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Carbonyl Compounds Aldehydes and Ketones
Contents ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Aldehydes vs. Ketones ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Back to  Contents
Testing for Carbonyl Compounds ,[object Object],[object Object],[object Object],[object Object],[object Object],Back to  Contents
Distinguishing Between Aldehydes and Ketones     Mild  Oxidation ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],In both tests the aldehyde is oxidised to a carboxylate salt  Tollen’s Reagent is better because it works with all aldehydes. Both don’t work with ketones but vigorous oxidation will work Back to  Contents
Oxidation of Aldehydes (Primary Alcohols) ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Back to  Contents
Oxidation of Ketones (Secondary Alcohols) ,[object Object],[object Object],[object Object],Back to  Contents
Neucleophilic Addition Reaction ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Primary alcohol Secondary alcohol Back to  Contents
Definitions  ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Back to  Contents
Summary Back to  Contents Aldehyde Reacts with 2,4-DNP(H) Yellow/orange precipitate Reduced to Primary alcohol Oxidised to Carboxylic acid Ketones Reacts with 2,4-DNP(H) Yellow/orange precipitate Reduced to Secondary alcohol Not oxidised

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Carbonyl Compounds

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  • 10. Summary Back to Contents Aldehyde Reacts with 2,4-DNP(H) Yellow/orange precipitate Reduced to Primary alcohol Oxidised to Carboxylic acid Ketones Reacts with 2,4-DNP(H) Yellow/orange precipitate Reduced to Secondary alcohol Not oxidised