Inaugural presentation_Yiannis Pontikes_2017

P
Fe-Ca-silicate slags:
when purpose-driven research
challenges perception of
what is feasible
Leuven, March, 2017
Yiannis Pontikes
In the next ~30min
Few slides about my motivation
&
more slides about the SREMat group:
why and what we do,
now and in the near future.
We will start from a high altitude and land smoothly!
My motivation
AFP/Getty images
My motivation
AFP/Getty images
My motivation
AFP/Getty images
My motivation
AFP/Getty images
My motivation
AFP/Getty images
My motivation
These slides speak about me
I am 2nd generation refugee (see: “population exchange” of 1923)
That grew up next to an American base, with Greek-Canadian
citizenships, having family in 3 US states, and my sister in London
Now an immigrant (or “expat”?)
Emotionally bonded with Belgium, but Europe (the world) also
And a father (did you meet Sebastian Theodore?)
That believes global warming is real, we don’t live in a sustainable way,
and finds demagogues threatening!
My motivation
And I feel responsible
And just watching, is just too difficult
The real damage is done by those millions who want to 'survive.' The honest men
who just want to be left in peace…Sophie Scholl
But I am not alone
So, what do I want to do?
Use science and expand our understanding, so that we
develop processes with smaller environmental footprint
Create tools for individuals to have more safe, healthy
and comfortable lives
Educate others to become more aware of their impact
and options
…
Inaugural presentation_Yiannis Pontikes_2017
Taking action (?)
Paris Agreement
Technology research, development and demonstration
Foster industrial symbiosis and open collaboration/innovation/ecology
Industrial Symbiosis in Kalundborng, Denmark
16
A strategy
Implementing that in our region
Aperam, Châtelet
- stainless steel: 700 kt/year*
- slag: 200 kt/year*
Metallo-Chimique, Beerse
- slag: 180 kt/year*
Umicore, Hoboken
- slag: 150 kt/year*
ArcelorMittal, Gent
- steel: 4000 kt/year*
- BOF slag: 450 kt/year*
Group Machiels, Houthalen
- slag: depends
Aperam, Genk
- stainless steel: 900 kt/year*
- slag: 250 kt/year*
Metal Valley
Transform local supply of residues towards new materials
Circular economy through zero waste processing
…and the vision
And circular economy/zero waste is…?
https://www.ricoh.com/environment/management/concept.html
> 20 years ago!
OK!
OK?
Are we getting there?
…we have 15 years to make it happen…but we started good!
Figure: P.T. Jones
Fe2O3-Al2O3-CaO-SiO2
FeO-Al2O3-CaO-SiO2
SiO2-”FeO”-CaO-Al2O3
CaO-SiO2-MgO
CaO-”FeO”-MgO-SiO2
…comes down to the 4 most abundant metallic elements
FeOx-CaO-Al2O3-SiO2
But isn’t every slag different?
And the more you look…
Two slags from completely different processes have MO/SiO2 close to 2, the
3rd major oxide being at approx. 7wt%, everything else < 5wt%
Aperam and Metallo slags are not that far!
Iacobescu et al. J. Clean. Prod., 112(1), 872–881, 2016
Iacobescu et al. Front. Chem. Sci. Eng. DOI 10.1007/s11705-017-1622-6 (accepted)
And the more you look…
Two slags from completely different processes have MO/SiO2 close to 2, the
3rd major oxide being at approx. 7wt%, everything else < 5wt%
Aperam and Metallo slags are not that far!
Iacobescu et al. J. Clean. Prod., 112(1), 872–881, 2016
Iacobescu et al. Front. Chem. Sci. Eng. DOI 10.1007/s11705-017-1622-6 (accepted)
Al2O3
Al2O3Al2O3
Cu, Zn,
FeNi
Al2O3
Cu, Pb
In the high temperature process, metal is also recovered!
Carbon steel,
stainless steel
But what if we go towards one “unified”?
Al2O3
Al2O3Al2O3
Cu, Zn,
FeNi
Al2O3
Cu, Pb
In the high temperature process, metal is also recovered!
Carbon steel,
stainless steel
But what if we go towards one “unified”?
J. Van De Sande et al,
5th SVS, 3-5 April, 2017
SREMat: group for a cause
27
The group aspires to conceive and develop
innovative processes in order to transform
secondary resources towards engineered materials,
while considering the sustainability of the envisaged
process and the fate of (critical) metals.
The vision of our team is to create sustainable
material loops.
SREMat: group for a cause
SREMat: Secondary Resources for Engineered Materials, is one of
two research units in the HiTemp research group at MTM
Members: 3.5 post-docs, 9+3+1+2 PhD, typically 5 MSc students
per year and 2 visiting
The person is important, strong bonding. Very international team
BE, GE, GR, RO, SK, FIN, SRB, COL, ECU, IN, ET (BRA, IT, CHN)
SREMat: group for a cause
Cementitious
binders
Inorganic
Polymers
ProcessingOur structure
Design new clinkers
Improve performance of mortars
Design new precursors
Improve performance of mortars
In practice
Additives
Granulation New slag
In practice
Granulation New slag
In practice
Granulation New slag
From the slag to the material
Additives for
engineered
microstructure
Final material
Slag to
paste
Paste to inorganic
polymer or hydrate
From the slag to the material
Additives for
engineered
microstructure
Slag to
paste
Final material
Paste to
inorganic
polymer or
hydrate
Applications we explore with colleagues
Porous materials for
thermal insulation
Porous materials as
substrates for
(photo)catalysis
Dense materials
for shielding
Dense fiber-reinforced
materials for high
strength concrete
Dense
materials for
sound
absorption
Dense materials for
immobilisation
Dense for high
temperatures
Sandwich
structures
Responsive
materials to
electromagnetic
fields
Porous
materials as
catalysts
Fundamental
Research
Strategic Basic
Research
Competitive
Research
Competitive
Development
FlandersEUWorld
FWO on alkali
activated binders
DBOF red mud
IWT O&O Coziras2
IWT O&O VALORAS
COST
NORM4Building*
MIP ICON PLASMAT
IWT O&O Energy…
MSCA ETN REDMUD
SBO CeComStruct
SIM ICON Supermex
MSCA ETN New-mine
CR3 RED MUD 2
H2020 MetGrow+
MSCA ETN Socrates
Portfolio of projects
On-going
To be submitted
36
Collaborations and programs
Academic and other
research partners
Industrial partners37
Be specific
So, what do I want to do?
Use science and expand our understanding, so that we develop
processes with smaller environmental footprint
Create tools for individuals to have more safe, healthy and
comfortable lives
Educate others to become more aware of their impact and options
science and processes (engineering)
tools
educate
Multi-scale modeling
Science & engineering
Focus on material: describe and predict
Focus on process: properties
Novel process/material
Focus on engineering: real-life aspects
Upscaling
Arne explores the area more from an experimental
perspective, Christina more from a computational.
Jos and David go into thermodynamic modeling of cement
hydration, and coupled with high temp modeling+statistics,
we have better understanding
Science & engineering: materials
Raw Mössbauer spectra of activated mixtures
recorded after different reaction time intervals
(left) Douvalis et al. 5th SVS, April 3-5, 2017; (right) Simon et al, coming up
Fourier transforms of k3‐weighted Fe-EXAFS of the slags and IP.
Peaks are corresponding atomic pair correlations.
Data not published yet
Tobias will soon announce a new process on BR
Glenn is developing diagnostics and goes towards rheology
Georgia is introducing microwave processing and we explore
also induction
Science & engineering: processing
Possible implementation
of the described process
for valorization of
bauxite residue in
inorganic polymers
Hertel et al, J. Sustain. Metall. (2016) 2:394–404
Lukas et al has built boats, tiles, blocks and walls, now stairs!
Science & engineering: upscaling
Lukas et al has built boats, tiles, blocks and walls, now stairs!
Science & engineering: upscaling
Science & engineering: upscaling
Science & engineering: upscaling
Design: Philippe Caers and Dirk Wenmakers
This is one of our
ambassadors!
Outreach/educate
website
SREMat software
A new solar system…
Outreach/educate
Outreach/educate
These are the
conferences
that are
collaborating
with the
journal
Presents
news on
“sustainability
+ metal” from
>10 portals
These are the
conferences
that are
collaborating
with the
journal
As they
appear at
Springer
website
As they
appear at
Zenodo
https://zenodo.org/com
munities/sustainmetall/
Tools
The “tool” will allow people to make their own
houses, without going through intermediates
players in the value chain
And yes, Flanders, is quite OK,
but we don’t make this tool for
Flanders only, we make it for
the world (and users like UN…)
Tools
http://www.atlas.d-waste.com/Documents/Waste-Atlas-report-2014-webEdition.pdf
Tools
http://www.atlas.d-waste.com/Documents/Waste-Atlas-report-2014-webEdition.pdf
Before we close…
And if we succeed…
Yes, we almost close the loop!
And we close…
Thank you for being here!
I am greatly indebted to every member of SREMat (MSc and PhD
candidates, but postdocs in particular for making things happen),
colleagues at MTM and KU Leuven, SIM2 especially, and to the people I
collaborated at industries as well as institutions that we have received
funding and trust from. Big thank you to SO...
1 of 54

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Inaugural presentation_Yiannis Pontikes_2017

  • 1. Fe-Ca-silicate slags: when purpose-driven research challenges perception of what is feasible Leuven, March, 2017 Yiannis Pontikes
  • 2. In the next ~30min Few slides about my motivation & more slides about the SREMat group: why and what we do, now and in the near future. We will start from a high altitude and land smoothly!
  • 8. My motivation These slides speak about me I am 2nd generation refugee (see: “population exchange” of 1923) That grew up next to an American base, with Greek-Canadian citizenships, having family in 3 US states, and my sister in London Now an immigrant (or “expat”?) Emotionally bonded with Belgium, but Europe (the world) also And a father (did you meet Sebastian Theodore?) That believes global warming is real, we don’t live in a sustainable way, and finds demagogues threatening!
  • 9. My motivation And I feel responsible And just watching, is just too difficult The real damage is done by those millions who want to 'survive.' The honest men who just want to be left in peace…Sophie Scholl
  • 10. But I am not alone
  • 11. So, what do I want to do? Use science and expand our understanding, so that we develop processes with smaller environmental footprint Create tools for individuals to have more safe, healthy and comfortable lives Educate others to become more aware of their impact and options …
  • 15. Technology research, development and demonstration
  • 16. Foster industrial symbiosis and open collaboration/innovation/ecology Industrial Symbiosis in Kalundborng, Denmark 16 A strategy
  • 17. Implementing that in our region Aperam, Châtelet - stainless steel: 700 kt/year* - slag: 200 kt/year* Metallo-Chimique, Beerse - slag: 180 kt/year* Umicore, Hoboken - slag: 150 kt/year* ArcelorMittal, Gent - steel: 4000 kt/year* - BOF slag: 450 kt/year* Group Machiels, Houthalen - slag: depends Aperam, Genk - stainless steel: 900 kt/year* - slag: 250 kt/year* Metal Valley
  • 18. Transform local supply of residues towards new materials Circular economy through zero waste processing …and the vision
  • 19. And circular economy/zero waste is…? https://www.ricoh.com/environment/management/concept.html > 20 years ago!
  • 20. OK! OK? Are we getting there? …we have 15 years to make it happen…but we started good! Figure: P.T. Jones
  • 21. Fe2O3-Al2O3-CaO-SiO2 FeO-Al2O3-CaO-SiO2 SiO2-”FeO”-CaO-Al2O3 CaO-SiO2-MgO CaO-”FeO”-MgO-SiO2 …comes down to the 4 most abundant metallic elements FeOx-CaO-Al2O3-SiO2 But isn’t every slag different?
  • 22. And the more you look… Two slags from completely different processes have MO/SiO2 close to 2, the 3rd major oxide being at approx. 7wt%, everything else < 5wt% Aperam and Metallo slags are not that far! Iacobescu et al. J. Clean. Prod., 112(1), 872–881, 2016 Iacobescu et al. Front. Chem. Sci. Eng. DOI 10.1007/s11705-017-1622-6 (accepted)
  • 23. And the more you look… Two slags from completely different processes have MO/SiO2 close to 2, the 3rd major oxide being at approx. 7wt%, everything else < 5wt% Aperam and Metallo slags are not that far! Iacobescu et al. J. Clean. Prod., 112(1), 872–881, 2016 Iacobescu et al. Front. Chem. Sci. Eng. DOI 10.1007/s11705-017-1622-6 (accepted)
  • 24. Al2O3 Al2O3Al2O3 Cu, Zn, FeNi Al2O3 Cu, Pb In the high temperature process, metal is also recovered! Carbon steel, stainless steel But what if we go towards one “unified”?
  • 25. Al2O3 Al2O3Al2O3 Cu, Zn, FeNi Al2O3 Cu, Pb In the high temperature process, metal is also recovered! Carbon steel, stainless steel But what if we go towards one “unified”? J. Van De Sande et al, 5th SVS, 3-5 April, 2017
  • 26. SREMat: group for a cause
  • 27. 27 The group aspires to conceive and develop innovative processes in order to transform secondary resources towards engineered materials, while considering the sustainability of the envisaged process and the fate of (critical) metals. The vision of our team is to create sustainable material loops. SREMat: group for a cause
  • 28. SREMat: Secondary Resources for Engineered Materials, is one of two research units in the HiTemp research group at MTM Members: 3.5 post-docs, 9+3+1+2 PhD, typically 5 MSc students per year and 2 visiting The person is important, strong bonding. Very international team BE, GE, GR, RO, SK, FIN, SRB, COL, ECU, IN, ET (BRA, IT, CHN) SREMat: group for a cause
  • 29. Cementitious binders Inorganic Polymers ProcessingOur structure Design new clinkers Improve performance of mortars Design new precursors Improve performance of mortars
  • 33. From the slag to the material Additives for engineered microstructure Final material Slag to paste Paste to inorganic polymer or hydrate
  • 34. From the slag to the material Additives for engineered microstructure Slag to paste Final material Paste to inorganic polymer or hydrate
  • 35. Applications we explore with colleagues Porous materials for thermal insulation Porous materials as substrates for (photo)catalysis Dense materials for shielding Dense fiber-reinforced materials for high strength concrete Dense materials for sound absorption Dense materials for immobilisation Dense for high temperatures Sandwich structures Responsive materials to electromagnetic fields Porous materials as catalysts
  • 36. Fundamental Research Strategic Basic Research Competitive Research Competitive Development FlandersEUWorld FWO on alkali activated binders DBOF red mud IWT O&O Coziras2 IWT O&O VALORAS COST NORM4Building* MIP ICON PLASMAT IWT O&O Energy… MSCA ETN REDMUD SBO CeComStruct SIM ICON Supermex MSCA ETN New-mine CR3 RED MUD 2 H2020 MetGrow+ MSCA ETN Socrates Portfolio of projects On-going To be submitted 36
  • 37. Collaborations and programs Academic and other research partners Industrial partners37
  • 39. So, what do I want to do? Use science and expand our understanding, so that we develop processes with smaller environmental footprint Create tools for individuals to have more safe, healthy and comfortable lives Educate others to become more aware of their impact and options science and processes (engineering) tools educate
  • 40. Multi-scale modeling Science & engineering Focus on material: describe and predict Focus on process: properties Novel process/material Focus on engineering: real-life aspects Upscaling
  • 41. Arne explores the area more from an experimental perspective, Christina more from a computational. Jos and David go into thermodynamic modeling of cement hydration, and coupled with high temp modeling+statistics, we have better understanding Science & engineering: materials Raw Mössbauer spectra of activated mixtures recorded after different reaction time intervals (left) Douvalis et al. 5th SVS, April 3-5, 2017; (right) Simon et al, coming up Fourier transforms of k3‐weighted Fe-EXAFS of the slags and IP. Peaks are corresponding atomic pair correlations. Data not published yet
  • 42. Tobias will soon announce a new process on BR Glenn is developing diagnostics and goes towards rheology Georgia is introducing microwave processing and we explore also induction Science & engineering: processing Possible implementation of the described process for valorization of bauxite residue in inorganic polymers Hertel et al, J. Sustain. Metall. (2016) 2:394–404
  • 43. Lukas et al has built boats, tiles, blocks and walls, now stairs! Science & engineering: upscaling
  • 44. Lukas et al has built boats, tiles, blocks and walls, now stairs! Science & engineering: upscaling
  • 46. Science & engineering: upscaling Design: Philippe Caers and Dirk Wenmakers This is one of our ambassadors!
  • 49. Outreach/educate These are the conferences that are collaborating with the journal Presents news on “sustainability + metal” from >10 portals These are the conferences that are collaborating with the journal As they appear at Springer website As they appear at Zenodo https://zenodo.org/com munities/sustainmetall/
  • 50. Tools The “tool” will allow people to make their own houses, without going through intermediates players in the value chain And yes, Flanders, is quite OK, but we don’t make this tool for Flanders only, we make it for the world (and users like UN…)
  • 53. Before we close… And if we succeed… Yes, we almost close the loop!
  • 54. And we close… Thank you for being here! I am greatly indebted to every member of SREMat (MSc and PhD candidates, but postdocs in particular for making things happen), colleagues at MTM and KU Leuven, SIM2 especially, and to the people I collaborated at industries as well as institutions that we have received funding and trust from. Big thank you to SO...