Click http://www.guidechem.com/cas-84/84-66-2.html for suppliers of this productDiethyl phthalate (cas 84-66-2) MSDS1.1.1IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKINGProduct identifiersProduct nameProduct NumberBrandCAS-No.::::Diethyl phthalate36737Fluka84-66-21.2 Relevant identified uses of the substance or mixture and uses advised againstIdentified uses : Laboratory chemicals, Manufacture of substances18.104.22.168.33.3.1HAZARDS IDENTIFICATIONClassification of the substance or mixtureNot a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.This substance is not classified as dangerous according to Directive 67/548/EEC.Label elementsNot a hazardous substance or mixture according to EC-directives 67/548/EEC or 1999/45/EC.Other hazards - noneCOMPOSITION/INFORMATION ON INGREDIENTSSubstancesSynonymsFormulaMolecular Weight:::DEPC12H14O4222,24 g/mol4.4.1FIRST AID MEASURESDescription of first aid measuresGeneral adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaledIf breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.In case of skin contactWash off with soap and plenty of water. Consult a physician.In case of eye contactRinse thoroughly with plenty of water for at least 15 minutes and consult a physician.If swallowedNever give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.22.214.171.124.126.96.36.199Most important symptoms and effects, both acute and delayedTo the best of our knowledge, the chemical, physical, and toxicological properties have not beenthoroughly investigated.Indication of any immediate medical attention and special treatment neededno data availableFIREFIGHTING MEASURESExtinguishing mediaSuitable extinguishing mediaUse water spray, alcohol-resistant foam, dry chemical or carbon dioxide.Special hazards arising from the substance or mixtureCarbon oxidesAdvice for firefightersWear self contained breathing apparatus for fire fighting if necessary.Further information
188.8.131.52.184.108.40.206.27.3no data availableACCIDENTAL RELEASE MEASURESPersonal precautions, protective equipment and emergency proceduresUse personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation.Environmental precautionsPrevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into theenvironment must be avoided.Methods and materials for containment and cleaning upSoak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closedcontainers for disposal.Reference to other sectionsFor disposal see section 13.HANDLING AND STORAGEPrecautions for safe handlingAvoid contact with skin and eyes. Avoid inhalation of vapour or mist.Conditions for safe storage, including any incompatibilitiesStore in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which areopened must be carefully resealed and kept upright to prevent leakage.Specific end usesno data available220.127.116.11EXPOSURE CONTROLS/PERSONAL PROTECTIONControl parametersComponents with workplace control parametersExposure controlsAppropriate engineering controlsHandle in accordance with good industrial hygiene and safety practice. Wash hands before breaks andat the end of workday.Personal protective equipmentEye/face protectionSafety glasses with side-shields conforming to EN166 Use equipment for eye protection testedand approved under appropriate government standards such as NIOSH (US) or EN 166(EU).Skin protectionHandle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching gloves outer surface) to avoid skin contact with this product. Dispose ofcontaminated gloves after use in accordance with applicable laws and good laboratory practices.Wash and dry hands.The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC andthe standard EN 374 derived from it.Immersion protectionMaterial: Nitrile rubberMinimum layer thickness: 0,11 mmBreak through time: > 480 minMaterial tested:Dermatril? (Anonymous Z677272, Size M)Splash protectionMaterial: Nitrile rubberMinimum layer thickness: 0,11 mmBreak through time: > 30 minMaterial tested:Dermatril? (Anonymous Z677272, Size M)data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 873000, e-mail firstname.lastname@example.org,test method: EN374If used in solution, or mixed with other substances, and under conditions which differ from EN 374,contact the supplier of the CE approved gloves. This recommendation is advisory only and mustbe evaluated by an Industrial Hygienist familiar with the specific situation of anticipated use by ourcustomers. It should not be construed as offering an approval for any specific use scenario.
9.9.1Body Protectionimpervious clothing, The type of protective equipment must be selected according to theconcentration and amount of the dangerous substance at the specific workplace.Respiratory protectionWhere risk assessment shows air-purifying respirators are appropriate use a full-face respiratorwith multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backupto engineering controls. If the respirator is the sole means of protection, use a full-face supplied airrespirator. Use respirators and components tested and approved under appropriate governmentstandards such as NIOSH (US) or CEN (EU).PHYSICAL AND CHEMICAL PROPERTIESInformation on basic physical and chemical propertiesa)b)c)d)AppearanceOdourOdour ThresholdpHForm: liquidno data availableno data availableno data availablee)f)g)h)Melting point/freezingpointInitial boiling point andboiling rangeFlash pointEvaporation rateMelting point/range: 3 °C298 - 299 °C156,0 °C - closed cupno data availablei) Flammability (solid, gas) no data availablej)k)l)Upper/lowerflammability orexplosive limitsVapour pressureVapour densityLower explosion limit: 0,75 %(V)no data available7,7 - (Air = 1.0)m) Relative density 1,12 g/mL at 25 °Cn)o)p)q)r)s)t)Water solubilityPartition coefficient: n-octanol/waterAutoignitiontemperatureDecompositiontemperatureViscosityExplosive propertiesOxidizing propertiesslightly solubleno data available457,0 °Cno data availableno data availableno data availableno data available18.104.22.168.210.310.410.510.611.11.1Other safety informationno data availableSTABILITYAND REACTIVITYReactivityno data availableChemical stabilityno data availablePossibility of hazardous reactionsno data availableConditions to avoidno data availableIncompatible materialsOxidizing agents, acidsHazardous decomposition productsOther decomposition products - no data availableTOXICOLOGICAL INFORMATIONInformation on toxicological effectsAcute toxicityLD50 Oral - rat - 8.600 mg/kg
Remarks: Behavioral:Somnolence (general depressed activity).LC50 Inhalation - rat - 6 h - > 4.640 mg/m3LD50 Dermal - guinea pig - > 22,4 g/kgSkin corrosion/irritationSkin - guinea pig - Mild skin irritationSerious eye damage/eye irritationEyes - rabbit - Mild eye irritationRespiratory or skin sensitizationBuehler Test - guinea pig - Did not cause sensitization on laboratory animals.Germ cell mutagenicityno data availableCarcinogenicityCarcinogenicity - mouse - SkinTumorigenic:Equivocal tumorigenic agent by RTECS criteria. Liver:Tumors.This product is or contains a component that is not classifiable as to its carcinogenicity based on its IARC,ACGIH, NTP, or EPA classification.IARC: No component of this product present at levels greater than or equal to 0.1% is identified asprobable, possible or confirmed human carcinogen by IARC.Reproductive toxicityReproductive toxicity - rat - IntraperitonealEffects on Fertility: Post-implantation mortality (e.g., dead and/or resorbed implants per total number ofimplants). Effects on Embryo or Fetus: Fetotoxicity (except death, e.g., stunted fetus). SpecificDevelopmental Abnormalities: Musculoskeletal system.Reproductive toxicity - mouse - male - OralPaternal Effects: Spermatogenesis (including genetic material, sperm morphology,motility, and count).Paternal Effects: Prostate, seminal vessicle, Cowpers gland, accessory glands. Effects on Newborn: Livebirth index (# fetuses per litter; measured after birth).Developmental Toxicity - rat - OralSpecific Developmental Abnormalities: Musculoskeletal system.Developmental Toxicity - mouse - SkinEffects on Embryo or Fetus: Fetotoxicity (except death, e.g., stunted fetus). Specific DevelopmentalAbnormalities: Musculoskeletal system.Specific target organ toxicity - single exposureno data availableSpecific target organ toxicity - repeated exposureno data availableAspiration hazardno data availablePotential health effectsInhalationIngestionSkinEyesMay be harmful if inhaled. May cause respiratory tract irritation.May be harmful if swallowed.May be harmful if absorbed through skin. May cause skin irritation.Causes eye irritation.Signs and Symptoms of ExposureTo the best of our knowledge, the chemical, physical, and toxicological properties have not beenthoroughly investigated.Additional InformationRTECS: TI105000012.12.1ECOLOGICAL INFORMATIONToxicityToxicity to fishToxicity to daphnia andother aquaticinvertebratesToxicity to algaeLC50 - Oncorhynchus mykiss (rainbow trout) - 12,00 mg/l - 96 hNOEC - Lepomis macrochirus (Bluegill) - 1,65 mg/l - 96 hEC50 - Daphnia magna (Water flea) - 86,00 mg/l - 48 hEC50 - Pseudokirchneriella subcapitata (green algae) - 16 mg/l - 96 h12.2 Persistence and degradabilityBiodegradability aerobic - Exposure time 24 h
Result: > 94,8 % - Readily biodegradable.12.3 Bioaccumulative potentialBioaccumulation Lepomis macrochirus (Bluegill) - 21 d -0,00942 mg/lBioconcentration factor (BCF): 11712.412.512.622.214.171.124.1Mobility in soilno data availableResults of PBT and vPvB assessmentno data availableOther adverse effectsHarmful to aquatic life.DISPOSAL CONSIDERATIONSWaste treatment methodsProductOffer surplus and non-recyclable solutions to a licensed disposal company.Contaminated packagingDispose of as unused product.TRANSPORT INFORMATIONUN number14.214.314.414.514.615.ADR/RID: -UN proper shipping nameADR/RID: Not dangerous goodsIMDG: Not dangerous goodsIATA: Not dangerous goodsTransport hazard class(es)ADR/RID: -Packaging groupADR/RID: -Environmental hazardsADR/RID: noSpecial precautions for userno data availableREGULATORYINFORMATIONIMDG: -IMDG: -IMDG: -IMDG Marine pollutant: noIATA: -IATA: -IATA: -IATA: noThis safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.15.115.2Safety, health and environmental regulations/legislation specific for the substance or mixtureno data availableChemical Safety Assessmentno data available16. OTHER INFORMATIONFurther informationThe above information is believed to be correct but does not purport to be all inclusive andshall be used only as a guide. The information this document is based on the resent stateof our knowledge and is applicable to the product with regard to appropriate safety precautions.It does not represent any guarantee of the properties of the product. guidechem shall not beheld liable for any damage resulting from handling or from contact with the above product.See reverse side of invoice or packing slip for additional terms and conditions of sale.