AN INTRODUCTION TOMATERIALS ENGINEERINGAND SCIENCE
AN INTRODUCTION TOMATERIALS ENGINEERINGAND SCIENCEFOR CHEMICAL ANDMATERIALS ENGINEERSBrian S. MitchellDepartment of Chemic...
This book is printed on acid-free paper.Copyright  2004 by John Wiley & Sons, Inc., Hoboken, New Jersey. All rights reser...
To my parents; whose     Material was loam;   Engineering was labor;      Science was lore;And greatest product was love.
CONTENTSPreface                                                 xiAcknowledgments                                         ...
viii         CONTENTS       4.2 Heat Transport Properties of Materials                    316       4.3 Mass Transport Pro...
CONTENTS    ix    Appendix 1:    Energy Values for Single Bonds                                  851    Appendix 2:    Str...
PREFACEThis textbook is intended for use in a one- or two-semester undergraduate course inmaterials science that is primar...
xii       PREFACE                       Metals &       Ceramics &                        Alloys          Glasses          ...
PREFACE      xiiithat incorporate concepts from several chapters, that involve significant informationretrieval or outside ...
ACKNOWLEDGMENTSThe author wishes to thank the many people who have provided thoughtful input tothe content and presentatio...
CHAPTER 1The Structure of Materials1.0    INTRODUCTION AND OBJECTIVESA wealth of information can be obtained by looking at...
2       THE STRUCTURE OF MATERIALS    ž   Calculate the concentration of point defects in solids.    ž   Draw a Burger’s c...
INTRODUCTION AND OBJECTIVES       3                 Table 1.1    Relative Abundance of Elements in the                 Uni...
4       THE STRUCTURE OF MATERIALS1.0.2     Trends in the Periodic TableA closer look at the periodic table points out som...
INTRODUCTION AND OBJECTIVES            5         1                                                                        ...
6Table 1.3        Electronic Structure and Melting Points of the Elements        1                      es = electronic st...
INTRODUCTION AND OBJECTIVES          7the most weakly bound (usually outermost) electron from an isolated gaseous atom    ...
8       THE STRUCTURE OF MATERIALS1.0.2.2 Electron Affinity (EA). Electron affinity is the reverse process to the ioniza-tio...
Table 1.4 Ionization Energies, Electron Affinities, and Electronegativities of the Elementsa               1               ...
10      THE STRUCTURE OF MATERIALSThe excess binding energy, in turn, is related to a measurable quantity, namely thebond ...
INTRODUCTION AND OBJECTIVES      11bond, results when electrons are transferred from the more electropositive atom to them...
12    THE STRUCTURE OF MATERIALSdescribe intermolecular forces and bonding, that the electron cloud does indeed have“struc...
INTRODUCTION AND OBJECTIVES     13bonding is of the same order of magnitude in strength as van der Waals bonding, it canha...
14    THE STRUCTURE OF MATERIALS                  Table 1.6 Values of the Repulsion Exponent                  Noble Gas   ...
INTRODUCTION AND OBJECTIVES         15                                               +                                  Re...
16     THE STRUCTURE OF MATERIALS    The potential energy well concept is an important one, not only for the calculationof...
INTRODUCTION AND OBJECTIVES      171.0.4.1 The Ionic Bond. To form an ionic bond, we must account for the com-plete transf...
18     THE STRUCTURE OF MATERIALSparameters can be grouped to form the constant, a. Recall that by definition the attrac-ti...
INTRODUCTION AND OBJECTIVES    19                 Table 1.7   Typical Values for the Madelung Constant                    ...
20     THE STRUCTURE OF MATERIALS                            Atomic orbitals                              Molecular orbita...
INTRODUCTION AND OBJECTIVES      21                                   s*2p                                           p*2p ...
22     THE STRUCTURE OF MATERIALS                                        Example Problem 1.2 Construct the molecular orbit...
INTRODUCTION AND OBJECTIVES   23                                 A orbitals     AB orbitals          B orbitals           ...
24    THE STRUCTURE OF MATERIALS                            x                               x                             ...
An introduction to materials engineering and science
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An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
An introduction to materials engineering and science
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