Amet tm chemical evaluation_and_safety assessment_for_usa_sds_authoring

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Amet tm chemical evaluation_and_safety assessment_for_usa_sds_authoring

  1. 1. CHEMICAL EVALUATION AND SAFETY ASSESSMENT FOR OSHA HAZCOM 2012 SAFETY DATA SHEETS AUTHORING Theodore M. Amet Regulatory Research AnalystA. MIXTURE/PREPARATION Ordered Steps: 1. Hazards Determination (Physical, Health and Safety) Table 1. Reactivity Prediction (Compatibility) Composition/Information on Ingredients CAMEO Chemicals:http://www.cameochemicals.noaa.gov/ • Build a list of chemicals • Predict reactivity • Extract pertinent information on chemical substances: (Exposure/First Aid, Fire Hazards, Accidental Release and Containment, Physical Data, Transportation Classification, Regulatory Information, etc.) Table 2. Chemical Evaluation (Environment, Health and Safety) Information on Chemical Substances TSCA: http://www.epa.gov/enviro/facts/tsca/tsca_search.html Substance Registry Services (SRS) Advanced Search: http://iaspub.epa.gov/sor_internet/registry/substreg/searchandretrieve/advancedsearch/search.do ChemSub Online:http://chemsub.online.fr/ ESIS (European chemical Substances Information System): http://esis.jrc.ec.europa.eu/ / http://esis.jrc.ec.europa.eu/index.php?PGM=cla ECHA (European Chemical Agency): http://www.echa.europa.eu/ • Obtain Hazard, Risk and Safety Information Table 3. Toxicological Information on Substances Toxicological Information Resources • IARC: http://www.iarc.fr/ • NTP: http://ntp.niehs.nih.gov/ • OSHA: http://www.osha.gov/dts/chemicalsampling/toc/toc_chemsamp.html • ACGIH: http://www.acgih.org/home.htm • TOXNET: http://toxnet.nlm.nih.gov/ • HSDB: http://toxnet.nlm.nih.gov/cgi-bin/sis/htmlgen?HSDB http://sis.nlm.nih.gov/enviro/hsdbchemicalslist.html • ASTDR: http://www.atsdr.cdc.gov/ • ACToR: http://actor.epa.gov/actor/faces/ACToRHome.jsp • CROETWeb: http://www.croetweb.com/ • NPIC: http://npic.orst.edu/ • California Proposition 65: http://www.oehha.ca.gov/prop65.html Links: http://meso.spawar.navy.mil/Links/toxicology.html Carcinogens Table: http://publicsafety.tufts.edu/ehs/files/carcinogens.pdf 1
  2. 2. 2. GHS Label Elements Determination GHS Hazard Communication Pictograms Assignment • GHS Konverter: http://ghs-konverter.de/ghs/konverter/index.htm3. Exposure, Symptoms, Adverse Effects and First Aid Measures Information on Hazardous Chemicals • Haz-Map: http://hazmap.nlm.nih.gov/index.php • Haz-Map Database: http://www.haz-map.com/refernc.htm#NAERG • CAMEO Chemicals: http://www.cameochemicals.noaa.gov/ • Chemical Safety: http://www.cdc.gov/niosh/topics/chemical-safety/ • Emergency Response Card: https://erplan.net/eplan/home.htm • First Responders: http://www.cdc.gov/niosh/docs/2008-115/ • NIOSH: http://www.cdc.gov/niosh/ • 2012 Emergency Response Guide Book: http://phmsa.dot.gov/hazmat/library/erg4. Fire-Fighting Measures Hazard Class Fire Fighting Measures • CAMEO Chemicals: http://www.cameochemicals.noaa.gov/ • 2012 Emergency Response Guide Book: http://phmsa.dot.gov/hazmat/library/erg • Emergency Response Card: https://erplan.net/eplan/home.htm5. Spillage and Disposal Spillage and Disposal • CAMEO Chemicals: http://www.cameochemicals.noaa.gov/ • 2012 Emergency Response Guide Book: http://phmsa.dot.gov/hazmat/library/erg • Emergency Response Card: https://erplan.net/eplan/home.htm6. Storage and Isolation Storage and Isolation • CAMEO Chemicals: http://www.cameochemicals.noaa.gov/ • IPCS: http://inchem.org/ http://www.who.int/ipcs/en/#7. Substance Workplace Exposure Limits Occupational Exposure Limits • OSHA Chemical Sampling Information: http://www.osha.gov/dts/chemicalsampling/toc/toc_chemsamp.html • CAMEO Chemicals: http://www.cameochemicals.noaa.gov/ • Haz-Map: http://hazmap.nlm.nih.gov/index.php • International Chemical Safety Card: http://www.cdc.gov/niosh/ipcs/icstart.html http://www.cdc.gov/niosh/ipcs/ipcscard.html8. Physical and Chemical Dangers Physical and Chemical Properties • QC Data Sheet and Certificate of Analysis9. Stability and Reactivity Stability and Reactivity • CAMEO Chemicals: http://www.cameochemicals.noaa.gov/ • Incompatibility Charts: http://www.uos.harvard.edu/ehs/environmental/EPAChemicalCompatibilityChart.pdf • http://www.google.com/search?q=chemical+incompatibility+chart&hl=en&prmd=imvns&tbm=isch&tbo=u&s ource=univ&sa=X&ei=_HiIUOT4KoOOygGiloCgDg&ved=0CCAQsAQ&biw=1280&bih=640 2
  3. 3. 10. Toxicological Data Toxicological Profile Information • Product toxicology data; or • Substance data (Step 1, Table 3)11. Transportation Transportation Information • See Safety Data Sheet Authoring Guide http://www.slideshare.net/TOXICOGENOMICS • Hazardous Materials Table (49 CFR § 172.101): http://www.setonresourcecenter.com/transportation/49CFR/172_101tb.pdf12. Regulatory Information Lookup: California Proposition 65: http://www.oehha.ca.gov/prop65.html CAMEO Chemicals: http://www.cameochemicals.noaa.gov/ Clean Air Act: http://www.thecre.com/fedlaw/legal14air/contents.htm http://www.epa.gov/air/caa/ http://www.epa.gov/lawsregs/laws/caa.html Clean Air Act, Section 112 (Hazardous Air Pollutants) http://scorecard.goodguide.com/chemical-groups/one-list.tcl?short_list_name=hap (HAPs) http://www.epa.gov/ttn/atw/112g/112gpg.html http://www.law.cornell.edu/uscode/text/42/7412 http://www.scdhec.gov/environment/baq/112r/ 40 CFR Part 61 - National Emission Standards for Hazardous Air Pollutants (NESHAPS): http://www.ecfr.gov/cgi-bin/text-idx?c=ecfr&tpl=/ecfrbrowse/Title40/40cfr61_main_02.tpl http://www.law.cornell.edu/cfr/text/40/61 http://www.tceq.state.tx.us/permitting/air/rules/federal/61/61hmpg.html Collecting and Assessing Information on Chemicals http://www.epa.gov/oppt/existingchemicals/pubs/collectinfo.html Emergency Planning and Community Right-To-Know Act (EPCRA): http://www.epa.gov/oecaagct/lcra.html http://www.epa.gov/oem/content/epcra/epcra_storage.htm (EPCRA Sections 311-312) http://www.gecap.org/tghtml/epcra2pg.html http://oecscomply.com/index.html EPA Envirofacts http://www.epa.gov/enviro/index.html EPA’s Existing Chemicals: http://www.epa.gov/oppt/existingchemicals/index.html http://www.epa.gov/oppt/existingchemicals/ http://www.epa.gov/oppt/existingchemicals/pubs/findinfo.html (Finding Public Information on Chemicals) EPA’s Substance Registry Services: http://iaspub.epa.gov/sor_internet/registry/substreg/searchandretrieve/advancedsearch/search.do Toxic Release Inventory: http://www.epa.gov/TRI/ http://www.epa.gov/enviro/facts/tri/ez.html http://www.epa.gov/tri/trichemicals/ (SARA 313) 3
  4. 4. TSCA Chemical CAS Number Lookup:http://www.epa.gov/emefdata/TSCA.lookup_window?v_type=N&v_field=fac_valueTSCA Chemical Name Lookup:http://www.epa.gov/emefdata/TSCA.lookup_window?v_type=C&v_field=fac_value Note: For training purposes only! Use at your own risk. 4

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