1t·ross a J>('riod.
ll..-woo l '..im..ut ' ..i,,a:-.:n (h,;.,
:- t,
'
' ' lffi r..n1 ~o r-m oopm t,-.:pm u:
Kl kl
" 1'.l
• 1 ·. -l . " :. (
Kl "l
(®) @ @ @)
tt : I. CatltNa Is always smaller than the parTnt aatom. fmm "hkh it i" fornle"d.
.. .... afeleclron(s). bcncc proton(s) arc more than ekctmn(sl ma catum So el«1rtllb ~
•••rs ad 1ft: pulled mward. Hence the Slll dccrca.c;cs.
8. l
r
, _+ 1'I, ..
10 I
"' J2 I
a C
F 0-:
9
-26 42
(,r
decreases
Down a group
On mo mg down a po-,,
1ze nrri-"-'..C and the cblll'&C
mcreases 1be
ze
nuclear c
electron me--
9. Across o pertod
On m mg acrou a period. nuclear pull
due LO the mc..rease m atonuc number. and
t<,mtc.. u.e decrea'>t:'>. Hence, <:lemc:nts
l r n t I , elcc.trons eatly.
Therefort: ti m tall, lur, durca e curo
n 11 from left t ngl t
I amp/ . In the 2nd period. lithium is the
mo l met,tlhc
C 8
I 0 F
1
R
Metalload Non-metah
Met.aJrc. c.haracter decreases or
-m •allic character increases
Jn the 3rd period, sodium is the most metallic
,•leme111
.
~ Non-metallic character
77wse elements which have a tenden9 to gain
t!u trans, in order to attain octet m their owemwst
orhl/ are conridered as non-metals.
Non-metals usually have 5, 6 or 7 electrons in
their outermost orbits. They can gain 3, 2 or 1 electron
respectively, in order to attain octet or to complete their
valence shells (outermost orbits) and form an anion.
For example, chlorine (Cl) and oxygen (0) gain
I and 2 electron(s) respectively to form anions.
Cl + e- ➔ c1-
(2, o,7) (2, 8, 8)
0 + 2e- ➔ 0 2-
(2, 6) (2, 8)
Non-metallic character also depends on :
#J . .aiz.e and (ii) nuclear charge.
,lu : Smaller the atomic size, greater
~ pull and the tendency to gain
- .........efore, the element is more
nds ir n,u~-
own a group
The atomic s
of new .hell ov
nuclear charge i
atomic.: number,
size is greater.
decreasef down
•
nuclear charge,
lr p Group t.i
C ;-.;on-metal
S, ~letalloid
Ge .Metalloid
Sn ~ktal
Pb ~letal
A,..r,.,.,.,. the period Cleft to nght)
On mo ing acro~s a penod. the tenuenc~ to
gain electron(s) inc.rea,e, due to an incre..iM! in
nuclear pull and a decrea~e in the .1tom1c -.1ze.
T herefore. o t c c ,
a pen .. from left to nghr.
For example, in the 3rd period.
Na < Mg < Al < Si < P < S < Cl
~1etab Metalloid ~ on-metab
Non-metallic character increases
Note : Non-metals are oxidising agents.
The nature of oxides also show periodicity.
Across a period : The oxides of elements in a
panil:ul.lr pcnod ho,r Jt"Cr1 •1 ,,,,~ bnHc riat11re nd
finally become aciJ1c. For example. the oxides of
elements of the third period.
Na20 MgO A120 3 Si02 P205 S03 Cl20 7
Strongly Basic Amphotcric Fcebl) Acidic More Most
basic acidic acidic acidic
Down a group : The ba'iic natu,e ofcuidel ofmei
uscreases.
The reactivity of elements depends upon their
tendency to lose or gain electrons to complete their
outermost orbit. Greater the tendency to lose
electron(s), greater is the reactivity in the case ?f
aetals. Similarly greater the tendency to gain
~ gr.eater is tbe reactivity of non-metals.
ffllGCNV
10. 1 5 4 10
n1sat1on pot nt101 or Ion, otion
energy (I E) or on sot on nthatpy
l' kno 1h.11 I hl' eIce Ifflll', 111 "11 "'', n, .11 l '
<lll.JJUcd b) lhe po,111vd) ch,11g1•d 1111L' ll' ll' Sn, ii l'
V..tnt to remove au ck-c1 1nn f,0111 :u1 .1 !<>111 , ~0111l' t' 11,·11'
ha., tu he '>trpplicd to O't'lt:<nnL' lliL· ..,li<>ll" :111111< 11011
01
Ifie 11uck·11-.. J11d :tl1t·1 lht• L'kc1ron !'t';-., 1t·111u,l·tl
frou1 Ilic atc1111, lhl' .tlum 1hl'll :icqt1ir,,.., rn1~· u11i1 pmi1ivv
cli.ugc ·•11·' I) 'l'< 11 • • • • ·
u U L > It <l [)0ill! lllll (OI l'.111011)
1
l,i· t'lll'i I,' IC'tJllin·cl t o l't'11w1 ·<• 1111 f'/1•c' f11111 /10111 11
ticutral i10/11t,•tl }:a .,,•011.,· IIUJ/11 anti c·11111 ·1·rt it i11to ti
/
1
<
111
1
11
•"/. char~ed ga.1·t•o11.1 ion i.1 nlll,·d io11i.111ti1111
f'ote111iu/ (J.P.) or ionisation ener,:y (I.E.) 01 first
ionisation energy (IE
I
J.
M (g) + I.E. -) M+(g) + c-
M can be any clement.
Unit : I.E. H "" awred in elC'cIron I oft ,· per alnm
(eV/a/0111) {UU} Wi SJ unit ir kiloj,111/, !/{, 1110/c (/..J mo/ I).
Ionisation energy depends on :
(i) atomic size (ii) nuclear charge
(i) Atomic size : The greater the atomic size, the
lesser the force ofattraction. Since the electrons
ofthe outennost shell lie further away from the
nucleus. thus make their removal easier, i.e.,
the ionisation energy required is less.
(ii) Nuclear charge : The greater the nuclear
C~e, greateris the attraction for the electrons
efthe outermost shell. Therefore, the electrons
ost shell are more finnly held
whicpgi;cater energy is required to
~
I h,· 1·11111n 1l'I
~, M
oftl11 , cl
p,•1lml
"' I'
I.I .
I'll) , ., 1 lt'h 11,1 I 11'1'/ t ,
Ill kl 111ol I
Down a group
• 1 1, ,,.,1• 111 i111111J1L 111J111hu in,,,
j Ji1 ' JL
' I ' ,(II II l
J I H i-, 11, d, ,w11 11,, t 1•,11p cl,, II 0
rli;ll)'l") ;111( .I 11111 I
J I •1 , lwll.., J111 1; 11J1 ft.t 1: 111 1l1 ,
11
,
:1dd1l1<JJI () l 1' ,,,
IIH
..: i·JI,·, I ,,f ,111 i11 1. 1r, , •• i1
1 II
l/l' O Vl" I l ()JIil '>
JI ii( k:11' t;l 1;111•t .
1 h r for lll/11 " 111111 "' 1 I , a
II
I I I It tltf I I
/lie ! 1 a I Ill f I tl(Ofl /t 11 I,
1//(11 l 1/ull /I ti J.;fllllfl
( El1•11u·nt r/j T N;,
~K (KJ mol 1
J I mi j '1%
r_-~ <
1
~7
;~~J
:l~
INote : • I lcliu111 will have the _highcsl !<mi11atJon
1 cncr~y 2'n2•0 kJ mol I whtlc caesium (Ca)
Iwill have the lowest ionisation energy of
375-0 kJ mol 1
(I.E. of Fr is not determined
correctly as ii is radioactive).
• Metals usually have low I.E. whereas
non-metals have high LE.
1.5.5 Electron Affinity CE.A.) or Electron
Gain Enthalpy
We have just studied that to remove an electron
from an atom. energy is required. Similarly, when
an extra electron is added to an atom. energy ii
released.
12. ~(
I
I
'I
n l ~•I
I 1!
'11 1l1
,,
lJ ~
Ii
l
,,
.
••I
,,,
.,, '"
•t1 11,
..
I
:.I
'"
)'
•I•
II
'I•
ll
...
"'I I
I
•I• '
1 1 ll
I I ,
I
{:J
,,
I •(1
'"
I
.,,
,,,
'I
I ,,
•11 1 1
l
,, ,,
"'
'"
,,,
t '•i. ·.:
•11 ~/, .,,
, ·,;1,
:'}, •,1,
1 1 II
,,, 11 ~ I I I
'I ")
, .
I
•I •
,,
I'
4:J·
'J '
,}1 Ii
H, ;;
. ,f
.,,
I t,
·/
1
t
•1
:J
t
i ~
''!
,., ,'
;,J
11: fl
~ ~
1·!, ~
,1, (
L 11
! 'II
1:
,1,
~ l' Ill
n1 nt
' ~h
'~- tJJ flJ
1
1 !: J
nJ u• 1
11
t fU il
II J I 'II
j ~ J f I 1.:;l
tlf t: t S
Iii ;i: X Ill 1,
•u
'!i
:t
<11
I
I
j' 1, I
1 t ~l /
I j ' I() I" ~
1,rlrm I
I I rJJ ~ er
•11 I S
1'- ~
0)
13. !e
t': - -~....:.
4 5 s s ~ , .:,
A !3 C [) ::-
3
-
., ~3 • 4 E 1'5 1- 13
J K M r~ Q =
~ Q h?SE'
a are mo~! e e:- ::--e;:3::-.e e e-e-~
~ s a -.a:-:,Je.n ,
c s a- .1 "a:.: me'..?_ ...
d s a,.. e e-e-1,.... •2. e-::~! -
e) han~ e3s. 0- s::.· ,.., ::-.,,·-
-.. .... - .... :::-,
._
:, " ....
~~ 0~D:: ee--e-:s ~;-e:="en~~ -:-ar-Jeare;pen ::ie::,
(t-0•::-, s :"'e ·st --e--r,e• ;)[ t'le group a-.c i "h..a r.1 s
tne as.'
So·o-- . u-- - c.~· Ga um ':id ...'."!"I, Toa um
A.rs,·,e· ."'e 0 Ci "9 auest10ns,., reatio:1 t.:, the abc.e
g Ou:'.' C' e e""ents :
(a) W;::h element has the most rie•a ic ::"'aracte· ~
lt-) ',nr~h element would be expected t0 ha" e ~"e
h•ghest elec:tronegativity ?
(c) If the electronic configuration of alum n 1.r s 2 S,
3, how many electrons are there n the oute• s.'"ie
of "8lium?
(d) The atomic numberof boron is 5. Write the cher c.aJ
fomua ofthe compound formed When boron reacts
wlh chlorine.
(e) WI 118 elements in the ~ 10 the nght of tt11s
bolall ~ be more metallic or less metallic ·n
cll8Je+1a 7 Justly~ answer.
Alomlc number (Z)
•-~r o
n . Atomic IIIUIIHr is
• IJ ofan elemtllt, Ha111Se IIO ht'O
a.same aromic ••••
·c number (Z = ~1...mberofprolDDS.
= ~umber meltdruu&.
• It d -.tingm~hes J.n element .... allmr tla ues,
became no
number.
• It gi, e~ the electronic .:o
e.~.. an element " 1th at
eiectronic configuntion
• It help,; u5 in finding
the penod.1c table.
, - r -
El,iatnn
H. -
B,., -
c~
" ,...- -
' --
01 ~· cl
f ... l ~-:-
,. -
' .... ~~
Y.;-., ~
Ahl- i:.:y-
S1h: 1'n
P:~ ,;1,.:~~
S-~
:--"~r
C~.:n..~
!:,. .
Pou,, ...
C1k u.m
H
He
s~
ti
('
~
0
:
~~
K.
M
;
s
:>
:-
(
Ar
IR
c~
Mass number (A)
her
I -
I ~
Q
Mass number (Al = Zo. of pro1oos p
+ So. of neuuoos n
A d~ look a, w r~ ·-
of Uilrur ~~~111s ":r
wlakA ltav~ a• ere■ ••IIIIHr
·•"•••j111i,,_ • ic •11 1hn Jiu _.
-
-
-•rrs fWltt llliiP • •at ltn