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Name .............................................................
School ..................................…………………
Roll Number.........................………………….
Puntland State of Somalia
Ministry of Education
Puntland National Examination Board
Form 4
CHEMISTRY Examination
2008
Time 2 hours
Plus 10 minutes before the exam for reading through the paper
TOTAL TIME 2 hours 10 minutes
INSTRUCTIONS TO CANDIDATES
This paper consists of 17 printed pages
Count them now. If there are any missing, inform the invigilator
There are two parts:
SECTION A – Multiple Choice Questions 10 MARKS
SECTION B – Structured Questions 90 MARKS
TOTAL 100 MARKS
 Answer all questions
 All answers and working must be written on this paper in the spaces provided
immediately after each question
 Rough work can be done on page 2. This will not be marked
 No extra paper is allowed
 No calculators are allowed
 If you make a mistake, cross out the incorrect answer and clearly write your correct
answer
Puntland National Examination Board Secondary School Form Four Examinations
Puntland Certificate of Education Chemistry Examination June 2008
© PNEB 20082
Use This Page for Rough Work, It Will Not Be Marked
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Puntland National Examination Board Secondary School Form Four Examinations
Puntland Certificate of Education Chemistry Examination June 2008
© PNEB 20083
SECTION A: MULTIPLE CHOICE QUESTIONS (10 MARKS)
Instructions for this section: For each question in this section, circle the correct answer
1. What products are formed when an acid and a base react?
A. Water and Hydrogen B. Hydrogen and Oxygen
C. Salt and Water D. Base and Water
2. Which of the following methods is suitable for separation of ethanol and
water
A. Evaporation B. Distillation
C Sublimation D. Precipitation
3. Pick the formula that represents an alcohol
A. C2H6O B. C2H4O2
C. C2H4CL2 D. C2H2O4
4. The following factors affect rate of a reversible reaction. Which one
does not.
A. Temperature B. Pressure
C. Humidity D. Concentration
5. An element T with atomic number 13 belongs to?
A. Group 1, Period 3 B. Group 3, Period 1
C. Group 2, Period 3 D. Group 3, Period 3
6. Change of state from gas to liquid is called
A. Melting B. Freezing
C. Condensation D. Evaporation
7. When a blue litmus paper is dipped in an acidic solution
A. Turns red B. Turns pink
C. Turns colourless D. Remains blue
Puntland National Examination Board Secondary School Form Four Examinations
Puntland Certificate of Education Chemistry Examination June 2008
© PNEB 20084
8. Which of the following is an allotrope of sulphur?
A. Sulphur Dioxide B. Monoclinic
C. Graphite D. Diamond
9. Molarity is defined as
A. Moles per litre B. Grams per litre
C. Mass divided by R.M.M D. Mass divided by volume
10. A certain solution recorded a pH of 9. This can be described as
A. Neutral B. Basic
C. Acid D. Amphoteric
Puntland National Examination Board Secondary School Form Four Examinations
Puntland Certificate of Education Chemistry Examination June 2008
© PNEB 20085
SECTION B: Answer ALL the Questions.
1. a) Study the figure below and answer the questions that follow
(i) What property of hydrogen made it possible to be collected as
shown in the diagram (1 mark)
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
Round – bottomed flask
Granulated zinc
Hydrogen
Gas jar
Trough
Water
Diluted Sulphuric (VI) acid
Puntland National Examination Board Secondary School Form Four Examinations
Puntland Certificate of Education Chemistry Examination June 2008
© PNEB 20086
(ii) Write down the chemical equation for the reaction taking place in
the flask (3 marks)
……………………………………………………………………………………………………………
…………………………………………………………………………………………………………..
(iii) Name TWO physical properties of Hydrogen gas (2 marks)
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
(iv) Is the gas collected by upward or downward delivery method? Explain your answer
(1mark)
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
b) Study the following chart and answer the questions that follow
HCl (g) Solid Y Solution of Y
Green ppt
HCl (aq )
Heated
iron
NaOH(aq )
Water
Gas WKMnO4
Solid Z Solution of Z
Water
Brown ptt
NaOH(aq )
Water
Heated Iron
Puntland National Examination Board Secondary School Form Four Examinations
Puntland Certificate of Education Chemistry Examination June 2008
© PNEB 20087
(i) Identify the substances
W…………………………… (1mark)
Y…………………………….. (1mark)
Z…………………………….. (1mark)
(ii) Write equations for the formation of the brown precipitate (3 marks)
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
TOTAL 13 MARKS
2. (a) Draw and name the four structural isomers of the following C4H9OH
(8 marks)
(i)
(ii)
(iii)
Puntland National Examination Board Secondary School Form Four Examinations
Puntland Certificate of Education Chemistry Examination June 2008
© PNEB 20088
(iv)
b) Hydrogen bromide was reacted with propene
(i) Draw the structure of the product (1mark)
(ii) Give the name of the product (1mark)
……………………………………………………………………………………………………………
TOTAL 10 MARKS
3. (a) The following are chemical species:
H2O, H2, Mg, Ca2+
, O2-
and Cu
Classify them into;
(i) Atoms (1mark)
(ii) Ions (1mark)
(iii) Molecules (1mark)
Puntland National Examination Board Secondary School Form Four Examinations
Puntland Certificate of Education Chemistry Examination June 2008
© PNEB 20089
(b) The table below shows the structures of several particles. By using the
information in the table, answer the questions that follow :-
Particle Electrons Protons Neutrons
A 10 13 14
B 11 11 12
C 10 8 8
D 9 9 10
(i) Which two particles are neutral atoms? (2 marks)
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
(ii) Which two particles are ions? (2 marks)
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
(iii) Which particle is a positive ion? (1 mark)
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
(iv What charge is on this positive ion in (iii) above? (1 mark)
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
(v) Which particle is a negative ion? (1 mark)
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
(vi) What charge is on this negative ion in (v) above? (1 mark)
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
TOTAL 11 MARKS
Puntland National Examination Board Secondary School Form Four Examinations
Puntland Certificate of Education Chemistry Examination June 2008
© PNEB 200810
4. a) Below is a grid representing part of the Periodic Table. The letters
are not the actual symbols of the elements
D E F
A B G H
C
(i) Which is the element with the largest atom? (1 mark)
………………………………………………………………………………………………………….
(ii) Identify the most reactive non metal (1 mark)
…………………………………………………………………………………………………………..
(iii) Give the electron arrangement of following elements
Element D ………………………………………………………………………. (1 mark)
Element G………………………………………………………………………. (1 mark)
(iv) Write an equation for the reaction between element A and element E
……………………………………………………………………………………………………………
………………………………………………………………………………………….. (2 marks)
(b) Write down the electronic configuration in both quantum and orbital configuration for:
Potassium (atomic number 19, mass number 39) (2 marks)
………………………………………………………………………………………………………
………………………………………………………………………………………………………
(c) An element Q has the following electronic orbital configuration
1S2
2S2
2P5
(i) Suggest the group and the period where element B is in the periodic table
Group………………………………………………………………….. (1mark)
Period……………………………………………… …………………. (1mark)
Puntland National Examination Board Secondary School Form Four Examinations
Puntland Certificate of Education Chemistry Examination June 2008
© PNEB 200811
(d) Suggest TWO physical properties of elements A and C (2 marks)
…………………………………………………………………………………………………………
…………………………………………………………………………………………………………
TOTAL 12 MARKS
5. The diagram below shows how impure copper is refined by electrolysis
(i) Give the materials that can be used to make electrodes A and B
Electrode A………………………………………………… (1mark)
Electrode B…………………………..……………………… (1mark)
(ii) Identify substance C and D
C………………………………………………… (1mark)
D………………………………………………… (1mark)
(iii) Write the ionic equation for the reaction taking place at
the anode……………………………………………………....................
…………………………………………………………………………….. (2 marks)
the cathode………………………………………………………………...
…………………………………………………………………………….. (2 marks)
B
A
- +
C
D
Puntland National Examination Board Secondary School Form Four Examinations
Puntland Certificate of Education Chemistry Examination June 2008
© PNEB 200812
(iv) What is the economic importance of substance D (1mark)
…………………………………………………………………………………………………………
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
TOTAL 9 MARKS
6. (a) The experiment below was set up by a student to determine the conditions under which
iron nail will rust. Study it and answer the questions that follow:-
(i) State the purpose of the anhydrous calcium chloride in the tube B
(1 mark)
…………………………………………………………………………………….……………………
………………………………………………………. ………………………………………………..
(ii) Give a reason for using boiling water in tube C (1mark)
…………………………………………………………………………………………………………...
…………………………………………………………………………………………………………..
(iii) State and explain observations that would be in tube A after one week
(2marks)
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
…………………………………………………………………………………………………………..
water
Anhydrous
Calcium
Chloride
Boiled
water
Oil
Water
Puntland National Examination Board Secondary School Form Four Examinations
Puntland Certificate of Education Chemistry Examination June 2008
© PNEB 200813
b) (i) State two observations that would made when magnesium ribbon
is burn in air (2 marks)
……………………………………………………………………………………………………………
…………………………………………………………….……………………………………………
…………………… ……………………………………………………………………………………
(ii) The product formed in b (i) above is dissolved in water. State whether
the solution obtained is acidic or basic. (2marks)
………………………………………………………………………………………………………
………………………………………………………………………………………………………
………………………………………………………………………………………………………
(c) One of the air pollutants is sulphur (IV) oxide. State its source and effect.
(2marks)
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
TOTAL 10 MARKS
7. (a) A student added dilute sodium hydroxide solution to a white solid M and
the solid dissolved. He also added dilute hydrochloric acid to a sample of
solid M and it also dissolved. What type of substance is solid M. Explain.
(2marks)
………………………………………………………………………………………………………
………………………………………………………………………………………………………
……………………………………………………………………………………………………..
(b) Name one hydroxide that would dissolve in both dilute sodium
hydroxide and aqueous ammonia. (1mark)
…………………………………………………………………………………………………….
Puntland National Examination Board Secondary School Form Four Examinations
Puntland Certificate of Education Chemistry Examination June 2008
© PNEB 200814
(c) When air is bubbled through pure water of pH 7.0, the pH drops to 6.0.
explain this observation (2 marks)
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
TOTAL 5 MARKS
8. (a) During an experiment using Zinc powder and dilute HCl of different concentrations, the
time required to evolve 100cm3
of the gas for every experiment was recorded.
Concentration
of HCl
1.5 1.25 1.00 0.75 0.50 0.25
Time (sec) 9.0 10.2 11.4 13 16.5 18
Rate (1 / t) 0.111 0.0878 0.0696
(i) Complete the table (3 marks)
Puntland National Examination Board Secondary School Form Four Examinations
Puntland Certificate of Education Chemistry Examination June 2008
© PNEB 200815
(ii) On the grid provided below, plot a graph rate (vertical axis) against
concentration (horizontal axis). (3 marks)
Puntland National Examination Board Secondary School Form Four Examinations
Puntland Certificate of Education Chemistry Examination June 2008
© PNEB 200816
(iii) From the graph, determine the concentration needed to produce 100cm3
of Hydrogen
when time is 12.0 seconds. (1 mark)
…………………………………………………………………………………......
(iv) From your graph, comment on the relationship between rate of reaction and
concentration. (2 marks)
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
…………………………………....................................................................................................
(b) A dynamic equilibrium was obtained for the following reaction
N2(g) + 3H2(g) 2NH3(g) H = - ve
(i) Define the term dynamic equilibrium (1 mark)
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
…………………………………...................................................................................................
(ii) How will the yield of ammonia be affected with increase in temperature? Explain
your answer. (2 marks)
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
TOTAL 12 MARKS
9. (a) 1.5 grams of pure sodium chloride is dissolved in water to make
250cm3
of solution. Calculate the molarity of the solution.
(Na = 23, Cl = 35.4) (3 marks)
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
Puntland National Examination Board Secondary School Form Four Examinations
Puntland Certificate of Education Chemistry Examination June 2008
© PNEB 200817
(b) Analysis of a compound gave 92.3% carbon and 7.7% hydrogen. Its
relative molecular mass was found to be 78. Calculate its empirical
and molecular formula. (C = 12, H = 1) (5 marks)
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
....................................................................................................................................................
....................................................................................................................................................
TOTAL 8 MARKS
END

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History  2009 PNEB (PUNTLAND NATIONAL EXAMINATION BOARD)History  2009 PNEB (PUNTLAND NATIONAL EXAMINATION BOARD)
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Geograph 2009 PNEB (PUNTLAND NATIONAL EXAMINATION BOARD)
Geograph  2009 PNEB (PUNTLAND NATIONAL EXAMINATION BOARD)Geograph  2009 PNEB (PUNTLAND NATIONAL EXAMINATION BOARD)
Geograph 2009 PNEB (PUNTLAND NATIONAL EXAMINATION BOARD)
 

Chemistry

  • 1. Name ............................................................. School ..................................………………… Roll Number.........................…………………. Puntland State of Somalia Ministry of Education Puntland National Examination Board Form 4 CHEMISTRY Examination 2008 Time 2 hours Plus 10 minutes before the exam for reading through the paper TOTAL TIME 2 hours 10 minutes INSTRUCTIONS TO CANDIDATES This paper consists of 17 printed pages Count them now. If there are any missing, inform the invigilator There are two parts: SECTION A – Multiple Choice Questions 10 MARKS SECTION B – Structured Questions 90 MARKS TOTAL 100 MARKS  Answer all questions  All answers and working must be written on this paper in the spaces provided immediately after each question  Rough work can be done on page 2. This will not be marked  No extra paper is allowed  No calculators are allowed  If you make a mistake, cross out the incorrect answer and clearly write your correct answer
  • 2. Puntland National Examination Board Secondary School Form Four Examinations Puntland Certificate of Education Chemistry Examination June 2008 © PNEB 20082 Use This Page for Rough Work, It Will Not Be Marked …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… ………………………………….……………………………………………………………………… …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… ………………………………….……………………………………………………………………… …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… ………………………………….……………………………………………………………………… …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… ………………………………….………………………………………………………………………
  • 3. Puntland National Examination Board Secondary School Form Four Examinations Puntland Certificate of Education Chemistry Examination June 2008 © PNEB 20083 SECTION A: MULTIPLE CHOICE QUESTIONS (10 MARKS) Instructions for this section: For each question in this section, circle the correct answer 1. What products are formed when an acid and a base react? A. Water and Hydrogen B. Hydrogen and Oxygen C. Salt and Water D. Base and Water 2. Which of the following methods is suitable for separation of ethanol and water A. Evaporation B. Distillation C Sublimation D. Precipitation 3. Pick the formula that represents an alcohol A. C2H6O B. C2H4O2 C. C2H4CL2 D. C2H2O4 4. The following factors affect rate of a reversible reaction. Which one does not. A. Temperature B. Pressure C. Humidity D. Concentration 5. An element T with atomic number 13 belongs to? A. Group 1, Period 3 B. Group 3, Period 1 C. Group 2, Period 3 D. Group 3, Period 3 6. Change of state from gas to liquid is called A. Melting B. Freezing C. Condensation D. Evaporation 7. When a blue litmus paper is dipped in an acidic solution A. Turns red B. Turns pink C. Turns colourless D. Remains blue
  • 4. Puntland National Examination Board Secondary School Form Four Examinations Puntland Certificate of Education Chemistry Examination June 2008 © PNEB 20084 8. Which of the following is an allotrope of sulphur? A. Sulphur Dioxide B. Monoclinic C. Graphite D. Diamond 9. Molarity is defined as A. Moles per litre B. Grams per litre C. Mass divided by R.M.M D. Mass divided by volume 10. A certain solution recorded a pH of 9. This can be described as A. Neutral B. Basic C. Acid D. Amphoteric
  • 5. Puntland National Examination Board Secondary School Form Four Examinations Puntland Certificate of Education Chemistry Examination June 2008 © PNEB 20085 SECTION B: Answer ALL the Questions. 1. a) Study the figure below and answer the questions that follow (i) What property of hydrogen made it possible to be collected as shown in the diagram (1 mark) …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… Round – bottomed flask Granulated zinc Hydrogen Gas jar Trough Water Diluted Sulphuric (VI) acid
  • 6. Puntland National Examination Board Secondary School Form Four Examinations Puntland Certificate of Education Chemistry Examination June 2008 © PNEB 20086 (ii) Write down the chemical equation for the reaction taking place in the flask (3 marks) …………………………………………………………………………………………………………… ………………………………………………………………………………………………………….. (iii) Name TWO physical properties of Hydrogen gas (2 marks) …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… (iv) Is the gas collected by upward or downward delivery method? Explain your answer (1mark) …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… b) Study the following chart and answer the questions that follow HCl (g) Solid Y Solution of Y Green ppt HCl (aq ) Heated iron NaOH(aq ) Water Gas WKMnO4 Solid Z Solution of Z Water Brown ptt NaOH(aq ) Water Heated Iron
  • 7. Puntland National Examination Board Secondary School Form Four Examinations Puntland Certificate of Education Chemistry Examination June 2008 © PNEB 20087 (i) Identify the substances W…………………………… (1mark) Y…………………………….. (1mark) Z…………………………….. (1mark) (ii) Write equations for the formation of the brown precipitate (3 marks) …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… TOTAL 13 MARKS 2. (a) Draw and name the four structural isomers of the following C4H9OH (8 marks) (i) (ii) (iii)
  • 8. Puntland National Examination Board Secondary School Form Four Examinations Puntland Certificate of Education Chemistry Examination June 2008 © PNEB 20088 (iv) b) Hydrogen bromide was reacted with propene (i) Draw the structure of the product (1mark) (ii) Give the name of the product (1mark) …………………………………………………………………………………………………………… TOTAL 10 MARKS 3. (a) The following are chemical species: H2O, H2, Mg, Ca2+ , O2- and Cu Classify them into; (i) Atoms (1mark) (ii) Ions (1mark) (iii) Molecules (1mark)
  • 9. Puntland National Examination Board Secondary School Form Four Examinations Puntland Certificate of Education Chemistry Examination June 2008 © PNEB 20089 (b) The table below shows the structures of several particles. By using the information in the table, answer the questions that follow :- Particle Electrons Protons Neutrons A 10 13 14 B 11 11 12 C 10 8 8 D 9 9 10 (i) Which two particles are neutral atoms? (2 marks) …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… (ii) Which two particles are ions? (2 marks) …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… (iii) Which particle is a positive ion? (1 mark) …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… (iv What charge is on this positive ion in (iii) above? (1 mark) …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… (v) Which particle is a negative ion? (1 mark) …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… (vi) What charge is on this negative ion in (v) above? (1 mark) …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… TOTAL 11 MARKS
  • 10. Puntland National Examination Board Secondary School Form Four Examinations Puntland Certificate of Education Chemistry Examination June 2008 © PNEB 200810 4. a) Below is a grid representing part of the Periodic Table. The letters are not the actual symbols of the elements D E F A B G H C (i) Which is the element with the largest atom? (1 mark) …………………………………………………………………………………………………………. (ii) Identify the most reactive non metal (1 mark) ………………………………………………………………………………………………………….. (iii) Give the electron arrangement of following elements Element D ………………………………………………………………………. (1 mark) Element G………………………………………………………………………. (1 mark) (iv) Write an equation for the reaction between element A and element E …………………………………………………………………………………………………………… ………………………………………………………………………………………….. (2 marks) (b) Write down the electronic configuration in both quantum and orbital configuration for: Potassium (atomic number 19, mass number 39) (2 marks) ……………………………………………………………………………………………………… ……………………………………………………………………………………………………… (c) An element Q has the following electronic orbital configuration 1S2 2S2 2P5 (i) Suggest the group and the period where element B is in the periodic table Group………………………………………………………………….. (1mark) Period……………………………………………… …………………. (1mark)
  • 11. Puntland National Examination Board Secondary School Form Four Examinations Puntland Certificate of Education Chemistry Examination June 2008 © PNEB 200811 (d) Suggest TWO physical properties of elements A and C (2 marks) ………………………………………………………………………………………………………… ………………………………………………………………………………………………………… TOTAL 12 MARKS 5. The diagram below shows how impure copper is refined by electrolysis (i) Give the materials that can be used to make electrodes A and B Electrode A………………………………………………… (1mark) Electrode B…………………………..……………………… (1mark) (ii) Identify substance C and D C………………………………………………… (1mark) D………………………………………………… (1mark) (iii) Write the ionic equation for the reaction taking place at the anode…………………………………………………….................... …………………………………………………………………………….. (2 marks) the cathode………………………………………………………………... …………………………………………………………………………….. (2 marks) B A - + C D
  • 12. Puntland National Examination Board Secondary School Form Four Examinations Puntland Certificate of Education Chemistry Examination June 2008 © PNEB 200812 (iv) What is the economic importance of substance D (1mark) ………………………………………………………………………………………………………… …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… TOTAL 9 MARKS 6. (a) The experiment below was set up by a student to determine the conditions under which iron nail will rust. Study it and answer the questions that follow:- (i) State the purpose of the anhydrous calcium chloride in the tube B (1 mark) …………………………………………………………………………………….…………………… ………………………………………………………. ……………………………………………….. (ii) Give a reason for using boiling water in tube C (1mark) …………………………………………………………………………………………………………... ………………………………………………………………………………………………………….. (iii) State and explain observations that would be in tube A after one week (2marks) …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… ………………………………………………………………………………………………………….. water Anhydrous Calcium Chloride Boiled water Oil Water
  • 13. Puntland National Examination Board Secondary School Form Four Examinations Puntland Certificate of Education Chemistry Examination June 2008 © PNEB 200813 b) (i) State two observations that would made when magnesium ribbon is burn in air (2 marks) …………………………………………………………………………………………………………… …………………………………………………………….…………………………………………… …………………… …………………………………………………………………………………… (ii) The product formed in b (i) above is dissolved in water. State whether the solution obtained is acidic or basic. (2marks) ……………………………………………………………………………………………………… ……………………………………………………………………………………………………… ……………………………………………………………………………………………………… (c) One of the air pollutants is sulphur (IV) oxide. State its source and effect. (2marks) …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… TOTAL 10 MARKS 7. (a) A student added dilute sodium hydroxide solution to a white solid M and the solid dissolved. He also added dilute hydrochloric acid to a sample of solid M and it also dissolved. What type of substance is solid M. Explain. (2marks) ……………………………………………………………………………………………………… ……………………………………………………………………………………………………… …………………………………………………………………………………………………….. (b) Name one hydroxide that would dissolve in both dilute sodium hydroxide and aqueous ammonia. (1mark) …………………………………………………………………………………………………….
  • 14. Puntland National Examination Board Secondary School Form Four Examinations Puntland Certificate of Education Chemistry Examination June 2008 © PNEB 200814 (c) When air is bubbled through pure water of pH 7.0, the pH drops to 6.0. explain this observation (2 marks) …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… TOTAL 5 MARKS 8. (a) During an experiment using Zinc powder and dilute HCl of different concentrations, the time required to evolve 100cm3 of the gas for every experiment was recorded. Concentration of HCl 1.5 1.25 1.00 0.75 0.50 0.25 Time (sec) 9.0 10.2 11.4 13 16.5 18 Rate (1 / t) 0.111 0.0878 0.0696 (i) Complete the table (3 marks)
  • 15. Puntland National Examination Board Secondary School Form Four Examinations Puntland Certificate of Education Chemistry Examination June 2008 © PNEB 200815 (ii) On the grid provided below, plot a graph rate (vertical axis) against concentration (horizontal axis). (3 marks)
  • 16. Puntland National Examination Board Secondary School Form Four Examinations Puntland Certificate of Education Chemistry Examination June 2008 © PNEB 200816 (iii) From the graph, determine the concentration needed to produce 100cm3 of Hydrogen when time is 12.0 seconds. (1 mark) …………………………………………………………………………………...... (iv) From your graph, comment on the relationship between rate of reaction and concentration. (2 marks) …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… ………………………………….................................................................................................... (b) A dynamic equilibrium was obtained for the following reaction N2(g) + 3H2(g) 2NH3(g) H = - ve (i) Define the term dynamic equilibrium (1 mark) …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… …………………………………................................................................................................... (ii) How will the yield of ammonia be affected with increase in temperature? Explain your answer. (2 marks) …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… TOTAL 12 MARKS 9. (a) 1.5 grams of pure sodium chloride is dissolved in water to make 250cm3 of solution. Calculate the molarity of the solution. (Na = 23, Cl = 35.4) (3 marks) …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… ……………………………………………………………………………………………………………
  • 17. Puntland National Examination Board Secondary School Form Four Examinations Puntland Certificate of Education Chemistry Examination June 2008 © PNEB 200817 (b) Analysis of a compound gave 92.3% carbon and 7.7% hydrogen. Its relative molecular mass was found to be 78. Calculate its empirical and molecular formula. (C = 12, H = 1) (5 marks) …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… …………………………………………………………………………………………………………… .................................................................................................................................................... .................................................................................................................................................... TOTAL 8 MARKS END