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Spectroscopy ( स्पेक्ट्रोस्कोपी ) Chemistry Notes PDF | Hindi English Both Medium | Irfanullah Mehar | UV Spectroscopy | Lambert Beer's Law | Woodwerd Fieser Rule | IR Spectroscopy | NMR Spectroscopy

Spectroscopy ( स्पेक्ट्रोस्कोपी ) Chemistry Notes PDF | Hindi English Both Medium | Irfanullah Mehar | UV Spectroscopy | Lambert Beer's Law | Woodwerd Fieser Rule | IR Spectroscopy | NMR Spectroscopy

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H,c. <br> H,C* <br> CHEMISTRY <br> CH3 <br> LEARN UNDERSTAND EXPLORE <br> bg <br> Compiled by <br> IRFANULLAH MEHAR <br> 9 Pokaran, Jaisalmer (Raj.) <br> @irfanullah_mehar <br> World of Wisdom <br> M irfanullah3119@gmail.com <br> CH, H <br> World of Wisdom <br> CH, <br>
Scan to Join Telegram Channel <br> @WORLDOFWISDOMSS <br> SpechoscopA (agfaf) <br> Spechosco p meane the dspeefon t Lght nto <br> compont autows. n simple woras, & i q methe <br> hos much igt e absobed by <br> ushat Etety <br> to ecswe <br> ahemfcl sub <tance nal at <br> related conten <br> Join Telegram Channel for more <br> Light pases 7hmgh <br> element <br> chuheetetfe spechum. <br> componieut hau a <br> wnique <br>
afs Spectra <br> Ligt <br> Pism <br> Eletromagnetfc Radahfon <br> ald <br> fafao) <br> VI BGYOR <br> R <br> rolet <br> Bue <br> Gmeen <br> Yellou <br> Rec) <br> eloetýc,4 magnetfe Gild EMA <br> E Perperdfeulas/rA <br> 3pespen'eul (90°) a <br> ( <br> ( <br> ( <br>
N <br> EMR <br> electse ield <br> mapnete 'eld <br> Ligkt vedscity <br> ma X. <br> Cathcle Anoole Ras 0R <br> s <br> X <br> X <br> valaty <br> OR <br> Change <br>
Grest (9) <br> Ampi tude <br> d= 1js) 1 <br>
Wave length (d) - <br> ARstance Kgo two <br> cnjugutáve Orest or <br> tough). <br> muimuern mete <br> m, nm, <br> Unit <br> 16X10s m <br> micro meter <br> 10 <br> -)2 <br> 16 m <br> 10m <br> 10 m <br> 9 <br> 10 Cm <br> micvum <br> () - Do, of seuve in wnit leneth <br> 1 m <br> be gcm <br> naw no. <br> t cmer m <br>
ton= DX10 -10 <br> 1 <br> 10 cm Ans <br> d25X10 <br> 10, 000 <br> 2..9 <br> 4000cr} <br> 2 5 X )o cm <br>
warking <br> IR <br> UV, <br> Audio <br> |ero <br> IR <br> Neas <br> Raclio <br> Dave <br> IR <br> Neu Visible <br> Tay|X-Ray Far <br> U,V, <br> sfaes f <br> B00 <br> 200 <br> 100n m <br> EJ, ),dt, V <br> hC <br> d <br> i <br>
Q. <br> NOTE <br> micro mro <br> IR <br> ED)A Light <br> Ligkt <br> U.v. - visible fp <br> (Near U.V.) <br> 200-%00 nm <br> ersee <br> (n cny') <br> merGsane <br> U.v. vaible tuoy <br> Neint-FRlameit <br> Podine lanp <br> Same <br> kyetere <br> Terpeat <br> JaV. 'síble ( Ne U,V.) Regin=200-800nn <br>
IR Regin - <br> Neas <br> Coasti'on: <br> 12500 Cm <br> FRRgi m = <br> Auocsume <br> IR <br> 1) Lam bet- &eess <br> 15em <br> 4000! G66.6 cm! <br> Various eiyts <br> Fas <br> IR <br> )2 5UO50 cm <br> Base T <br> Lou <br> 50 cm <br> U.V. VfarbLe/(U.v. Speatoscopy) <br> 666• 6 cm <br> JJ. sir, <br> wremophe <br> rmsitom <br> Bathoeumic, hypso chume, <br> hyperem'e ¢ hypaesme. <br>
Hadl Que <br> 4) <br> Cmax <br> Calaulati n (dens, poyenee t <br> woodusand- sheh <br> Relalcol Queatlme <br> Lambet beels <br> Menoelemat <br> feb eduton <br> enne cumpun) <br> A ecA <br> Lsepilon <br> rule. <br> uelets <br> fnefolen Ugt) orft (Decrereent) <br> J.J, ír <br> Pass <br> Pass a <br> 9T Comeentratin o Soluti'on ((doy) <br> A <br> l= lenth in Cm <br>
A= &CO) <br> c= ImdLtr <br> 8= mo las ex tintim coehtt dent <br> gotts ) <br> Io <br> Menoeematie Dgut <br> wnit Length <br> Liqt <br> Unit Cnch <br>
Lambe Lauo <br> ongth. <br> LdI <br> de <br> I <br> Baafcaly <br> rtsgatin <br> -lnI <br> =kî <br> b <br> the o <br> Rule à Rulee <br> mixtwe <br> Adlc <br> Bee ambet (au <br> nIo <br> 1 <br> nI-n = Kx <br> =Kc lo20 <br> log <br> 20303 <br>
Ema <br> d max <br> 1-oekx <br> absorbance R <br> i5 eleeénfc traneít'em oROT <br> (r bomdg) (antibondang) <br> orbitil <br> tmeeule <br> bonding <br> Bend brmaten H 0) <br>
Tranaf torm ele bon'ng <br> T -T* <br> n-T--T <br> Fan U.v, SIŠl <br> bonolng <br> -Bond <br> R- Bom <br> Uv. wsiblie <br>
(k- bemd) <br> Lp with o bund) <br> n-T(R- Bamnd) <br> Alkeune,A1kane <br> I4n m <br> 1 <br> bonl <br> I80nm <br> (odhio) <br> f <br>
Cinomopshure <br> (GoIyes) <br> (i) <br> Respomaisle <br> C <br> wnsaturated rp <br> Auxocome <br> (gofes ) <br> tù)Aoche <br> lene pa'r <br> N=N <br> A zo rp <br> NOT <br>
NOTE ) AuXoceme <br> max <br> AuaochUme <br> L Lie paùr <br> max <br> Real sluft <br> Dye <br> Colow <br> Ex <br> Bathochamic htt <br> olow <br> Vaiu shifts <br> a Satuated Cemprunsls <br> Auxocme <br> -H, NH, R-Q-R NH-R, <br> Chnemofheme <br> VIBGYOR <br> Ke <br> bbest <br> ypsocomfc <br> e <br>
dmax 2,54 mm <br> () <br> tbeet <br> subcti tuet <br> e- geleasi ng gps <br> tR,+H,+E <br> +R <br> Cha <br> V <br> 261nm <br> ERG (e eleosing gry) <br> -I <br> , Reasn <br> . <br> S6lvant ) bbeot <br> o=c- Cna <br> Bue elil <br> atthdsauing gn <br>
Ema: <br> (Blue) <br> hypso. <br> o <br> Emay Substituent eot <br> Cmgx <br> Hypencumic <br> Hypo <br> clnnic <br> Ratho. (Red shit) <br> Ean 1) <br> 204 <br> T <br> ma <br> 225 <br>
Al shits n <br> max <br> eat CGonjugation <br> Comjugat'en <br> Homo <br> Moleeuoh osbit <br> Lwmo <br> graph <br> Hypes" <br> cm d. <br> Batho <br> max <br> (Bathoehnác Shat <br> Loet wnoeeupled <br> Moleoular ab <br>
CH, = CH, } 1 T bend <br> Lumo <br> M.o, <br> Hono <br> (cH,= cH-cH= cn) <br> TgI 1,3 butaei'ene' <br> Enengts <br> d=165hm D <br> H oleuble bene <br> + T? , <br>
Lumo <br> 165nm <br> Homo <br> Lumo <br> Homo a <br> 1,3- butane <br> Reason <br> Reeonanee <br> Consugaon <br>
J <br> Dive <br> () Wocel ubetd freses Rule So <br> 1,9,butaci'ene <br> Poyene <br> i) Diene 4 <br> Vole <br> ne foz <br> max <br> dmax <br> Caloulation <br> Payene fos <br> Polyene. <br> Calaula'en <br> t) Panental ) nfuqadlon 0nst'theut ch)Rng <br> ex tend <br> =Bmd Ccbny <br> Rules <br> esiclue <br> duoe <br> aaie ) <br>
(4) Paneutal ae <br> Ch, zChCH=Ch, <br> butad'ene <br> a) <br> Homoannula <br> 1 <br> 2|7+26 =25nm <br> Hrrno yete <br> (,8-butcene) <br> I,3- butacien <br> aun <br> Heteo ahulas <br> 2)9-3 14 <br> Heteo <br> Syctem <br>
NOTE <br> afe <br> 11 <br> Homo <br> (6) Extenoled <br> R ) Conpound Homo ¢ Heteno <br> Homo anula g <br> pPautl walee 25 3 <br> onjugatin <br> Homo H) <br> avtenaled Confugatien <br> Coj <br> ertendco anfugton <br> benn <br>
CH,= CH- cH = H, = CH <br> ) Substi ueut <br> 21T+ 30 = <br> Cn, = ch- Ch= Ch, t cng <br> extenalecd Confugaten <br> +5 <br> 30 <br> (R) <br> le22nm) <br>
Ring <br> Nalen <br> nesfelue <br> (,3, butaiene) <br> 953+ 10 <br> 5X2 <br> +5 <br> 263 <br> 9 Exocyclfe alauble bond <br> Sxo yole clouble bona <br> Hetero <br> 214 +g0 = (234 <br> giten <br> L <br> e <br> 54 <br> Cpen <br>
Exampes <br> (D) <br> (m) <br> stem <br> Ero <br> ar dlousle bond aa| <br> Exo) <br> K <br> Exoyelc double bnd for <br> n-Ring <br> exo kor -c <br>
(iv) <br> () <br> (vi) <br> &xo <br> extended <br> B <br> ) Paentad Walue <br> Enoycfe doubl bonel <br> ero ycl'e dukle bond <br> Sumnay <br> Gxo <br> d ohbio bond <br> Aeyclfe <br> 30 <br> 1e totul 10 Add <br> Hmo = 213 136 253 <br> y eteo 219-3 2/4 <br>
() <br> dmax <br> (îm) <br> Caleuation b <br> CH, = C- Ch = CH2 <br> Jso prene <br> 214 t 5 = (22 m) <br> ystem <br> 2X30 <br> extended <br> (244 nm) <br> Cn= Ch- CH =Cn, <br> Gx tende <br> Conjgatin <br>
(a) <br> u) <br> &Xs) SI <br> hio <br> ho <br> uu 9 <br>
(i) <br> (i) <br> Hmo <br> &x tendesl <br> 3 <br> ex teno <br> R <br> 253 <br> 30 <br> 5 <br> 5 <br> 303mm <br> 263 <br> (919+36 ) <br> R <br> I3- butadiee <br> extenelel camu. <br> 303nm <br> R <br>
Ho <br> Sytendd <br> exlonde <br> 253 <br> 5 <br> 343 <br> Exo <br> Homo = <br> 253 <br> t, <br> 5 <br> 243 <br> fasak extanaled <br> ertende <br>
(xi) <br> (xim) <br> (xiv) <br> 8 <br> R <br> Hete <br> 4r <br> 20 <br> 244 <br> 214+ 10 =22+ <br> Tr. <br> cu <br> 217 <br> Exo <br> 237 <br> Eyo <br>
(Kv) <br> (xvi) <br> 2022 <br> (x) <br> R <br> |0 + IO + 2 23 <br> Homo -2B9 <br> Sxt 30 <br> (A) <br> (B) 343 <br> (C) <br> 300 <br> (D) <br> 33% <br> 333 <br> S 313 nm <br>
(x vin) <br> Exo <br> R <br> Paental Value = Humo <br> 2 xtenaleol <br> Hemo = 233 <br> 2 2 <br> 3 Ero = <br> 25 <br> 253 <br> 393 <br> 60 <br> i243 <br> Aus-B| <br> 5 <br>
(ii) aloo dusanel bies e lauo (r <br> Cn <br> Ch, CH CH à <br> extended <br> Conjugatlon <br> rstem <br> eneQ <br> - Bnsctuated <br> Cabenye <br> 5 membee) <br>
Rules <br> (99 Paretat Value <br> Tck <br> A <br> (c) <br> (1)d- B nsatwhated Keton= 15 <br> (15 72) <br> 1st <br> (3) rtene Value= <br> LS)-B unsctuated He,s2 keten <br> Aono aunnulu = 439 <br> double bene <br> (3 buaal'ene) <br> 30 <br> J <br> (36 +3) <br> 5 membe <br> d- B <br> unsatted <br> 202 <br> Heted annuly <br>
(ir) R ro <br> () <br> (i) <br> oslu 2025 <br> 215 <br> 207 <br> 1 m o <br> Hetr = <br> R tr <br> +6 membe <br> +5 <br> Sumnu <br> 5 <br> En@on <br> Ketn <br> Ald. <br> 36+3 39 <br> B <br> 12 <br> oe35 <br> 35 <br> 30 <br> Rules <br> B=36 <br> 5 membey <br> Ald., Ketm <br>
Iinnples <br> R <br> Parentad Velus <br> 2 <br> Ayolle keton 215 <br> B 2X12 <br> Y <br> > 24 <br> 29 9 <br>
NOTE <br> (i) <br> Paentat Value l6 memb) F <br> Po V. <br> &rienle <br> R (B) <br> Homeennuley <br> 12 <br> 18 <br> 30 <br> Exo <br> 215 <br> |2. <br> 12 <br> 239 <br> Humotunula <br> extended <br>
Civ) <br> Panental Wale = <br> (v) <br> ex+ <br> .Homo <br> OH <br> Cxo+ xtended <br> 215 <br> 0 <br> 12 <br> 45 <br> 30 <br> 39 <br> 359 <br> aH <br> PV 20 2 <br> 35 <br> r2 <br> (5 menb <br>
(vi) <br> (vii) <br> CH Cn C- H <br> Al <br> d(rr) <br> &() <br> Extende <br> Btedee <br> 245 <br> 39 <br> PV= 204 <br> Sxteuded = 30 <br> 973 <br>
(vin) <br> HO <br> tuutmem <br> &xeum <br> 1 <br> ho <br> pu 2|5 <br> on(p) 30 <br> (m) <br> tutomeuy <br>
Q.y <br> ob tmax <br> K -bund <br> gmmehy allowad <br> E ordeh <br> h <br> R- band <br> B: Syn-torbid <br> - - <br>
S6lvent <br> K-bend <br> Bethochumíc <br> dmax <br> Po laty <br> bsate <br> »140) <br> R-bun <br> A- band <br> (n) <br> ypeachsoýe <br> shitt <br> Pala' <br> weete, <br>
k- ban <br> (T-T*) <br> - (Batho) <br> Nompolas <br> hexane) <br> Solveud <br> Polaty <br> Pda lusates) <br> Eneg <br> Buthocumfc sit <br> (nT) <br> R- bnd <br> (h *) <br> (hypeo) <br> Pole <br> E <br> dmax SAT <br>
Q.6 Anilene o U.Vo Pealk 230 ¢ 230 <br> Q.7 <br> (R-bond) <br> -I <br> HCI <br> C rematle ) <br> but <br> Nam <br> NH <br> I^ An leniun ien <br> Nao sio 235 <br> So <br> nm <br> duui <br> t <br> (3athoni <br> dmax1 <br>
Ex <br> U.V. <br> SpectroscoRY <br> Trans Cmax <br> Doansitiorn <br> So d <br> my X <br> gemetcad iimeu <br> max Gis <br> h00c <br> temen <br> (Trcm) <br> (mne polane) <br>
Aue <br> UiN. Spehoscopy <br> laut mesm <br> ene form <br> Eman <br> Applcaton s <br> (S) Suetue <br> keto-enol <br> Iautomeim <br> Geometrteal gsomerutm <br> (stabi t <br> Dousle bnd Unsatuhatead ) -e)s <br> elues'olation <br> U.V. Sphoscuy <br>
Queshim <br> Q.10 <br> boused on <br> A= Ecl, I <br> To <br> A <br> beey- lumbeds <br> (aaa) <br> inteusty reklavt sadation <br> Caleuate abeorbanae (A), % anmilfanee <br> Trantnittunee(HHA <br> 3 <br> Log <br> 0.22) <br>
2 O3 <br> 3 ooy <br> f <br> B0 <br> I2 80 $7 0 <br> I, <br> 56 <br>
IR <br> Regten <br> R Spactocy Region. <br> Z8- Spefroscopy <br> IR <br> 12500Tm - 50 Um <br> 66cm <br> (2 5 - 15 ee m) <br> Vf brat' m l trnsi Hn <br> IR Actine molecule <br> noment (u) brah'en <br>
() Hom o l'atome meleule alusays <br> ireetve <br> be ele <br> Center <br> (m) moleoule a <br> vibraion <br> IR <br> e xd <br> (Par <br> E) <br> istnee <br> et <br> clugesp <br>
NNg N, <br> (c) <br> + <br> Lone par s6 areet'on <br> (a) <br> (Lene pawr) <br> (Po las molecule ) <br> (b) <br> (tve <br> mone <br> to <br> (4) <br> -ve) <br> +uat meoune <br> CessEN <br> elechyengae <br> Palas <br> ( chem) <br> FF <br> melecle <br>
Ex- (a) BeCl, <br> A <br> Cl ße-c) <br> 180 <br> fRan ancel <br> (d) pCls <br> Reculkugt <br> ,(33BE, <br> 3. <br> ZerO <br> abseut et) u <br> B <br> hen-pSlos <br> 120F <br> (agt) <br> F 6) Resulfut <br>
(m) <br> (e) SF <br> () <br> () co, <br> CO,, CaH CHy <br> ( Veu) <br> S <br> ) <br> F. <br> F <br> IR cLet've <br> hymmette Strethg (*nfan) <br> but iu Amete <br> stne'n <br> BL <br> Bl,G <br>
Mode <br> Moleele <br> Fandamental <br> bondls <br> vibratiem <br> Bonl Legth <br> IR. <br> A° <br> Bondy <br> meleeuts bathen <br> tem <br> OR <br> atem) band <br> Bond stetch <br> wbraten <br> poy <br> frequeny <br> mode <br> Moleeulal <br> wbration <br>
Shretcing <br> (ada) <br> Bond auge gme <br> Bored lenh <br> Aspmetbic <br> Ex- C02 <br> Chy, <br> nplone <br> BK0) IRacie <br> Bond Cegth <br> atom plane <br> (Batagi1) <br> (s) <br> BA. <br> Bendi'ng <br> (s) <br> lo <br> &awe. <br> Out Plare <br> Roking <br> e <br> Axis Raped <br>
tne <br> -W, +ve <br> Out o Plave <br> (%1ncin) <br> Ais Respeat <br> e <br> +ve <br> ve <br>
str <br> bonding, <br> tge plut Reqion <br> (79r120)) <br> Regim <br> egrer Feedom .no. lrabton <br> (cnty <br> alusys.(3N)Tranaitlont + Vibratind <br> Rottinal mody <br>
vi bratin <br> Monoatumíc <br> no, <br> hmatnal soltion <br> aluy <br> mode <br> Xyz uis <br> vib. <br> Lfnea <br> artonle + <br> (Rolyatomte Uheay <br> 31- (242) <br> 2N- y <br> (aN-32 <br> mode <br> Lineh= 2 <br> Nom-neas - 3 <br> rot, <br> Non-Uey <br> 3N- (313) <br> Bed <br> 2M-5 <br>
Q.2 Qlaulate <br> Aue <br> tur (a) He <br> i)D.f. <br> (im) Shreteng msde (N-1) <br> (iv) Bendig moce <br> 3N gi 3) <br> (i) He Monoeutoonfc <br> Toaaitional <br> (b) <br> (b) H) <br> 3N = 3X2= 6 <br> Mode. V. <br> JN-3 <br> =3-3 <br> He! <br> Vibmod <br> BN-5 <br> 6-5-1 <br> (3N) <br> (c) Co, lajns0) (e)NI <br> Shrddlig <br> (N= 2) Ditunf <br> |-)0 <br> N-) <br> |N=1) <br> Shrelelng <br> 2-) <br> (mon) <br> aly <br> , <br> 2N-4 <br>
(c) <br> 3X3=9 <br> 3N= <br> Pelyatamfe <br> vib. <br> ( N=3) <br> SN-5 <br> 3X3-5-4 <br> BN-6. <br> G'hèas <br> 9-6 3 <br> (à) ,0 Poy atonic t Non Gheas) <br> N-1. <br> R acHve <br> Lyaá00 cm <br> Sretchig <br> 3-12 <br> IR <br> active <br> 2 N)-5 <br> 6-53) <br>
3N 3X =l2 <br> Vib <br> - 3N-6 <br> 6y atomfe d Norn inear <br> Sheteling <br> Telegram Channel Join Karein Aur PDFs <br> Download Karein <br> Scan to Join Telegram Channel <br> @WORLDOFWISDOMSS <br> 2N-5 <br> B-53 <br>
Uinton <br> Hook's lao <br> Stmp haumrufe oscilato <br> Rule <br> Brf1 nd ange <br> Chave <br> Furce Consjant <br> applfeake <br> Benaegtu <br> lamutilon <br> veduee <br> d <br>
Fqyny <br> Ulaneiuum be <br> () C -4 <br> Squae <br> 8000 Cm <br> C <br> C <br> 21TC <br> k <br> 250O cm <br> ( <br> N <br> c- <br> 2300 ~3000 ( <br>
NOTE <br> (im) 0-H <br> IR °Material (S Suetune ald <br> b)) <br> kBa <br> rmx fôyT <br> Reason - Optfeaty tranapeont R <br>
unetiona P <br> Regin <br> asition o TR Bounde 4000 - 666 ~'66chy <br> H000- 1300 cm- l00 <br> Shetchig band <br> Sume <br> etandeo <br> () R-U. <br> NOTE) CGmpaun vE) Ad9 <br> sithouh. H-bnd <br> (Pwve t Cmeh) <br> hahp. <br> 3650 ~35y cm <br> (n 350) <br>
Aldywale <br> Ketuve <br> (Aciel helde) <br> (b20 <br> Acdy <br> Reaetivity <br> Amine <br> cD) <br> ores eoTi <br> 3550m <br> (R-Nn,) <br> 1950 <br> Aetme 20 <br> nsem <br> 1730 ~|750 <br> T0-)20 <br> Reaativity orden <br> estea) Arnde <br> (R-C- 6R <br> 150 <br> 6B0 <br> Nopoak <br>
3300 <br> D022 <br> NOTwo peaks <br> G9 Gs - Al kene <br> Trons,- Al<ee <br> 1 <br> 9 50-em <br> IR <br> 16504. Bome <br> 2000- 3006m <br> 6) Pesd< <br> (RsD) <br>
Q. J5 <br> ) 2000 <br> ) 33O b <br> (B) Add.hede() enhy dsubl <br>
: <br> 5 0O <br> Fleetrms <br> IR <br> Faator Aetng TR Froqueny <br> 330D <br> Resson- MOT Co <br> D <br> (Aue- A <br> Blectrons withdalggep (-,R) <br> eleotrn TDJ) 2 B01, K1, D <br>
Ph <br> 1720 <br> +I <br> Mose ele <br> = 1930 <br> Ph <br> 1-00 <br> 3>|)2 <br> J20 <br> +1 <br> 1700 <br> I9 60 <br> Usele <br> ph ph <br> 1930 <br> +R <br> 16%0 <br> 3>)2 <br>
lcoun 13o cm <br> C <br> 115-1720 <br> S07. <br> o- PhPh <br> +m <br> denei <br> ph <br> 4m 3 dut <br> bend <br> 100 <br>
Angle <br> 4220 <br> eet Rng <br> 6 membeeal ng Avoe <br> Marimum <br> No <br> factrs. <br> 1720 <br> shrun <br> stren <br> Bond Angle <br> 150 <br> Srai <br> 3 memsered <br> 17%0 <br> 1825 m <br> kactor ver elecuc <br>
Hydagen -bond' <br> () Due to <br> Jadenoleoulas <br> On bond - <br> wthet H-bond <br> Cen <br> n- Bomd GH,NH shelcbhg <br> ¢ H , <br> stretcnin <br> Ttecmleeulo <br> (Puse t Cone) <br> 3360 <br> Sol Et h-bon <br> onpity Bteumele oulas <br>
NO7 E Tatra moleculas H- bond lilutien <br> R1 <br> NNo seat. <br> fielad etteet <br> tp-tp Reputin - <br> H <br> X <br> b) <br>
Non <br> (9) <br> IR <br> Repulain <br> distingui's <br> (1) Ch, - <br> h <br> Aceto acette kste <br> (Keto omm <br> Kettn 1320 <br> -ns <br> 7 <br> ( Speetra Peak s, but. didigin <br> Ph <br> (4) <br> l675 <br> lc=cGheci <br>
(b) <br> {q)c=6 oeak (1) 192,0 <br> Peak X <br> +R <br> (a)àN peadk <br> (B4 GD-3600) <br> (b)e0l686 <br> H <br> C <br> CH <br> +R eny <br> 11 <br> Comgiugationàle <br> 1680 <br>
+H <br> Nn <br> +R <br> I <br> keten <br> (1720) <br> cotHa <br> -R <br> +R <br> -I <br> (1750) <br>
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