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1
Griltex Hotmelts
for Composites
www.emsgriltech.com
2
Content
Page
Griltex Hotmelts for:
Reinforcement of UD-tapes, knitted,
woven and multiply fabrics 3
Thermoplastic Composites 10
3
Reinforcement of UD-tapes and fabrics
Especially designed High Performance Polymers
for applications in Composites
made from epoxi-resins and
- Carbon fibers
- Mineral fibers (Glass, Basalt)
- Polymer fibers (Kevlar, Aramide)
- Natural fibers
4
Properties
Stabilising of unidirectional filaments
multiply, woven and knitted fabrics
nonwovens
⇒ Better and easier handling
⇒ Antifray
⇒ Gluing of multiple layers to one component
⇒ Production of preforms without additional auxiliaries
5
Mechanical Benefits CAI
High positive influence on impact
CAI values rise by 65% - Delamination areas decrease by 85%
18g/m2
Griltex, RTM 6; Testmethod: AITM 1.0010
CAI
0
50
100
150
200
250
300
Reference D 2433E D 2351E D 2419E
MPa
Delamination area
0
1000
2000
3000
4000
5000
6000
7000
Reference D 2433E D 2351E D 2419E
mm2
6
Mechanical Benefits Peeling Force
Polymers are insoluble in Epoxi resin
⇒ Maintain the Tg of Epoxi-matrix
High peeling forces between Griltex High Performance
Polymers and epoxi-resins
⇒ Maintain adhesion from Epoximatrix to fibers.
Bisphenol-A and amine hardener cured at RT on a Griltex polymer film over 16 h
Peel Strength
0
20
40
60
80
100
120
140
160
D 2433E D 2351E D 2419E Standard
CoPES
Flexible
CoPES
Standard
CoPA
PA12 EVA PE
[N/5cm]
7
Mechanical Benefit ILSS
ILSS-values increase up to 36%
18g/m2
Griltex; RTM 6;
Test method: ASTM D2344M;
Values at 120°C in preparation
ILSS - Test
0
10
20
30
40
50
60
70
80
Reference D 2433E D 2351E D 2419E
MPa
23°C 80°C
8
Technical Data
Griltex Polymer
D 2433E D 2351E D 2419E
Melting range* °C 98-107 95-103 130-140
Glass Transition
temperature*
°C 18 18 17
Melt viscosity**
(160°C/2.16Kg)
Pas 450 226 330
Melt volume rate**
(160°C/2.16Kg)
cm3/10' 23 48 32
Density*** g/cm3 1.31 1.31 1.31
* DSC
** ISO 1133
*** ISO 1183
9
Application Techniques
→ Hotmelt lamination
→ Powder scattering
→ Powderdot, Pastedot
→ Meltblown
→ Webs
Suitable for all standard application techniques :
Meltblown hotmelt by standard
spray head.
10
Thermoplastic Composites
Matrix material by EMS high performance polymers
→ Easy to handle
→ Short cycle times
→ Reformable by temperature
Applications
→ Orthoses
→ Guards
→ Sports equipment
→ Organosheets
11
Technical Data
Griltex Polymer
2A D 1428A
Melting range* °C 120-130 175-180
Glass Transition
temperature*
°C 15 45
Melt viscosity**
(°C/2.16Kg)
Pas
560
@160°C
180
@ 230°C
Melt volume rate**
(°C/2.16Kg)
cm3/10'
18
@160°C
50
@ 230°C
Density*** g/cm3 1.02 1.01
Use Matrix
Matrix
Surface
Availability
Granules
Powder
Suspension
Granules
Powder
* DSC
** ISO 1133
*** ISO 1183
12
EMS-GRILTECH worldwide
www.emsgriltech.com
info@emsgriltech.com
Europe Americas
EMS-CHEMIE AG EMS-CHEMIE AG (North America) Inc.
Business Unit EMS-GRILTECH Business Unit EMS-GRILTECH
Via Innovativa 1 2060 Corporate Way
CH-7013 Domat/Ems P.O. Box 1717
Phone: +41 81 632 72 02 Sumter, SC 29151-1717, USA
Fax: +41 81 632 74 02 Toll free: +1 877 367 83 23
E-mail: info@emsgriltech.com Phone: +1 803 481 61 90
Fax: +1 803 481 61 29
E-mail: info@us.emsgriltech.com
Asia Japan
EMS-CHEMIE AG (Asia) Ltd. EMS-CHEMIE AG (Japan) Ltd.
Business Unit EMS-GRILTECH Business Unit EMS-GRILTECH
36, Kwang Fu South Road Osaka Office, Umeda Shinmichi Bldg.
Hsin Chu Industrial Park 1-1-5, Dojima, Kita-ku
Fu Kou Hsiang, Hsin Chu Hsien Osaka 530-0003, Japan
Taiwang, R.O.C. Phone: +81 6 6348 1655
Phone: +886 35 983 335 Fax: +81 6 6348 1702
Fax: +886 35 985 731 E-mail: info@jp.emsgriltech.com
E-mail: info@tw.emsgriltech.com
Issued by: Technical Service Coatings + Additives
EMS-CHEMIE AG business unit EMS-GRILTECH
Date: March 2012
Copyright: All rights reserved to EMS-CHEMIE AG.
Any unauthorized copying and publishing is forbidden
GRILTEX is a registered trademark of EMS-CHEMIE AG

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EMS Griltex hotmelts for composites

  • 2. 2 Content Page Griltex Hotmelts for: Reinforcement of UD-tapes, knitted, woven and multiply fabrics 3 Thermoplastic Composites 10
  • 3. 3 Reinforcement of UD-tapes and fabrics Especially designed High Performance Polymers for applications in Composites made from epoxi-resins and - Carbon fibers - Mineral fibers (Glass, Basalt) - Polymer fibers (Kevlar, Aramide) - Natural fibers
  • 4. 4 Properties Stabilising of unidirectional filaments multiply, woven and knitted fabrics nonwovens ⇒ Better and easier handling ⇒ Antifray ⇒ Gluing of multiple layers to one component ⇒ Production of preforms without additional auxiliaries
  • 5. 5 Mechanical Benefits CAI High positive influence on impact CAI values rise by 65% - Delamination areas decrease by 85% 18g/m2 Griltex, RTM 6; Testmethod: AITM 1.0010 CAI 0 50 100 150 200 250 300 Reference D 2433E D 2351E D 2419E MPa Delamination area 0 1000 2000 3000 4000 5000 6000 7000 Reference D 2433E D 2351E D 2419E mm2
  • 6. 6 Mechanical Benefits Peeling Force Polymers are insoluble in Epoxi resin ⇒ Maintain the Tg of Epoxi-matrix High peeling forces between Griltex High Performance Polymers and epoxi-resins ⇒ Maintain adhesion from Epoximatrix to fibers. Bisphenol-A and amine hardener cured at RT on a Griltex polymer film over 16 h Peel Strength 0 20 40 60 80 100 120 140 160 D 2433E D 2351E D 2419E Standard CoPES Flexible CoPES Standard CoPA PA12 EVA PE [N/5cm]
  • 7. 7 Mechanical Benefit ILSS ILSS-values increase up to 36% 18g/m2 Griltex; RTM 6; Test method: ASTM D2344M; Values at 120°C in preparation ILSS - Test 0 10 20 30 40 50 60 70 80 Reference D 2433E D 2351E D 2419E MPa 23°C 80°C
  • 8. 8 Technical Data Griltex Polymer D 2433E D 2351E D 2419E Melting range* °C 98-107 95-103 130-140 Glass Transition temperature* °C 18 18 17 Melt viscosity** (160°C/2.16Kg) Pas 450 226 330 Melt volume rate** (160°C/2.16Kg) cm3/10' 23 48 32 Density*** g/cm3 1.31 1.31 1.31 * DSC ** ISO 1133 *** ISO 1183
  • 9. 9 Application Techniques → Hotmelt lamination → Powder scattering → Powderdot, Pastedot → Meltblown → Webs Suitable for all standard application techniques : Meltblown hotmelt by standard spray head.
  • 10. 10 Thermoplastic Composites Matrix material by EMS high performance polymers → Easy to handle → Short cycle times → Reformable by temperature Applications → Orthoses → Guards → Sports equipment → Organosheets
  • 11. 11 Technical Data Griltex Polymer 2A D 1428A Melting range* °C 120-130 175-180 Glass Transition temperature* °C 15 45 Melt viscosity** (°C/2.16Kg) Pas 560 @160°C 180 @ 230°C Melt volume rate** (°C/2.16Kg) cm3/10' 18 @160°C 50 @ 230°C Density*** g/cm3 1.02 1.01 Use Matrix Matrix Surface Availability Granules Powder Suspension Granules Powder * DSC ** ISO 1133 *** ISO 1183
  • 12. 12 EMS-GRILTECH worldwide www.emsgriltech.com info@emsgriltech.com Europe Americas EMS-CHEMIE AG EMS-CHEMIE AG (North America) Inc. Business Unit EMS-GRILTECH Business Unit EMS-GRILTECH Via Innovativa 1 2060 Corporate Way CH-7013 Domat/Ems P.O. Box 1717 Phone: +41 81 632 72 02 Sumter, SC 29151-1717, USA Fax: +41 81 632 74 02 Toll free: +1 877 367 83 23 E-mail: info@emsgriltech.com Phone: +1 803 481 61 90 Fax: +1 803 481 61 29 E-mail: info@us.emsgriltech.com Asia Japan EMS-CHEMIE AG (Asia) Ltd. EMS-CHEMIE AG (Japan) Ltd. Business Unit EMS-GRILTECH Business Unit EMS-GRILTECH 36, Kwang Fu South Road Osaka Office, Umeda Shinmichi Bldg. Hsin Chu Industrial Park 1-1-5, Dojima, Kita-ku Fu Kou Hsiang, Hsin Chu Hsien Osaka 530-0003, Japan Taiwang, R.O.C. Phone: +81 6 6348 1655 Phone: +886 35 983 335 Fax: +81 6 6348 1702 Fax: +886 35 985 731 E-mail: info@jp.emsgriltech.com E-mail: info@tw.emsgriltech.com Issued by: Technical Service Coatings + Additives EMS-CHEMIE AG business unit EMS-GRILTECH Date: March 2012 Copyright: All rights reserved to EMS-CHEMIE AG. Any unauthorized copying and publishing is forbidden GRILTEX is a registered trademark of EMS-CHEMIE AG