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SmartLi - Smart Technologies for the
Conversion of Industrial Lignins into
Sustainable Materials
SmartLi FACTSHEET, JANUARY 2016
Solution Architect for Global
Bioeconomy & Cleantech Opportunities
There is a demand for renewable biochemicals, materials and fuels as more sustainable
and renewable alternatives. Lignin as a phenolic polymer could provide a valuable
renewable aromatic resource for the chemical industry to replace the synthetic
aromatics, or other biomaterials. Thus, development of economically and sustainably
viable lignin upgrading process technologies is urgent.
The SmartLi project has the following aims:
•	 add value to underexploited biomass side stream lignin
•	 provide homogenous raw materials for bio-based industries
•	 lower the need for oil-based raw materials in the production of materials
	 and chemicals
•	 enhance sustainable processing e.g. by reducing GHG emissions
The primary objective of SmartLi is to develop valorization routes for lignin aiming
at materials that have potential to replace oil-based products. Both the kraft lignin
and lignosulphonates will be studied as potential raw materials. The target products
are composite materials and resins utilizing both the polymeric lignin and smaller
molecular aromatic mixtures. Lignin will be also utilized as a functional additive in
composites and plastics. The whole value chain from lignin raw materials to the final
products is covered by the involvement of pulp mills, machine producers as well as
resin and composite manufacturers.
LIGNIN
PULP MILLLIFE CYCLE
ANALYSIS
VALUE CHAIN
BIOBASED
MATERIALS
RENEWABLE
BIOCHEMICALS
SULPHUR
REMOVAL
PRETREATMENT
DEPOLYMERIZATION
MEMBRANE
SEPARATION
LIGNIN
ACTIVATION
PLASTIZATION
CONSTANT
QUALITY
COMPOSITES
PF RESINS
POLYURETHANE FOAMS
EPOXY SYSTEMS
For more information, please contact
Christine Hagström-Näsi
Mob +358 50 3222 401
Email christine.hagstrom-nasi@clicinnovation.fi
CLIC Innovation Ltd, P.O.Box 10
FI-00130 Helsinki, FINLAND
The chair material, manufactured by Formica
Group, contains Absorbex Kraft Paper
which is treated with thermosetting resins
(www.kotkamills.com). The resins could be
manufactured from lignin-derived materials.
The composites structure of the Punch One
car (www.solarteam.be) contains a 95%
bio-based CNSL resin developed by AEP
and produced by Cardolite. Lignin-derived
materials could be used instead.
This project started 1.7.2015 and runs until 30.6.2018.
This project has received funding
from the Bio-Based Industries Joint
Undertaking under the European
Union’s Horizon 2020 research and
innovation programme under grant
agreement No 668467.
AudioQuest NightHawk headphones
exhibit many groundbreaking components,
including sophisticated earcups developed
in collaboration with the German firm
TECNARO GmbH, using ARBOFORM®, or
“Liquid Wood”. (www.tecnaro.de).
About CLIC Innovation Ltd
The SmartLi consortium is managed by
CLIC Innovation Ltd. CLIC Innovation
is an open innovation cluster with the
mission of creating breakthrough solutions
in bioeconomy, energy and cleantech.
CLIC Innovation coordinates R&D&I
project portfolios to construct systemic
solutions which are beyond the resources
of individual operators. The cluster is a
cross-organizational fast-moving network.
The shareholders of the nonprofit CLIC
Innovation Ltd include 30 companies and
17 universities and research institutions.
www.clicinnovation.fi
SmartLi – PROJECT IDEA
Solution Architect for Global
Bioeconomy & Cleantech Opportunities
WP 1: Lignin pretreatmens for improved and
constant quality
The WP aims to develop separation and
purification technologies for selected wood
lignin sources that preserve the polymeric
character of lignin, but lower significantly
its sulphur content and odour. Another
important task is to develop protocols for the
production of lignin with constant quality and
provide it as starting material to downstream
processing. The selected pretreatments will
be upscaled for the delivery of adequate
amounts of lignin to other work packages.
WP 2: Generation of lignin-based building
blocks
The key objective is to develop lignin
depolymerisation techniques based on
base-catalysed degradation. Also separation
concepts and technologies as post
treatments for the depolymerisation will be
looked. Furthermore, the production of lignin
fractions will be upscaled for application
testing.
The project has
the following work
packages (WP)
WP 3: Lignin based polyols and biobased
materials
The WP aims to develop ways to convert
lignin for various applications such as a)
into thermoplastic and moldable biopolymer
for composite applications, b) to use
pretreated lignin fractions as reinforcing
fillers, plasticizers or flame retardants in
composites, c) to use lignin oligomers by
chemical modification for polyurethane and
epoxy resin applications, e) to replace phenol
in phenol-formaldehyde (PF) resins.
WP 4: Life cycle assessment and techno-
economic performance
The WP performs a multi-criteria evaluation
of the sustainability of the entire value chains
- the novel process technologies and lignin
based products. The approach takes into
account environmental, economic and social
aspects. The WP covers the most promising
technologies and evaluate their potential
from wide sustainability perspectives.
Additionally, WP 5 deals with the
administratinon of the project and innovation
management.
Participating organisations
The SmartLi consortium consists of 13
organisations: Tecnaro Gesellschaft zur
Industriellen Anwendung Nachwachsender
Rohstoffe Mbh / Germany, AEP Polymers
Srl / Italy, Fraunhofer Gesellschaft zur
Forderung der Angewandten Forschung EV /
Germany, VITO De Vlaamse Instelling Voor
Technologisch Onderzoek N.V / Belgium,
Metsä Fibre Oy / Finland, Teknologian
Tutkimuskeskus VTT Oy / Finland, Sappi
Netherlands Services B.V. / the Netherlands,
Foresa Industrias Quimicas Del Noroeste Sa /
Spain, WOOD K Plus Kompetenzzentrum
Holz GmbH / Austria, Prefere Resins
Finland Oy / Finland, Kotkamills Oy / Finland,
Andritz Oy / Finland, CLIC Innovation Oy /
Finland
* Not studied in SmartLi
Kraft
mill*
Black
liquor*
Kraft
lignin re-
covery*
Sulphite
mill*
Spent
liquor*
Lignosul-
phonate
recovery
PRETREATMENTS
FOR BETTER AND
CONSTANT QUALITY
BCD
Membrane
filtration
Activation
EPOXY
RESINS
PU
RESINS
PF
RESINS
M
ono
/ oligo
fractions
Filler
Plasticiser
Fractionstoresins
DEGRADATION AND
FRACTIONATION
CONVERSION TO
BIOMATERIALS
FUNCTION OF LIGNIN
IN THE BIOMATERIAL
COMPOSITES
Matrix
component
Internal
platicisation
•	 Thermoplastic componet
•	Plasticiser
•	 Fire retardant
•	 Resols and LPF resins for
	 plywood, impregnation resins,
	 MDF panelboards, automotive
	 composites, foundry, rockwool
	 and abrasive resins
•	 Polyols for rigid
	 and flexible PU foams
•	 Crosslinkers for fiber
	 reinforced epoxy composites
	 and coatings
PRETREATMENT 1
PRETREATMENT
PRETREATMENT
PRETREATMENT
2
3
4

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SmartLi factsheet

  • 1. SmartLi - Smart Technologies for the Conversion of Industrial Lignins into Sustainable Materials SmartLi FACTSHEET, JANUARY 2016 Solution Architect for Global Bioeconomy & Cleantech Opportunities There is a demand for renewable biochemicals, materials and fuels as more sustainable and renewable alternatives. Lignin as a phenolic polymer could provide a valuable renewable aromatic resource for the chemical industry to replace the synthetic aromatics, or other biomaterials. Thus, development of economically and sustainably viable lignin upgrading process technologies is urgent. The SmartLi project has the following aims: • add value to underexploited biomass side stream lignin • provide homogenous raw materials for bio-based industries • lower the need for oil-based raw materials in the production of materials and chemicals • enhance sustainable processing e.g. by reducing GHG emissions The primary objective of SmartLi is to develop valorization routes for lignin aiming at materials that have potential to replace oil-based products. Both the kraft lignin and lignosulphonates will be studied as potential raw materials. The target products are composite materials and resins utilizing both the polymeric lignin and smaller molecular aromatic mixtures. Lignin will be also utilized as a functional additive in composites and plastics. The whole value chain from lignin raw materials to the final products is covered by the involvement of pulp mills, machine producers as well as resin and composite manufacturers. LIGNIN PULP MILLLIFE CYCLE ANALYSIS VALUE CHAIN BIOBASED MATERIALS RENEWABLE BIOCHEMICALS SULPHUR REMOVAL PRETREATMENT DEPOLYMERIZATION MEMBRANE SEPARATION LIGNIN ACTIVATION PLASTIZATION CONSTANT QUALITY COMPOSITES PF RESINS POLYURETHANE FOAMS EPOXY SYSTEMS For more information, please contact Christine Hagström-Näsi Mob +358 50 3222 401 Email christine.hagstrom-nasi@clicinnovation.fi CLIC Innovation Ltd, P.O.Box 10 FI-00130 Helsinki, FINLAND The chair material, manufactured by Formica Group, contains Absorbex Kraft Paper which is treated with thermosetting resins (www.kotkamills.com). The resins could be manufactured from lignin-derived materials. The composites structure of the Punch One car (www.solarteam.be) contains a 95% bio-based CNSL resin developed by AEP and produced by Cardolite. Lignin-derived materials could be used instead. This project started 1.7.2015 and runs until 30.6.2018. This project has received funding from the Bio-Based Industries Joint Undertaking under the European Union’s Horizon 2020 research and innovation programme under grant agreement No 668467. AudioQuest NightHawk headphones exhibit many groundbreaking components, including sophisticated earcups developed in collaboration with the German firm TECNARO GmbH, using ARBOFORM®, or “Liquid Wood”. (www.tecnaro.de).
  • 2. About CLIC Innovation Ltd The SmartLi consortium is managed by CLIC Innovation Ltd. CLIC Innovation is an open innovation cluster with the mission of creating breakthrough solutions in bioeconomy, energy and cleantech. CLIC Innovation coordinates R&D&I project portfolios to construct systemic solutions which are beyond the resources of individual operators. The cluster is a cross-organizational fast-moving network. The shareholders of the nonprofit CLIC Innovation Ltd include 30 companies and 17 universities and research institutions. www.clicinnovation.fi SmartLi – PROJECT IDEA Solution Architect for Global Bioeconomy & Cleantech Opportunities WP 1: Lignin pretreatmens for improved and constant quality The WP aims to develop separation and purification technologies for selected wood lignin sources that preserve the polymeric character of lignin, but lower significantly its sulphur content and odour. Another important task is to develop protocols for the production of lignin with constant quality and provide it as starting material to downstream processing. The selected pretreatments will be upscaled for the delivery of adequate amounts of lignin to other work packages. WP 2: Generation of lignin-based building blocks The key objective is to develop lignin depolymerisation techniques based on base-catalysed degradation. Also separation concepts and technologies as post treatments for the depolymerisation will be looked. Furthermore, the production of lignin fractions will be upscaled for application testing. The project has the following work packages (WP) WP 3: Lignin based polyols and biobased materials The WP aims to develop ways to convert lignin for various applications such as a) into thermoplastic and moldable biopolymer for composite applications, b) to use pretreated lignin fractions as reinforcing fillers, plasticizers or flame retardants in composites, c) to use lignin oligomers by chemical modification for polyurethane and epoxy resin applications, e) to replace phenol in phenol-formaldehyde (PF) resins. WP 4: Life cycle assessment and techno- economic performance The WP performs a multi-criteria evaluation of the sustainability of the entire value chains - the novel process technologies and lignin based products. The approach takes into account environmental, economic and social aspects. The WP covers the most promising technologies and evaluate their potential from wide sustainability perspectives. Additionally, WP 5 deals with the administratinon of the project and innovation management. Participating organisations The SmartLi consortium consists of 13 organisations: Tecnaro Gesellschaft zur Industriellen Anwendung Nachwachsender Rohstoffe Mbh / Germany, AEP Polymers Srl / Italy, Fraunhofer Gesellschaft zur Forderung der Angewandten Forschung EV / Germany, VITO De Vlaamse Instelling Voor Technologisch Onderzoek N.V / Belgium, Metsä Fibre Oy / Finland, Teknologian Tutkimuskeskus VTT Oy / Finland, Sappi Netherlands Services B.V. / the Netherlands, Foresa Industrias Quimicas Del Noroeste Sa / Spain, WOOD K Plus Kompetenzzentrum Holz GmbH / Austria, Prefere Resins Finland Oy / Finland, Kotkamills Oy / Finland, Andritz Oy / Finland, CLIC Innovation Oy / Finland * Not studied in SmartLi Kraft mill* Black liquor* Kraft lignin re- covery* Sulphite mill* Spent liquor* Lignosul- phonate recovery PRETREATMENTS FOR BETTER AND CONSTANT QUALITY BCD Membrane filtration Activation EPOXY RESINS PU RESINS PF RESINS M ono / oligo fractions Filler Plasticiser Fractionstoresins DEGRADATION AND FRACTIONATION CONVERSION TO BIOMATERIALS FUNCTION OF LIGNIN IN THE BIOMATERIAL COMPOSITES Matrix component Internal platicisation • Thermoplastic componet • Plasticiser • Fire retardant • Resols and LPF resins for plywood, impregnation resins, MDF panelboards, automotive composites, foundry, rockwool and abrasive resins • Polyols for rigid and flexible PU foams • Crosslinkers for fiber reinforced epoxy composites and coatings PRETREATMENT 1 PRETREATMENT PRETREATMENT PRETREATMENT 2 3 4