Phonon-assisted luminescence in Hexagonal Boron Nitride
Hexagonal Boron Nitride is a wide band gap material. In particular first principles calculations agree upon the existence of an indirect quasiparticle band gap : the conduction band minimum sits at the M point while the valence band maximum is around the K point of the Brillouin zone. On the experimental side the nature of the electronic band structure of hBN has animated a long-standing debate. Pioneering works of Watanabe et al. [1] have revealed the high UV radiative efficiency of hBN at room temperature. He first came to the conclusion that hBN was driven by direct excitonic recombination. Recently Cassabois et al. [2] instead explained the luminescence lines to phonon-assisted recombination from an indirect exciton. Aiming to describe phonon-assisted luminescence a theoretical formulation that combines electron-hole interactions and electron-phonon coupling is needed. In recent years the method of finite differences [3] turned out to be a powerful tool to treat the electron-phonon coupling in a perturbative way. So we combine Green’s function theory with finite difference electron-phonon coupling to get to an accurate description of the phonon assisted luminescence spectrum of hBN. [1] Watanabe et al. Nature Materials 3, 404 (2004) [2] Cassabois et al. Nature Photonics, 10, 262 (2016) [3] B. Monserrat, Journal of Physics: Condensed Matter 30, 083001 (2018)
Phonon-assisted luminescence in Hexagonal Boron Nitride
Hexagonal Boron Nitride is a wide band gap material. In particular first principles calculations agree upon the existence of an indirect quasiparticle band gap : the conduction band minimum sits at the M point while the valence band maximum is around the K point of the Brillouin zone. On the experimental side the nature of the electronic band structure of hBN has animated a long-standing debate. Pioneering works of Watanabe et al. [1] have revealed the high UV radiative efficiency of hBN at room temperature. He first came to the conclusion that hBN was driven by direct excitonic recombination. Recently Cassabois et al. [2] instead explained the luminescence lines to phonon-assisted recombination from an indirect exciton. Aiming to describe phonon-assisted luminescence a theoretical formulation that combines electron-hole interactions and electron-phonon coupling is needed. In recent years the method of finite differences [3] turned out to be a powerful tool to treat the electron-phonon coupling in a perturbative way. So we combine Green’s function theory with finite difference electron-phonon coupling to get to an accurate description of the phonon assisted luminescence spectrum of hBN. [1] Watanabe et al. Nature Materials 3, 404 (2004) [2] Cassabois et al. Nature Photonics, 10, 262 (2016) [3] B. Monserrat, Journal of Physics: Condensed Matter 30, 083001 (2018)
![²
Phononassisted Luminescence in hexagonal BN
Elena Cannuccia (a), Bartomeu Monserrat (b), Claudio Attaccalite (c)
(a) Dip. di Fisica, Univ. di Roma “Tor Vergata” & Laboratoire PIIM, Aix-Marseille Université (France)
(b) Cavendish Laboratory, Univ. of Cambridge, J. J. Thomson Avenue, Cambridge CB3 0HE, United Kingdom
(c) CNRS/Aix-Marseille Université, Laboratoire CINaM, Campus de Luminy, Marseille, France
MOTIVATIONS:
Aix-Marseille
Université
(France)
Direct or indirect band gap ...?
²
Here we study luminescence of hexagonal boron nitride (hBN) by means of nonequilibrium Green’s functions plus finitedifference electronphonon
coupling. We derive a formula for light emission in solids in the limit of a weak excitation that includes perturbatively the contribution of electronphonon
coupling at the first order. This formula is applied to study luminescence in bulk hBN. This material has attracted interest due to its strong luminescence
in the ultraviolet region of the electromagnetic spectrum [Watanabe et al., Nat. Mat. 3, 404(2004)]. The origin of this intense luminescence signal has been
widely discussed, but only recently a clear signature of phonon mediated light emission started emerging from the experiments [Cassabois et al., Nat.
Phot. 10, 262(2016)]. By means of our new theoretical framework we provide a clear and full explanation of light emission in hBN.
ABSTRACT
T
The growth of high quality
hBN single crystals has
opened new possibilities for
light emitting devices in the
UV range
Phonon band structure dispersion
Photoluminescence Experiments
Hexagonal boron nitride is an indirect bandgap
semiconductor
G. Cassabois et al., Nature Photonics, 10, 262 (2016)
Directbandgap properties and evidence for ultraviolet
lasing of hexagonal boron nitride single crystal
K. WATANABE, et al., Nature Materials, 3, 404 (2004)
A sharp luminescence peak is reported at 215 nm whose
intensity is 103
times higher than in a pure diamond
crystal. Watanabe et al. came to the conclusion that
hBN luminescence is driven by direct excitonic
recombination.
Cassabois et al. attributed the luminescence
lines to phononassisted transitions (phonon
replicas) from an indirect exciton (iX) .
… That is the question
THE INDIRECT
SEMICONDUCTORS PROBLEM HOW TO SOLVE THE RIDDLE ?
Internal quantum yield
The 45% hBN IQY goes
against the common
wisdom that indirect
band gap semiconductors
are bad light emitters.
0.1%
Diamond
45%
hBNZnO
50%
Direct and indirect excitons with high
binding energies in hBN.
L. Schué et al. arXiv:1803.03766 (2018)
hBN is an indirect
semiconductor with a
large band gap (~ 7eV).
The top of the valence
bands is located close to K
while the minimum of the
conduction bands is at M.
Light absorption and
emission in indirect
semiconductors is assisted
by absorption/emission of
phonons.
Exciton interference in hBN
L. Sponza, H. Amara, C. Attaccalite,
F. Ducastelle, A. Loiseau
PRB 97 (7), 075121(2017)
iX: the lowest
excitons with
momentum
q = |M – K|.
The high luminescence
efficiency evidences the
presence of a strong
excitonphonon coupling
in hBN.
The electronic band structure of hBN
The phonons involved in the luminescence process are
those with a momentum compatible with q = |K M|
vector. Therefore they fall
in the middle of the Brillouin zone (T) between and K. Γ
q0=K /12≈0.14 ˚A−1
A nondiagonal
supercell that
maps both K and
M points at Γ
Theory of phononassisted luminescence in solids: application to
hexagonal boron nitride
E Cannuccia,et al. arXiv:1807.11797
iX excitons are replicated by the different phonon modes
and acquire a finite optical weight. Excitonphonon
coupling is included through finite difference method. We reproduce the position and
the intensity of various peaks.
The doublets are generated by
LOTO, and LATA splitting
The EP scattering is limited to
one phonon at a time.
We cannot reproduce the
overtones involving interlayer
shear modes and the
asymmetric tails of the
emission peaks.
CONCLUSIONS
HOW TO SOLVE THE RIDDLE ?
We found that luminescence in h
BN is dominated by phonon
assisted transitions and that
strong excitonphonon coupling
leads to its intensity being
unexpectedly large and
comparable to that of direct band
gap materials.
We considered a density of excited carriers of n = 10 15
cm3
between K and M
Lattice dynamics and electron-phonon coupling
calculations using nondiagonal supercells
J. H. Lloyd-Williams and B. Monserrat PRB 97 (7),
075121(2017)](https://image.slidesharecdn.com/posterphassistedluminescence-190110230848/75/phononassisted-luminescence-in-hexagonal-boron-nitride-1-2048.jpg?cb=1670455648)
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Phonon-assisted luminescence in Hexagonal Boron Nitride
- 1. ² Phononassisted Luminescence in hexagonal BN Elena Cannuccia (a), Bartomeu Monserrat (b), Claudio Attaccalite (c) (a) Dip. di Fisica, Univ. di Roma “Tor Vergata” & Laboratoire PIIM, Aix-Marseille Université (France) (b) Cavendish Laboratory, Univ. of Cambridge, J. J. Thomson Avenue, Cambridge CB3 0HE, United Kingdom (c) CNRS/Aix-Marseille Université, Laboratoire CINaM, Campus de Luminy, Marseille, France MOTIVATIONS: Aix-Marseille Université (France) Direct or indirect band gap ...? ² Here we study luminescence of hexagonal boron nitride (hBN) by means of nonequilibrium Green’s functions plus finitedifference electronphonon coupling. We derive a formula for light emission in solids in the limit of a weak excitation that includes perturbatively the contribution of electronphonon coupling at the first order. This formula is applied to study luminescence in bulk hBN. This material has attracted interest due to its strong luminescence in the ultraviolet region of the electromagnetic spectrum [Watanabe et al., Nat. Mat. 3, 404(2004)]. The origin of this intense luminescence signal has been widely discussed, but only recently a clear signature of phonon mediated light emission started emerging from the experiments [Cassabois et al., Nat. Phot. 10, 262(2016)]. By means of our new theoretical framework we provide a clear and full explanation of light emission in hBN. ABSTRACT T The growth of high quality hBN single crystals has opened new possibilities for light emitting devices in the UV range Phonon band structure dispersion Photoluminescence Experiments Hexagonal boron nitride is an indirect bandgap semiconductor G. Cassabois et al., Nature Photonics, 10, 262 (2016) Directbandgap properties and evidence for ultraviolet lasing of hexagonal boron nitride single crystal K. WATANABE, et al., Nature Materials, 3, 404 (2004) A sharp luminescence peak is reported at 215 nm whose intensity is 103 times higher than in a pure diamond crystal. Watanabe et al. came to the conclusion that hBN luminescence is driven by direct excitonic recombination. Cassabois et al. attributed the luminescence lines to phononassisted transitions (phonon replicas) from an indirect exciton (iX) . … That is the question THE INDIRECT SEMICONDUCTORS PROBLEM HOW TO SOLVE THE RIDDLE ? Internal quantum yield The 45% hBN IQY goes against the common wisdom that indirect band gap semiconductors are bad light emitters. 0.1% Diamond 45% hBNZnO 50% Direct and indirect excitons with high binding energies in hBN. L. Schué et al. arXiv:1803.03766 (2018) hBN is an indirect semiconductor with a large band gap (~ 7eV). The top of the valence bands is located close to K while the minimum of the conduction bands is at M. Light absorption and emission in indirect semiconductors is assisted by absorption/emission of phonons. Exciton interference in hBN L. Sponza, H. Amara, C. Attaccalite, F. Ducastelle, A. Loiseau PRB 97 (7), 075121(2017) iX: the lowest excitons with momentum q = |M – K|. The high luminescence efficiency evidences the presence of a strong excitonphonon coupling in hBN. The electronic band structure of hBN The phonons involved in the luminescence process are those with a momentum compatible with q = |K M| vector. Therefore they fall in the middle of the Brillouin zone (T) between and K. Γ q0=K /12≈0.14 ˚A−1 A nondiagonal supercell that maps both K and M points at Γ Theory of phononassisted luminescence in solids: application to hexagonal boron nitride E Cannuccia,et al. arXiv:1807.11797 iX excitons are replicated by the different phonon modes and acquire a finite optical weight. Excitonphonon coupling is included through finite difference method. We reproduce the position and the intensity of various peaks. The doublets are generated by LOTO, and LATA splitting The EP scattering is limited to one phonon at a time. We cannot reproduce the overtones involving interlayer shear modes and the asymmetric tails of the emission peaks. CONCLUSIONS HOW TO SOLVE THE RIDDLE ? We found that luminescence in h BN is dominated by phonon assisted transitions and that strong excitonphonon coupling leads to its intensity being unexpectedly large and comparable to that of direct band gap materials. We considered a density of excited carriers of n = 10 15 cm3 between K and M Lattice dynamics and electron-phonon coupling calculations using nondiagonal supercells J. H. Lloyd-Williams and B. Monserrat PRB 97 (7), 075121(2017)