Processing polymer


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Processing polymer

  1. 1. Polymer ProcessingThere are many processes for plastics. Selection of a process depends on many factors including:- Quantity and production rate- Dimensional accuracy and surface finish- Form and detail of the product- Nature of material- Size of final productIn general, plastics processes have three phases:1. Heating - To soften or melt the plastic2. Shaping / Forming - Under constraint of some kind3. Cooling - So that it retains its shape
  2. 2. Thermoplastics start as regular pellets orgranules and can be remelted.Thermosetting materials start as liquids/syrups,often called "resins", as powders or partiallycured products ("preforms") which need heat forthe shaping phase. The shaping is accompaniedby a chemical reaction, which means that thematerial does not soften on reheating. Thereaction may be exothermic (giving heat out), inwhich case cooling is required.
  3. 3. Processes1. Thermoforming2. Compression and transfer molding3. Rotational molding and sintering4. Extrusion5. Extrusion-based processes6. Injection molding7. Blow molding8. Plastic foam molding
  4. 4. 1.Thermoforming
  5. 5. -air pressure and plugassisted forming of thesoftened sheet.-invariably automated andfaster cycle times-only thermoplastics sheetcan be processed by thismethod.-The largest application isfor Food Packaging.-Other industries includeToiletries, Pharmaceuticalsand Electronics
  6. 6. -Food related applicationssuch as Meat Trays,Microwave & Deep FreezeContainers, Ice Cream andMargarine Tubs, SnackTubs, Bakery andPatisserie packaging,Sandwich Packs andVending Drink Cups-Manufacturing Collationtrays, Blister packagingand Point of Sale displaytrays.
  7. 7. 2. Compression and transfer molding
  8. 8. -place a pre-weighed amount ofmaterial in a matched metalmold and closing the mold.-heat and pressure cause thematerial to liquify and flow intothe voids in the tool where itchemically reacts and hardensinto the final shape.-very large shapes can bemolded in compression presses.
  9. 9. Advantages of compression molding (comparedwith injection molding)-Low scrap arisings-Low orientation in the moldings -well distributed fibrous fillers -low residual stress product -retained mechanical and electrical properties -low mold maintenance -low capital and tooling costs
  10. 10. -พัฒนามาจาก compression คือจะมีทใสสารแลวคอยกดอัดผาน runners ไปสู ี่cavities ซึ่งเกิดขึ้นภายในแมพมพ ิ-ตองการใหไดสวนที่เล็ก ๆ ของแบบไดงายขึ้น-ลดการสูญเสียหรือแตกหักจากสวนของแมพิมพทบางหรือซับซอน ี่-เร็วกวา compression เพราะ heat transfer ในชวงทีผาน runner ่
  11. 11. Disadvantages when compared with compression-Give unwelcome orientation in the product-Increase wear and maintenance costs-Tooling is more complex and more expensive-Runners owe scrap
  12. 12. 3.Rotational molding and sintering
  13. 13. -cast hollow plastic parts with few restrictionsregarding size or complexityVery stable parts - no molded in stressesLow tooling cost for large partsSuited for low volume productionCan produce complex part geometriesCan mold in metal inserts and graphics
  14. 14. 4.Extrusion-the forcing of a plastic or molten material through ashaped die by means of pressure.
  15. 15. Single screw extruderTwin screw extruder
  16. 16. -screw has one or two ‘flights’ spiraling along itslength.-φ to outside of the flight is constant along thelength to allow the close fit in the barrel.-core is of varying φ and so the spiraling channelvaries in depth.-in general, the channel depth ↓ from feed end to dieend pressure ↑
  17. 17. The zones in an extruder1. Feed zone -preheat polymer and convey it to the subsequent zones. -screw depth is constant2. Compression zone -channel depth ↓ -expel air trapped between original granules -heat transfer from the heated barrel walls is improved ‘coz material thickness ↓ -density change during melting is accommodated melt sharply very short compression zone melt gradually very long compression zone
  18. 18. 3.Metering zone -constant screw depth -homogenize the melt -supply to the die region material which is of homogeneous quality at constant T & P4. Die zone -breaker plate - screen pack (perforated steel plate) a) sieve out extraneous material, e.g. ungeled polymer, dirt and foreign bodies b) allow head P to develop by providing a resistance for the pumping action of the metering zone c) remove ‘turning memory’ from the melt
  19. 19. Flow mechanisms: Conveying-Drag flow -dragging along by the screw of the melt as the result of the frictional forces -equivalent to viscous drag between stationary and moving plates separated by a viscous medium. -constitute output component for the extruder. -Pressure flow -P gradient along the extruder (high P at the output end, low at the feed end-Leak flow -finite space between screw and barrel through which material can leak backwards. Total flow = drag flow – pressure flow – leak flow
  20. 20. The extrusion die1. Basic flow patterns Maintain laminar flow2. Die entry effects Tensile stress exceed the tensile strength of the melt extrudate will be of irregular shape called melt fracture
  21. 21. The die entrance is tapered:1. Eliminate the dead spots in the corners, maintaining a steady heat and shear history2. Minimize the development of tensile stresses, and minimize distortion of the streamlinesLong die land extend the process time which helps to eliminate memory of earlier processing, e.g. screw turning memoryDeborah Number, Ndeb*
  22. 22. Relaxation time – the characteristic timescale for which a melt has memory -describe as its viscous and elastic responses to an applied stress vis cos ity Ns × m 2 relaxation _ time = = 2 =s mod ulus m × N relaxation _ time _ of _ material , in _ processN deb = timescale _ of _ processIf Ndeb>1, process is dominantly elastic.If Ndeb<1, process is predominantly viscous.
  23. 23. 3. Die exit instabilities sharkskin -roughening of the surface of the extrudate -caused by tensile stresses: the melt, with max velocity at the center and zero at the wall, leaves the die lips material at the wall accelerate to the velocity at which the extrudate is leaving the die generate tensile stress.. If tensile stress exceeds tensile strength, surface ruptures. orange peel -when conditions become more intense, e.g. P at the extruder becomes excessive, or the die T drops -coarser-grained appearance
  24. 24. bambooing -the whole extrudate ‘snaps back’Extra heating of the die will often help to remedy these defects, by thermally relaxing the stresses and lowering viscosity
  25. 25. 4. Die swell-Effect in which the polymer swells as it leaves the die.-Extrudate differs in its dimensions from those of the die orifice.-Extruded rod has larger diameter and pipe has thicker walls, e.g. o.d. ↑, i.d. ↓Result of the elastic component in the overall response of the polymer melt to stress. recovery of the elastic deformation as the extrudate leaves the constraint of the die channel and before it freezes.
  26. 26. Part Cost - lowTool Cost - lowProduction Capability -highShort lead times toproductionUniform cross section ofpartsMultiple materials arepossible in the same part.
  27. 27. 5.Extrusion-based processesProfile extrusion: pipe, sheetTubular blown film extrusion: ถุงรอนCross-head extrusion: สายเคเบิ้ลSynthetic fibers: เสนใยสังเคราะห เชน เสนใยโพลิเอสเตอรNetting: ถุงใสผัก ผลไมCo-extrusion
  28. 28. Pipe extrusion
  29. 29. Sheet extrusionFilm thickness: 0.5 – 20 mil (1 mil = 0.001 inch)
  30. 30. Tubular blown film extrusion
  31. 31. Netting-Garden uses, fruit packaging-Made with annular dies but with outer die and thecentral mandrel counter-rotating and close fitting-Both parts have slots so that concentric sets offilaments extrude-When counter-rotation starts the filaments crossone another to form welded junctions and a netpattern.
  32. 32. Co-extrusion-Extrusion of more than one type ofpolymer at once to give a laminateproduct.-Require a separate extruder for eachpolymer-Multilayer product forming at a die-‘tie-layers’: bond the functional layerstogether
  33. 33. Multi-Layer … Mono MaterialFor non-demanding applications, a mono materialsheet is usually specified. This is a sheet in whichthere is only one material. With a more demandingapplication, a multi-layer sheet is used. Multi headextruders feed into the extrusion die with thediffering materials.Multi layer sheeting, with a heat compliant top layer,can used to make heat-sealed applications. PVC / PEfor Meat Trays, and CPET / APET for Meat Trays andReady Meals.
  34. 34. 6. Injection moldingInjection molding is accomplished by forcing moltenplastic under pressure into a cavity formed between twomatched metal mold halves. Once the plastic cools, themolds are opened and the part is removed.
  35. 35. -Part cost - low-Tooling cost - high-Production Rate - high-Can produce intricateparts-Large variety of polymersgives wide range ofproperties.-Can produce a widerange of part sizes withdifferent press sizes.
  36. 36. mold
  37. 37. Functions:1. Allow rapid freezing of polymer: isolate the cavity and permits withdrawal of the screw2. Narrow and thin solid section: be sheared off easily after demolding3. Increase shear rates as melt flows through: lower viscosity to ease rapid and complete filling of complex shapes
  38. 38. Problems:-sink marks and voids-weld lines
  39. 39. Weld line: formed where polymer flows meetCan be moved to a position on the molding whereunimportant
  40. 40. 7. Blow moldingExtrusion blow molding‘parison’ ขวดน้ําเปลา สีขาวขุน ทําจาก PP
  41. 41. Extrusion blow moldingTypical productsBottles and containersAutomotive fuel tanksVenting ductsWatering cans
  42. 42. -Part cost - moderate-Tooling Cost - moderate-Production rate - moderateto high-Blow molding producesparts with the higheststrength to weight ratio ofany plastic process.Complex, hollow parts areformed with no internalstresses. Parts as large as12 ft. x 4 ft. x 4 ft. can beformed
  43. 43. Stages1. The hot plastic extruded into the mold in pipe form.2. While still hot, the plastic is trapped in the mold, ahot knife cuts it off at the top and it is also pinched atthe bottom.3. The mold then moves to the right. An air hose isinserted into the top.4. The plastic in the mold expands to fill the mold.5. The mold then separates, which releases the plastic(bottle).
  44. 44. Injection blow moldingCarbonated drinks using PETThe tube ‘preform’ made by injection molding to avery cold mold to quench it in its amorphous stateIs reheated to blowing T (just about its Tg ) andstretch blownDevelop biaxial orientation in the productAlternate name for this process is ‘stretch-blow’
  45. 45. Injection blow molding
  46. 46. 8.Plastic foam molding-low-pressure injection molding process that iscapable of producing very large structural parts.-The molten plastic material is injected into a moldafter being mixed with a blowing agent or high-pressure gas.-This produces bubbles in the plastic causing it tofoam. The foam retains the properties of the plasticbut weighs less because of reduced density.