Upcoming SlideShare
×

# 02 part7 second law thermodynamics

1,176 views

Published on

02 part7 second law thermodynamics

Published in: Technology
3 Likes
Statistics
Notes
• Full Name
Comment goes here.

Are you sure you want to Yes No
• Be the first to comment

Views
Total views
1,176
On SlideShare
0
From Embeds
0
Number of Embeds
3
Actions
Shares
0
63
0
Likes
3
Embeds 0
No embeds

No notes for slide

### 02 part7 second law thermodynamics

1. 1. Second Law of Thermodynamics S.Gunabalan Associate Professor Mechanical Engineering Department Bharathiyar College of Engineering & Technology Karaikal - 609 609. e-Mail : gunabalans@yahoo.com
2. 2. Second law of thermodynamics • The second law of thermodynamics about the direction of heat transfer • Second law can be visualized in terms of the waterfall – You can not send water up with out energy
3. 3. Second law of thermodynamics • Second Law for Heat Engines It is impossible to extract heat QHot from a hot reservoir and use it all to do work W . Some amount of heat QCold must be exhausted to a cold reservoir. Called Kelvin-Planck statement
4. 4. Second law of thermodynamics • Second Law for Refrigerator • It is not possible for heat to flow from a colder body to a warmer body without any work having been done to accomplish this flow. Called Clausius statement
5. 5. Second law of thermodynamics Second Law: Entropy A measure of the amount of energy which is unavailable to do work. A state variable whose change is defined for a reversible process at T where Q is the heat absorbed A measure of the disorder of a system.
6. 6. First Law efficiency • Efficiency = output energy of device / input energy of device – Irrespective of form of energy – Availability of energy at different temperature
7. 7. Second Law efficiency • Efficiency = • Defined as the available energy for the work
8. 8. Exergy Balance For a Closed System • Exergy balance for a closed system can be developed by combining the energy and entropy balances for a closed system. • Energy Balance ∫ = ∆ + ----------(1)
9. 9. Exergy Balance For a Closed System • ∫ = ∆ + −−−− −(1) • Entropy Balance ∫ / = ∆ --------------(2) • Multiplying the second equation by T0 and subtracting it from the first one yields • ∫ = . ∆
10. 10. Exergy Balance For a Closed System • ∫ = ∆ + −−−− −(1) • ∫ = . ∆ • Subtract ------------------------------------ • ∫ 1 − = ∆ + − . ∆ • E = u + v2/2+gZ
11. 11. Exergy Balance For a Closed System • ∫ 1 − = ∆ + − . ∆ • E = u + v2/2+gZ 1 − = 2 − 1 + ( 2 2 − 1 2 2 ) + 0( 2 − 1) − ( 2 − 1)
12. 12. Reference • http://hyperphysics.phy-astr.gsu.edu/hbase/thermo/seclaw.html • Rajput, R. K. 2010. Engineering thermodynamics. Jones and Bartlett Publishers, Sudbury, Mass. • Nag, P. K. 2002. Basic and applied thermodynamics. Tata McGraw-Hill, New Delhi.