6. Difficulty in creating green LED
• Manufacturing a pure green LED is very difficult.
• The LED-based lights available today circumvent the problem by aiming the blue light at a
phosphor, which then emits green light.
• In this way, we can produce white light, but it is still wasteful compared to a white light that makes
use of three distinct, all-LED components.
Reference:- http://www.gizmag.com/first-green-led-light-manufactured/14761/
8. Semiconductor die
• By using Czochralski crystal growth (or liquid
encapsulation) method, semiconductor wafer of
Gallium(III) phosphide (GaP) is made.
• Additional layers of semiconductor crystal are
grown on the surface of the wafer. The crystal
layers are grown this time by a process
called Liquid Phase Epitaxy (LPE)
Reference:- http://www.wafertech.co.uk/technology/crystal-growth/
9. Semiconductor die
• LPE creates an exceptionally uniform layer of material, which makes it a preferred growth and
doping technique. The layers formed are several microns thick
• After depositing epitaxial layers, Nitrogen is added to the top layer of the diode to make the light
more green.
Demerit:- This fabrication process doesn’t allow us to fabricate a pure green LED, as growing Indium
gallium nitride (InGaN) / Gallium(III) nitride (GaN) using Czochralski crystal growth is
difficult.
10. Mounting and Packaging
• Individual dies are mounted on the appropriate
package
• Finally, the entire assembly is sealed in plastic.
The wires and die are suspended inside a mold that
is shaped according.
Reference:- http://www.madehow.com/Volume-1/Light-Emitting-Diode-LED.html
11. LED Using MOCVD
• By using Metal-Organic Chemical Vapor Deposition (MOCVD), we can produce
high quality gallium nitride.
• This led to the creation of Blue LEDs.
• With the addition of indium, blue LED can be converted into Green LED
• Initially in traffic lights, we used filter the green light from a light source emitting
at the full spectrum of the visible light.
• With these new LEDs we can cut down the power consumption by half.
Reference:- http://iopscience.iop.org/1347-4065/34/7A/L797
Proposed in 2000
12. National Renewable Energy Laboratory
• LED can be thought of as the reverse of a solar panel.
• Reversing the process of absorbing sunlight in the green
spectral region in order to manufacture a green LED.
• Mascarenhas's idea was to reverse the process that is,
making a current flow between appropriately spaced
layers of lattice to obtain green light and reportedly
managed to produce a radiant deep green light on the
very first try.
Reference:- http://www.nrel.gov/news/features/feature_detail.cfm/feature_id=1545
Proposed in 2010
14. Few FAQs
• Why people are trying to build Green LEDs, can’t they just coat green color upon a white LED?
Ans:- Pure white LED is difficult to create. We need to combine Red, Blue, Green colors to get
white light.
• Why a Green LED appears brighter than a Red LED even though both use same current?
Ans:- Human eye has maximum sensitivity to light near 550 nm region of yellow - green part of
the visible spectrum
• Does a typical Diode produces light? How the LED is different from a Diode?
Ans:- Yes, it produces light. But we can’t observe it, as most of the light produced fall in either IR
or UV region. The materials and the dopants used differentiate the LED from a diode.
The crystalline semiconductor is grown in a high temperature, high pressure chamber. Gallium, arsenic, and/or phosphor are purified and mixed together in the chamber. The heat and pressure liquify and press the components together so that they are forced into a solution. To keep them from escaping into the pressurized gas in the chamber, they are often covered with a layer of liquid boron oxide, which seals them off so that they must "stick together."
A substrate is brought into contact with a saturated solution of the film material at an appropriate temperature. The substrate is then cooled at a suitable rate to lead to film growth.