Overview of New YSI Laboratory Products 
Trulab, MultiLab, Ion Selective Electrodes (ISEs) 
August 12, 2014 
Chris Cushman...
Outline 
• 
TruLab 
- 
Analog pH/mV(ORP)/ISE benchtop instruments 
• 
MultiLab 
- 
Digital multiparameter benchtop instrum...
TruLab: Analog pH/mV(ORP)/ISE Benchtop Instruments with new suite of pH electrodes
YSI TruLab Product Line 
• 
Analog line of pH, mV and ISE instruments – released March 2014 
• 
Specialty line of pH and I...
YSI TruLab Instruments 
TruLab pH 1110 
• 
Single channel analog instrument 
• 
pH, mV(ORP), Temp 
• 
No memory 
• 
Segmen...
YSI TruLab Instruments 
TruLab pH/ISE 1320 
• 
Dual channel analog instrument 
• 
pH, mV(ORP), Temp, ISEs 
• 
Connect 2 IS...
YSI TruLab Instruments 
Features of all models: 
• 
3 year warranty 
• 
BNC connectors 
• 
Calibration timer 
• 
AutoRead ...
TruLine, IoLine, and ScienceLine Electrodes 
TruLine: 6 single junction pH electrodes and 2 ORP electrodes 
• 
Glass or ep...
TruLine, IoLine, and ScienceLine Electrodes 
IoLine: 2 triple junction glass electrodes with iodine/iodide reference 
• 
N...
TruLine, IoLine, and ScienceLine Electrodes 
Product line features: 
• 
German engineered/manufactured 
• 
Variety of elec...
MultiLab: Digital Multiparameter Benchtop Instruments
• 
4 instruments: 
- 
4010-1(P), single channel 
- 
4010-2, dual channel 
- 
4010-3, triple channel 
• 
All instruments in...
YSI MultiLab Instruments 
MultiLab 4010-1 
• 
Single channel digital instrument 
• 
pH, mV(ORP), Temp, DO/BOD, cond. 
• 
D...
YSI MultiLab Instruments 
MultiLab 4010-2/3 
• 
Two or three channel digital instrument 
• 
pH, mV(ORP), Temp, DO/BOD, con...
• 
Digital sensor recognition, processing and data transfer 
• 
Plug-and-play connectivity; probe auto- recognized 
• 
Sen...
Ion Selective Electrodes: YSI TruLine ISEs
Measurement Basics: Nernst Equation 
• 
ISEs measure ion activity (i.e. “effective concentration”) 
-Ion activity < actual...
ISE Electrode Types 
Half cell ISEs: 
• 
Contain only the ion sensor (half cell); separate reference must be used 
-Both h...
Measurement Methods 
Direct measurement: 
• 
Simple and most commonly used ISE method 
• 
Measure mV output in samples and...
Currently Available ISEs: YSI and Competition 
YSI 
Brand A 
Brand B 
Brand C 
NH3 
 
 
 
 
NH4+ 
 
 
 
 
Br- 
 
...
• 
16 parameters 
• 
All electrodes are refillable and include double-junction reference 
• 
4 sensor technologies 
-Gas s...
• 
Technology: Gas-sensing 
• 
Features: Replaceable Membrane Modules, pH sensor inside 
• 
Range: 0.02-17,000 mg/L 
• 
Sl...
•Technology: Polymer/PVC Membrane 
•Features: Refillable, Replaceable Sensor Modules 
•Range: 0.02-1,800 mg/L 
•Slope: 54-...
•Technology: Solid State 
•Features: Refillable, non-replaceable sensor 
•Range: 0.4-79,900 mg/L 
•Slope: 54-59 mv/decade ...
• 
Technology: Solid State 
• 
Features: Refillable, non-replaceable sensor 
• 
Range: 0.1-11,200 mg/L 
• 
Slope: 26-29 mv...
• 
Technology: Polymer/PVC Membrane 
• 
Features: Refillable, Replaceable Sensor Modules 
• 
Range: 0.02-40,000 mg/L 
• 
S...
• 
Technology: Solid State 
• 
Features: Refillable, non-replaceable sensor 
• 
Range: 1.8-35,500 mg/L 
• 
Slope: 54-59 mv...
• 
Technology: Solid State 
• 
Features: Refillable, non-replaceable sensor 
• 
Range: 0.6-6,400 mg/L 
• 
Slope: 26-29 mv/...
• 
Technology: Solid State 
• 
Features: Refillable, non-replaceable sensor 
• 
Range: 0.2-260 mg/L 
• 
Slope: 54-59 mv/de...
• 
Technology: Solid State Crystal 
• 
Features: Refillable, non-replaceable sensor 
• 
Range: 0.02 mg/L - saturation 
• 
...
• 
Technology: Solid State 
• 
Features: Refillable, non-replaceable sensor 
• 
Range: 0.006-127,000 mg/L 
• 
Slope: 54-59...
• 
Technology: Solid State 
• 
Features: Refillable, non-replaceable sensor 
• 
Range: 0.02-20,700 mg/L 
• 
Slope: 26-30 m...
• 
Technology: Polymer/PVC Membrane 
• 
Features: Refillable, Replaceable Sensor Modules 
• 
Range: 0.4-62,000 mg/L 
• 
Sl...
• 
Technology: Polymer/PVC Membrane 
• 
Features: Refillable, Replaceable Sensor Modules 
• 
Range: 0.04-39,000 mg/L 
• 
S...
• 
Technology: Solid State 
• 
Features: Refillable, non-replaceable sensor 
• 
Range: 0.01-107,900 mg/L (Silver) 0.003-32...
• 
Technology: Glass Sensor 
• 
Features: Refillable, non-replaceable sensor 
• 
Range: 0.1-23,000 mg/L 
• 
Slope: 54-59 m...
TruLine ISE Tips 
• 
Takes ~1-2 mL to fill electrode 
• 
One order of magnitude (i.e. decade) difference between two stand...
Thank you for attending 1-937-767-7241 ccushman@ysi.com lstpierre@ysi.com
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TruLab, MultiLab and ISEs for Laboratory Measurements | YSI

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The YSI TruLab instruments for pH, ORP (mV), Ion Selective Electrodes (ISEs) and temperature includes 5 separate instruments for routine environmental laboratory measurements.

YSI MultiLab includes instruments that allow the measurement of BOD, pH, ORP, conductivity and ISEs. Intelligent Digital Sensors provide accurate, reliable measurements.

In addition, YSI offers 15 ISE electrodes.

Learn more in this overview from a recent webinar we presented. Contact info@ysi.com with any questions.

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TruLab, MultiLab and ISEs for Laboratory Measurements | YSI

  1. 1. Overview of New YSI Laboratory Products Trulab, MultiLab, Ion Selective Electrodes (ISEs) August 12, 2014 Chris Cushman, Assistant Product Manager ccushman@ysi.com Laura St. Pierre, Senior Product Manager lstpierre@ysi.com
  2. 2. Outline • TruLab - Analog pH/mV(ORP)/ISE benchtop instruments • MultiLab - Digital multiparameter benchtop instruments • New TruLine ISEs
  3. 3. TruLab: Analog pH/mV(ORP)/ISE Benchtop Instruments with new suite of pH electrodes
  4. 4. YSI TruLab Product Line • Analog line of pH, mV and ISE instruments – released March 2014 • Specialty line of pH and ISE probes for various applications • Positioned to compete against Thermo and Hanna • Complimentary to MultiLab products
  5. 5. YSI TruLab Instruments TruLab pH 1110 • Single channel analog instrument • pH, mV(ORP), Temp • No memory • Segmented display • 3 stored buffer sets TruLab pH 1310 • Single channel analog instrument • pH, mV(ORP), Temp • Memory (500 manual, 5000 auto) • USB output; data importer software • 22 stored pH buffer sets • Backlit graphic display • Printer option (1310P)
  6. 6. YSI TruLab Instruments TruLab pH/ISE 1320 • Dual channel analog instrument • pH, mV(ORP), Temp, ISEs • Connect 2 ISEs simultaneously • Direct ion concentration readout for: Ag+, Br-, Ca2+, Cd2+, Cl-, Cu2+, CN-, F-, I-, K+, Na+, NO3-, Pb2+, S2-, NH3, NH4+, CO2 • Memory (500 manual, 5000 auto) • USB output; data importer software • 22 stored pH buffer sets • Backlit graphic display • Printer option (1320P)
  7. 7. YSI TruLab Instruments Features of all models: • 3 year warranty • BNC connectors • Calibration timer • AutoRead for repeatability • Electrode stand included • Universal power supply • USB cable and PC data importer included when applicable (1310/20) • Wide range of pH electrode options for specialized applications • Stored buffer sets (3 for 1110, 22 for 1310/20) • Battery or AC operation; USB power for 1310 and 1320
  8. 8. TruLine, IoLine, and ScienceLine Electrodes TruLine: 6 single junction pH electrodes and 2 ORP electrodes • Glass or epoxy body, refillable, and temperature/non-temp • 1 spear tip pH electrode for penetrating solids; 1 flat tip for surfaces • Cover about 80% of pH lab applications • Can be used with variety of meters (BNC) • Fast response • Refillable electrodes offer long, usable life
  9. 9. TruLine, IoLine, and ScienceLine Electrodes IoLine: 2 triple junction glass electrodes with iodine/iodide reference • No contamination of sample with metal ions (Tris buffers) • 3-chamber reference system allows for stability in all media and at changing temps; used in variety of applications • 1 micro version for small sample size ScienceLine: 3 double junction electrodes with high electrolyte outflow • Unique applications requiring particular junction • Ground joint: highest outflow, best for solutions with a lot of solids, useful for solutions with low ions • Platinum: high outflow to prevent clogging, but not as high as ground joint; micro size available • Fast response; double junction reduces the chances that the reference will touch the sample, avoiding possible contamination.
  10. 10. TruLine, IoLine, and ScienceLine Electrodes Product line features: • German engineered/manufactured • Variety of electrode designs to meet a large range of applications • 1 meter cable • Longevity and fast response • Competitive pricing • Temperature included with all IoLine and ScienceLine, optional for TruLine Measurement reminder: • Refilling opening must be OPEN during calibration and measurement
  11. 11. MultiLab: Digital Multiparameter Benchtop Instruments
  12. 12. • 4 instruments: - 4010-1(P), single channel - 4010-2, dual channel - 4010-3, triple channel • All instruments include: - 3-year warranty! - MultiLab importer PC software - universal power supply - USB cable - electrode stand • All instruments work with BOD Analyst Pro YSI MultiLab Product Line
  13. 13. YSI MultiLab Instruments MultiLab 4010-1 • Single channel digital instrument • pH, mV(ORP), Temp, DO/BOD, cond. • Data storage -500 data sets in manual mode -5,000 data sets in automatic logging mode -Send data to PC (ASCII and .CSV); import directly into Excel® • Large, easy to read backlit graphic display
  14. 14. YSI MultiLab Instruments MultiLab 4010-2/3 • Two or three channel digital instrument • pH, mV(ORP), Temp, DO/BOD, cond. • ISE option with analog adapter -Covers one digital input • Data storage -500 data sets in manual mode -10,000 data sets in automatic logging mode -Send data to PC, USB stick, or USB printer • Large, easy to read color display • Antibacterial keypad
  15. 15. • Digital sensor recognition, processing and data transfer • Plug-and-play connectivity; probe auto- recognized • Sensors store unique ID with serial number and calibration status • Monitors sensor performance and calibration to notify when it is time to change sensor cap or refill/replace pH sensor • Includes pH, ORP, conductivity and optical based self-stirring BOD YSI MultiLab Intelligent Digital Sensors (IDS)
  16. 16. Ion Selective Electrodes: YSI TruLine ISEs
  17. 17. Measurement Basics: Nernst Equation • ISEs measure ion activity (i.e. “effective concentration”) -Ion activity < actual ion concentration due to interaction of ions in solution, reduces ions available to react • ISEs are designed to measure specific ions, but other ions can interfere -Adding ionic strength adjustor acts to minimize/mask effect of interfering ions • pH electrode is a Hydrogen ISE • ISE output is in mV; follows Nernst Equation • Slope of electrode: 2.303∗ 푅푅푅푅 푛푛푛푛 -Divalent (e.g. Ca2+) ~ 29 mV/decade (typical 26-29) -Must have decade (i.e. order of magnitude) difference in calibration standards; can “fill-in” between standards if many used 푆푆푆푆푆푆푆푆푆푆 Ca2+=2.303∗ 8.314 퐽퐽 퐾퐾 푚푚푚∗298.15 퐾퐾∗ 12∗ 푚푚푚9.649∗104 퐶퐶 =2.958∗10−2 퐽퐽 퐶퐶−1=29.58 푚푚푚푚
  18. 18. ISE Electrode Types Half cell ISEs: • Contain only the ion sensor (half cell); separate reference must be used -Both have ion exchange with the sample -mV output determined by difference in potential b/w the sensing half cell and the reference Combination ISEs: • Contain the sensing electrode and reference electrode in the same body • Much easier to use; preferred by most customers • YSI TruLine electrodes
  19. 19. Measurement Methods Direct measurement: • Simple and most commonly used ISE method • Measure mV output in samples and determine concentration based on calibration (i.e. just as is done with pH) Incremental methods: • Standard addition, standard subtraction, sample addition, sample subtraction • Methods of spiking the sample • Sample ion concentration calculated from change in potential • YSI TruLab 1320 and MultiLab 4010-2/3 have all incremental methods preprogrammed
  20. 20. Currently Available ISEs: YSI and Competition YSI Brand A Brand B Brand C NH3     NH4+     Br-    Cd2+    Ca2+    Cl-     Cu2+    CN-    F-     I-    Pb2+    NO3-     K+    Ag+/S2-    Na+    
  21. 21. • 16 parameters • All electrodes are refillable and include double-junction reference • 4 sensor technologies -Gas sensing, polymer/PVC membrane, solid state, glass sensor • Included with electrode purchase: -Unfilled electrode -1 replacement sensor module for polymer/PVC type electrodes due to shorter shelf life -Reference fill solution, ionic strength adjustor (ISA), and small bottle of standard • 9-12 months warranty depending on ISE • Made in the U.S.A. YSI TruLine ISE Electrodes
  22. 22. • Technology: Gas-sensing • Features: Replaceable Membrane Modules, pH sensor inside • Range: 0.02-17,000 mg/L • Slope: 54-59 mv/decade • pH range: Must be 11 or higher to make NH3 gaseous. ISA has blue color at this pH • Interferences: few, volatile amines • Applications/Notes: Popular for wastewater, aquaculture, agriculture, industrial. pH shift caused by ammonia gas is correlated to concentration Ammonia (NH3)
  23. 23. •Technology: Polymer/PVC Membrane •Features: Refillable, Replaceable Sensor Modules •Range: 0.02-1,800 mg/L •Slope: 54-59 mv/decade •pH range: 4-10 •Interferences: few, Na+, K+ •Applications/Notes: Popular for wastewater, environmental, industrial, food/beverage Ammonium (NH4+)
  24. 24. •Technology: Solid State •Features: Refillable, non-replaceable sensor •Range: 0.4-79,900 mg/L •Slope: 54-59 mv/decade •pH range: <12 •Interferences: I-, Cl-, CN-, NH3- •Applications/Notes: Pool & spa, industrial Bromide (Br-)
  25. 25. • Technology: Solid State • Features: Refillable, non-replaceable sensor • Range: 0.1-11,200 mg/L • Slope: 26-29 mv/decade • pH range: 2-8 • Interferences: Hg2+, Ag+, Cu2+, Pb2+ • Applications/Notes: Industrial, environmental Cadmium (Cd2+)
  26. 26. • Technology: Polymer/PVC Membrane • Features: Refillable, Replaceable Sensor Modules • Range: 0.02-40,000 mg/L • Slope: 25-29 mv/decade • pH range: 2.5-11 • Interferences: Pb2+, Hg2+, Si2+, Mg2+, Cu2+, K+, Tris+, Na+, others • Applications/Notes: Popular for Aquarium, industrial, food/beverage Calcium (Ca2+)
  27. 27. • Technology: Solid State • Features: Refillable, non-replaceable sensor • Range: 1.8-35,500 mg/L • Slope: 54-59 mv/decade • pH range: 2-12 • Interferences: CN-, Br-, I-, OH-, S2-, NH3 • Applications/Notes: Very popular for industrial, wastewater, drinking water, food/beverage, environmental. This sensor is slightly photosensitive – store in dark place when not in use. Chloride (Cl-)
  28. 28. • Technology: Solid State • Features: Refillable, non-replaceable sensor • Range: 0.6-6,400 mg/L • Slope: 26-29 mv/decade • pH range: 2-6 • Interferences: Hg2+, Ag+, Fe2+, Br-, Cl- • Applications/Notes: Industrial, environmental. Also known as Cupric ISE. Copper (Cu2+)
  29. 29. • Technology: Solid State • Features: Refillable, non-replaceable sensor • Range: 0.2-260 mg/L • Slope: 54-59 mv/decade • pH range: 10-14 • Interferences: I-, Br-, Cl-, S2- • Applications/Notes: Industrial, environmental. Standard solutions not included in electrode package (safety issue) Cyanide (CN-)
  30. 30. • Technology: Solid State Crystal • Features: Refillable, non-replaceable sensor • Range: 0.02 mg/L - saturation • Slope: 54-59 mv/decade • pH range: 5-7 at low range, 11 at higher range • Interferences: OH- • Applications/Notes: Very popular for drinking water, industrial. Lanthanum fluoride crystal is the sensor. Fluoride (F-)
  31. 31. • Technology: Solid State • Features: Refillable, non-replaceable sensor • Range: 0.006-127,000 mg/L • Slope: 54-59 mv/decade • pH range: <14 • Interferences: CN-, Cl-, S2O32-, S2-, NH3 • Applications/Notes: Drinking water, industrial, food/beverage Iodide (I-)
  32. 32. • Technology: Solid State • Features: Refillable, non-replaceable sensor • Range: 0.02-20,700 mg/L • Slope: 26-30 mv/decade • pH range: 4-7 • Interferences: Hg2+, Ag+, Cu2+, Fe2+, Cd2+ • Applications/Notes: Industrial, environmental Lead (Pb2+)
  33. 33. • Technology: Polymer/PVC Membrane • Features: Refillable, Replaceable Sensor Modules • Range: 0.4-62,000 mg/L • Slope: 54-59 mv/decade • pH range: 2.5-11 • Interferences: few, ClO4-, ClO3-, I-, F- • Applications/Notes: Very popular for environmental, industrial, agriculture, food/beverage Nitrate (NO3-)
  34. 34. • Technology: Polymer/PVC Membrane • Features: Refillable, Replaceable Sensor Modules • Range: 0.04-39,000 mg/L • Slope: 54-59 mv/decade • pH range: 2-12 • Interferences: Cs+, NH4+, Tl+, H+, Ag+,Tris+, Na+, Li+ • Applications/Notes: Popular for agriculture, food/beverage, environmental, industrial Potassium (K+)
  35. 35. • Technology: Solid State • Features: Refillable, non-replaceable sensor • Range: 0.01-107,900 mg/L (Silver) 0.003-32,100 mg/L (Sulfide) • Slope: 54-59 mv/decade (Silver) 26-29 mv/decade (Sulfide) • pH range: 2-12 • Interferences: Hg2+ • Applications/Notes: Industrial, environmental, food/beverage. Sulfide does not come with standard solution (stability) Silver/Sulfide (Ag+/S2-)
  36. 36. • Technology: Glass Sensor • Features: Refillable, non-replaceable sensor • Range: 0.1-23,000 mg/L • Slope: 54-59 mv/decade • pH range: >9 • Interferences: H+, K+ • Applications/Notes: Industrial, agriculture, power, food/beverage. Looks like a pH electrode! Sodium (Na+)
  37. 37. TruLine ISE Tips • Takes ~1-2 mL to fill electrode • One order of magnitude (i.e. decade) difference between two standards; can include standards between • Add ISA to both samples and standards to ensure similar ionic strength • Short term (1-3 day) storage: place in low standard and fill the reference • Long term: store dry (i.e. drain reference) and avoid sunlight • Fill hole should be open during calibration and measurement, closed during storage
  38. 38. Thank you for attending 1-937-767-7241 ccushman@ysi.com lstpierre@ysi.com

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